Chem. Commun.

Palladium-Catalyzed Intramolecular Reductive Olefin Hydrocarbonation: Benzylic Hydrogen Playing as a New Hydrogen Donor ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01423F, Communication Xu Dong, Jie Cui, Jian Song, Ying Han, qing Liu, Yunhui Dong, Hui Liu A palladium-catalyzed intramolecular hydrocarbonation of unactivated alkenes was achieved, in which toluene is used as hydrogen donor for the first time. The radical transfer hydrogenation is designed and realized basing... The content of this RSS Feed (c) The Royal Society of Chemistry
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Supramolecular Chemistry of Pillar[n]arenes Functionalised by Copper(I)-Catalysed Alkyne-Azide Cycloaddition "Click" Reaction ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01833A, Feature Article Takahiro Kakuta, Tada-aki Yamagishi, Tomoki Ogoshi Since we discovered pillar[n]arenes in 2008, many chemists have developed a strong interest in pillar[n]arene chemistry because of the many advantages associated with these material, including their facile and high... The content of this RSS Feed (c) The Royal Society of Chemistry
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Efficient synthesis of 3-hydroxyimino-1-isoindolinones and 3-methylene-1-isoindolinones via Cu-promoted C-H activation-nitroalkylation-intramolecular cyclization tandem processes ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01097D, Communication Lin Yu, Hang Huang, Xiang Chen, Liang Hu, Yongqi Yu, Ze Tan Efficient and selective syntheses of 3-hydroxyimino-1-isoindolinones and 3-methylene-1-isoindolinones were achieved via 8-aminoquinoline assisted Cu-promoted coupling of benzamides with nitroalkanes. The reaction was found to go through C-H activation, nitroalkylation followed... The content of this RSS Feed (c) The Royal Society of Chemistry
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Designed Adenine Functionalization for Creating Complex Architectures for Material and Biological Applications ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00222J, Feature Article Balaram Mohapatra, Pratibha Pratibha, Sandeep Verma In this feature article, targeted design strategies are outlined for modified adenine nucleobase derivatives in order to construct metal-mediated discrete complexes, ring-expanded purine skeletons, linear and catenated coordination polymers, shape-selective... The content of this RSS Feed (c) The Royal Society of Chemistry
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End-to-end assembly and disassembly of gold nanorods based on photo-responsive host-guest interaction ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01678F, Communication Jie Wu, Yun Xu, Dengfeng Li, Xiang Ma, He Tian The host-guest interaction based on thiol-[small beta]-cyclodextrin and a symmetric compound containing two azobenzene units on ends has been utilized to form end-to-end assembly of gold nanorods. Both UV light irradiation... The content of this RSS Feed (c) The Royal Society of Chemistry
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Molecular Imaging Probes for Multi-Spectral Optoacoustic Tomography ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C6CC09421J, Feature Article Vipul Gujrati, Anurag Mishra, Vasilis Ntziachristos Multi-Spectral Optoacoustic Tomography (MSOT) merges the power of high-resolution imaging at tissue depths of several millimeters to centimeters with the advantages of optical imaging, in large part by exploiting spectral... The content of this RSS Feed (c) The Royal Society of Chemistry
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Quantitative prediction of nuclear-spin-diffusion-limited coherence times of molecular quantum bits based on copper(II) ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C6CC07813C, Communication Samuel Lenz, Katharina Bader, Heiko Bamberger, Joris van Slageren We have investigated the electron spin dynamics in a series of copper(II) [small beta]-diketonate complexes both in frozen solutions and doped solids. Double digit microsecond coherence times were found at low... The content of this RSS Feed (c) The Royal Society of Chemistry
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Photoelectrochemical dimethoxylation of furan via a bromide redox mediator using a BiVO4/WO3 photoanode ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01190C, Communication Hiroyuki Tateno, Yugo Miseki, Kazuhiro Sayama Photoelectrochemical dimethoxylation of furan with methanol using a BiVO4/WO3 photoanode and Br+/Br- as a mediator was demonstrated with low applied potential. The current efficiency for the dimethoxylation with a Et4NBF4... The content of this RSS Feed (c) The Royal Society of Chemistry
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Photoredox-catalyzed oxytrifluoromethylation of allenes: Stereoselective synthesis of 2-trifluoromethylated allyl acetates ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01759F, Communication Ren Tomita, Takashi Koike, Munetaka Akita We have developed novel oxytrifluoromethylation of aryl-substituted allenes by photoredox catalysis. The present photocatalytic system allows direct and stereoselective synthesis of 2-CF3-allyl acetates bearing tetrasubstituted CF3-alkene scaffolds in a single... The content of this RSS Feed (c) The Royal Society of Chemistry
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Polyfluoroarylation of oxazolones: access to non-natural fluorinated amino acids ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01606A, Communication Kip A. Teegardin, Jimmie D. Weaver Herein, we demonstrate the use of the oxazolone enolate to access non-natural fluorinated amino acid derivatives. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A bidirectional synthesis of spiroacetals via Rh(II)-catalysed C-H insertion ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00459A, Communication Romain J. Lepage, Jonathan M. White, Mark J. Coster Acyclic methylene acetals bearing two diazoester subunits have been converted to [5,5]-spiroacetals VIA bidirectional C-H insertion under Rh(II) catalysis. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Specific and relative detection of urinary microRNA signatures in bladder cancer for point-of-care diagnostics ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01007A, Communication Nan Cheng, Yuancong Xu, Yunbo Luo, Liye Zhu, Yitong Zhang, Kunlun Huang, Wentao Xu The proposed assay employing BSH-EXPAR and LFNAB is expected to be of great promise for bladder cancer diagnosis and point-of-care diagnostics. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Protecting patches in colloidal synthesis of Au semishells ()
