Chem. Commun.

Core-shell nanoparticle-peptide@metal−organic framework as dual-recognition switch for pH and enzyme stepwise-responsive imaging in living cells ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04621B, Communication Hong Shen, Jintong Liu, Jianping Lei, Huangxian Ju A core-shell nanostructure is fabricated with a pH-sensitive metal−organic framework shell and a peptide functionalized gold nanoparticle core via a mild synthetic route. The nanostructure can be applied as dual-recognition... The content of this RSS Feed (c) The Royal Society of Chemistry
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Dramatic photoluminescence quenching in carbon dots induced by cyclic voltammetry ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC03617A, Communication Yuchuan Tian, Li Li, Xuhong Guo, Anna Wojtowicz, Luis Estevez, marta krysmann, Antonios Kelarakis The study focuses on the structural rearrengements and the photoluminescent behavior of pyrolytically derived carbon dots when subjected to a series of cyclic voltammetry sweeps. Although the electrical signals involved... The content of this RSS Feed (c) The Royal Society of Chemistry
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Correction: An efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H2O as the hydrogen source ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC90326C, Correction Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Huan Liu, Da Yang, Dong-Liang Wang, Peng Wang, Yong Lu, Giang Vo-Thanh, Ye Liu To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Elucidation of the Roles of Conserved Residues in the Biosynthesis of the Lasso Peptide Paeninodin ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04411B, Communication Julian D Hegemann, Christopher J. Schwalen, Douglas A. Mitchell, Wilfred A van der Donk Substrate binding assays, in vitro proteolytic processing assays, and heterologous lasso peptide production were used to investigate the roles of conserved precursor peptide residues during paeninodin maturation. Specifically, we delineate... The content of this RSS Feed (c) The Royal Society of Chemistry
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Complexation of asymmetric diborenes with magnesium bromide ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04775H, Communication Wei Lu, Rei Kinjo Complexation between asymmetric diborenes and MgBr2 is reported. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Correction: Heparin-induced tau filaments are structurally heterogeneous and differ from Alzheimer's disease filaments ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC90325E, Correction Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Yann Fichou, Michael Vigers, Andrew K. Goring, Neil A. Eschmann, Songi Han To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Wavelength Dependent Photochemical Charge Transfer at the Cu2O – BiVO4 Particle Interface – Evidence for Tandem Excitation ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04123G, Communication Zongkai Wu, Ghunbong Cheung, Jiarui Wang, Zeqiong Zhao, Frank Osterloh The understanding of the photochemical charge transfer properties of powdered semiconductors is of relevance to artificial photosynthesis and the production of solar fuels. Here we use surface photovoltage spectroscopy to... The content of this RSS Feed (c) The Royal Society of Chemistry
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Modulating the GSH/Trx Selectivity of a Fluorogenic Disulfide-based Thiol Sensor to Reveal Diminished GSH Levels under ER Stress ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04846K, Communication Youngjin Wi, Hoa Thi Le, Peter Verwilst, Kyoung Sunwoo, Seo Jin Kim, Jung Eun Song, Hey Young Yoon , Geon Han, Jong Seung Kim, Chulhun Kang, Tae Woo Kim We synthesized a fluorogenic disulfide-based naphthalimide thiol probe (ER-Naph) with a hydrophilic endoplasmic reticulum (ER)-guiding glibenclamide unit. Its ER targeting ability and high selectivity to GSH over thioredoxin, a potent... The content of this RSS Feed (c) The Royal Society of Chemistry
