Chem. Commun.



Label-free and amplified detection of apoptosis-associated caspase using branched rolling circle amplification ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01564D, Communication Meng Liu, Di Zhang, Xuechong Zhang, Qinfeng Xu, Fei Ma, Chun-yang Zhang We develop a label-free fluorescent method for ultrasensitive detection of apoptosis-associated caspase activity based on branched rolling circle amplification. This work demonstrates for the first time the use of nucleic... The content of this RSS Feed (c) The Royal Society of Chemistry
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Light-controlled imaging of biocatalytic reactions via scanning photoelectrochemical microscopy for multiplexed sensing ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00777C, Communication Marc Riedel, Adrian Ruff, Wolfgang Schuhmann, Fred Lisdat, Felipe Conzuelo A light-controlled multiplexing platform has been developed on the basis of a quantum dot-sensitized inverse opal TiO2 electrode with integrated biocatalytic reactions. Spatially resolved illumination enables multiplexed sensing and imaging... The content of this RSS Feed (c) The Royal Society of Chemistry
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Conformational control of N-methyl-N,N'-diacylhydrazines by noncovalent carbon bonding in solution ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00943A, Communication Bani Kanta Sarma, Jugal Kishore Rai Deka, Biswajit Sahariah, Kalpita Baruah, Arun Kumar Bar In recent years, some X-ray structural and computational evidence have emerged for noncovalent carbon bonding (C-bond). However, evidence of C-bonds in solution is limited. Herein, from the conformational analyses of... The content of this RSS Feed (c) The Royal Society of Chemistry
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Uncovering the Pathological Functions of Ser404 Phosphorylation by Semisynthesis of Phosphorylated TDP-43 Prion-Like Domain ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01409E, Communication Qian-Qian Li, Yun-Yi Luo, Yuqing Liu, Ting-Ting Chu, Na Gao, Puguang Chen, Yong-Xiang Chen, Yanmei Li Herein, we successfully semi-synthesized TDP-43 prion-like domain with Ser404 phosphorylation. We demonstrated that Ser404 phosphorylation could accelerate the amyloid aggregation of TDP-43 prion-like domain and aggravate its cytotoxicity. The content of this RSS Feed (c) The Royal Society of Chemistry
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A New Insight Derived from Two-Compartment Cell: Electrochemical Behavior of FeF3 Positive Electrode ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01162B, Communication Kazuki Yoshii, Noboru Taguchi, Takeshi Miyazaki, Masahiro Shikano, Hikari Sakaebe A designed two-compartment cell was applied to the degradation analysis of FeF3 having high theoretical energy density. Comparing the result of the coin cell, the two-compartment cell gave us insights... The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal-free dehydrosulfurization of thioamides to nitriles under visible light ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01380C, Communication Tianxiao Xu, Tianpeng Cao, Qingyuan Feng, Shenlin Huang, Saihu Liao A visible light mediated, metal-free dehydrosulfurization process has been developed for the synthesis of nitriles from thioamides. The reaction features a cheap organic dye as the photoredox catalyst, air as... The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of Isoquinolones by Visible-Light-Induced Deaminative [4+2] Annulation Reactions ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01333A, Communication Wujiong Xia, Yating Zhao, Chengcheng Shi, Xing Su Herein a metal-free approach for the synthesis of isoquinolone derivatives by means of photoinitiated deaminative [4+2] annulation of alkyne and N-amidepyridinium salt is described. This protocol exhibits broad scope, good... The content of this RSS Feed (c) The Royal Society of Chemistry
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In-Situ Generation of Sub-10 nm Silver Nanowires under electron beam irradiation in the TEM ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00909A, Communication Junjie Li, Leonard Deepak Francis Here, we report a facile irradiation-assisted route to fabricate sub-10 nm Ag nanowires from oxide supports in TEM. The obtained Ag nanowires show a tunable length/diameter aspect ratio with a... The content of this RSS Feed (c) The Royal Society of Chemistry
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Conformational enhancement of fidelity in toehold-sequestered DNA nanodevices ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00882F, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Antoine Bader, Scott Lee Cockroft The operation of DNA nanodevices is often limited by erroneous strand displacement. Here we demonstrate simple design principles that reduce such leakage by upto two orders of magnitude. Enhanced operational... The content of this RSS Feed (c) The Royal Society of Chemistry
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Activatable fluorescence probes for hydrolase enzymes based on coumarin-hemicyanine hybrid fluorophore with large Stokes shift ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00559B, Communication Hiroyoshi Fujioka, Shin-nosuke Uno, Mako Kamiya, Ryosuke Kojima, Kai Johnsson, Yasuteru Urano We show that the equilibrium of intramolecular spirocyclization of coumarin-hemicyanine hybrid fluorophores can be finely tuned by means of chemical modifications. We used this scaffold to develop activatable fluorescence probes... The content of this RSS Feed (c) The Royal Society of Chemistry
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Trapping of ZnCl2 by bipyridyl-functionalized organotin sulfide clusters, and its effect on optical properties ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01887B, Communication Stefanie Susanne Dehnen, Eugenie Geringer, Eliza Leusmann, Frank Tambornino, Marina Gerhard, Martin Koch We report the syntheses of two new organotin sulfide clusters with heteroaromatic substituents. A phenanthroline-functionalized tin sulfide cluster [(RPhenSn)4S6] (1; RPhen = CMe2CH2C(Me)N-NC(H)C12H7N2) and a bipyridyl-terminated cluster [(R4-bipySn)4S6] (2; R4-bipy... The content of this RSS Feed (c) The Royal Society of Chemistry