Chem. Commun., 2017, 53,3898-3901 DOI: 10.1039/C7CC00689F, Communication Daniel Mann, Stefanie Voogt, Ryan van Zandvoort, Helmut Keul, Martin Moller, Marcel Verheijen, Daniel Nascimento-Duplat, Man Xu, H. Paul Urbach, Aurele J. L. Adam, Pascal Buskens Extending the concept of protecting group chemistry from molecular to colloidal synthesis: three-step colloidal synthesis of Au semishells as a prototypical example. The content of this RSS Feed (c) The Royal Society of Chemistry
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Asymmetric hydrogenation of maleic anhydrides catalyzed by Rh/bisphosphine-thiourea: efficient construction of chiral succinic anhydrides ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01626C, Communication Zhengyu Han, Rui Wang, Guoxian Gu, Xiu-Qin Dong, Xumu Zhang Asymmetric hydrogenation of various 3-substituted maleic anhydrides catalyzed by Rh/bisphosphine-thiourea (ZhaoPhos) under mild conditions was successfully developed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ni-Catalyzed regio- and stereoselective addition of arylboronic acids to terminal alkynes with a directing group tether ()
Chem. Commun., 2017, 53,3894-3897 DOI: 10.1039/C6CC10256E, Communication Madala Hari Babu, Gadi Ranjith Kumar, Ruchir Kant, Maddi Sridhar Reddy Addition of arylboronic acids to directing group tethered acetylenes in a regio and stereoselective manner using an inexpensive catalytic system is achieved for the first time to access highly sought after allyl/homoallyl alcohol/amine units. The content of this RSS Feed (c) The Royal Society of Chemistry
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Supramolecular electrode assemblies for bioelectrochemistry ()
Chem. Commun., 2017, 53,3801-3809 DOI: 10.1039/C7CC01154G, Feature Article Theodoros Laftsoglou, Lars J. C. Jeuken Supramolecular approaches in bioelectrochemistry have boosted enzyme loading on electrodes and shaped biocompatible environments for enzymes. The content of this RSS Feed (c) The Royal Society of Chemistry
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Hydrogen generation from glucose catalyzed by organoruthenium catalysts under mild conditions ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00177K, Communication Yulu Zhan, Yangbin Shen, Shuping Li, Baohua Yue, Xiaochun Zhou Here, we describe a catalytic reaction system where H2 can be produced from glucose using a homogeneous catalyst. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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SMI-Ribosome inactivating protein conjugates selectively inhibit tumor cell growth ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00745K, Communication Saumya Roy, Jun Y. Axup, Jane S. Forsyth, Rajib K. Goswami, Benjamin M. Hutchins, Krishna M. Bajuri, Stephanie A. Kazane, Vaughn V. Smider, Brunhilde H. Felding, Subhash C. Sinha Cell-targeting conjugates of Saporin 6, prepared using a small molecule inhibitor of integrins [small alpha]v[small beta]3 and [small alpha]v[small beta]5 and the Saporin A157C mutant, selectively and potently inhibited proliferation of tumor cells expressing the target integrins. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Selective perrhenate recognition in pure water by halogen bonding and hydrogen bonding alpha-cyclodextrin based receptors ()
Chem. Commun., 2017, 53,3866-3869 DOI: 10.1039/C7CC01605K, Communication Stuart P. Cornes, Mark R. Sambrook, Paul D. Beer Alpha-cyclodextrin based anion receptors containing halogen and hydrogen bond donor motifs display selective association of perrhenate in neutral aqueous media. The content of this RSS Feed (c) The Royal Society of Chemistry
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In situ deprotection and dynamic covalent assembly using a dual role catalyst ()
Chem. Commun., 2017, 53,3874-3877 DOI: 10.1039/C7CC01028A, Communication T. Wei, J. C. Furgal, T. F. Scott Sc(OTf)3 is employed as a dual role catalyst to effect the in situ deprotection and dynamic covalent assembly of oligo(peptoid)s. The content of this RSS Feed (c) The Royal Society of Chemistry
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Spontaneous and specific binding of enterohemorrhagic Escherichia coli to overoxidized polypyrrole-coated microspheres ()
Chem. Commun., 2017, 53,3890-3893 DOI: 10.1039/C7CC00244K, Communication Xueling Shan, Takuya Yamauchi, Yojiro Yamamoto, Saroh Niyomdecha, Kengo Ishiki, Dung Q. Le, Hiroshi Shiigi, Tsutomu Nagaoka Specific identification of enterohemorrhagic Escherichia coli was achieved using microspheres coated with overoxidized polypyrrole. The content of this RSS Feed (c) The Royal Society of Chemistry
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Designing an anion-functionalized fluorescent ionic liquid as an efficient and reversible turn-off sensor for detecting SO2 ()
Chem. Commun., 2017, 53,3862-3865 DOI: 10.1039/C7CC00676D, Communication Siying Che, Rina Dao, Weidong Zhang, Xiaoyu Lv, Haoran Li, Congmin Wang A novel anion-functionalized fluorescent ionic liquid was designed as an efficient turn-off fluorescent sensor for gaseous SO2, which exhibited high selectivity, good quantification, and excellent reversibility. The content of this RSS Feed (c) The Royal Society of Chemistry
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Difluoromethylcarbene for iron-catalyzed cyclopropanation ()
Chem. Commun., 2017, 53,3870-3873 DOI: 10.1039/C7CC01636K, Communication Yaya Duan, Jin-Hong Lin, Ji-Chang Xiao, Yu-Cheng Gu Fe-Catalyzed cyclopropanation of olefins with difluoromethylcarbene generated from sulfonium ylide Ph2S+-CH-CF2H with high diastereoselectivity is described. The content of this RSS Feed (c) The Royal Society of Chemistry
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Toward steric control of guest binding modality: a cationic Co(II) complex exhibiting cation binding and zero-field relaxation ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01172E, Communication Tarik J. Ozumerzifon, Indrani Bhowmick, William C. Spaller, Anthony K. Rappe, Matthew P. Shores A cationic Co(II) complex shows slow magnetic relaxation in zero field and cation binding properties; computations support distortion-driven magnetic anisotropy. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Cyclic enzymatic repairing-mediated dual-signal amplification for real-time monitoring of thymine DNA glycosylase ()
Chem. Commun., 2017, 53,3878-3881 DOI: 10.1039/C7CC00946A, Communication Li-Juan Wang, Zi-Yue Wang, Qianyi Zhang, Bo Tang, Chun-Yang Zhang We develop a new fluorescence method for real-time monitoring of thymine DNA glycosylase activity through cyclic enzymatic repairing-mediated dual-signal amplification. The content of this RSS Feed (c) The Royal Society of Chemistry
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Stabilizing the monomeric amyloid-[small beta] peptide by tyrocidine A prevents and reverses amyloidogenesis without the accumulation of oligomers ()
