Chem. Commun.

Copper-Catalyzed Construction of Eight-Membered Rings via Oxidative Ring Expansion and Intermolecular Cyclization Sequence of Indoles with Amidines: Efficient Synthesis of Benzo[1,3,5]triazocin-6(5H)-ones ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02815F, Communication Wen-Bing Cao, Xue-Qiang Chu, Yu Zhou, Ling Yin, Xiao-Ping Xu, Shun-Jun Ji Novel and efficient synthesis of eight-membered nitrogen heterocycles in one pot by copper-catalyzed oxidative ring expansion and intermolecular cyclization sequence of indoles with amidines has been described. This protocol features... The content of this RSS Feed (c) The Royal Society of Chemistry
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Polydopamine Nanocoated Whole-Cell Asymmetric Biocatalyst ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01283G, Communication Li Wang, Zhiyi Hu, Xiao-Yu Yang, Bo-Bo Zhang, Wei Geng, Gustaaf Van Tendeloo, Bao-Lian Su Our whole-cell biocatalyst with a polydopamine nanocoating shows high catalytic activity (5 times better productivity than the native cell) and reusability (84% of the initial yield after 5 batches, 8... The content of this RSS Feed (c) The Royal Society of Chemistry
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A square-planar nickel dithiolate complex as an efficient molecular catalyst for the electro- and photoreduction of protons ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01942D, Communication Geng-Geng Luo, Yong-Heng Wang, Jianghai Wang, Jihuai Wu, Ruibo Wu A square-planar nickel(II) dithiolate complex is an active molecular catalyst for both photoreduction of protons from water with a turnover number (> 1500) and electroreduction of protons from weakly acidic... The content of this RSS Feed (c) The Royal Society of Chemistry
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Investigation of a new "N2S2O2" chelating agent with high Po(IV) affinity ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03198J, Communication David Deniaud, Sebastien G Gouin, Gilles Montavon, Roxane Peumery, Thibaut Chalopin, Marcel Mokili, Cyrille Alliot, Julie Champion, Emy Andre-Joyaux, Ali Younes A water-soluble "N2S2O2" complexing agent was designed for polonium (IV) decorporation. The bifunctional ligand showed outstanding Po(IV) complexing abilities, with a conditional stability constant three orders of magnitude higher than... The content of this RSS Feed (c) The Royal Society of Chemistry
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A novel singlet oxygen involved peroxymonosulfate activation mechanism for degradation of ofloxacin and phenol in water ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02820B, Communication Xi-Ke Tian, Panpan Gao, Yulun Nie, chao Yang, Zhao-xin Zhou, Yong Li, Yanixn Wang This study proposed a new and previously unconsidered reaction mechanism in activation of peroxymonosulfate. We report singlet oxygen (1O2) rather than [round bullet, filled]OH or SO4[round bullet, filled]- was the dominant reactive oxygen species... The content of this RSS Feed (c) The Royal Society of Chemistry
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Stereospecific control of the helical orientation of indolocarbazole-pyridine hybrid foldamers by rational modification of terminal chiral appendages ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03552G, Communication Junyoung Kim, Hae-Geun Jeon, Philjae Kang, Kyu-Sung Jeong The helical handedness excess of an indolocarbazole-pyridine hybrid oligomer capable of folding into a stable helical structure was achieved up to 96% by rational modification of terminal chiral residues The content of this RSS Feed (c) The Royal Society of Chemistry
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Controlled synthesis of pillar[6]arene-based hexagonal cylindrical structures on an electrode surface by electrochemical oxidation ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02969A, Communication Chiaki Tsuneishi, Yuki Koizumi, Ryuta Sueto, Hiroki Nishiyama, Kazuma Yasuhara, YAMAGISHI Tadaaki, Tomoki Ogoshi, Ikuyoshi Tomita, Shinsuke Inagi Electrochemical oxidation of pillar[6]arene containing six hydroquinones resulted in the formation of hexagonal cylindrical structures on an electrode surface driven by charge transfer interaction. The electrochemical approach successfully controlled the... The content of this RSS Feed (c) The Royal Society of Chemistry
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Correction: Isoprene chain shuttling polymerisation between cis and trans regulating catalysts: straightforward access to a new material ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC90207G, Correction Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Y. Phuphuak, F. Bonnet, G. Stoclet, M. Bria, P. Zinck To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalytic Asymmetric [2+2] Cycloaddition between Quinones and Fulvenes and a Subsequent Stereoselective Isomerization to 2,3-Dihydrobenzofurans ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03211K, Communication Haifeng Zheng, Chaoran Xu, Yan Wang, Tengfei Kang, Xiaohua Liu, Lili Lin, Xiaoming Feng The first catalytic enantioselective [2+2] cycloaddition between quinones and fulvenes was addressed by the use of a chiral copper(II) complex catalyst. The transformation afforded a series of enantiomerically enriched [6,4,5]-tricyclic... The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of CaCO3 nano- and micro- particles by dry ice carbonation ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01420A, Communication Fearghal Donnelly, Finn Purcell-Milton, Vincent Framont, Olan Cleary, Peter Dunne, Yurii Gun'ko Here we report a new low temperature dry ice carbonation approach for synthesis of carbonate-based nano- and micro- particulate materials, which enable the preparation of monodispersed calcium carbonate nanoparticles and... The content of this RSS Feed (c) The Royal Society of Chemistry
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Direct N-Acylation of Sulfoximines with Carboxylic Acids Catalyzed by the B3NO2 Heterocycle ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03386A, Communication Hidetoshi Noda, Yasuko Asada, Masakatsu Shibasaki, Naoya Kumagai In contrast to recent significant progress in the development of catalytic methodologies for nitrogen acylations, syntheses of N-acyl sulfoximines have been slow to evolve, and still largely rely on the... The content of this RSS Feed (c) The Royal Society of Chemistry