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Diastereoselective self-assembly of bisheptahelicene on Cu(111) ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04160A, Communication Anaïs Mairena, Manfred Parschau, Johannes Seibel, Martin Wienke, Daniel Rentsch, Andreas Terfort, Karl-Heinz Ernst Diastereospecific two-dimensional crystallization is reported for bishelicenes on a Cu(111) surface. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Self-assembly of conformationally flexible molecules under 2D confinement: structural analysis from computer simulations ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04272A, Communication Damian Nieckarz, Paweł Szabelski Monte Carlo simulations reveal the role of surface conformers in self-assembly on crystalline supports. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Controlling the phase and morphology of amorphous Se nanoparticles: their prolonged stabilization and anticancer efficacy ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC05375H, Communication Apurav Guleria, Snigdha Chakraborty, Suman Neogy, Dharmendra K. Maurya, Soumyakanti Adhikari Resolving issues related to the synthesis and stabilization of amorphous selenium nanoparticles: recycling of a matrix and promising biological applications. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Uracil grafted imine-based covalent organic framework for nucleobase recognition ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04346A, Communication Sergio Royuela, Eduardo García-Garrido, Miguel Martín Arroyo, María J. Mancheño, María M. Ramos, David González-Rodríguez, Álvaro Somoza, Félix Zamora, José L. Segura An imine-based covalent organic framework (COF) decorated in its cavities with uracil groups has shown selective recognition towards adenine in water. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A novel design of a polynuclear co-delivery system for safe and efficient cancer therapy ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03720E, Communication Lei Xing, Jia-Liang Zhang, Tian-jiao Zhou, Yu-Jing He, Peng-Fei Cui, Jia-Hui Gong, Minjie Sun, Jin-Jian Lu, Zhangjian Huang, Liang Jin, Hu-Lin Jiang A polynuclear nanoparticle fabricated through a sequential hydrophobic and electrostatic interaction mechanism can circumvent the contradictory problem of siRNA binding capacity and toxicities of cationic vectors. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Unexpected reactivity of cyclic perfluorinated iodanes with electrophiles ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04558E, Communication Stefan Gruber, Simon M. Ametamey, Roger Schibli New concept of reactivity umpolung: perfluorinated compounds can be prepared by reacting perfluorinated iodanes (considered as electrophilic reagents) with electrophiles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Insights into β-ketoacyl-chain recognition for β-ketoacyl-ACP utilizing AHL synthases ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04532A, Communication Mila Nhu Lam, Dastagiri Dudekula, Bri Durham, Noah Collingwood, Eric C. Brown, Rajesh Nagarajan The design, synthesis and kinetic evaluation of beta-ketoacyl-ACP mimics for two 3-oxoacyl-ACP utilizing quorum signal synthases are reported. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Rational design of atomically dispersed nickel active sites in β-Mo2C for the hydrogen evolution reaction at all pH values ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03975E, Communication Ting Ouyang, An-Na Chen, Zhen-Zhao He, Zhao-Qing Liu, Yexiang Tong Atomically dispersed Ni in β-Mo2C (Ni/β-Mo2C) is designed as an efficient catalyst for the HER at all pH values. The remarkable electrochemical properties of Ni/β-Mo2C are mainly attributed to the synergistic effect between atomically dispersed Ni species and β-Mo2C. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A molecular-regulation strategy towards low-voltage driven, multi degree of freedom IPMC catheters ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04967J, Communication Chao Lu, Lei Zhao, Yimin Hu, Wei Chen A multi degree of freedom IPMC active catheter with controllable bending ability under a low voltage (∼1.0 V) was developed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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1,2-Diarylation of alkenes with aryldiazonium salts and arenes enabled by visible light photoredox catalysis ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04526G, Communication Xuan-Hui Ouyang, Jiang Cheng, Jin-Heng Li Visible light-driven three-component alkene 1,2-diarylation with aryldiazonium salts and arenes involving aryl C(sp2)–H functionalization is described. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Detection of a transient FeV(O)(OH) species involved in olefin oxidation by a bio-inspired non-haem iron catalyst ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03990A, Communication Shuangning Xu, Jedidiah J. Veach, Williamson N. Oloo, Kevin C. Peters, Junyi Wang, Richard H. Perry, Lawrence Que Here we provide direct evidence for the formation of an FeV(O)(OH) species in non-haem iron catalysis using ambient mass spectrometry. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A biosensor based on a 3D-DNA walking machine network and distance-controlled electrochemiluminescence energy transfer for ultrasensitive detection of tenascin C and lead ions ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04953J, Communication Zi-Qi Xu, Pu Zhang, Ya-Qin Chai, Hai-Jun Wang, Ruo Yuan An electrochemiluminescence biosensor was proposed based on distance-controlled energy transfer and a 3D-DNA walking machine network. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Two-dimensional self-assembled nanostructures of nucleobases and their related derivatives on Au(111) ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03585G, Feature Article Yuanqi Ding, Xinyi Wang, Lei Xie, Xinyi Yao, Wei Xu Two-dimensional self-assembled nanostructures can be constructed by nucleobases and various reactants on Au(111). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Water solubility is essential for fluorescent probes to image hypochlorous acid in live cells ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04631J, Communication Panfei Xing, Zhe Zhang, Yiming Niu, Yaning Qi, Lei Dong, Chunming Wang We synthesized four probes and compared their HClO-detecting ability in different solvents. The data showed that only the hydrophilic probes could sensitively and accurately detect HClO in live cells. Meanwhile,... The content of this RSS Feed (c) The Royal Society of Chemistry
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Hydrogen Sulfide Induced Supramolecular Self-Assembly in Living Cells ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC05174G, Communication Simin Wei, Xi-Rui Zhou, Zhentao Huang, Qingxin Yao, Yuan Gao Here we developed a critical gasotransmitter (H2S) mediated reduction to instruct the supramolecular self-assembly in multiple living cell lines. Specifically, the reduction converted an azido group to amine which allowed... The content of this RSS Feed (c) The Royal Society of Chemistry
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Diversity-oriented synthesis of imidazo[2,1-a]isoquinolines ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC05390A, Communication Shaoyu Mai, yixin luo, Xianyun Huang, Zhenghao Shu, Bingnan Li, Yu Lan, Qiuling Song Herein, we report an efficient and practical strategy on the synthesis of five types of imidazo[2,1-a]isoquinolines via Cp*RhIII-catalyzed [4+2] annulation of 2-arylimidazoles and α-diazoketoesters, whose structural and substituted diversity at... The content of this RSS Feed (c) The Royal Society of Chemistry
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A novel exonuclease-assisted isothermal nucleic acid amplification with ultrahigh specificity mediated by full-length Bst DNA polymerase ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04577A, Communication Xin Ye, Yang Li, Lijuan Wang, Xueen Fang, Jilie Kong Here, we introduced a novel exonuclease-assisted isothermal nucleic acid amplification (Exo-NAT) utilizing the full-length Bst DNA polymerase combined with a melting curve analysis. This method achieved an ultrahigh specificity with... The content of this RSS Feed (c) The Royal Society of Chemistry
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Activation of Carbon Suboxide (C3O2) by U(III) to form a Cyclobutane-1,3-dione Ring. ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04391D, Communication Nikolaos Tsoureas, Frederick Geoffrey Cloke The activation of C3O2 by the U(III) complex [U(η5-Cp’)3] (Cp’ = C5H4SiMe3) is described. The reaction results in the reductive coupling of three C3O2 units to form a tetranuclear complex... The content of this RSS Feed (c) The Royal Society of Chemistry
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Dihydrogen Phosphate-containing Dinuclear Double Assemblies that Demonstrate Phosphate Reactivity to the Tetrafluoroborate Anion. ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04900A, Communication Craig Rice, Robert Allan Faulkner, Nathan John Patmore, Chris Slater The ligands L1 and L2 both form dinuclear assemblies with Cu(II) and these react with dihydrogen phosphate so that the anion is incorporated within the assembly (e.g. [Cu2L2(H2PO4)]3+). However, in... The content of this RSS Feed (c) The Royal Society of Chemistry