Chem. Commun., 2017, 53,3886-3889 DOI: 10.1039/C7CC00506G, Communication Gesi Wen, Wenjing Qin, Daoyuan Chen, Youqiao Wang, Xin Yue, Ziyi Liu, Yingnan Cao, Jun Du, Binhua Zhou, Xianzhang Bu Stabilizing the monomeric amyloid-[small beta] peptide by tyrocidine A prevents accumulation of oligomers. The content of this RSS Feed (c) The Royal Society of Chemistry
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Azomethine-isocyanide [3+2] cycloaddition to imidazoles promoted by silver and DBU ()
Chem. Commun., 2017, 53,3858-3861 DOI: 10.1039/C7CC00772H, Communication Xiaoshan Huang, Xuefeng Cong, Pengbing Mi, Xihe Bi A new silver-promoted [3+2] cycloaddition of azomethine ylides with isocyanides has been described to construct a variety of 1,2,4-trisubstituted imidazoles of vital bioactive molecules. The content of this RSS Feed (c) The Royal Society of Chemistry
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Effects of chalcogen atom substitution on the optoelectronic and charge-transport properties in picene-type [small pi]-systems ()
Chem. Commun., 2017, 53,3814-3817 DOI: 10.1039/C7CC01292F, Communication Tatsuya Oyama, Yu Seok Yang, Kyohei Matsuo, Takuma Yasuda [small pi]-Conjugated 3,10-dialkyl-dinaphtho[1,2-b:2[prime or minute],1[prime or minute]-d]chalcogenophenes incorporating S, Se, and Te as the central chalcogen atom were developed, and their optoelectronic and charge-transport properties were systematically investigated. The content of this RSS Feed (c) The Royal Society of Chemistry
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One-pot synthesis of alternating peptides exploiting a new polymerization technique based on Ugi's 4CC reaction ()
Chem. Commun., 2017, 53,3846-3849 DOI: 10.1039/C6CC09379E, Communication Yasuhito Koyama, Prashant G. Gudeangadi A catalyst-free, one-pot synthetic technique for alternating peptides was developed on the basis of Ugi's 4 component condensation reaction. The content of this RSS Feed (c) The Royal Society of Chemistry
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A layered wide-gap oxyhalide semiconductor with an infinite ZnO2 square planar sheet: Sr2ZnO2Cl2 ()
Chem. Commun., 2017, 53,3826-3829 DOI: 10.1039/C7CC01011G, Communication Yu Su, Yoshihiro Tsujimoto, Akira Miura, Shinichiro Asai, Maxim Avdeev, Hiraku Ogino, Miho Ako, Alexei A. Belik, Takatsugu Masuda, Tetsuo Uchikoshi, Kazunari Yamaura A new layered perovskite zinc oxychloride, Sr2ZnO2Cl2, with a square planar geometry was successfully synthesized using a high pressure method. The content of this RSS Feed (c) The Royal Society of Chemistry
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A one-pot route to thioamides discovered by gas-phase studies: palladium-mediated CO2 extrusion followed by insertion of isothiocyanates ()
Chem. Commun., 2017, 53,3854-3857 DOI: 10.1039/C7CC00865A, Communication Asif Noor, Jiawei Li, George N. Khairallah, Zhen Li, Hossein Ghari, Allan J. Canty, Alireza Ariafard, Paul S. Donnelly, Richard A. J. O'Hair A palladium mediated synthesis of thioamides from aromatic carboxylic acids and substituted isothiocyanates was discovered by gas-phase experiments and theoretical studies. The content of this RSS Feed (c) The Royal Society of Chemistry
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Dimension-controlled assemblies of anion-responsive [small pi]-electronic systems bearing aryl substituents with fan-shaped geometries ()
Chem. Commun., 2017, 53,3834-3837 DOI: 10.1039/C7CC01551H, Communication Vellanki Lakshmi, Yohei Haketa, Ryohei Yamakado, Nobuhiro Yasuda, Hiromitsu Maeda Pyrrole-4-aryl-substituted dipyrrolyldiketone BF2 complexes showed fan-shaped and rod-shaped geometries for anion-free states and receptor-anion complexes, respectively, as building units of dimension-controlled assemblies. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis and evaluation of a tag-free photoactive phospho-ceramide analogue-1 (PCERA-1) probe to study immunomodulation in macrophages ()
Chem. Commun., 2017, 53,3842-3845 DOI: 10.1039/C6CC09849E, Communication Rambabu Dandela, Roi Mashiach, Raju Adepu, Rachel Gregor, Muhammad Athamna, Efrat Zecharia, Orna Ernst, Tsaffrir Zor, Michael M. Meijler Phospho-ceramide analogue-1 (PCERA-1), a synthetic analogue of ceramide-1-phosphate (C1P), has been previously shown to act as a potent modulator of macrophage activity and inflammation. The content of this RSS Feed (c) The Royal Society of Chemistry
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The mechanism of aquaporin inhibition by gold compounds elucidated by biophysical and computational methods ()
Chem. Commun., 2017, 53,3830-3833 DOI: 10.1039/C7CC00318H, Communication Andreia de Almeida, Andreia F. Mosca, Darren Wragg, Margot Wenzel, Paul Kavanagh, Giampaolo Barone, Stefano Leoni, Graca Soveral, Angela Casini The mechanism of inhibition of water and glycerol permeation via human aquaglyceroporin-3 (AQP3) by gold(III) complexes has been described, for the first time, using molecular dynamics (MD), combined with density functional theory (DFT) and electrochemical studies. The content of this RSS Feed (c) The Royal Society of Chemistry
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SF5-Pyridylaryl-[small lambda]3-iodonium salts and their utility as electrophilic reagents to access SF5-pyridine derivatives in the late-stage of synthesis ()
Chem. Commun., 2017, 53,3850-3853 DOI: 10.1039/C7CC01043E, Communication Prajwalita Das, Masahiro Takada, Kohei Matsuzaki, Norimichi Saito, Norio Shibata Electrophilic SF5-pyridylation of C, N, O and S-nucleophiles using diaryliodonium reagents is disclosed. The content of this RSS Feed (c) The Royal Society of Chemistry
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Oxidase-mimicking activity of the nitrogen-doped Fe3C@C composites ()
Chem. Commun., 2017, 53,3882-3885 DOI: 10.1039/C7CC00610A, Communication Hankun Yang, Jingyu Xiao, Lei Su, Ting Feng, Qingye Lv, Xueji Zhang The nitrogen-doped Fe3C@C composites could behave as oxidase-mimics to catalyze the reaction between TMB and molecular oxygen to produce quinonediimine and H2O. The content of this RSS Feed (c) The Royal Society of Chemistry
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When self-assembly meets topology: an enhanced micelle stability ()
Chem. Commun., 2017, 53,3822-3825 DOI: 10.1039/C7CC00914C, Communication Xiaopeng Dong, Xuliang Guo, Guangqin Liu, Aiping Fan, Zheng Wang, Yanjun Zhao Curvature-induced dipole moment and unique geometry can enhance micelle stability. The content of this RSS Feed (c) The Royal Society of Chemistry
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Structural characterization of fluoride species in shark teeth ()
Chem. Commun., 2017, 53,3838-3841 DOI: 10.1039/C6CC10114C, Communication Hsun-Hui Chang, Ming-Jou Chien, Chun-Chieh Kao, Yu-Jo Chao, Pao-Tao Yu, Chun-Yu Chang, Shing-Jong Huang, Yuan-Ling Lee, Jerry C. C. Chan Multiple fluoride species have been found in shark teeth. The content of this RSS Feed (c) The Royal Society of Chemistry