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Hydrazone switches and things in between ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02879B, Feature Article Ivan Aprahamian This feature article surveys the various ways by which a structurally simple hydrazone can be used in accessing different functional materials, mainly photo/chemically activated switches, fluorophores and sensors. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A Facile Approach toward 1,2-Diazabenzo[ghi]perylene Derivatives: Structures and Electronic Properties ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03362A, Communication haipeng wei, Tiancheng Qiu, Xiaobo Huang, Jun Zhou, Jing Guo, Chuanling Jiang, Sheng-lian Luo, Zebing Zeng, Jishan Wu A new type of pyridazine fused aromatics, 1,2-diazabenzo[ghi]perylenes, were conveniently synthesized from 2,7-dihydroxynaphthalene by intermolecular oxidative coupling followed by condensation reaction. These new compounds were fully characterized by X-ray crystallographic... The content of this RSS Feed (c) The Royal Society of Chemistry
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Polymer and graphene layer to increase dye regeneration and suppress back electron transfer in dye sensitized solar cells ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03276E, Communication V Sudhakar Nesan, ArulKashmir Arulraj, Kothandam Krishnamoorthy Recombination of electron residing in either dye or in the TiO2 with the hole in the electrolyte and the regeneration of dyes are two key events in energy conversion in... The content of this RSS Feed (c) The Royal Society of Chemistry
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Uniform distribution of post-synthetic linker exchange in metal-organic frameworks revealed by Rutherford Backscattering Spectrometry ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02631E, Communication Ulrike Fluch, Valentina Paneta, Daniel Primetzhofer, Sascha Ott Rutherford Backscattering Spectrometry (RBS) has been used for the first time to study post-synthetic linker exchange (PSE) in metal organic frameworks. RBS is a non-invasive method to quantify the amount... The content of this RSS Feed (c) The Royal Society of Chemistry
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Segmented Flow Platform for On-Demand Medicinal Chemistry and Compound Synthesis in Oscillating Droplets ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03584E, Communication Ye-Jin Hwang, Connor W Coley, Milad Abolhasani, Andreas Marzinzik, Guido Koch, Carsten Spanka, Hansjoerg Lehmann, Klavs F Jensen We report an automated flow chemistry platform that can efficiently perform a wide range of chemistries, including single/multi-phase and single/multi-step, with a reaction volume of just 14 uL. The breadth... The content of this RSS Feed (c) The Royal Society of Chemistry
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Fe2O3 nanoparticles anchored on 2D kaolinite with enhanced antibacterial activity ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02905E, Communication Mei Long, Yi Zhang, Zhan Shu, Aidong Tang, Jing Ouyang, Huaming Yang Fe2O3 nanoparticles with different dispersion states on the surface of modified kaolinite were controlled for enhancing antibacterial activity. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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On surface O-glycosylation by catalytic microcontact printing ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02505J, Communication Moritz Buhl, Serena Traboni, Martin Korsgen, Sebastian Lamping, Heinrich F. Arlinghaus, Bart Jan Ravoo Carbohydrate microarrays are made by microcontact printing of glycosyl donors on hydroxyl terminated substrates. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Copper(I)-mediated carboamination of vinyl azides by aryldiazonium salts: synthesis of N2-substituted 1,2,3-triazoles ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02391J, Communication Zhenhua Liu, Huimin Ji, Wen Gao, Guangyu Zhu, Lili Tong, Fengcai Lei, Bo Tang Copper(I)-mediated carboamination reaction of vinyl azides with sole aryldiazonium salt for N2-substituted 1,2,3-triazoles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Iptycenes with an acridinone motif developed through [4+2] cycloaddition of tethered naphthalene and iminoquinone via a radical reaction ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03030D, Communication Selvam Raju, Pratheepkumar Annamalai, Pei-Ling Chen, Yi-Hung Liu, Shih-Ching Chuang A new class of iptycenes was developed by combining 2-(naphthalen-1-yl)anilines and p-benzoquinones through copper(II)-mediated radical cyclisation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Rh(III)-Catalyzed bilateral cyclization of aldehydes with nitrosos toward unsymmetrical acridines proceeding with C-H functionalization enabled by a transient directing group ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03006A, Communication Weiming Hu, Qingheng Zheng, Song Sun, Jiang Cheng A Rh(III)-catalyzed bilateral cyclization was developed for the efficient construction of acridines proceeding with C-H functionalization by in situ formation and removal of a transient directing group. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A deciduous directing group approach for the addition of aryl and vinyl nucleophiles to maleimides ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02392H, Communication Kiran R. Bettadapur, Veeranjaneyulu Lanke, Kandikere Ramaiah Prabhu A Rh(III)-catalyzed C-H activation followed by conjugate addition to maleimides, using carboxylic acid as a traceless/deciduous directing group, to formally furnish a Csp2-Csp3 bond is presented. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Strong chiroptical activity from achiral gold nanorods assembled with proteins ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03089D, Communication Hideyuki Shinmori, Chihiro Mochizuki The optical activity of side-by-side gold nanorod assembly induced by interaction with proteins has the highest anisotropy factor in colloidal solution. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Palladium-catalyzed oxidative carbonylation of N-aryl enamino esters with CO and alcohols: synthesis of N-aryl aminomethylenemalonates ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02852K, Communication Ming Chen, Le Yu, Zhi-Hui Ren, Yao-Yu Wang, Zheng-Hui Guan A novel palladium-catalyzed oxidative carbonylation of tri-substituted alkenes with CO and alcohols to synthesize N-aryl aminomethylenemalonates has been developed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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NiCo2O4@Ni-Co-Ci core-shell nanowires array as an efficient electrocatalyst for water oxidation at near-neutral pH ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03146G, Communication Ruixiang Ge, Min Ma, Xiang Ren, Fengli Qu, Zhiang Liu, Gu Du, Abdullah M. Asiri, Liang Chen, Baozhan Zheng, Xuping Sun It is attractive but still remains challenging to develop efficient water oxidation electrocatalysts working in carbonate (Ci) electrolyte. In this communication, we report that Ni-Co-Ci layer can be developed on... The content of this RSS Feed (c) The Royal Society of Chemistry