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A terbium(III) luminescent ATCUN-based peptide sensor for selective and reversible detection of copper(II) in biological media ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC01007C, Communication Enrico Falcone, Paulina Gonzalez, Lucie Lorusso, Olivier Sénèque, Peter Faller, Laurent Raibaut Detection of copper(II) in biological media via time-delayed luminescence by a selective and reversible terbium(III)-luminescent peptide sensor with pM affinity. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A one-pot route to stable Pickering emulsions featuring nanocrystalline Ag and Au ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC00967A, Communication Oliver L. Armstrong, Sean N. Baxter, F. L. Deepak, P. John Thomas A simple one-pot scheme yielding stable Pickering emulsions with Au or Ag nanoparticle surfactants is described. The dimensions and temporal stability of emulsion droplets as well the nanoparticle surfactants are studied. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Construction of a novel “ball-and-rod” MSNs-pp-PEG system: a promising antitumor drug delivery system with a particle size switchable function ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC00600A, Communication Xin He, Dong Wang, Peng Chen, Youbei Qiao, Tiehong Yang, Zhe Yu, Chaoli Wang, Hong Wu The “ball-and-rod” drug delivery system achieved a size-switchable goal in tumors due to its properties of long circulation and deep penetration. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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An intrinsically stretchable and compressible Zn–air battery ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC00823K, Communication Yueyang Wang, Jie Liu, Yuping Feng, Ningyuan Nie, Mengmeng Hu, Jiaqi Wang, Guangxing Pan, Jiaheng Zhang, Yan Huang An intrinsically 300% stretchable and 85% compressible Zn–air rechargeable battery with good electrochemical performances was fabricated for the first time. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Iron-catalysed alkylation of 2-methyl and 4-methyl azaarenes with alcohols via C–H bond activation ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC01593H, Communication Lalit Mohan Kabadwal, Sourajit Bera, Debasis Banerjee Iron-catalysed alkylation of methylazaarenes with primary alcohols is presented. The catalytic protocol is highly selective for the alkylation process and generates water as a by-product. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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With metal or not? a computationally predicted rule for a dirhodium catalyst in [3+3] cycloadditions of triazole with thiirane ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC01293A, Communication Shi-Jun Li, Xue Li, Huilin Mo, Ling-Bo Qu, Donghui Wei, Yu Lan Three possible pathways were explored to determine the inherent role of dirhodium in triazole transformation/functionalization. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal free amination of congested and functionalized alkyl bromides at room temperature ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC00826E, Communication Arshad J. Ansari, Ayushi Yadav, Anirban Mukherjee, Elagandhula Sathish, Kommu Nagesh, Ritesh Singh A metal free approach to access congested aryl amines using aza-oxyallyl cations as electrophiles has been reported. The given method could readily be adapted for the synthesis of coveted 3,5-benzodizepinones. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Reactivity of Ce(IV) imido compounds with heteroallenes ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC10052K, Communication Ekaterina N. Lapsheva, Thibault Cheisson, Carlos Álvarez Lamsfus, Patrick J. Carroll, Michael R. Gau, Laurent Maron, Eric J. Schelter The reactivity of alkali metal capped Ce(IV) imido compounds [M(DME)2][CeNArF(TriNOx)] (1-M with M = K, Rb, Cs and ArF = 3,5-bis(trifluoromethyl)phenyl) with CO2 and organic isocyanates has been evaluated. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Unexpected structural transformation into noria-like Ag13 metal clusters and a copper-doping induced boost in photoluminescence ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC09818F, Communication Su-Kao Peng, Zhou Lu, Mo Xie, Yong-Liang Huang, Dong Luo, Jia-Nan Wang, Xiao-Wei Zhu, Xue Li, Xiao-Ping Zhou, Dan Li We describe silver clusters which unexpectedly transform from cyclic trinuclear complexes and σ-donating phenylacetylene, featuring a noria-like conformation. The introduction of Cu ions leads to isomorphic clusters which boost emission efficiency. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Bimetallic coatings synergistically enhance the speeds of photocatalytic TiO2 micromotors ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC00212G, Communication Zuyao Xiao, Jingyuan Chen, Shifang Duan, Xianglong Lv, Jizhuang Wang, Xing Ma, Jinyao Tang, Wei Wang A bimetallic cap containing sputtered silver is a better catalyst that significantly improves the performance of catalytically powered micromotors. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly active Rh1/CeO2 single-atom catalyst for low-temperature CO Oxidation ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00230E, Communication Bing Han, Tianbo Li, Junying Zhang, Chaobin Zeng, Hiroaki Matsumoto, Yang Su, Botao Qiao, Tao Zhang Rh1/CeO2 single-atom catalyst is highly active for CO oxidation which is potential to server as a multifunctional catalyst to save other noble metals in three way catalysts. The high activity... The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly selective hydrosilylation of equilibrating allylic azides ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01316A, Communication Ruzhang Liu, Zhen Wei, Juan Wang, Yongmei Liu, Huaiguo Xue The Pt-catalyzed hydrosilylation of equilibrating allylic azides is reported. The reaction provides only one out of four possible hydrosilylation products in good yields and with very high chemoselectivity (alk-1-ene vs... The content of this RSS Feed (c) The Royal Society of Chemistry
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Transition Metal Dichalcogenide/Multi-walled Carbon Nanotube-based Fibers as Flexible Electrodes for Electrocatalytic Hydrogen Evolution ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00506A, Communication Bo Chen, Gengzhi Sun, Jie Wang, Guigao Liu, Chaoliang Tan, Ye Chen, Hongfei Cheng, Junze Chen, Qinglang Ma, Ling Huang, Peng Chen, Hua Zhang We report a general strategy for the fabrication of binder-free, flexible and weavable transition-metal dichalcogenide nanosheet-based hybrid fibers by using well-aligned multi-walled carbon nanotubes as host. The resulting hybrid fibers... The content of this RSS Feed (c) The Royal Society of Chemistry
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Atomically thin TiO2 nanosheets synthesized using liquid metal chemistry ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01456G, Communication Turki Alkathiri, Nripen Dhar, Azmira Jannat, Nitu Syed, Md Mohiuddin, Manal M. Y. A. Alsaif, Robi Datta, Kibret Messalea, Baoyue Zhang, Muhammad Waqas Khan, Aaron James Elbourne, Naresh Pillai, Jian Zhen Ou, Ali Zavabeti, Torben Daeneke The library of true two-dimensional materials is limited since many transition metal compounds are not stratified and can thus not be easily isolated as nanosheets. Here, micron-sized ultrathin rutile TiO2... The content of this RSS Feed (c) The Royal Society of Chemistry