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Dithiolato-bridged nickel-iron complexes as models for the active site of [NiFe]-hydrogenases ()
Chem. Commun., 2017, 53,3818-3821 DOI: 10.1039/C7CC00149E, Communication Li-Cheng Song, Xi-Yue Yang, Meng Cao, Xiu-Yun Gao, Bei-Bei Liu, Liang Zhu, Feng Jiang While the first NiFe-based [small mu ]-hydroxo model [3]+ can be prepared by reaction of a dicarbonyl model [1]2+ with Me3NO[middle dot]2H2O, the functional modeling of H2 activation catalyzed by the Ni-SIa state gives the t-hydride model [2]+ in high yield. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly monodisperse supported metal nanoparticles by basic ammonium functionalization of mesopore walls for industrially relevant catalysis ()
Chem. Commun., 2017, 53,3810-3813 DOI: 10.1039/C7CC00479F, Communication Jangkeun Cho, Leilei Xu, Changbum Jo, Ryong Ryoo A strategy for achieving a high dispersion of metal and metal oxide nanoparticles in a mono-modal fashion is developed. The content of this RSS Feed (c) The Royal Society of Chemistry
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A Potentiometric resolved ratiometric photoelectrochemical aptasensor ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01582H, Communication Ying Zhang, Nan Hao, Zhou Zhou, Rong Hua, Jing Qian, Qian Liu, Henan Li, Kun Wang A novel ratiometric photoelectrochemical aptasensor based on the potentiometric resolved photocurrents generated from different PEC active materials was designed for the first time. The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal extraction with a short-chain imidazolium nitrate ionic liquid ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01685A, Communication Daphne Depuydt, Arne Van den Bossche, Wim Dehaen, Koen Binnemans A short-chain symmetrical dihexyl imidazolium nitrate ionic liquid for conventional solvent extraction of metals was developed. Rare earths were found to be preferentially extracted over 1st row transition metals leading... The content of this RSS Feed (c) The Royal Society of Chemistry
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Site-selective Benzoin-type Cyclization of Unsymmetrical Dialdoses Catalyzed by N-Heterocyclic Carbenes for Divergent Cyclitol Synthesis ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01191A, Communication bubwoon Kang, Yinli Wang, Satoru Kuwano, Yousuke Yamaoka, Kiyosei Takasu, Ken-ichi Yamada A highly site-selective N-heterocyclic carbene (NHC)-catalyzed benzoin-type cyclization of unsymmetrical dialdoses is developed to enable a divergent cyclitol synthesis. The choice of chiral NHCs and protecting groups affects the site-selectivity.... The content of this RSS Feed (c) The Royal Society of Chemistry
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One-Step Colorimetric Detection of Antibody Based on Protein-Induced Unfolding of G-quadruplex Switch ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00687J, Communication Xiaolu Hu, Chao Li, Chang Feng, Xiaoxia Mao, Yang Xiang, Genxi Li A simple colorimetric assay is developed for the sensitive and selective detection of antibody, which combines protein binding-induced signaling approach with a novel DNAzyme-based conformational switching strategy. The content of this RSS Feed (c) The Royal Society of Chemistry
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A selective and light-up fluorescent probe for [small beta]-galactosidase activity detection and imaging in living cells based on an AIE tetraphenylethylene derivative ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00249A, Communication Guo-yu Jiang, Guanjie Zeng, Wenping Zhu, Yongdong Li, Xiaobiao Dong, Guanxin Zhang, Xiaolin Fan, Jianguo Wang, Yongquan Wu, Ben Zhong Tang An aggregation induced emission (AIE) based bioimaging probe, TPE-Gal, was designed for light-up imaging of [small beta]-galactosidase in living cells. The applicability of TPE-Gal in imaging endogenous [small beta]-galactosidase activity was confirmed... The content of this RSS Feed (c) The Royal Society of Chemistry
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Difluorocarbene transfer from a cobalt complex to an electron-deficient alkene ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01418J, Communication Monalisa Goswami, Bas de Bruin, Wojciech Dzik We report the synthesis of the trifluoromethyl cobalt(III)tetraphenylporphyrinato complex [Co(TPP)CF3], which loses fluoride upon one-electron reduction and transfers a difluorocarbene moiety to n-butyl acrylate to produce the corresponding gem-difluorocyclopropane. Catalytic... The content of this RSS Feed (c) The Royal Society of Chemistry
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Gold-catalyzed Oxidative Couplings of Two Indoles with One Aryldiazo Cyanide under Oxidant-free Conditions ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01304C, Communication Rai-Shung Liu, RahulKumar Rajmani Singh Gold-catalyzed oxidative couplings of two indoles and one -cyano gold carbene to form useful bis(indolyl)methane derivatives are described; the reactions release molecular hydrogen that is detectable with GC. This gold... The content of this RSS Feed (c) The Royal Society of Chemistry
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Cobalt-Catalyzed (Z)-Selective Semihydrogenation of Alkynes with Molecular Hydrogen ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01228D, Communication Caiyou Chen, Yi Huang, Zongpeng Zhang, Xiu-Qin Dong, Xumu Zhang A cobalt-catalyzed highly (Z)-selective semihydrogenation of alkynes using molecular H2 was developed using commercially available and cheap cobalt precursors. A variety of (Z)-alkenes were obtained in moderate to excellent selectivities... The content of this RSS Feed (c) The Royal Society of Chemistry
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Stereospecific Functionalizations and Transformations of Secondary and Tertiary Boronic Esters ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01254C, Feature Article Christopher Sandford, Varinder K Aggarwal The formation of highly enantioenriched boronic esters through both stoichiometric and catalytic methods has received much attention over the past decade. Accordingly, the transformations of the boronic ester moiety into... The content of this RSS Feed (c) The Royal Society of Chemistry
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A room-temperature phosphorescent polymer film containing a molecular web based on one-dimensional chiral stacking of a simple luminophore ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00395A, Communication Kyohei Yoshida, Yutaka Kuwahara, Koji Miyamoto, Seiya Nakashima, Hirokuni Jintoku, Makoto Takafuji, Hirotaka Ihara We propose a new approach for a totally organic, room-temperature phosphorescent system with a lifetime on the order of milliseconds, which is achieved by promotion of the one-dimensional chiral stacking... The content of this RSS Feed (c) The Royal Society of Chemistry