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One-pot Preparation of a Novel CO-Releasing Material based on a CO-Releasing Molecule@Metal-Organic Framework System ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03605A, Communication Francisco Jesus Carmona, Sara Rojas, Carlos Romao, Jorge A R Navarro, Elisa Barea, Carmen R Maldonado A novel CO releasing material has been prepared by a one-pot synthesis-encapsulation strategy using the hierarchical metal organic framework [Zn2(dhtp)] (dhtp = 2,5-dihydroxyterephtalate) as a host of the photoactivable molybdenum... The content of this RSS Feed (c) The Royal Society of Chemistry
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Dual Gold/Photoredox-Catalyzed Bis-Arylative Cyclization of Chiral Homopropargyl Sulfonamides with Diazonium Salts: Rapid Access to Enantioenriched 2,3-Dihydropyrroles ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03262E, Communication Ze-Shu Wang, Tong-De Tan, Cai-Ming Wang, Ding-Qiang Yuan, Te Zhang, pengfei zhu, Chunyin Zhu, Jin-Mei Zhou, Long-Wu Ye A novel dual gold/photoredox-catalyzed bis-arylative cyclization of chiral homopropargyl sulfonamides with diazonium salts has been developed, allowing the facile synthesis of various enantioenriched 2,3-dihydropyrroles in generally moderate to good yields... The content of this RSS Feed (c) The Royal Society of Chemistry
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First synthesis of Bi self-doped Bi2MoO6-Bi2Mo3O12 composite and its excellent photocatalytic performance for selective oxidation of aromatic alkanes under visible light irradiation ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02890C, Communication Lu-Na Song, Lang Chen, Jie He, Peng Chen, Huang-Kai Zeng, Chak-tong Au, Shuang-Feng Yin We report the synthesis of Bi self-doped Bi2MoO6-Bi2Mo3O12 composites with heterostructures by a one-step method using Bi3.64Mo0.36O6.55 as precursor. Among them, Bi2.1MoO6-Bi2.1Mo3O12 shows excellent selectivity as well as recyclability for... The content of this RSS Feed (c) The Royal Society of Chemistry
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Photo-Clickable MicroRNA for In-Situ Fluorescence Labeling and Imaging of MicroRNA in Living Cells ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03328A, Communication Lei Huang, Yingjie Chen, Lei Chen, Xiao Xiao, Xingxing Wang, Jinbo Li, Yan Zhang A photo-clickable microRNA whose fluorescence was able to be turned on by mild light irradiation was constructed and the in-situ fluorescence turn-on of the photo-clickable microRNA-122 in living cells was... The content of this RSS Feed (c) The Royal Society of Chemistry
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A Metal-Organic Framework as a Flask: Photophysics of Confined Chromophores with a Benzylidene Imidazolinone Core ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02253K, Communication Ekaterina A. Dolgopolova, Thomas Moore, Otega Ejegbavwo, Perry J Pellechia, Mark D. Smith, Natalia Shustova Photophysics and dynamics of chromophores with a benzylidene imidazolinone core, responsible for emission of green fluorescent protein variants, were studied as a function of host topology by three approaches. Coordinative,... The content of this RSS Feed (c) The Royal Society of Chemistry
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Ultrafast Synthesis of High-Silica Erionite Zeolite with Improved Hydrothermal Stability ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03166A, Communication Jie Zhu, Zhendong Liu, Kenta Iyoki, Anand Chokkalingam, Kaname Yoshida, Yukichi Sasaki, Sohei Sukenaga, Mariko Ando, Hiroyuki Shibata, Toru Wakihara, Tatsuya Okubo High-silica erionite (ERI) zeolite is conventionally synthesised via a so-called charge density mismatch (CDM) approach, and a typical synthesis takes several days to complete. We herein demonstrate an ultrafast route... The content of this RSS Feed (c) The Royal Society of Chemistry
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Rational Catalyst Design of CO oxidation Using the Bonding Contribution Equation ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02900D, Communication Ziyun Wang, Peijun Hu Rational design of heterogeneous catalysts is an important yet challenging task. We show how the bonding contribution equation, a quantitative relation between surface structure and adsorption energy, can be utilized... The content of this RSS Feed (c) The Royal Society of Chemistry
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Coordination strategy induced selective C-H amination of 8-animoquinolines ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02601C, Communication Hong Yi, Hong Chen, Changliang Bian, Zilu Tang, Atul K. Singh, Xiaotian Qi, Xiaoyu Yue, Yu Lan, Jyh-Fu Lee, Aiwen Lei In this work, we broke through the directing function of the amide group. Instead, the coordination interaction between metal and "directing-group" played the role to enhance the reactivity of substrate.... The content of this RSS Feed (c) The Royal Society of Chemistry
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Supramolecular hydrogels for environmental remediation: G4-quartet gels that selectively absorb anionic dyes from water ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03118A, Communication Taylor N. Plank, Luke P. Skala, Jeffery T. Davis Binary mixtures of guanosine and 8-aminoguanosine form stable, transparent hydrogels with Ba2+ that selectively bind anionic dyes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A more critical role for silicon in the catalytic Staudinger amidation: silanes as non-innocent reductants ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03076B, Communication Keith G. Andrews, Ross M. Denton We demonstrate that in situ-generated silyl ester intermediates are key mediators of the catalytic, traceless Staudinger amidation reaction. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Galvanic replacement reaction: recent developments for engineering metal nanostructures towards catalytic applications ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02352A, Feature Article Anderson G. M. da Silva, Thenner S. Rodrigues, Sarah J. Haigh, Pedro H. C. Camargo Recent developments to achieve further physicochemical control in metallic nanomaterials by galvanic replacement are discussed towards applications in catalysis. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A novel single-fluorophore-based ratiometric fluorescent probe for direct detection of isocyanates in air ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02269G, Communication Zhenzhong Gao, Baichuan Han, Kai Chen, Jin Sun, Xianfeng Hou Airborne isocyanates were conveniently detected by a test paper loaded with a novel single fluorophore ratiometric fluorescent probe. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A label-free ratiometric electrochemical DNA sensor for monitoring intracellular redox homeostasis ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03239K, Communication Xinping Liu, Zhengqing Yan, Yuhuan Sun, Jinsong Ren, Xiaogang Qu A label-free ratiometric electrochemical determination of GSH by DNA metallization-mediated HCR amplification is reported. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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5-Benzylidene-4-oxazolidinones potently inhibit biofilm formation in Methicillin-resistant Staphylococcus aureus ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03626D, Communication Grant A. Edwards, Nataliia V. Shymanska, Joshua G. Pierce Investigation into the biological function of 5-benzylidene-4-oxazolidinones revealed dose-dependent inhibition of biofilm formation in Methicillin-resistant S. aureus (MRSA). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Room temperature solvent-free reduction of SiCl4 to nano-Si for high-performance Li-ion batteries ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02857A, Communication Zhiliang Liu, Xinghua Chang, Bingxue Sun, Sungjin Yang, Jie Zheng, Xingguo Li A highly efficient method to prepare Si nanoparticles for high-performance lithium ion batteries: direct reduction of SiCl4 using Na metal by mechanical milling at room temperature without using any organic solvents. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of biotin-labelled core glycans of GPI anchors and their application in the study of GPI interaction with pore-forming bacterial toxins ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03056H, Communication Jian Gao, Zhifang Zhou, Jiatong Guo, Zhongwu Guo A concise and convergent synthesis of biotin-GPI glycan conjugates that were utilized to explore GPI-bacterial toxin interaction. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Novel Ag-doped glass frits for high-efficiency crystalline silicon solar cells ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02838E, Communication Sheng Yuan, Yongji Chen, Zongwei Mei, Ming-Jian Zhang, Zhou Gao, Xingbo Wang, Xing Jiang, Feng Pan Novel Ag-doped glass frits remarkably improved the interface between bulk Ag and n-Si, which greatly reduced the contact resistance of c-Si solar cells. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Hemin-catalyzed sulfonium ylide formation and subsequently reactant-controlled chemoselective rearrangements ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02484C, Communication Xiaofei Xu, Chang Li, Mingteng Xiong, Zhihao Tao, Yuanjiang Pan The Stevens and Sommelet-Hauser rearrangements can be controlled by the electronic property of the substituents on the benzyl group together with solvent effects. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Non-stoichiometric MoO3-x Quantum Dots as Light-harvesting Material for Interfacial Water Evaporation ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01427A, Communication Dandan Ding, Weicheng Huang, Chuanqi Song, Mei Yan, Chongshen Guo, Shaoqin Liu We herein present oxygen-deficient molybdenum oxide quantum dots (MoO3-x QDs), which possess matched-absorption-spectrum to the solar light in both of visible and near infrared regions, for the proof-of-concept of interfacial... The content of this RSS Feed (c) The Royal Society of Chemistry
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Formation of (PNP)Rh complexes containing covalent rhodium-zinc bonds in studies of potential Rh-catalysed Negishi coupling ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02707A, Communication Christopher J. Pell, Wei-Chun Shih, Sylvain Gatard, Oleg V Ozerov While investigating rhodium-catalyzed Negishi coupling, it was observed that the (PNP)Rh fragment readily inserted into zinc-carbon bonds to form isolable molecules with covalent rhodium-zinc bonds. The content of this RSS Feed (c) The Royal Society of Chemistry
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Three Dimensional Porous Hofmann Clathrate [MIIPtII(CN)4][infinity] (M = Co, Ni) Synthesized by Using Postsynthetic Reductive Elimination ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01766A, Communication Takuro Okamura, Bin Wu, Hiroaki Iguchi, Brian K. Breedlove, Masahiro Yamashita, Wataru Kosaka, Hitoshi Miyasaka, Shinya Takaishi We synthesized cyano-bridged three dimensional metal-organic frameworks [MII(H2O)2PtIV(CN)4Br2][infinity][middle dot]n(H2O) (1: M = Co, 2: M = Ni) with an NbO type topology. Although 1 and 2 have no accessible pores, these... The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of well-defined pentagonally prismatic silver nanoparticles: role of bromide in (100) stabilization and facet preservation ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02594G, Communication Vladimir Kitaev, Tomendro Subedi We have demonstrated effect of bromide for exclusive (100) stabilization that enabled preparation of pentagonal prisms (AgPPNPs), a newly developed nanoscale shape. High-quality precursors and exact amount of bromide were... The content of this RSS Feed (c) The Royal Society of Chemistry
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Copper-catalyzed acyltrifluoromethylation of alkenes: rapid access to trifluoroethyl indanones and related compounds ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02537H, Communication Zhicheng Liu, Yihui Bai, Jian Zhang, Yongqi Yu, Ze Tan, Gangguo Zhu Copper-catalyzed acyltrifluoromethylation of alkenes has been developed for the first time, producing trifluoroethyl indanones and related cyclic ketones in promising yields with excellent diastereoselectivity. The fast incorporation of CF3 and... The content of this RSS Feed (c) The Royal Society of Chemistry
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Gold-catalyzed diastereoselective domino dearomatization/ipso-cyclization/aza-Michael sequence: A facile access to diverse fused azaspiro tetracyclic scaffolds ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03152A, Communication Yi He, Zhenghua Li, Guilong Tian, Liangliang Song, Luc Van Meervelt, Erik V�lery Van der Eycken A facile and diversity-oriented access to complex tetracyclic benzo[e]pyrrolo[2,3-c]indole-2,4,7(5H)-triones through a post-Ugi gold(I)-catalyzed domino dearomatization/ipso-cyclization/aza-Michael sequence is elaborated. This process furnishes tetracyclic scaffolds in good yields from readily available precursors... The content of this RSS Feed (c) The Royal Society of Chemistry
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Iron-Catalyzed C-H/N-H Activation by Triazole Guidance: Versatile Alkyne Annulation ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03376A, Communication Gianpiero Cera, Tobias Haven, Lutz Ackermann Iron-catalyzed C-H/N-H functionalizations were achieved by the aid of modular triazole amides. The alkyne annulation allowed for the expedient synthesis of valuable isoquinolone scaffolds with high levels of chemo-, site-... The content of this RSS Feed (c) The Royal Society of Chemistry