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Multielectron C–H Photoactivation with an Sb(V) Oxo Corrole ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/C9CC09892E, Communication Christopher M Lemon, Andrew G. Maher, Anthony R. Mazzotti, David Charles Powers, Miguel I. Gonzalez, Daniel G. Nocera Pnictogen complexes are ideal for mediating multi-electron chemical reactions in two-electron steps. We report a Sb(V) bis-μ-oxo corrole that photochemically oxidises the C–H bonds of organic substrates. In the case... The content of this RSS Feed (c) The Royal Society of Chemistry
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Self-Sacrificial MOFs for Ultra-Long Controlled Release of Bisphosphonate Anti-Osteoporotic Drugs ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00439A, Communication Konstantinos D. Demadis, Daphne Chandrinou, Duane Choquesillo-Lazarte, Kostas Papathanasiou, Petri Turhanen, Maria Vassaki, Chrystalleni Hadjicharalambous In this paper we report drug delivery systems that are based on phosphonate MOFs. These employ biologically-acceptable metal ions (eg. Ca2+ and Mg2+) and several anti-osteoporosis bisphosphonate drugs (etidronate, pamidronate,... The content of this RSS Feed (c) The Royal Society of Chemistry
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Nitroprusside as a promising building block to assemble organic-inorganic hybrid for thermo-responsive switching material ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01877E, Communication Rong-Guan Qiu, Xiao-Xian Chen, Rui-Kang Huang, Dong-Dong Zhou, Wei-Jian Xu, Wei-Xiong Zhang, Xiao-Ming Chen We present a new organic-inorganic hybrid, (Me2NH2)[KFe(CN)5(NO)], possessing a unique nitroprusside-based inorganic host anionic framework in 4-connected sra topology encapsulating organic guest cations. The flexible host-guest hydrogen bonds together with... The content of this RSS Feed (c) The Royal Society of Chemistry
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Supramolecular Hydrogel Derived from a Simple Organic Salt Capable of Proton Conduction ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01467B, Communication Parthasarathi Dastidar, Poulami Chakraborty, Sourabh Bera, S. Datta, B. Das, P. Pal Exploiting supramolecular synthon approach based on a Cambridge Structural Database (CSD) analysis, a series of easily accessible primary ammonium sulfonates have been synthesized as potential supramolecular gelators. Single crystal X-ray... The content of this RSS Feed (c) The Royal Society of Chemistry
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Ring-Opening Iodination and Bromination of Unstrained Cycloalkanols through β-Scission of Alkoxy Radicals ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01720E, Communication Jiang-Ling Shi, Yuankai Wang, Zixuan Wang, Bowen Dou , Jianbo Wang A ring-opening iodination and bromination of unstrained cycloalkanols with NaI or NaBr and PhI(OAc)2 under visible light irradiation is developed. In this protocol the concentration of I2 is modulated through... The content of this RSS Feed (c) The Royal Society of Chemistry
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A promising p-type Co-ZnFe2O4 nanorods film as photocathode for photoelectrochemical water splitting ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00273A, Communication Yayao Lan, Zhifeng Liu, Zhengang Guo, Mengnan Ruan, Xifei Li The p-type Co-ZnFe2O4 film with one-dimensional (1D) rod-like morphology is firstly fabricated on Fluorine-doped tin oxide (FTO) through hydrothermal reaction and sintering treatment. The p-type Co-ZnFe2O4 is obtained by doping... The content of this RSS Feed (c) The Royal Society of Chemistry
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Are Ionic Liquids and Liquid Coordination Complexes Really Different? - Synthesis, Characterization, and Catalytic Activity of AlCl3/Base Catalysts ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01452D, Communication Rajkumar Kore, Steven Paul Kelley, Anand Sawant, Manish Kumar Mishra, Robin D. Rogers Lewis acid/base catalysts of AlCl3/N-methyl-2-pyrrolidone (O-NMP) and AlCl3/1-methylimidazole (N-Mim) were prepared and found to have higher catalytic activity in the Friedel–Crafts alkylation of benzene than the known super acidic ionic... The content of this RSS Feed (c) The Royal Society of Chemistry
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On-demand hydrogen production from formic acid by light-active dinuclear iridium catalysts ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC00704H, Communication Yuki Sofue, Kotohiro Nomura, Akiko Inagaki Light-active dinuclear iridium complexes catalyze the decomposition of formic acid to generate H2 under ambient temperature and base-free conditions. The catalyst activity is sensitive to light demonstrating the ON/OFF switching ability. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Correction: Can aromaticity be a kinetic trap? Example of mechanically interlocked aromatic [2-5]catenanes built from cyclo[18]carbon ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC90137G, Correction Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Nikita Fedik, Maksim Kulichenko, Dmitriy Steglenko, Alexander I. Boldyrev To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Modified Cation-Exchange Membrane for Phosphate Recovery in Electrochemically Assisted Adsorption-Desorption Process ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/C9CC09563B, Communication Kostadin Veselinov Petrov, Laura Paltrinieri, Lukasz Poltorak, Louis de Smet, Ernst JR Sudholter A novel ion separation methodology using a cation-exchange membrane modified with iron oxide nanoparticles (Fe3O4 NPs) coated with polyhexamethylene guanidine (PHMG) is proposed. The separation is performed in an electrodialysis... The content of this RSS Feed (c) The Royal Society of Chemistry
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Intermediate Layer Modulation between NiCoP and Ni Foam Substrate in Microwire Array Electrode for Enhanced Hydrogen Evolution Reaction ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01488E, Communication Dan Guo, Huayu Chen, Hanmin Tian, Shuxin Ouyang, Jianbo Wang, jun lv A hierarchical electrode consisting of Ni foam substrate, intermediate layer of Mo doped basic cobalt carbonate microwire array and surface NiCoP was fabricated for hydrogen evolution. The intermediate layer introduction... The content of this RSS Feed (c) The Royal Society of Chemistry
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Initiating ribosomal peptide synthesis with exotic building blocks ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01291B, Highlight Christos Tsiamantas, Joseph Matthew Rogers, Hiroaki Suga Ribosomal peptide synthesis begins almost exclusively with the amino acid methionine, across all domains of life. The ubiquity of methionine initiation raises the question; to what extent could polypeptide synthesis... The content of this RSS Feed (c) The Royal Society of Chemistry