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Ruthenium-catalyzed selective α-deuteration of aliphatic nitriles using D2O ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03971B, Communication Varadhan Krishnakumar, Chidambaram Gunanathan Ruthenium-catalysed selective α-deuteration of aliphatic nitriles using deuterium oxide is reported. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Experimental and Computational Studies on H2O-Promoted, Rh-Catalyzed Transient-Ligand-Free Ortho-C(sp2)–H Amidation of Benzaldehydes with Dioxazolones ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04904A, Communication Jun Ding, Wei Jiang, heyuan bai, Tong-Mei Ding, Dafang Gao, Xiaoguang Bao, Shuyu Zhang An efficient and convenient ligand-free, rhodium-catalyzed ortho-C(sp2)−H amidation of benzaldehydes with dioxazolones using H2O as the key promoter is described. Using this protocol, a wide range of benzaldehyde substrates were... The content of this RSS Feed (c) The Royal Society of Chemistry
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Csp3–H bond functionalization of amines via tunable iminium ions: divergent synthesis of trifluoromethylated arylamines ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04936J, Communication Lou Shi, Mingshan Wang, Ling Pan, Yifei Li, Qun Liu A novel generation of tunable iminium ions leads to divergent synthesis of trifluoromethylated arylamines via the direct α- and β-functionalization of saturated amines. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Novel D–A–D based near-infrared probes for the detection of β-amyloid and Tau fibrils in Alzheimer's disease ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC05259J, Communication Yuying Li, Kan Wang, Kaixiang Zhou, Wentao Guo, Bin Dai, Yi Liang, Jiapei Dai, Mengchao Cui Novel D–π–A–π–D probes were investigated for the detection of Aβ plaques and NFTs. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Chiral supramolecular coordination cages as high-performance inhibitors against amyloid-β aggregation ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04913K, Communication Ling-Yu Bao, Si-Jia Hao, Sai-Fei Xi, Xiaodong Yan, Hai-Xia Zhang, Rui Shen, Zhi-Guo Gu A family of chiral tetrahedral Ni48+ coordination cages with tunable size and multiple interaction sites can effectively inhibit Aβ aggregation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Copper-mediated intramolecular aminofluorination of 1,3-dienes by using nucleophilic fluorine reagents ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04909B, Communication Zuxiao Zhang, Pinhong Chen, Guosheng Liu A copper-mediated intramolecular aminofluorination of 1,3-dienes is disclosed, in which both AgF and Et3N·3HF can be used as the fluorine source. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Chemical and in silico tuning of the magnetisation reversal barrier in pentagonal bipyramidal Dy(III) single-ion magnets ()
Chem. Commun., 2018, 54,8273-8276 DOI: 10.1039/C8CC03929A, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Angelos B. Canaj, Mukesh Kumar Singh, Claire Wilson, Gopalan Rajaraman, Mark Murrie New air-stable axial Dy(III) complexes show magnetic hysteresis up to 10 K, while in silico generated model complexes reveal the importance of outer-sphere interactions in controlling the magnetisation reversal barrier. The content of this RSS Feed (c) The Royal Society of Chemistry
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Supramolecular nanoparticles based on β-CD modified hyaluronic acid for DNA encapsulation and controlled release ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04783A, Communication Yang Yang, Xin Jia, Ying-Ming Zhang, Nan Li, Yu Liu Supramolecular nanoparticles composed of doubly positively charged adamantane (ADA2+) and β-CD modified hyaluronic acid (HACD) were constructed and the controlled binding and release of pDNA was realized. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Maltodextrin recognition by a macrocyclic synthetic lectin ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC05074K, Communication Patrick Stewart, Charles M. Renney, Tiddo J. Mooibroek, Sadia Ferheen, Anthony P. Davis This carbohydrate receptor achieves high affinities in water and shows an unusual preference for α-linked maltodextrins. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A neptunium(V)-mediated interwoven transuranium-rotaxane network incorporating a mechanically interlocked [c2]daisy chain unit ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC05122D, Communication Lei Mei, Chao Xu, Qun-yan Wu, Kong-qiu Hu, Li-yong Yuan, Jing Chen, Cheng-liang Xiao, Shu-ao Wang, Zhi-fang Chai, Wei-qun Shi A combination of an NpV center and a cucurbituril-based pseudorotaxane ligand generates the first transuranium-rotaxane complex, NRCP-1, which has a mechanically-interlocked [c2]daisy chain unit. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A new strategy for hydrophobic drug delivery using a hydrophilic polymer equipped with stacking units ()