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Coupling between the photo-excited cyclic [small pi] system and the 4f electronic system in a lanthanide single molecule magnet ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02960H, Communication K. Kizaki, H. Ozawa, T. Kobayashi, R. Matsuoka, Y. Sakaguchi, A. Fuyuhiro, T. Fukuda, N. Ishikawa Does the angular momentum of the 4f system couple with a photo-induced orbital angular momentum L in the cyclic [small pi] system in a lanthanide SMM? To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Chimeric design of heterospin 2p-3d, 2p-4f, and 2p-3d-4f complexes using a novel family of paramagnetic dissymmetric compartmental ligands ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03236F, Communication Marius Andruh, Andrei Patrascu, Sergiu Calancea, Matteo Briganti, Stephane Serge Yves Gerome Soriano, Augustin M Madalan, Rafael A. A. Cassaro, Andrea Caneschi, Federico Totti, Maria G. F. Vaz End-off bicompartmental ligands bearing a nitronyl-nitroxide arm have been designed for synthesizing various heterospin molecular systems. These ligands can selectively interact with 3d and 4f metal ions, leading to 2p-4f,... The content of this RSS Feed (c) The Royal Society of Chemistry
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Insights into the mechanism of electrocatalysis of oxygen reduction reaction by a porphyrinic metal organic framework ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02113E, Communication Mathieu Lions, Jean-Bernard Tomasino, Raphael Chattot, Brain Abeykoon, Nathalie Guillou, Thomas Devic, Aude Demessence, Luis Cardenas, Frederic Maillard, Alexandra Fateeva Metal Organic Frameworks (MOFs) have been recently proposed as promising electrocatalysts, yet the exact nature of the mechanisms in play has not been deeply adressed. By comparing the electrocatalytic activity... The content of this RSS Feed (c) The Royal Society of Chemistry
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Pillar[n]arene-based Supramolecular Organic Frameworks with High Hydrocarbon Storage and Selectivity ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03638H, Communication Li-Li Tan, Youlong Zhu, Hai Long, Yinghua Jin, Wei Zhang, Ying-Wei Yang We report the high hydrocarbon storage capacity and adsorption selectivity of two low-density pillar[n]arene-based SOFs. Our study would open new perspectives in the development of pillar[n]arene-based SOFs and study of... The content of this RSS Feed (c) The Royal Society of Chemistry
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A Wash-Free SNAP-tag Fluorogenic Probe based on Additive Effects of Quencher Release and Environmental Sensitivity ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01483J, Communication Zhaochao Xu, Shuang Leng, Qinglong Qiao, Lu Miao, Wuguo Deng, JN Cui A 1,8-naphthalimide-derived fluorogenic probe was reportd to label SNAP-tag fusion proteins in living cells. The probe can rapidly label SNAP-tag and exhibit fluorescence increase of 36-fold due to the additive... The content of this RSS Feed (c) The Royal Society of Chemistry
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Relaxation-encoded NMR experiments for mixture analysis: REST and beer ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03150E, Communication Guilherme Dal Poggetto, LAURA CASTANAR ACEDO, Ralph W. Adams, Gareth Morris, Mathias Nilsson A new family of NMR experiments for mixture analysis (Relaxation-Encoded Selective TOCSY, REST) allows the extraction of component spectra from mixtures. It uses isotropic mixing to label whole spin systems... The content of this RSS Feed (c) The Royal Society of Chemistry
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A new approach to surface activation of porous nanomaterials using non-thermal helium atmospheric pressure plasma jet treatment ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02927F, Communication Farkfun Duriyasart, Masataka OHTANI, Jun-Seok Oh, Akimitsu Hatta, Kazuya Kobiro Non-thermal helium atmospheric pressure plasma jet treatment is applied to the surface activation of porous TiO2 nanoparticle assemblies. Treatment conditions such as the working distance of plasma discharge, helium gas... The content of this RSS Feed (c) The Royal Society of Chemistry
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Towards Seamlessly-Integrated Textile Electronics: [space]Methods to Coat Fabrics and Fibers with Conducting Polymers for Electronic Applications ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02592K, Feature Article Linden Allison, Steven Hoxie, Trisha L. Andrew Traditional textile materials can be transformed into functional electronic components upon being dyed or coated with films of intrinsically conducting polymers, such as poly(aniline), poly(pyrrole) and poly(3,4-ethylenedioxythiophene). A variety of... The content of this RSS Feed (c) The Royal Society of Chemistry
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Thermo-electrochemical cells for waste heat harvesting - progress and perspectives ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02160G, Feature Article M. F. Dupont, D. R. MacFarlane, J. M. Pringle This feature article provides an overview of recent advances in the development of thermo-electrochemical cells for thermal energy harvesting applications. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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The Strategies for Identification and Quantification of SUMOylation ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00901A, Feature Article Yan Zhang, Yueying Li, Bo Tang, Chun-yang Zhang SUMOylation is a post-translational modification that plays critical roles in multitude cellular processes including transcription, cellular localization, DNA repair and cell cycle progression. Similar to ubiquitin, the small ubiquitin-like modifiers... The content of this RSS Feed (c) The Royal Society of Chemistry
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Dielectrophoretic assembly of liquid-phase-exfoliated TiS3 nanoribbons for photodetecting applications ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01845B, Communication R. Frisenda, E. Giovanelli, P. Mishra, P. Gant, E. Flores, C. Sanchez, J. R. Ares, D. Perez de Lara, I. J. Ferrer, E. M. Perez, A. Castellanos-Gomez Liquid-phase exfoliation produces colloidal two-dimensional materials that can be assembled by dielectrophoresis to fabricate optoelectronic devices. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Size-dependent conformational change in halogen-[small pi] interaction: from benzene to graphene ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03116E, Communication Dong Yeon Kim, Jenica Marie L. Madridejos, Miran Ha, Jun-Hyeong Kim, David ChangMo Yang, Chunggi Baig, Kwang S. Kim Diatomic halogen molecules (Cl2, Br2) favor the stacked conformation on graphene, while they favor the edge-to-face conformation on benzene. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Lanthanoplatins: emissive Eu(III) and Tb(III) complexes staining nucleoli targeted through Pt-DNA crosslinking ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02047C, Communication Khushbu Singh, Swati Singh, Payal Srivastava, Sri Sivakumar, Ashis K. Patra Luminescent photostable heterometallic LnPt2 complexes were designed for their preferential nucleoli staining through formation of Pt-DNA cross-links observed through fluorescence microscopy. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Enhanced catalytic performance of a PdO catalyst prepared via a two-step method of in situ reduction-oxidation ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01997A, Communication Wei Hu, Guang-Xia Li, Jian-Jun Chen, Fu-Jin Huang, Yang Wu, Shan-Dong Yuan, Lin Zhong, Yao-Qiang Chen A Pd-based catalyst prepared by a controllable two-step method of in situ reduction-oxidation showed significantly enhanced activity and selectivity. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Selective conversion of coconut oil to fatty alcohols in methanol over a hydrothermally prepared Cu/SiO2 catalyst without extraneous hydrogen ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01126A, Communication Liubi Wu, Lulu Li, Bolong Li, Chen Zhao A novel one-pot approach selects a hydrothermally synthesized Cu/SiO2 catalyst (consisting of Cu2O[middle dot]SiO2 and Cu0 surface species) to convert of coconut oil to fatty alcohols at 240 [degree]C in methanol without hydrogen, attaining 85% conversion and 100% selectivity. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Development of Ir and La-codoped BaTa2O6 photocatalysts using visible light up to 640 nm as an H2-evolving photocatalyst for Z-schematic water splitting ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02687K, Communication Akihide Iwase, Akihiko Kudo A novel Z-scheme system was constructed using a newly developed Ir and La-codoped BaTa2O6 photocatalyst for H2 evolution. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A ruthenium tetrazole complex-based high efficiency near infrared light electrochemical cell ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02878D, Communication Hashem Shahroosvand, Saeid Abaspour, Babak Pashaei, Eros Radicchi, Filippo De Angelis, Francesco Bonaccorso We report on the exploitation of a new tetrazole-substituted 1,10-phenanthroline and a 2,2[prime or minute]-bipyridine (bpy) ancillary ligand modified with an electron-donating group in cationic ruthenium complexes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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DNA-friendly Cu(II)/TEMPO-catalyzed 5-hydroxymethylcytosine-specific oxidation ()
Chem. Commun., 2017, 53,5756-5759 DOI: 10.1039/C7CC02814H, Communication Taku Matsushita, Yuya Moriyama, Genta Nagae, Hiroyuki Aburatani, Akimitsu Okamoto An allyl alcohol-selective oxidant Cu(II)/TEMPO complex makes it possible to specifically detect 5-hydroxymethylcytosine in the human brain genome using a DNA sequence analyzer after a very easy pretreatment. The content of this RSS Feed (c) The Royal Society of Chemistry
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A programmed terminal extension strategy to light up multiple beacons for DNA and cellular telomerase detection ()
Chem. Commun., 2017, 53,5752-5755 DOI: 10.1039/C7CC02515G, Communication Yucai Yang, Chao Li, Xiaolu Hu, Yi Yang, Yongmei Yin, Zhaoxia Wang A new method to detect DNA and cellular telomerase is developed using an enzyme-triggered terminal extension strategy. The content of this RSS Feed (c) The Royal Society of Chemistry
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Binding groups for highly ordered SAM formation: carboxylic versus thiol ()
Chem. Commun., 2017, 53,5748-5751 DOI: 10.1039/C7CC01939D, Communication A. Krzykawska, J. Ossowski, T. Zaba, P. Cyganik Carboxylic molecules can form in a short time very stable and much better ordered SAMs than thiol analogues. The content of this RSS Feed (c) The Royal Society of Chemistry
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Copper-catalyzed remote ([small delta]) C(sp3)-H bond amination: a practical strategy to construct pyrrolidine derivatives ()
Chem. Commun., 2017, 53,5744-5747 DOI: 10.1039/C7CC02624B, Communication Dongmei Meng, Yongzhen Tang, Junfa Wei, Xianying Shi, Mingyu Yang This work reported a copper-catalyzed remote C(sp3)-H bond amination of primary, secondary and tertiary C-H bonds, which converted acyclic amines to pyrrolidine derivatives. The content of this RSS Feed (c) The Royal Society of Chemistry
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A near-room-temperature organic-inorganic hybrid ferroelectric: [C6H5CH2CH2NH3]2[CdI4] ()
Chem. Commun., 2017, 53,5764-5766 DOI: 10.1039/C7CC02408H, Communication Bo Huang, Lin-Ying Sun, Sha-Sha Wang, Jian-Yu Zhang, Cheng-Min Ji, Jun-Hua Luo, Wei-Xiong Zhang, Xiao-Ming Chen The features of synchronously switchable dielectric constant, SHG, and pyroelectric current provide a promising multifunctional switching material applied in the field of electrical/optical switches and sensors at near room temperature. The content of this RSS Feed (c) The Royal Society of Chemistry
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Alkynyl sulfoxides as [small alpha]-sulfinyl carbene equivalents: gold-catalysed oxidative cyclopropanation ()
Chem. Commun., 2017, 53,5733-5736 DOI: 10.1039/C7CC02244A, Communication Matthew J. Barrett, Ghulam F. Khan, Paul W. Davies, Richard S. Grainger Gold catalysed oxidation of alkynyl sulfoxides provides access to a desirable [small alpha]-sulfinyl metal carbene reactivity profile that is inaccessible using diazo chemistry. The content of this RSS Feed (c) The Royal Society of Chemistry
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An example of unusual pyridine donor Schiff base uranyl (UO22+) complexes ()
Chem. Commun., 2017, 53,5718-5720 DOI: 10.1039/C7CC02747H, Communication E. E. Hardy, K. M. Wyss, M. A. Eddy, A. E. V. Gorden New pyridyl Schiff base ligands with pentadentate coordination environments were designed to fully occupy the equatorial plane of uranyl (UO22+). The content of this RSS Feed (c) The Royal Society of Chemistry
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A phenazine-barbituric acid based colorimetric and ratiometric near-infrared fluorescent probe for sensitively differentiating biothiols and its application in TiO2 sensor devices ()
Chem. Commun., 2017, 53,5760-5763 DOI: 10.1039/C7CC01925D, Communication Xiao Zhang, Yongchao Yan, Yandi Hang, Jian Wang, Jianli Hua, He Tian A colorimetric and ratiometric NIR fluorescent probe based on phenazine-barbituric acid was developed for biothiols and applied to detect in cells and construct TiO2 sensor devices. The content of this RSS Feed (c) The Royal Society of Chemistry
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Analysis of the electron transfer properties of carbon quantum dots on gold nanorod surfaces via plasmonic resonance scattering spectroscopy ()
Chem. Commun., 2017, 53,5729-5732 DOI: 10.1039/C7CC01464C, Communication Yue Cao, Hao Zhou, Ruo-Can Qian, Jingquan Liu, Yi-Lun Ying, Yi-Tao Long Colloidal nanocomposites consisting of carbon quantum dots and gold nanorods were fabricated on ITO electrode surfaces via electrostatic interactions. The structural, electrochemical and scattering properties of the hybrid nanomaterials were systematically investigated. The content of this RSS Feed (c) The Royal Society of Chemistry