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Acridine Orange as a Coreactant for Efficient Electrogenerated Chemiluminescence of Tris(2,2′-bipyridine)ruthenium(II) and Its use for Selective and Sensitive Detection of Thiourea ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01273D, Communication Muhammad Saqib, Shahida Bashir, Shimeles Addisu Kitte, Haijuan Li, Yongdong Jin A new and efficient anodic Ru(bpy)32+ ECL system by using acridine orange (3,6-Bis(dimethylamino)acridine, AO) as a coreactant was reported in neutral medium. The developed Ru(bpy)32+–AO system displayed higher ECL intensity... The content of this RSS Feed (c) The Royal Society of Chemistry
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CH4 conversion over Ni/HZSM-5 catalyst in the absence of oxygen: decomposition or dehydroaromatization? ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC01345E, Communication Yuebing Xu, Mengyao Chen, Bing Liu, Feng Jiang, Xiaohao Liu Complete CH4 decomposition occurs over Ni clusters supported on HZSM-5 zeolite, while CH4 forms aromatics over Ni-exchanged sites on HZSM-5 with high selectivity, in the absence of O2. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Hierarchical porous and hydrophilic metal–organic frameworks with enhanced enzyme activity ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC00748J, Communication Hui Li, Xuedong Lu, Qiuhao Lu, Yi Liu, Xun Cao, Yuanyuan Lu, Xun He, Kequan Chen, Pingkai Ouyang, Weimin Tan Metal–organic frameworks (MOFs) for enzyme encapsulation induced biomimetic mineralization are commonly microporous and hydrophobic, which result in a rather high mass transfer resistance of the reactants and restrain the enzyme catalytic activity. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Valence Tautomerism in a Cobalt-Verdazyl Coordination Compound ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01770A, Communication Connor Fleming, Dorothy Chung, Servando Ponce, Raja Das, David James Rawsthorne Brook, Jeffrey daRos, Andrew Ozarowski, Sebastian A Stoian Coordination of 1-isopropyl-3,5-dipyridyl-6-oxoverdazyl to cobalt results in a dication best described in the solid state as a high spin cobalt(II) ion coordinated to two radical ligands with an S=3/2 ground... The content of this RSS Feed (c) The Royal Society of Chemistry
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The Design of Hypercrosslinked Polymers from Benzyl Ether Self-Condensing Compounds and External Crosslinkers ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01002B, Communication Robert Thomas Woodward Hypercrosslinked polymers were produced via the self-condensation of benzyl ether compounds, providing a one-component route to highly porous networks and significant reductions in catalyst waste compared to conventional routes. These... The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of Functionalized Tetrahydrobenzofuran via Cascade Cycloaddition Involving Silyloxyallyl Cation Intermediate ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01796E, Communication Fatimat Badmus, Joshua Malone, Frank R Fronczek, Rendy Kartika An expedient synthesis of highly substituted tetrahydrobenzofuran via unsymmetrical silyloxyallyl cation is reported. Conveniently generated under catalytic Brønsted acid conditions, nucleophilic capture of this reactive intermediate with silylenolate, followed by... The content of this RSS Feed (c) The Royal Society of Chemistry
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A Dual-Round Signal Amplification Strategy for Colorimetric/Photoacoustic/Fluorescence Triple Read-Out Detection of Prostate Specific Antigen ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01086C, Communication Chao Jiang , Yan Huang, Ting He, Peng Huang, Jing Lin The detection of prostate specific antigen (PSA) is extremely important for the early diagnosis of prostate cancer. Herein, we report a dual-round signal amplification strategy for colorimetric/fluorescence/photoacoustic triple read-out detection... The content of this RSS Feed (c) The Royal Society of Chemistry
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A DNA-Tetrahedron-Based Molecular Computation Device for Logic Sensing of Dual MicroRNAs in Living Cells ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01231A, Communication Qing Lin, Anmin Wang, Shiyuan Liu, Jing Li, Jiaoli Wang, Ke Quan, Xiaohai Yang, Jin Huang, Kemin Wang Endogenous miRNA expression patterns are well cell type-specific, thereby offering high prediction accuracy regard to different cell identities, compared with single miRNA analysis. “AND” logic gate can be utilized as... The content of this RSS Feed (c) The Royal Society of Chemistry
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Enhanced single-molecule magnetism in dysprosium complexes of a pristine cyclobutadienyl ligand ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC01722A, Communication James P. Durrant, Jinkui Tang, Akseli Mansikkamäki, Richard A. Layfield Cyclobutadienyl ligands can generate much stronger axial crystal fields in dysprosium single-molecule magnets (SMMs) than more common cyclopentadienyl ligands, providing clues as to how the performance of SMMs can be substantially improved. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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New fluorescent light-up quinoxalines differentiate between parallel and nonparallel G-quadruplex topologies using different excitation/emission channels ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC01242D, Communication Ming-Hao Hu, Xiao Chen A fluorescent light-up quinoxaline probe that could differentiate between parallel and nonparallel G4 topologies via different excitation/emission channels was developed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Facile assembly of three cycloalkyne-modules onto a platform compound bearing thiophene S,S-dioxide moiety and two azido groups ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC01810D, Communication Tomohiro Meguro, Yuki Sakata, Takamoto Morita, Takamitsu Hosoya, Suguru Yoshida An efficient method to assemble three cycloalkyne-modules onto a platform bearing a thiophene S,S-dioxide moiety and two azido groups has been developed. The sequential reactions without catalysis or additives enabled the facile preparation of trifunctional molecules by a simple procedure. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Quantifying the nitrogen effect on CO2 capture using isoporous network polymers ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC00982B, Communication Thien S. Nguyen, Cafer T. Yavuz The impact of nitrogen atoms on CO2 binding was evaluated for two isostructural porous bisimidazole-linked polymers (BILPs), which serendipitously had identical surface areas and pore size distributions, a very rare observation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Preparation of textured and transparent BiVO4 photoelectrodes based on Mo-doped BiVO4 nanoparticles for constructing a stand-alone tandem water splitting device ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC09305B, Communication Ze Wang, Chunwei Dong, Sen Liang, Shiyu Yao, Zidong Wang, Qingsen Zeng, Chongming Liu, Yi Liu, Bai Yang, Hao Zhang Crystallographic orientation control is an effective method to improve the photoelectrochemical water splitting efficiency of BiVO4 photoanodes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Correction: Thioamide quenching of intrinsic protein fluorescence ()