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Missing metal-linker connectivities in a 3-D robust sulfonate-based metal-organic framework for enhanced proton conductivity ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01461A, Communication Guiyang Zhang, Honghan Fei We demonstrate the first example of proton conductivity control with the missing metal-ligand connectivities within a rare 3-D porous sulfonate-based MOF. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly durable photochromic radical complexes having no steric protections of radicals ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01439B, Communication Yoichi Kobayashi, Yasuhiro Mishima, Katsuya Mutoh, Jiro Abe Durable radical-dissociation type photochromic reactions are demonstrated without the steric protections of the radicals. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Correlated mass spectrometry and confocal microscopy imaging verifies the dual-targeting action of an organoruthenium anticancer complex ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01503H, Communication Suyan Liu, Wei Zheng, Kui Wu, Yu Lin, Feifei Jia, Yang Zhang, Zhaoying Wang, Qun Luo, Yao Zhao, Fuyi Wang A correlated ToF-SIMS and CLSM imaging strategy was developed to visualize the subcellular distribution of an organoruthenium anticancer complex, showing its accumulation in both cell membrane and nuclei and verifying its dual-targeting feature. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Rational design of a luminescent nanoprobe for hypoxia imaging in vivo via ratiometric and photoluminescence lifetime imaging microscopy ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00668C, Communication Qi Yu, Tianci Huang, Yipeng Li, Huanjie Wei, Shujuan Liu, Wei Huang, Jing Du, Qiang Zhao A nanoprobe has been employed for hypoxia imaging in vitro and in vivo via ratiometric and, photoluminescence lifetime imaging techniques. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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The convergent chemical synthesis of histone H3 protein for site-specific acetylation at Lys56 and ubiquitination at Lys122 ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01721A, Communication Yun-Kun Qi, Qiao-Qiao He, Hua-Song Ai, Jing Guo, Jia-Bin Li The first total chemical synthesis of modified H3 bearing Lys56 acetylation and Lys122 ubiquitination. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Fabrication of conjugated microporous polytriazine nanotubes and nanospheres for highly selective CO2 capture ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00704C, Communication Zhiqiang Wang, Junling Liu, Yu Fu, Cheng Liu, Chunyue Pan, Zhiyong Liu, Guipeng Yu A new strategy for fabricating CMPs with a controllable morphology and a molecular design for enhancing host-guest interactions lead to high capacities for CO2 and exceptionally high ideal selectivities over N2. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Rationalizing the relative abundances of trimetallic nitride template-based endohedral metallofullerenes from aromaticity measures ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01750B, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. M. Garcia-Borras, S. Osuna, J. M. Luis, M. Sola The synthesis of endohedral metallofullerenes (EMFs) from a carbon soot sample leads to a variety of EMFs that are obtained in different relative abundances. In this work, we show that these abundances can be predicted from aromaticity calculations. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Molecular control over colloidal assembly ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC09985H, Feature Article M. Gerth, I. K. Voets A perspective on molecularly controlled colloidal assembly and its use in fundamental science and technology. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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endo-Cyclization of unsaturated RO2 radicals from the gas-phase ozonolysis of cyclohexadienes ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01350G, Communication Stefanie Richters, Mark Pfeifle, Matthias Olzmann, Torsten Berndt Experimental investigations supported by theoretical calculations show that unsaturated RO2 radicals can undergo an endo-cyclization step for atmospheric reaction conditions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Site-specific antibody modification and immobilization on a microfluidic chip to promote the capture of circulating tumor cells and microemboli ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00247E, Communication Chian-Hui Lai, Syer Choon Lim, Liang-Chun Wu, Chien-Fang Wang, Wen-Sy Tsai, Han-Chung Wu, Ying-Chih Chang Antibody coating via Fc-domain site-specific immobilization improves capture efficiency of circulating tumor cells and microemboli in microfluidics. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Chemoproteomics-enabled covalent ligand screen reveals a cysteine hotspot in reticulon 4 that impairs ER morphology and cancer pathogenicity ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01480E, Communication L. A. Bateman, T. B. Nguyen, A. M. Roberts, D. K. Miyamoto, W.-M. Ku, T. R. Huffman, Y. Petri, M. J. Heslin, C. M. Contreras, C. F. Skibola, J. A. Olzmann, D. K. Nomura Chemoproteomics-enabled covalent ligand discovery reveals a covalent ligand targeting RTN4 that alters ER morphology and impairs cancer pathogenicity. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Mesoscopic helical architectures via self-assembly of porphyrin-based discotic systems ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01670K, Communication Sonia Vela, Jose Augusto Berrocal, Carmen Atienza, E. W. Meijer, Nazario Martin Mesoscopic super-helices with preferred helicity have been serendipitously formed via the self-assembly of electroactive extended core discotic molecules. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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N-Heterocyclic carbene copper-catalyzed direct alkylation of terminal alkynes with non-activated alkyl triflates ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00891K, Communication Liqun Jin, Wangfang Hao, Jianeng Xu, Nan Sun, Baoxiang Hu, Zhenlu Shen, Weimin Mo, Xinquan Hu (NHC)-Cu-catalyzed C(sp)-C(sp3) bond formation has been successfully achieved under mild conditions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Formamidine and cesium-based quasi-two-dimensional perovskites as photovoltaic absorbers ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00921F, Communication Ryuki Hamaguchi, Masahiro Yoshizawa-Fujita, Tsutomu Miyasaka, Hideyuki Kunugita, Kazuhiro Ema, Yuko Takeoka, Masahiro Rikukawa Formamidine (FA) and cesium (Cs) cations were introduced into quasi-two-dimensional (2D) perovskites as B site cations. The unique crystalline growth of the resulting (n-C6H13NH3)2FAPb2I7, which promotes charge transport in photovoltaic... The content of this RSS Feed (c) The Royal Society of Chemistry