Chem. Commun., 2018, 54,8218-8221 DOI: 10.1039/C8CC04363A, Communication Peng-Fei Cui, Wan-Ru Zhuang, Xi Hu, Lei Xing, Ru-Yi Yu, Jian-Bin Qiao, Yu-Jing He, Fangyuan Li, Daishun Ling, Hu-Lin Jiang A highly hydrophilic polymer was used to deliver aromatic ring-containing hydrophobic agent doxorubicin (DOX) via π–π interaction. The content of this RSS Feed (c) The Royal Society of Chemistry
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NaI-mediated divergent synthesis of isatins and isoindigoes: a new protocol enabled by an oxidation relay strategy ()
Chem. Commun., 2018, 54,8265-8268 DOI: 10.1039/C8CC04471F, Communication Hong-hua Zhang, Yong-qiang Wang, Long-tao Huang, Long-qing Zhu, Yi-yue Feng, Ying-mei Lu, Quan-yi Zhao, Xue-qiang Wang, Zhen Wang A new approach for the synthesis of isatins and isoindigoes by an inexpensive and environmentally friendly NaI-mediated transformation is disclosed. The content of this RSS Feed (c) The Royal Society of Chemistry
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Peptide nucleic acid mediated inhibition of the bacterial signal recognition particle ()
Chem. Commun., 2018, 54,8257-8260 DOI: 10.1039/C8CC04715D, Communication Sudipta Ghosh, Snehlata Saini, Ishu Saraogi Here we propose and validate the signal recognition particle (SRP), a protein transport machinery, as an antibacterial target for the first time. The content of this RSS Feed (c) The Royal Society of Chemistry
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First complex oxide superconductor by atomic layer deposition ()
Chem. Commun., 2018, 54,8253-8256 DOI: 10.1039/C8CC04998J, Communication Henrik Hovde Sønsteby, Thomas Aarholt, Øystein Prytz, Helmer Fjellvåg, Ola Nilsen The first reported complex oxide superconductor (La2−xSrxCuO4−y) by atomic layer deposition. The content of this RSS Feed (c) The Royal Society of Chemistry
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Thermally induced formal [4+2] cycloaddition of 3-aminocyclobutenones with electron-deficient alkynes: facile and efficient synthesis of 4-pyridones ()
Chem. Commun., 2018, 54,8229-8232 DOI: 10.1039/C8CC03974G, Communication Yang Yu, Yan Zhang, Li-Yun Xiao, Qin-Qin Peng, Yu-Long Zhao A thermally induced novel formal [4+2] cycloaddition of cyclobutenones with electron-deficient alkynes under metal-free conditions has been developed. The reaction provides a straightforward and efficient method for the synthesis of 4-pyridone derivatives in a single step. The content of this RSS Feed (c) The Royal Society of Chemistry
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Transforming benzylideneamine N,C-chelate boron compounds to BN-cycloocta-/cyclohepta-trienes bearing a tetrasubstituted BN unit via photoisomerization ()
Chem. Commun., 2018, 54,8245-8248 DOI: 10.1039/C8CC04535F, Communication Hai-Jun Li, Soren K. Mellerup, Xiang Wang, Suning Wang Simple benzylideneamine N,C-chelate boron compounds have been found to undergo clean photoisomerization forming rare 7- and 8-membered heterocycles that contain a tetrasubstituted BN unit. The content of this RSS Feed (c) The Royal Society of Chemistry
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All-inorganic bifacial CsPbBr3 perovskite solar cells with a 98.5%-bifacial factor ()
Chem. Commun., 2018, 54,8237-8240 DOI: 10.1039/C8CC04271C, Communication Yanan Li, Jialong Duan, Yuanyuan Zhao, Qunwei Tang A bifacial all-inorganic PSC with a bifacial factor as high as 98.5% is made by sharing a single carbon back-electrode. The content of this RSS Feed (c) The Royal Society of Chemistry
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A highly active diradical cobalt(III) catalyst for the cycloisomerization of alkynoic acids ()
Chem. Commun., 2018, 54,8241-8244 DOI: 10.1039/C8CC04459G, Communication Nicolas Leconte, Amaury du Moulinet d'Hardemare, Christian Philouze, Fabrice Thomas A well-defined diradical cobalt(III) complex derived of the N,N′-bis(2-aminophenyl)-o-phenylenediamine catalyses the cycloisomerization of alkynoic acids. The content of this RSS Feed (c) The Royal Society of Chemistry