Chem. Commun., 2020, 56,3699-3699 DOI: 10.1039/D0CC90120B, Correction Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Jacob M. Goldberg, Rebecca F. Wissner, Alyssa M. Klein, E. James Petersson The content of this RSS Feed (c) The Royal Society of Chemistry
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Correction: Mitochondria-targeted Ir@AuNRs as bifunctional therapeutic agents for hypoxia imaging and photothermal therapy ()
Chem. Commun., 2020, 56,3698-3698 DOI: 10.1039/D0CC90121K, Correction Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Libing Ke, Cheng Zhang, Xinxing Liao, Kangqiang Qiu, Thomas W. Rees, Yu Chen, Zizhuo Zhao, Liangnian Ji, Hui Chao The content of this RSS Feed (c) The Royal Society of Chemistry
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Correction: Fabrication of red blood cell membrane-camouflaged Cu2−xSe nanoparticles for phototherapy in the second near-infrared window ()
Chem. Commun., 2020, 56,3697-3697 DOI: 10.1039/D0CC90122A, Correction Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Zhou Liu, Jinquan Wang, Kangqiang Qiu, Xinxing Liao, Thomas W. Rees, Liangnian Ji, Hui Chao The content of this RSS Feed (c) The Royal Society of Chemistry
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Visible-light-induced ligand-free RuCl3 catalyzed C–H phosphorylation in water ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC00420K, Communication Xue-Ya Gou, Bo-Sheng Zhang, Xin-Gang Wang, Wei-Yu Shi, Hong-Chao Liu, Yang An, Zhe Zhang, Yong-Min Liang Visible-light-induced C–H phosphorylation of para-CAr–H and heteroarenes was realized using cost-effective RuCl3 as a catalyst. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A fluorescent nanobiosensor for the facile analysis of m6A RNA demethylase activity ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC10054G, Communication Seo-Hee Yim, Hyung Jin Cha, Se-Jin Park, Yeajee Yim, Jae-Sung Woo, Dal-Hee Min A fluorescent nanobiosensor for efficient quantitative analysis of the cancer-associated, m6A RNA demethylase ALKBH5 activity is developed, which shows high potential for robust anticancer drug screening against m6A RNA demethylase. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Solid-phase synthesis of DNA-encoded libraries via an “aldehyde explosion” strategy ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC01474E, Communication Nicholas G. Paciaroni, John M. Ndungu, Thomas Kodadek DNA-compatible conditions are reported for the on-resin transformation of aromatic aldehydes into many different functional groups. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Design and synthesis of non-fullerene acceptors based on a quinoxalineimide moiety as the central building block for organic solar cells ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC00896F, Communication Chunguang Zhu, Kang An, Wenkai Zhong, Zhenye Li, Yu Qian, Xiaozhe Su, Lei Ying The imide-functionalized quinoxaline unit allows for the incorporation of an additional solubilizing group without disturbing the planar structure of the core unit. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of CH2-linked α-galactosylceramide and its glucose analogues through glycosyl radical-mediated direct C-glycosylation ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC00785D, Communication Yu Hidaka, Noriaki Kiya, Makoto Yoritate, Kazuteru Usui, Go Hirai Direct C-glycosylation of a conformationally constrained and stable C1-sp3 hybridized carbohydrate donor with a carefully designed sphingosine unit afforded the CH2-linked analogue of antitumor-active KRN7000 and its glucose congener. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A donor–acceptor type macrocycle: toward photolyzable self-assembly ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC01350A, Communication Tian Tian, Tingjuan Qian, Tingting Jiang, Yakui Deng, Xiaopei Li, Wei Yuan, Yulan Chen, Yi-Xuan Wang, Wenping Hu A donor–acceptor macrocyclic host is reported, which shows efficient photodecomposition with electron-donating guests, yielding photolyzable host–guest complexes or aggregates. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Water-soluble pH-switchable cobalt complexes for aqueous symmetric redox flow batteries ()
Chem. Commun., 2020, 56,3605-3608 DOI: 10.1039/D0CC00383B, Communication Hao Wang, Sayed Youssef Sayed, Yuqiao Zhou, Brian C. Olsen, Erik J. Luber, Jillian M. Buriak A water soluble cobalt complex with two redox couples that fall within the water splitting window can be applied as both the posolyte and negolyte in an aqueous symmetric redox flow battery. The content of this RSS Feed (c) The Royal Society of Chemistry
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Interfacial engineering of a polymer–MOF composite by in situ vitrification ()
Chem. Commun., 2020, 56,3609-3612 DOI: 10.1039/D0CC00664E, Communication Rijia Lin, Jingwei Hou, Mengran Li, Zhanke Wang, Lei Ge, Shichun Li, Simon Smart, Zhonghua Zhu, Thomas D. Bennett, Vicki Chen In situ vitrification of MOF within polymer can rigidify the polymer chains and remove interfacial defects, leading to a significantly enhanced membrane selectivity. The content of this RSS Feed (c) The Royal Society of Chemistry
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One-pot synthesis of heterodimeric agonists that activate the canonical Wnt signaling pathway ()
Chem. Commun., 2020, 56,3685-3688 DOI: 10.1039/D0CC00920B, Communication Abhirup Mukherjee, Mark E. Stathos, Chad Varner, Ammar Arsiwala, Steven Frey, Yuge Hu, David M. Smalley, David V. Schaffer, Ravi S. Kane Heterodimers synthesized by conjugating anti-Frizzled and anti-LRP6 Fabs using SpyTag–SpyCatcher chemistry activate the canonical Wnt signaling pathway. The content of this RSS Feed (c) The Royal Society of Chemistry
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Validation of the inverted adsorption structure for free-base tetraphenyl porphyrin on Cu(111) ()
Chem. Commun., 2020, 56,3681-3684 DOI: 10.1039/C9CC09638H, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. P. T. P. Ryan, P. L. Lalaguna, F. Haag, M. M. Braim, P. Ding, D. J. Payne, J. V. Barth, T.-L. Lee, D. P. Woodruff, F. Allegretti, D. A. Duncan Utilising normal incidence X-ray standing waves we rigourously scrutinise the “inverted model” as the adsorption structure of free-base tetraphenyl porphyrin on Cu(111). The content of this RSS Feed (c) The Royal Society of Chemistry
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π-Conjugated polymeric phthalocyanine for the oxidative coupling of amines ()