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Efficient purification of arsenic-contaminated water using amyloid-carbon hybrid membranes ()
Chem. Commun., 2017, 53,5714-5717 DOI: 10.1039/C7CC00406K, Communication Sreenath Bolisetty, Noemi Reinhold, Christophe Zeder, Monica N. Orozco, Raffaele Mezzenga We show the purification of arsenic-contaminated water using amyloid fibril-based membranes, which adsorb both the arsenate (+5) and arsenite (+3) oxidation forms at efficiencies of [similar]99%. The content of this RSS Feed (c) The Royal Society of Chemistry
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18F-Fluoroform: a 18F-trifluoromethylating agent for the synthesis of SCF218F-aromatic derivatives ()
Chem. Commun., 2017, 53,5706-5709 DOI: 10.1039/C7CC02652H, Communication Elodie Carbonnel, Tatiana Besset, Thomas Poisson, Daniel Labar, Xavier Pannecoucke, Philippe Jubault A new protocol for the synthesis of SCF218F-aromatic derivatives from 18F-fluoroform is described. The content of this RSS Feed (c) The Royal Society of Chemistry
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Integrating natural biomass electro-oxidation and hydrogen evolution: using a porous Fe-doped CoP nanosheet array as a bifunctional catalyst ()
Chem. Commun., 2017, 53,5710-5713 DOI: 10.1039/C7CC01680H, Communication Shuai Hao, Libin Yang, Danni Liu, Rongmei Kong, Gu Du, Abdullah M. Asiri, Yingchun Yang, Xuping Sun An Fe-doped CoP nanosheet array acts as an efficient catalyst electrode for aloe extract oxidation reaction (AOR) and hydrogen evolution reaction (HER). Its two-electrode alkaline electrolyzer requires 1.51 V for 20 mA cm-2. The content of this RSS Feed (c) The Royal Society of Chemistry
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Molecular tectonics: gas adsorption and chiral uptake of (L)- and (D)-tryptophan by homochiral porous coordination polymers ()
Chem. Commun., 2017, 53,5740-5743 DOI: 10.1039/C7CC01554B, Communication Donata Asnaghi, Romain Corso, Patrick Larpent, Irene Bassanetti, Abdelaziz Jouaiti, Nathalie Kyritsakas, Angiolina Comotti, Piero Sozzani, Mir Wais Hosseini The combination of an enantiomerically pure tecton with a Cu(II) cation yields robust porous homochiral crystals displaying preferential adsorption of L-tryptophan. The content of this RSS Feed (c) The Royal Society of Chemistry
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A non-interpenetrating lead-organic framework with large channels based on 1D tube-shaped SBUs ()
Chem. Commun., 2017, 53,5694-5697 DOI: 10.1039/C7CC02134H, Communication Fangna Dai, Weidong Fan, Xue Yuan, Zhaodi Huang, Yutong Wang, Xuelian Xin, Huan Lin, Liangliang Zhang, Rongming Wang, Daofeng Sun A 3D open MOF based on 1D infinite tube-shaped SBUs shows efficient adsorption of I2 and selective adsorption of some dyes containing the SO3- group. The content of this RSS Feed (c) The Royal Society of Chemistry
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Lanthanide separation using size-selective crystallization of Ln-MOFs ()
Chem. Commun., 2017, 53,5737-5739 DOI: 10.1039/C7CC01898C, Communication Heng Ya Gao, Wen Li Peng, Pan Pan Meng, Xue Feng Feng, Jian Qiang Li, Hui Qiong Wu, Chang Sheng Yan, Yang Yang Xiong, Feng Luo We report herein an elaborate method, size-selective crystallization of Ln-MOFs, to isolate lanthanide (Ln) ions. The content of this RSS Feed (c) The Royal Society of Chemistry
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A mesoporous tin phosphate-graphene oxide hybrid toward the oxygen reduction reaction ()
Chem. Commun., 2017, 53,5721-5724 DOI: 10.1039/C7CC01311F, Communication Malay Pramanik, Cuiling Li, Yusuf Valentino Kaneti, Yusuke Yamauchi We report a one-pot synthetic strategy for the production of an efficient oxygen reduction reaction (ORR) electrocatalyst by the hybridization of hexagonally ordered mesoporous/crystalline tin phosphate (mesoSnPi) nanoflakes with thin layers of graphene oxide (GO). The content of this RSS Feed (c) The Royal Society of Chemistry
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Desorption of CO from individual ruthenium porphyrin molecules on a copper surface via an inelastic tunnelling process ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01310H, Communication Takuma Omiya, Paolo Poli, Heike Arnolds, Rasmita Raval, Mats Persson, Yousoo Kim The coordination of CO to metalloporphyrins changes their electronic and magnetic properties. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Nitrogen-doped porous carbon material derived from metal-organic gel for small biomolecular sensing ()
Chem. Commun., 2017, 53,5725-5728 DOI: 10.1039/C7CC00665A, Communication Yung-Han Shih, Jian-Hong Chen, Yaling Lin, Hsin-Tsung Chen, Chia-Her Lin, Hsi-Ya Huang A template strategy for fabricating N-doped porous carbon derived from MOG is demonstrated as a matrix for sensing small biomolecules. The content of this RSS Feed (c) The Royal Society of Chemistry
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Rearrangement of an aniline linked perylene bisimide under acidic conditions and visible to near-infrared emission from the intramolecular charge-transfer state of its fused derivatives ()
Chem. Commun., 2017, 53,5698-5701 DOI: 10.1039/C7CC01520H, Communication Mitsuru Kojima, Akira Tamoto, Naoki Aratani, Hiroko Yamada We have prepared a series of aniline-linked and fused perylene bisimides (PBIs) for making near-infrared (NIR) fluorophores. The content of this RSS Feed (c) The Royal Society of Chemistry
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Controlled defunctionalisation of biobased organic acids ()
Chem. Commun., 2017, 53,5682-5693 DOI: 10.1039/C7CC01380A, Feature Article Jasper Verduyckt, Dirk E. De Vos Considerable progress has been made in the field of hydrogenation, decarboxylation and deamination of both citric and amino acids to valuable chemicals, which is why they should be (re)considered as valid biobased platform chemicals. The content of this RSS Feed (c) The Royal Society of Chemistry
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Thermally populated "bright" states for wide-range and high temperature sensing in air ()
Chem. Commun., 2017, 53,5702-5705 DOI: 10.1039/C7CC00551B, Communication Qiyun Fang, Jiewei Li, Shayu Li, Ruihong Duan, Shuangqing Wang, Yuanping Yi, Xudong Guo, Yan Qian, Wei Huang, Guoqiang Yang Using thermally populated brighter excited states, organic sensors have been developed for wide-range and high temperature sensing in air. The content of this RSS Feed (c) The Royal Society of Chemistry
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Enabling iron catalyzed Doyle-Kirmse rearrangement reactions with in situ generated diazo compounds ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02801F, Communication Katharina J. Hock, Lucas Mertens, Rene Hommelsheim, Robin Spitzner, Rene M Koenigs Slow addition of sodium nitrite allows the in situ preparation of highly explosive diazo compounds and enables their safe and scalable application in iron catalyzed rearrangement reactions of allylic and... The content of this RSS Feed (c) The Royal Society of Chemistry