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Luciferase-Rose Bengal Conjugates for Singlet Oxygen Generation by Bioluminescence Resonant Energy Transfer ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00041C, Communication Seonghoon Kim, HyeongChan Jo, Mijeong Jeon, Myung-Gyu Choi, Sei Kwang Hahn, Seok-Hyun Yun The conjugates of Rose Bengal and Renilla luciferase showed the generation of singlet oxygen upon binding with coelenterazine via bioluminescence resonance energy transfer (BRET). Since the applications of conventional PDT... The content of this RSS Feed (c) The Royal Society of Chemistry
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Regioselective Hydrosilylation of Epoxides Catalysed by Nickel(II) Hydrido Complexes ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01655G, Communication Jan Wenz, Hubert Wadepohl, Lutz H Gade Bench-stable nickel fluoride complexes bearing NNN pincer ligands have been employed as precursors for the regioselective hydrosilylation of epoxides at room temperature. A nickel hydride assisted epoxide opening is followed... The content of this RSS Feed (c) The Royal Society of Chemistry
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Domino Ring-Opening Cyclization (DROC) of Activated Aziridines and Epoxides with Nitrones via Dual-Catalysis "On Water" ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01033H, Communication Imtiyaz Ahmad Wani, Masthanvali Sayyad, Manas K. Ghorai An efficient and green "On Water" regio- and stereoselective synthetic route to chiral 1,2,4-oxadiazinanes and 1,4,2-dioxazinanes with excellent yield (up to 99%) and de/ee ( >99%) has been developed for... The content of this RSS Feed (c) The Royal Society of Chemistry
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Pyreneacyl Sulfides as a Visible Light-Induced Versatile Ligation Platform ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00711F, Communication Bryan Tuten, Jan Philipp Menzel, Kai Pahnke, James P Blinco, Christopher Barner-Kowollik We report a visible light responsive moiety capable of generating highly reactive thioaldehydes. Upon irradiation with visible light (420 nm) the pyreneacyl sulfide species undergoes a Norrish II elimination yielding... The content of this RSS Feed (c) The Royal Society of Chemistry
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Tunable Differentiation of Tertiary C-H Bonds in Intramolecular Transition Metal-Catalyzed Nitrene Transfer Reactions ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01235G, Communication Joshua R. Corbin, Jennifer Schomaker Metal-catalyzed nitrene transfer reactions are an appealing and efficient strategy for accessing tetrasubstituted amines through the direct amination of tertiary C-H bonds. Traditional catalysts for these reactions rely on substrate... The content of this RSS Feed (c) The Royal Society of Chemistry
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C3-Selective Alkenylation of N-Acylindoles with Unactivated Internal Alkynes by Cooperative Nickel/Aluminium Catalysis ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00852J, Communication Fumiyoshi Inoue, Teruhiko Saito, Kazuhiko Semba, Yoshiaki Nakao The highly regio- and stereoselective alkenylation of N-acylindoles with unactivated internal alkynes has been accomplished by cooperative nickel/aluminium catalysis to afford C3-alkenylated indoles. Coordination of the acyl moiety to a... The content of this RSS Feed (c) The Royal Society of Chemistry
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Endoplasmic reticulum-selective ratiometric fluorescent probe for imaging copper pool ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01430A, Communication Sun Young Park, Woori Kim, Sun-Hee Park, Jinhyoung Han , Jinju Lee, Chulhun Kang, Minhee Lee Hydrazide-linked naphthalimides undergo copper ion-selective hydrolysis with concomitant ratiometric fluorescence change. In addition, probe 1 is biocompatible and mainly localized to the endoplasmic reticulum (ER) in live HeLa cells. It... The content of this RSS Feed (c) The Royal Society of Chemistry
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Supramolecular Architectures Self-Assembled Using Long Chain Alkylated Spin Crossover Cobalt(II) Compounds ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01501A, Communication Ryohei Akiyoshi, Keita Kuroiwa, Saliu Alao Amolegbe, Manabu Nakaya, Ryo Ohtani, Masaaki Nakamura, Leonard F Lindoy, Shinya Hayami Self-assembled hybrid supramolecular architectures formed between amphiphilic anions and long alkylated cationic cobalt(II) complexes of type [Co(Cn-terpy)2](C12-Glu)2 (n = 15-20) have been synthesized and characterized by TEM, PXRD and magnetic... The content of this RSS Feed (c) The Royal Society of Chemistry
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Oxahelicene NHC ligands in the asymmetric synthesis of nonracemic helicenes ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00781G, Communication I Stary, Isabel Gay Sanchez, Michal Samal, Jindrich Nejedly, Manfred Karras, Jiri Klivar, Jiri Rybacek, Milos Budesinsky, Lucie Bednarova, Beata Seidlerova, Irena G Stara A straightforward approach to enantiopure 2H-pyran-modified amino[5]helicenes and animo[6]helicene was developed. They were converted to 1,3-disubstituted imidazolium salts and used as NHC ligand precursors in the Ni0-catalysed enantioselective [2+2+2] cycloisomerisation... The content of this RSS Feed (c) The Royal Society of Chemistry
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A Porous Porphyrin Organic Polymer (PPOP) for Visible Light Triggered Hydrogen Production ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00879A, Communication Rahul Banerjee, Gargi Mukherjee, Jayshri Thote, Harshitha Barike Aiyappa, Sharath Kandambeth, Subhrashis Banerjee, Kumar Vanka A visible light active porphyrin-based porous organic polymer having high chemical stability and surface area has been synthesized and its ability to influence the photocatalytic activity of large band gap-TiO2... The content of this RSS Feed (c) The Royal Society of Chemistry
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Towards a Fragment-based Approach in gelator design: Halogen effect leading to thixotropic, mouldable and self-healing systems in Aryl-triazolyl Amino Acid-based gelators! ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00980A, Communication Muraleedharan Kannoth Manheri, Bhartendu K Srivastava Simple replacement of a H atom by Br transformed the non-gelating Aryl triazolyl amino acid benzyl ester to a versatile gelator, which formed shape-persistent, self-healing and mouldable gels. The 'bromo-aryl... The content of this RSS Feed (c) The Royal Society of Chemistry