Chem. Commun., 2020, 56,3637-3640 DOI: 10.1039/C9CC09422A, Communication Haihong Wu, Yanwei Cao, Gangli Zhu, Dehong Zeng, Xiang Zhu, Jimin Du, Lin He A cross-linked π-conjugated polymeric cobalt phthalocyanine material was prepared, showing high activity for the aerobic oxidative coupling of amines and recyclability. The content of this RSS Feed (c) The Royal Society of Chemistry
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Stepwise approach for sterically hindered Csp3–Csp3 bond formation by dehydrogenative O-alkylation and Lewis acid-catalyzed [1,3]-rearrangement towards the arylalkylcyclopentane skeleton of sesquiterpenes ()
Chem. Commun., 2020, 56,3621-3624 DOI: 10.1039/D0CC01017K, Communication Ban Fujitani, Kengo Hanaya, Takeshi Sugai, Shuhei Higashibayashi A stepwise dehydrogenative cross-coupling method was developed for the formation of sterically hindered Csp3–Csp3 bonds. The content of this RSS Feed (c) The Royal Society of Chemistry
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Carbon and carbon composites obtained using deep eutectic solvents and aqueous dilutions thereof ()
Chem. Commun., 2020, 56,3592-3604 DOI: 10.1039/D0CC00681E, Feature Article Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Gaspar Carrasco-Huertas, Rafael J. Jiménez-Riobóo, María Concepción Gutiérrez, María Luisa Ferrer, Francisco del Monte Extending the “all-in-one” features of DESs to DES/H2O binary mixtures. The content of this RSS Feed (c) The Royal Society of Chemistry
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Hysteresis in the gas sorption isotherms of metal–organic cages accompanied by subtle changes in molecular packing ()
Chem. Commun., 2020, 56,3689-3692 DOI: 10.1039/D0CC00932F, Communication Gavin A. Craig, Patrick Larpent, Hinano Urabe, Alexandre Legrand, Mickaele Bonneau, Shinpei Kusaka, Shuhei Furukawa Cooperative gas uptake in metal–organic cages is tuned using supramolecular chemistry. The content of this RSS Feed (c) The Royal Society of Chemistry
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Two-photon probes for the endoplasmic reticulum: its detection in a live tissue by two-photon microscopy ()
Chem. Commun., 2020, 56,3657-3660 DOI: 10.1039/D0CC00236D, Communication Ji-Woo Choi, Seung-Hye Choi, Seung Taek Hong, Mun Seok Kim, Seong Shick Ryu, Yeo Uk Yoon, Kyu Cheol Paik, Man So Han, Taebo Sim, Bong Rae Cho BER-blue and FER-green can detect the endoplasmic reticulum in a live tissue by two-photon microscopy. The content of this RSS Feed (c) The Royal Society of Chemistry
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Stabilizing synthetic DNA for long-term data storage with earth alkaline salts ()
Chem. Commun., 2020, 56,3613-3616 DOI: 10.1039/D0CC00222D, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. A. Xavier Kohll, Philipp L. Antkowiak, Weida D. Chen, Bichlien H. Nguyen, Wendelin J. Stark, Luis Ceze, Karin Strauss, Robert N. Grass Mimicking fossil bone, a storage system involving earth alkali salts enables the preservation of digital data in DNA. The content of this RSS Feed (c) The Royal Society of Chemistry
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‘Click’ conjugated porous polymer nanofilm with a large domain size created by a liquid/liquid interfacial protocol ()
Chem. Commun., 2020, 56,3677-3680 DOI: 10.1039/D0CC00360C, Communication Joe Komeda, Ryo Shiotsuki, Amalia Rapakousiou, Ryota Sakamoto, Ryojun Toyoda, Kazuyuki Iwase, Masaki Tsuji, Kazuhide Kamiya, Hiroshi Nishihara CuAAC between a triangular terminal alkyne and azide monomers at a water/dichloromethane interface generates a triazole-linked polymer nanofilm with a large aspect ratio. The nanofilm resists hydrolysis, and pyrolysis up to 300 °C. The content of this RSS Feed (c) The Royal Society of Chemistry
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Controlled synthesis of sugar-containing poly(ionic liquid)s ()
Chem. Commun., 2020, 56,3665-3668 DOI: 10.1039/C9CC09858E, Communication Jing Chen, Die Li, Chunyang Bao, Qiang Zhang A facile synthetic route is reported toward sugar-containing pyridinium-based poly(ionic liquid)s (PILs) for efficient killing of bacteria. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ambient electrochemical NH3 synthesis from N2 and water enabled by ZrO2 nanoparticles ()
Chem. Commun., 2020, 56,3673-3676 DOI: 10.1039/C9CC10087C, Communication Tong Xu, Dongwei Ma, Chengbo Li, Qian Liu, Siyu Lu, Abdullah M. Asiri, Chun Yang, Xuping Sun ZrO2 nanoparticles act as an efficient electrocatalyst for ambient N2-to-NH3 fixation. In 0.1 M HCl, it attains a large NH3 yield rate of 24.74 μg h−1 mgcat.−1 with a faradaic efficiency of 5.0% at −0.45 V vs. RHE. The content of this RSS Feed (c) The Royal Society of Chemistry
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Expanding the BN-embedded PAH family: 4a-aza-12a-borachrysene ()
Chem. Commun., 2020, 56,3669-3672 DOI: 10.1039/C9CC09998K, Communication Alberto Abengózar, Isabel Valencia, Guillermo G. Otárola, David Sucunza, Patricia García-García, Adrián Pérez-Redondo, Francisco Mendicuti, Juan J. Vaquero Previously unknown 4a-aza-12a-borachrysene has been synthesized in only four steps. The content of this RSS Feed (c) The Royal Society of Chemistry
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Near-infrared ratiometric self-assembled theranostic nanoprobe: imaging and tracking cancer chemotherapy ()
Chem. Commun., 2020, 56,3629-3632 DOI: 10.1039/D0CC00416B, Communication Xinwei Tian, Zhao Li, Ning Ding, Jiahang Zhang A novel near-infrared ratiometric fluorescent theranostic nanoprobe is applied for real-time fluorescence tracking and imaging cancer therapy in vivo and in situ. The content of this RSS Feed (c) The Royal Society of Chemistry
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Pyridine-d5 as a 2H NMR probe for investigation of macrostructure and pore shapes in a layered Sn(IV) phosphonate–phosphate material ()
Chem. Commun., 2020, 56,3653-3656 DOI: 10.1039/C9CC09254D, Communication Vladimir I. Bakhmutov, Douglas W. Elliott, Gregory P. Wylie, Abraham Clearfield, Aida Contreras-Ramirez, Hong-Cai Zhou Isotropic and anisotropic motions and molecular states of pyridine-d5, adsorbed on the surface within the pores of a layered Sn(IV) phosphonate–phosphate material (1) have been characterized thermodynamically and kinetically by solid-state NMR. The content of this RSS Feed (c) The Royal Society of Chemistry
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Sensitive and specific detection of tumour cells based on a multivalent DNA nanocreeper and a multiplexed fluorescence supersandwich ()
Chem. Commun., 2020, 56,3693-3696 DOI: 10.1039/C9CC08618H, Communication Lei Luo, Wenshan Li, Dongliu Xiang, Yanyun Ma, Yuan Zhou, Yaqing Xu, Nandi Chen, Qing Wang, Jin Huang, Jianbo Liu, Xiaohai Yang, Kemin Wang A self-assembled DNA nanostructure with improved binding affinity and fluorescence signal was developed for low abundance target cell detection. The content of this RSS Feed (c) The Royal Society of Chemistry
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Fluorinated cryptophane-A and porphyrin-based theranostics for multimodal imaging-guided photodynamic therapy ()