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Remarkable multimember-ring configurations in a new family of Na7MIISb5S12 (MII = Zn, Cd, Hg) exhibiting various three-dimensional tunnel structures ()
Chem. Commun., 2018, 54,8269-8272 DOI: 10.1039/C8CC04639E, Communication Kui Wu, Bingbing Zhang, Zhihua Yang, Shilie Pan A new series of thioantimonates featuring the newly discovered trimer (MII/Sb)3S9 and 12 + 12-MR configurations are verified as potential IR birefringent materials. The content of this RSS Feed (c) The Royal Society of Chemistry
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N-Sulfonyl acetylketenimine as a highly reactive intermediate for the synthesis of N-sulfonyl amidines ()
Chem. Commun., 2018, 54,8222-8225 DOI: 10.1039/C8CC04699A, Communication Weiguang Yang, Dayun Huang, Xiaobao Zeng, Dongping Luo, Xinyan Wang, Yuefei Hu A highly reactive intermediate N-sulfonyl acetylketenimine was generated from a 3-butyn-2-one participating CuAAC/ring-opening method. The content of this RSS Feed (c) The Royal Society of Chemistry
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Trifluoromethane modification of thermally activated delayed fluorescence molecules for high-efficiency blue organic light-emitting diodes ()
Chem. Commun., 2018, 54,8261-8264 DOI: 10.1039/C8CC03425G, Communication Masayuki Yokoyama, Ko Inada, Youichi Tsuchiya, Hajime Nakanotani, Chihaya Adachi Highly efficient blue and green thermally activated delayed fluorescence (TADF) molecules bearing trifluoromethane-modified carbazole groups were developed. The content of this RSS Feed (c) The Royal Society of Chemistry
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A heterobimetallic metal–organic framework as a “turn-on” sensor toward DMF ()
Chem. Commun., 2018, 54,8233-8236 DOI: 10.1039/C8CC03662D, Communication Fei-Yan Yi, Jinlei Chen, Shi-Cheng Wang, Minli Gu, Lei Han It is for the first time that a non-luminescent 3d–4f heterobimetallic CuEu organic framework (NBU-8) realized specific selective light recovery of Eu3+ ions toward N,N′-dimethylformamide (DMF) even in the presence of other amide molecules with similar functions. The content of this RSS Feed (c) The Royal Society of Chemistry
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A nanoclay-induced defective g-C3N4 photocatalyst for highly efficient catalytic reactions ()
Chem. Commun., 2018, 54,8249-8252 DOI: 10.1039/C8CC04100H, Communication Qihang Zhao, Liangjie Fu, Denghui Jiang, Yunfei Xi, Huaming Yang A kaolinite nanoclay-induced defective graphitic carbon nitride (g-C3N4) catalyst was successfully prepared for highly efficient degradation of organic pollutants. The content of this RSS Feed (c) The Royal Society of Chemistry
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In situ fluorescence monitoring of diagnosis and treatment: a versatile nanoprobe combining tumor targeting based on MUC1 and controllable DOX release by telomerase ()
Chem. Commun., 2018, 54,8277-8280 DOI: 10.1039/C8CC05052J, Communication Haibin Si, Lijuan Wang, Qingling Li, Xiaoxiao Li, Lu Li, Bo Tang In situ fluorescence monitoring of diagnosis and treatment: a versatile nanoprobe combining tumor targeting based on MUC1 and controllable DOX release by telomerase. The content of this RSS Feed (c) The Royal Society of Chemistry
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Tumor-selective catalytic nanosystem for activatable theranostics ()
Chem. Commun., 2018, 54,8214-8217 DOI: 10.1039/C8CC03922D, Communication Lu-Ying Duan, Yu-Jie Wang, Jin-Wen Liu, Yu-Min Wang, Na Li, Jian-Hui Jiang A novel catalytic nanosystem which successfully realizes efficient CDT and activatable fluorescence imaging in H2O2-rich tumor microenvironments was developed. The content of this RSS Feed (c) The Royal Society of Chemistry
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A simple and versatile strategy for realizing bright multicolor mechanoluminescence ()
Chem. Commun., 2018, 54,8206-8209 DOI: 10.1039/C8CC04358B, Communication Qikun Sun, Kai Zhang, Zhenzhen Zhang, Linagliang Tang, Zongliang Xie, Zhenguo Chi, Shanfeng Xue, Haichang Zhang, Wenjun Yang Bright multicolor mechanoluminescence (ML) was first realized using a stable organic blue ML emitter, N-phenylcarbazole, as the host. The content of this RSS Feed (c) The Royal Society of Chemistry
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Copper-catalyzed cyclization of 2-cyanobenzaldehydes and 2-isocyanoacetates: an efficient strategy for the synthesis of substituted 1-aminoisoquinolines ()