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Multi-functional, thiophenol-based surface chemistry for surface-enhanced Raman spectroscopy ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01577A, Feature Article Fang Sun, Daniel D. Galvan, Priyesh Jain, Qiuming Yu Surface-enhanced Raman spectroscopy (SERS) has been recognized as one of the most sensitive sensing technology and has been used for a variety of chemical, biological and medical applications. Comparing to... The content of this RSS Feed (c) The Royal Society of Chemistry
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Light-Responsive Molecular Containers ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01568B, Feature Article Alejandro Diaz-Moscoso, Pablo Ballester Encapsulation of small molecules into molecular containers able to release them in a controlled way in order to perform specific tasks (e.g. catalysis or drug delivery) constitutes an idea that... The content of this RSS Feed (c) The Royal Society of Chemistry
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KOtBu-catalyzed lithiation of PMDTA and the direct functionalization of bridged alkenes under mild conditions ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02006F, Communication Yuntao Wang, Jialin Liu, Lin Huang, Ranran Zhu, Xueyan Huang, Ross Moir, Jianhui Huang A practical preparation of PMDTALi reagent using super base system under mild conditions has been developed. This PMDTALi base has been demonstrated to be very efficient reagent for the lithiation... The content of this RSS Feed (c) The Royal Society of Chemistry
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A combination strategy of two novel cerium-based nanocomposites affinity probes for selective enrichment of mono- and multi-phosphopeptides in mass spectrometric analysis ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00540G, Communication Xing-yu Long, Zi-jin Zhang, Jia-yuan Li, Dong Sheng, Hong-Zhen Lian This work presents a sequential enrichment protocol, based on two self-designed cerium-based nanocomposites affinity probes, which not only can effectively separate phosphopeptides from non-phosphopeptides but also can further selectively differentiate... The content of this RSS Feed (c) The Royal Society of Chemistry
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Triplet transport in thin films: fundamentals and applications ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00861A, Feature Article Xin Li, Ming Lee Tang Triplet excitions are key players in multi-excitonic processes like singlet fission and triplet-triplet annihilation based photon upconversion, which may be useful in next-generation photovoltaics, photocatalysis and bioimaging. Here, we present... The content of this RSS Feed (c) The Royal Society of Chemistry
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Titanium Dioxide Visible Light Photocatalysis: Surface Association Enables Photocatalysis with Visible Light Irradiation ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01952A, Communication Spencer Paul Pitre, Tehshik Yoon, Tito Scaiano Titanium dioxide (TiO2) is a widely employed and inexpensive photocatalyst, but its use in organic synthesis has been limited by the short-wavelength ultraviolet irradiation typically used. We have discovered that... The content of this RSS Feed (c) The Royal Society of Chemistry
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N-Heterocyclic Carbene-Catalyzed Synthesis of Spirocyclopentene-oxindoles from Bromoenals ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C6CC10304A, Communication Zhao-Fei Zhang, Kun-Quan Chen, Chun-Lin Zhang, Song Ye The N-heterocyclic carbene-catalyzed tandem reaction of bromoenals and oxindoles was developed to give the corresponding chiral spirocyclopentene-oxindoles in good yields with good to high diastero- and enantioselectivies. The content of this RSS Feed (c) The Royal Society of Chemistry
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One-pot Operation Synthesize [small alpha]-Aminophosphonate via Cascade Sequence of Allylamine Isomerization/Hydrophosphonylations ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01391D, Communication Shang-Dong Yang, Liu-Liang Mao, Chen-Chen Li, Qiang Yang, Ming-Xing Cheng A Rh/Ni-catalyzed cascade sequence of allylamine isomerization and hydrophosphonylation for synthesis of [small alpha]-aminophosphonate has been disclosed. This method, not only allows the generation of widespread valuable [small alpha]-aminophosphonate under simple systems... The content of this RSS Feed (c) The Royal Society of Chemistry
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Spontaneous phase transition of hexagonal wurtzite CoO: application to electrochemical and photoelectrochemical water splitting ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00388A, Communication Kyu Yeon Jang, Gisang Park, Kyung Hee Oh, Jong Hyeok Seo, Ki Min Nam Spontaneous phase transition of h-CoO to [small beta]-Co(OH)2 is widely applicable for electrochemical and photoelectrochemical water oxidation reactions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Distinct activation of Cu-MOR for direct oxidation of methane to methanol ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00467B, Communication Younhwa Kim, Tae Yong Kim, Hyunjoo Lee, Jongheop Yi Enhancement of methanol production was achieved by N2O activation in virtue of the facile formation of active sites at elevated temperatures. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of highly efficient azure-to-blue-emitting Zn-Cu-Ga-S quantum dots ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00952F, Communication Bu-Yong Kim, Jong-Hoon Kim, Ki-Heon Lee, Eun-Pyo Jang, Chang-Yeol Han, Jung-Ho Jo, Ho Seong Jang, Heesun Yang Non-Cd, azure-to-blue-emitting Zn-Cu-Ga-S/ZnS quantum dots with exceptional quantum yields of 78-83% are synthesized. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A Ni-Mg-Al layered triple hydroxide-supported Pd catalyst for heterogeneous acceptorless dehydrogenative aromatization ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01182B, Communication Xiongjie Jin, Kento Taniguchi, Kazuya Yamaguchi, Kyoko Nozaki, Noritaka Mizuno In the presence of a Ni-Mg-Al layered triple hydroxide-supported Pd catalyst, the acceptorless dehydrogenative aromatization of a wide range of substrates efficiently proceeded with the liberation of molecular hydrogen. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Pico-HPLC system integrating an equal inner diameter femtopipette into a 900 nm I.D. porous layer open tubular column ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00799J, Communication Ruonan Li, Yunlong Shao, Yanmin Yu, Xiayan Wang, Guangsheng Guo A pico-HPLC method was developed using a bifunctional chromatographic column enabling femtoliter volume sampling and separation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Self-assembly and redox induced phase transfer of gold nanoparticles at a water-propylene carbonate interface ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC09638G, Communication Evgeny Smirnov, Pekka Peljo, Hubert H. Girault Citrate-stabilized gold nanoparticles were found to spontaneously self-assemble into a lustrous film at a bare water-propylene carbonate interface after vigorous shaking, due to the extremely low interfacial tension. The presence of the electron donor, tetrathiafulvalene, in the oil phase, led to the extraction of particles into the organic phase. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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C-Phycocyanin as a tumour-associated macrophage-targeted photosensitiser and a vehicle of phthalocyanine for enhanced photodynamic therapy ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC09541K, Communication Dong-Hua Wan, Bi-Yuan Zheng, Mei-Rong Ke, Ji-Ying Duan, Yun-Quan Zheng, Chih-Kuang Yeh, Jian-Dong Huang C-Phycocyanin was first reported as a tumour-associated macrophage targeted photosensitiser and a vehicle of zinc phthalocyanine for enhanced photodynamic therapy. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A mitochondria-targeted fluorescent probe for imaging endogenous malondialdehyde in HeLa cells and onion tissues ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00512A, Communication Longwei He, Xueling Yang, Kaixin Xu, Weiying Lin A turn-on mitochondria-targeted fluorescent probe (Mito-FMP) was engineered for monitoring endogenous malondialdehyde in HeLa cells and onion tissues. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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UV-light promoted C-H bond activation of benzene and fluorobenzenes by an iridium(I) pincer complex ()
Chem. Commun., 2017, 53,3634-3636 DOI: 10.1039/C6CC09807J, Communication Simone A. Hauser, Jack Emerson-King, Scott Habershon, Adrian B. Chaplin UV irradiation of [Ir(2,6-(PtBu2CH2)2C6H3)(CO)] generates the transient and reactive 14 VE Ir(I) fragment {Ir(2,6-(PtBu2CH2)2C6H3)}, which subsequently undergoes C-H bond activation of benzene and fluorobenzenes. The content of this RSS Feed (c) The Royal Society of Chemistry
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Organometallic chemistry using partially fluorinated benzenes ()
Chem. Commun., 2017, 53,3615-3633 DOI: 10.1039/C6CC09575E, Feature Article Sebastian D. Pike, Mark R. Crimmin, Adrian B. Chaplin Fluorobenzenes, in particular fluorobenzene (FB) and 1,2-difluorobenzene (1,2-DiFB), are versatile solvents for conducting organometallic chemistry and transition-metal-based catalysis. The content of this RSS Feed (c) The Royal Society of Chemistry
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An NIR-emitting lysosome-targeting probe with large Stokes shift via coupling cyanine and excited-state intramolecular proton transfer ()
Chem. Commun., 2017, 53,3697-3700 DOI: 10.1039/C7CC00700K, Communication Dipendra Dahal, Lucas McDonald, Xiaoman Bi, Chathura Abeywickrama, Farai Gombedza, Michael Konopka, Sailaja Paruchuri, Yi Pang A NIR-emitting probe with a large Stokes shift ([capital Delta][small lambda] [approximate] 234 nm) can selectively show lysosome organelles without exhibiting "an alkalinizing effect". The content of this RSS Feed (c) The Royal Society of Chemistry
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Sandwich rare earth complexes simultaneously involving aromatic phthalocyanine and antiaromatic hemiporphyrazine ligands showing a predominantly aromatic nature ()
Chem. Commun., 2017, 53,3765-3768 DOI: 10.1039/C7CC01279A, Communication Wenbo Liu, Houhe Pan, Ziqian Wang, Kang Wang, Dongdong Qi, Jianzhuang Jiang Sandwich rare earth complexes involving aromatic phthalocyanine and antiaromatic hemiporphyrazine ligands were prepared with their predominantly aromatic nature revealed by spectroscopic and theoretical results. The content of this RSS Feed (c) The Royal Society of Chemistry
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Convenient preparation of 4-diazoisochroman-3-imines and 3-subsituted 3,5-dihydroisochromeno[3,4-d][1,2,3]triazoles ()
Chem. Commun., 2017, 53,3769-3772 DOI: 10.1039/C7CC00603A, Communication Anni Ren, Ping Lu, Yanguang Wang 4-Diazoisochroman-3-imines were prepared via the Cu(I)-catalyzed reaction of (2-ethynylphenyl)methanols with sulfonyl azides, and converted to 3,5-dihydroisochromeno[3,4-d][1,2,3]triazoles by reaction with primary amines under catalyst-free conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Rapid access to cyclopentadiene derivatives through gold-catalyzed cycloisomerization of ynamides with cyclopropenes by preferential activation of alkenes over alkynes ()
Chem. Commun., 2017, 53,3745-3748 DOI: 10.1039/C7CC01368J, Communication Xing Cheng, Lei Zhu, Meijun Lin, Jianxin Chen, Xueliang Huang Double bond activation: the current transformation represents a rare example of preferential activation of alkenes over alkynes under gold catalysis. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of yolk-shell mesoporous silica nanoparticles via a facile one-pot approach ()
Chem. Commun., 2017, 53,3761-3764 DOI: 10.1039/C7CC01424D, Communication Jing-Chuan Song, Fei-Fei Xue, Xing-Xing Zhang, Zhong-Yuan Lu, Zhao-Yan Sun A simple and facile one-pot method is proposed for the fabrication of yolk-shell mesoporous silica particles for the first time and the particle size can be well controlled. The content of this RSS Feed (c) The Royal Society of Chemistry
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Room-temperature synthesis of core-shell structured magnetic covalent organic frameworks for efficient enrichment of peptides and simultaneous exclusion of proteins ()
Chem. Commun., 2017, 53,3649-3652 DOI: 10.1039/C7CC00482F, Communication Guo Lin, Chaohong Gao, Qiong Zheng, Zhixian Lei, Huijuan Geng, Zian Lin, Huanghao Yang, Zongwei Cai Core-shell structured Fe3O4@COFs were synthesized and used as a new absorbent for efficient enrichment of peptides and simultaneous exclusion of proteins. The content of this RSS Feed (c) The Royal Society of Chemistry
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Tertiary amine self-catalyzed intramolecular Csp3-H functionalization with in situ generated allenes for the formation of 3-alkenyl indolines ()
Chem. Commun., 2017, 53,3721-3724 DOI: 10.1039/C7CC00005G, Communication Yulei Zhao, Murong Xu, Zhong Zheng, Yang Yuan, Yanzhong Li Tandem Pd(0) catalyzed allenylation/tertiary amine self-catalyzed Csp3-H functionalization reaction for the synthesis of 3-alkenyl indolines. The content of this RSS Feed (c) The Royal Society of Chemistry
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