Chem. Commun., 2020, 56,3617-3620 DOI: 10.1039/D0CC00694G, Communication Huaibin Zhang, Qiao Yu, Yu Li, Zhigang Yang, Xin Zhou, Shizhen Chen, Zhong-Xing Jiang Herein, we developed fluorinated nanoemulsions with significantly enhanced in vitro and in vivo129Xe hyper-CEST MRI, 19F MRI and fluorescence imaging signals for selective and sensitive tumor detection and NIR-activated photodynamic therapy. The content of this RSS Feed (c) The Royal Society of Chemistry
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Fabrication of a multifunctional hydrogel with a robust interface bioinspired by the structure of the dentogingival junction ()
Chem. Commun., 2020, 56,3633-3636 DOI: 10.1039/D0CC00907E, Communication Xinyuan Xu, Hui Sun, Yaning Wang, Huijuan Cai, Dongyue Zhang, Hong Tan, Jianshu Li A multifunctional hydrogel with a robust interface is fabricated with a “perforating fiber” structure bioinspired by the dentogingival junction. The content of this RSS Feed (c) The Royal Society of Chemistry
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The solvent-induced isomerization of silver thiolate clusters with symmetry transformation ()
Chem. Commun., 2020, 56,3649-3652 DOI: 10.1039/D0CC01195A, Communication Xu-Ran Chen, Ling Yang, Yu-Ling Tan, Hong Yu, Chun-Yan Ni, Zheng Niu, Jian-Ping Lang The solvent-induced isomerizations of Ag12 clusters with symmetry transformations were realized by changing the coordinated solvent molecules at room temperature. The content of this RSS Feed (c) The Royal Society of Chemistry
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Engineering bromodomains with a photoactive amino acid by engaging ‘Privileged’ tRNA synthetases ()
Chem. Commun., 2020, 56,3641-3644 DOI: 10.1039/C9CC09891G, Communication Shana Wagner, Babu Sudhamalla, Philip Mannes, Sushma Sappa, Sam Kavoosi, Debasis Dey, Sinan Wang, Kabirul Islam An improved chemical synthesis, site-specific incorporation and enhanced photo-crosslinking ability of tmdF have been demonstrated in the context of protein–protein interactions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Bio-inspired assembly in a phospholipid bilayer: effective regulation of electrostatic and hydrophobic interactions for plasma membrane specific probes ()
Chem. Commun., 2020, 56,3661-3664 DOI: 10.1039/D0CC00679C, Communication Lei Shi, Kun Li, Yan-Hong Liu, Xin Liu, Qian Zhou, Qi Xu, Shan-Yong Chen, Xiao-Qi Yu A simple assembly system of phospholipid bilayer and probes via electrostatic and hydrophobic interactions was constructed. The content of this RSS Feed (c) The Royal Society of Chemistry
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An improved fluorescent protein-based expression reporter system that utilizes bioluminescence resonance energy transfer and peptide-assisted complementation ()
Chem. Commun., 2020, 56,3625-3628 DOI: 10.1039/C9CC08664A, Communication Taishi Kakizuka, Akira Takai, Keiko Yoshizawa, Yasushi Okada, Tomonobu M Watanabe A peptide-assisted complementation strategy with screened peptides has succeeded to eliminate maturation delay of a bioluminescence resonant energy transfer reporter for gene expression monitoring. The content of this RSS Feed (c) The Royal Society of Chemistry
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An air-stable anionic two-dimensional semiconducting metal-thiolate network and its exfoliation into ultrathin few-layer nanosheets ()
Chem. Commun., 2020, 56,3645-3648 DOI: 10.1039/C9CC09349D, Communication Qi Zeng, Lei Wang, Yitao Huang, Sai-Li Zheng, Yonghe He, Jun He, Wei-Ming Liao, Gang Xu, Matthias Zeller, Zhengtao Xu Metal-thiolate networks are topical electronic materials, but hard to crystallize: this one makes big single crystals, and boasts small band gap, stable radical organic linkers, and facile exfoliation into nanosheets. The content of this RSS Feed (c) The Royal Society of Chemistry
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The Synergy between the CsPbBr3 Nanoparticle Surface and the Organic Ligand Becomes Manifest in a Demanding Carbon-Carbon Coupling Reaction ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01339K, Communication Ignacio Rosa-Pardo, Carla Casadevall, Luciana Carina Schmidt, Miguel Claros, Raquel E. Eugenia Galian, Julio Lloret Fillol, Julia Perez-Prieto We demonstrate here the suitability of CsPbBr3 nanoparticles as photosensitizers for a demanding photoredox catalytic homo- and cross-coupling of alkyl bromides at room temperature by merely using visible light and... The content of this RSS Feed (c) The Royal Society of Chemistry
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CRISPR/Cas-directed programmable assembly of multi-enzyme complexes ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01174F, Communication Samuel Lim, Jiwoo Kim, Yujin Kim, Dawei Xu, Douglas S. Clark We describe a versatile CRISPR/Cas-based strategy to construct multi-enzyme complexes scaffolded on a DNA template in programmable patterns. Catalytically inactive dCas9 nuclease was used in combination with SpyCatcher-SpyTag chemistry to... The content of this RSS Feed (c) The Royal Society of Chemistry
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One-Dimensional Co-crystallized Coordination Polymers Showing Reversible Mechanochromic Luminescence: Cation-Anion Interaction Directed Rapid Self-Recovery ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/C9CC09806B, Communication Yongsheng Yang, Xiaoyu Fang, SI-Si Zhao, Feng-Yang Bai, Zhen Zhao, Ke-Zhi Wang, Dongpeng Yan Three one-dimensional (1D) chain polymers (1D-9HAC, 1D-Cd-9AC, 1D-Cd-9AC-HBIM) that contain different intermolecular interactions and stacking patterns have been designed and synthesized. Only 1D-Cd-9AC-HBIM with rigid (anion) and flexible (cation) units... The content of this RSS Feed (c) The Royal Society of Chemistry
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Unprecedented reductive cyclisation of salophen ligands to tetrahydroquinoxalines during metal complex formation ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01192D, Communication Katie J Lamb, Mark Dowsett, Michael North, Rachel R Parker, Adrian Charles Whitwood The synthesis of novel tetrahydroquinoxalines by a metal induced one–electron reductive cyclisation of salophen ligands was found to occur when a salophen ligand was treated with chromium(II) chloride or decamethylcobaltocene The content of this RSS Feed (c) The Royal Society of Chemistry
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Live cell fluorescent stain of bacterial curli and biofilm through supramolecular recognition between bromophenol blue and CsgA ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01643H, Communication Lixia Zhang, Zhenhua Li, Zhijun Chen Identification of curli-specific dyes for biofilm communities of microorganisms is an important task. We describe here a curli fluorescent light-up probe called bromophenol blue, which bind to curli via recognizing... The content of this RSS Feed (c) The Royal Society of Chemistry