Chem. Commun., 2018, 54,8194-8197 DOI: 10.1039/C8CC04733B, Communication Wen Bao, Jun-Qi Wang, Xue-Tao Xu, Bang-Hong Zhang, Wei-Ting Liu, Lin-Sheng Lei, Huan Liang, Kun Zhang, Shao-Hua Wang An efficient strategy for the synthesis of substituted 1-aminoisoquinoline has been developed. The content of this RSS Feed (c) The Royal Society of Chemistry
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Directed ortho C–H borylation catalyzed using Cp*Rh(III)–NHC complexes ()
Chem. Commun., 2018, 54,8202-8205 DOI: 10.1039/C8CC03144D, Communication Jompol Thongpaen, Thibault E. Schmid, Loic Toupet, Vincent Dorcet, Marc Mauduit, Olivier Baslé Cp*Rh(NHC) complexes with bulky chiral bidentate NHC-carboxylate ligands demonstrated high selectivity in the pyridine-directed C–H borylation of arenes under mild conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
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A flexible ionic synaptic device and diode-based aqueous ion sensor utilizing asymmetric polyelectrolyte distribution ()
Chem. Commun., 2018, 54,8186-8189 DOI: 10.1039/C8CC04539A, Communication Yiwei Zhao, Shilei Dai, Yingli Chu, Xiaohan Wu, Jia Huang Two terminal ionic synaptic devices and pH sensors based on ionic diodes were developed by utilizing asymmetric polyelectrolyte distribution. The content of this RSS Feed (c) The Royal Society of Chemistry
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Intramolecular strong electronic coupling in a discretely H-aggregated phthalocyanine dimer connected with a rigid linker ()
Chem. Commun., 2018, 54,8226-8228 DOI: 10.1039/C8CC04335C, Communication Yasuyuki Yamada, Katsuhiko Nawate, Tomoaki Maeno, Kentaro Tanaka This is the first example of a discrete dimer of phthalocyanines in an H-aggregate form. Intramolecular strong electronic coupling was observed between the phthalocyanines electrochemically. The content of this RSS Feed (c) The Royal Society of Chemistry
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Scalable solid-state synthesis of coralline-like nanostructured Co@CoNC electrocatalyst for Zn–air batteries ()
Chem. Commun., 2018, 54,8190-8193 DOI: 10.1039/C8CC02500B, Communication Hao Luo, Wen-Jie Jiang, Cong Lin, Wei Dong, Shuai Niu, Lin-Bo Huang, Xing Zhang, Zidong Wei, Jin-Song Hu A facile and scalable solid-state synthesis strategy is developed to produce hierarchical coralline-like nanostructured electrocatalysts with cobalt nanoparticles and Co–NX sites for efficient oxygen reduction. The content of this RSS Feed (c) The Royal Society of Chemistry
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Supramolecular chemotherapeutic drug constructed from pillararene-based supramolecular amphiphile ()
Chem. Commun., 2018, 54,8198-8201 DOI: 10.1039/C8CC04334E, Communication Dan Wu, Yang Li, Jie Shen, Zaizai Tong, Qinglian Hu, Liping Li, Guocan Yu A therapeutic supramolecular amphiphile, P5⊃CPT-ss-Py, with GSH-responsiveness was constructed using pillar[5]arene-based host–guest molecular recognition. Cellular internalization and anticancer efficacy were greatly increased through this supramolecular strategy. The content of this RSS Feed (c) The Royal Society of Chemistry
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Effect of the metal–support interaction on the activity and selectivity of methanol oxidation over Au supported on mesoporous oxides ()
Chem. Commun., 2018, 54,8174-8177 DOI: 10.1039/C8CC04295K, Communication Sunyoung Oh, You Kyung Kim, Chan Ho Jung, Won Hui Doh, Jeong Young Park To elucidate the factors affecting the catalytic properties of supported Au catalysts on the metal oxide support we investigated Au NPs deposited on crystallized mesoporous transition-metal oxides (m-oxides: Co3O4, NiO, and α-Fe2O3) prepared using the nanocasting method. The content of this RSS Feed (c) The Royal Society of Chemistry
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Trace water mediated growth of oriented single-crystalline mesoporous metal–organic frameworks on gold nanorods ()
Chem. Commun., 2018, 54,8182-8185 DOI: 10.1039/C8CC04147D, Communication Zehao Zhou, Mengyuan Li, Jian Zhao, Zhenghan Di, Chunzhi Di, Bei Liu, Chao Zhang, Chun-Hua Yan, Lele Li The growth of single-crystalline mesoporous MOFs with well-controlled orientation on the surface of gold nanorods was reported for the first time. The content of this RSS Feed (c) The Royal Society of Chemistry