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Single-Component White-light Emission via Intramolecular Electronic Conjugation-truncation with Perylenemonoimide ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02873C, Communication Kaushik Pal, Vikas Sharma, Apurba Lal Koner Solvent specific intramolecular electronic communication truncated optical behaviour, and white light emission with CIE chromaticity index (0.33, 0.33) using only a single component via non-covalent nano-assembling of alkyne-phenanthrene conjugated perylenemonoimide... The content of this RSS Feed (c) The Royal Society of Chemistry
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Halofunctionalization of alkenes by vanadium chloroperoxidase from Curvularia inaequalis ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03368K, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Jia Jia Dong, Elena Fernandez-Fueyo, Jingbo Li, Zheng Guo, Rokus Renirie, Ron Wever, Frank Hollmann The vanadium-dependent chloroperoxidase from Curvularia inaequalis is a stable and efficient biocatalyst for the hydroxyhalogenation of a broad range of alkenes into halohydrins. Up to 1.200.000 TON with 69 s-1... The content of this RSS Feed (c) The Royal Society of Chemistry
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Nickel-Catalyzed Hydrocarboxylation of Ynamides with CO2 and H2O: Observation of Unexpected Regioselectivity ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03127K, Communication Ryohei Doi, Iman Abdullah, Takahisa Taniguchi, Nozomi Saito, Yoshihiro Sato We describe the nickel-catalyzed hydrocarboxylation of ynamides with CO2 and H2O to afford a variety of [small alpha]-amino-[small alpha],[small beta]-unsaturated esters with high regioselectivities. Selective [small alpha]-carboxylation of ynamide with this catalytic protocol is... The content of this RSS Feed (c) The Royal Society of Chemistry
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Smart Drug: A pH-responsive photothermal ablation agent for Golgi apparatus activated cancer therapy ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03168H, Communication Fengfeng Xue, Ying Wen, Peng Wei, Yilin Gao, Zhiguo Zhou, Shuzhang Xiao, Tao Yi We report a pH-responsive photothermal ablation agent (pH-PTT) based on cyanine dye for photothermal therapy (PTT). The nanoparticles formed by BSA and pH-PTT preferentially accumulated in Golgi apparatus of cancer... The content of this RSS Feed (c) The Royal Society of Chemistry
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pH-Driven Self-Sorting in a Four Component Host-Guest System ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02432K, Communication Nuno Basilio, Johan Mendoza, Sandra Gago, A. Jorge Parola Water-soluble trans-chalcones bearing dimethyl- (1a) and diethylamino (1b) groups were employed as guests to examine a pH-responsive self-sorting system with macrocyclic hosts [small beta]-cyclodextrin ([small beta]-CD) and cucurbit[7]uril (CB7). Both [small beta]-CD and... The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly Sensitive Novel Cathodic Electrochemiluminescence of Tris(2,2´-bipyridine)Ruthenium (II) using Glutathione as a co-reactant ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03349D, Communication Shanmugam Senthil Kumar, Chikkili Venkateswara raju We demonstrated for the first time, glutathione used as a co-reactant to generating highly stable and enhanced a novel cathodic electrochemiluminescence (ECL) using Ru(bpy)32+ molecule in alkaline pH phosphate buffer... The content of this RSS Feed (c) The Royal Society of Chemistry
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A molecular self-assembled colourimetric chemosensor array for simultaneous detection of metal ions in water ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03218H, Communication Yui Sasaki, Tsukuru Minamiki, Shizuo Tokito, Tsuyoshi Minami We propose a novel strategy for a high-turoughput sensing of metal ions using a molecular self-assembled colourimetric chemosensor array. The proposed colourimetric assay has been achieved by only using the... The content of this RSS Feed (c) The Royal Society of Chemistry
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Two-photon imaging of formaldehyde in live cells and animals utilizing a lysosome-targetable and acidic pH-activatable fluorescent probe ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03050A, Communication Xilei Xie, Fuyan Tang, Xiaoyan Shangguan, Shiyi Che, Jinye Niu, Yongsheng Xiao, Xu Wang, Bo Tang Lyso-TPFP presents lysosomal targetability and acidic pH-activatable response toward formaldehyde. Thus, it exclusively visulizes lysosomal formaldehyde and is immune against that in neutral cytosol and other organelles. Additionally, two-photon fluorescence... The content of this RSS Feed (c) The Royal Society of Chemistry
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Encapsulation and solid state sequestration of gases by calix[6]arene-based molecular containers ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03078A, Communication Roy Lavendomme, Daniela Ajami, Steven Moerkerke, Johan Wouters, Kari Rissanen, Michel Luhmer, Ivan Jabin Two calix[6]arene-based molecular containers were synthesized in high yields. These containers can encapsulate small guests through an original "rotating door" complexation process. The sequestration of greenhouse gases is clearly demonstrated.... The content of this RSS Feed (c) The Royal Society of Chemistry
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Low-temperature, high-mobility, solution-processed metal oxide semiconductors fabricated with oxygen radical assisting perchlorate aqueous precursors ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01100H, Communication Peixiong Gao, Linfeng Lan, Zhenguo Lin, Sheng Sun, Yuzhi Li, Wei Song, Erlong Song, Peng Zhang, Junbiao Peng In this report, a simple and general chemical route for fabricating MO semiconducting films at relatively low temperature without any fuel additives or special annealing steps was demonstrated. The precursor,... The content of this RSS Feed (c) The Royal Society of Chemistry
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Metallocorroles as inherently chiral chromophores: resolution and electronic circular dichroism spectroscopy of a tungsten biscorrole ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02027A, Communication Christine Schies, Abraham B. Alemayehu, Hugo Vazquez-Lima, Kolle E. Thomas, Torsten Bruhn, Gerhard Bringmann, Abhik Ghosh A homoleptic tungsten biscorrole, an inherently chiral chromophore, has been resolved and characterized using electronic circular dichroism spectroscopy. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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