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Solvent-Driven Migration of Highly Polar Monomers into Hydrophobic PDMS Produces Thick Graft Layer via Subsurface Initiated ATRP for Efficient Antibiofouling ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00768D, Communication Xin Yu, Yang Yang, Wufang Yang, Xungai Wang, Xin Liu, Feng Zhou, Yan Zhao The sucessful grafting of highly polar polymer chains both on the surface and in the subsurface of PDMS via subsurface initiated ATRP for improved antibiofouling performance is enabled by the... The content of this RSS Feed (c) The Royal Society of Chemistry
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Efficient Cellular Uptake of Click Nucleic Acid Modified Proteins ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/C9CC09401F, Communication Albert Harguindey, Heidi Culver, Jasmine Sinha, Christopher N Bowman, Jennifer N Cha Efficient intracellular delivery of biomacromolecules such as proteins continues to remain a challenge despite its potential for medicine. In this work, we show that mScarlet, a non cytotoxic red fluorescent... The content of this RSS Feed (c) The Royal Society of Chemistry
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Oxyanion Transport across Lipid Bilayers: Direct Measurements in Large and Giant Unilamellar Vesicles ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/C9CC09888G, Communication Krzysztof Marek Bąk, Bartjan van Kolck, Krystyna Maslowska-Jarzyna, Panagiota Papadopoulou, Alexander Kros, Michał Jan Chmielewski A simple di(thioamido)carbazole 1 serves as a potent multispecific transporter for various biologically relevant oxyanions, such as drugs, metabolites and model organic phosphate. The transport kinetics of a wide range... The content of this RSS Feed (c) The Royal Society of Chemistry
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Cyanine dye mediated mitochondrial targeting enhances the anti-cancer activity of small-molecule cargoes ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC07931A, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Alexander R. Nödling, Emily M. Mills, Xuefei Li, Davide Cardella, Edward J. Sayers, Shih-Hsiung Wu, Arwyn T. Jones, Louis Y. P. Luk, Yu-Hsuan Tsai Conjugation of small molecules to a simple cyanine dye can lead to organelle-specific delivery. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Carbon-11 carboxylation of trialkoxysilane and trimethylsilane derivatives using [11C]CO2 ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC00449A, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Salvatore Bongarzone, Nicola Raucci, Igor Camargo Fontana, Federico Luzi, Antony D. Gee A simple and rapid carbon-11 carboxylation radiosynthesis method. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Single-step self-assembly to uniform fiber-like core-crystalline block copolymer micelles ()
Chem. Commun., 2020, Advance Article DOI: 10.1039/D0CC00153H, Communication Shaofei Song, Hang Zhou, Garion Hicks, Chandresh Kumar Rastogi, Qing Yu, Ian Manners, Mitchell A. Winnik Accessing uniform fiber-like micelles by single-step crystallization-driven co-self-assembly of a block copolymer with a trace of homopolymer. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Unambiguous localization of titanium and iron cations in doped manganese hollandite nanowires ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01888K, Communication José M González-Calbet, Isabel Gómez-Recio, Alberto Azor-Lafarga, Luisa Ruiz-Gonzalez, María Hernando, Marina Parras, José Juan Calvino, Maria Teresa Fernandez-Diaz, David Portehault, Clément Sanchez New insights into the chemical and structural features of iron or titanium-doped KxMnO2 hollandites are reported. Neutron diffraction and atomically resolved transmission electron microscopy elucidate the localization of the dopant... The content of this RSS Feed (c) The Royal Society of Chemistry
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Agonistic or antagonistic mucosal-associated invariant T (MAIT) cell activity is determined by the 6-alkylamino substituent on uracil MR1 ligands ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00247J, Communication Chriselle D Braganza, Chihiro Motozono, Koh-hei Sonoda, Sho Yamasaki, Kensuke Shibata, Mattie Simon Maria Timmer, Bridget L Stocker Mucosal-associated invariant T (MAIT) are a subset of innate-like T cells that are activated by uracil ligands presented by MR1. For the first time, we demonstrate that changes to the... The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of γ-cyclodextrin substituted bis(acyl)phosphane oxide derivative (BAPO-γ-CyD) serving as multiple photoinitiator and crosslinking agent ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01732A, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Hansjörg Grützmacher, Andrea Cosola, Riccardo Conti, Vijay Kumar Rana, Marco Sangermano, Annalisa Chiappone, Joëlle Levalois-Grützmacher A new multi-photoactive γ-cyclodextrin substituted bis(acyl)phosphane oxide derivative (BAPO-γ-CyD) was successfully prepared via a convergent synthesis using a Phospha-Michael-addition, as confirmed by 1H-, 13C-, 31P-NMR and IR spectroscopy and mass... The content of this RSS Feed (c) The Royal Society of Chemistry
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High performance of zinc stannate photoanode in dye sensitized solar cell with cobalt complex mediators ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01219J, Communication Lingling Tao, Zhe Sun, Lei Chen, Mao Liang, Song Xue The photoanode fabricated with agglomerated zinc stannate nanoparticles was applied into dye sensitized solar cell (DSC) based on cobalt complex mediators. The resultant device yields an impressive power conversion efficiency... The content of this RSS Feed (c) The Royal Society of Chemistry
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Direct conversion of syngas into aromatics over bifunctional catalyst without net releasing CO2 ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00608D, Communication Wei Zhou, Cheng Zhou, Haoren Yin, Jiaqing Shi, Guoquan Zhang, Xinlei Zheng, Xiaojian Min, Zhiqiang Zhang, Kang Cheng, Jincan Kang, Qinghong Zhang, Ye Wang Tandem catalysis via methanol intermediate is a promising route for the direct conversion of syngas into aromatics. However, the simultaneous formation of CO2 is a serious problem. Here, we demonstrate... The content of this RSS Feed (c) The Royal Society of Chemistry
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Correlated alkyl chain length to defect passivation efficacy in perovskite solar cells ()
Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC01197E, Communication wenhuai feng, Chengxi Zhang, Jun-Xing Zhong, Liming Ding, Wu-Qiang Wu We for the first time correlated the alkyl chain length of amine molecules to the defect passivation efficacy, either on surface or at grain boundaries of perovskite films. Blade-coated perovskite... The content of this RSS Feed (c) The Royal Society of Chemistry
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