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Cleavage of BN triple bonds by main group reagents ()
Chem. Commun., 2018, 54,8210-8213 DOI: 10.1039/C8CC02317D, Communication Lena Winner, Alexander Hermann, Guillaume Bélanger-Chabot, Oscar F. González-Belman, J. Oscar C. Jiménez-Halla, Hauke Kelch, Holger Braunschweig A silylene and a 1,2-diaminoalkyne respectively cleave the strong BN triple bond in iminoboranes. The content of this RSS Feed (c) The Royal Society of Chemistry
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White perovskite based lighting devices ()
Chem. Commun., 2018, 54,8150-8169 DOI: 10.1039/C8CC03166E, Feature Article M. Bidikoudi, E. Fresta, R. D. Costa Hybrid organic–inorganic and all-inorganic metal halide perovskites have been one of the most intensively studied materials during the last few years. The content of this RSS Feed (c) The Royal Society of Chemistry
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Bis-reaction-trigger as a strategy to improve the selectivity of fluorescent probes ()
Chem. Commun., 2018, 54,8170-8173 DOI: 10.1039/C8CC02830C, Communication Dan Li, Juan Cheng, Cheng-Kun Wang, Huazhou Ying, Yongzhou Hu, Feng Han, Xin Li Equipping a fluorophore with two ONOO−-specific reaction triggers yielded a probe able to report various degrees of nitrosative stress in live cells. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis, characterization and properties of aryl-fused bis-BN dihydropyrenes ()
Chem. Commun., 2018, 54,8178-8181 DOI: 10.1039/C8CC01748D, Communication Jinyun Zhang, Fude Liu, Zhe Sun, Chenglong Li, Qian Zhang, Chen Zhang, Zhiqiang Liu, Xuguang Liu A series of aryl-fused bis-BN dihydropyrenes are synthesized, their photophysical properties are fully investigated by experimental and theoretical calculations. The content of this RSS Feed (c) The Royal Society of Chemistry
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Fluorescent chemodosimeter for quantification of Cystathionine-y-synthase activity in plant extracts and imaging of endogenous biothiols ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04296A, Communication Hridesh Agarwalla, Anila A. Hoskere, Firoj Ali, Swaraj Rashmi Pradhan, Bishwajit Ganguly, Sumit Kumar Pramanik, Amitava Das A new reagent for quantification of CgS in plant extracts using a generalized methodology suitable for recognition of homocysteine (Hcy) with luminescence ON response. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly GSH-sensitive SN-38 prodrug with "OFF-to-ON" fluorescence switch as a bifunctional anticancer agent ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC05010D, Communication Chang-Hee Whang, Eunsoo Yoo, Seong Kwon Hur, Kyeong Soo Kim, Dongin Kim, Seongbong Jo SN-38 (7-ethyl-10-hydroxy-camptothecin) is an active metabolite of irinotecan (CPT-11) and the most potent camptothecin analogue. In this study, 2,4-dinitrobenzene sulfonyl (DNS) was covalently conjugated as GSH-sensitive trigger to 10’ –OH... The content of this RSS Feed (c) The Royal Society of Chemistry
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Field-induced single-molecule magnet behavior in ideal trigonal antiprismatic cobalt(II) complexes: precise geometrical control by a hydrogen-bonded rigid metalloligand ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04756A, Communication RYOJI MITSUHASHI, K Pedersen, Takaaki Ueda, Takayoshi Suzuki, Jesper Bendix, Masahiro Mikuriya A new cobalt(II) complex bearing a pair of cobalt(III) tris-chelate complexes as metalloligands was prepared and characterized. The CoII ion possesses a crystallographically elongated trigonal antiprismatic geometry because of the... The content of this RSS Feed (c) The Royal Society of Chemistry
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A Photocaged Fluorescent Probe for Imaging Hypochlorous Acid in Lysosome ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04926B, Communication Mingguang Ren, Zihong Li, Jing Nie, Li Wang, Weiying Lin By combining the advantages of the photocaging technology and traditional analyte-responsive fluorescent probe, we designed and sythesized the first photocaged lysosomal-targeted fluorescent HOCl probe (PL-HA). The new caged PL-HA probe... The content of this RSS Feed (c) The Royal Society of Chemistry
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Elastic Flexibility Tuning via Interaction Factor Modulation in Molecular Crystals ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04132F, Communication Manish Kumar Mishra, Sourabh B. Kadambi, Upadrasta Ramamurty, Soumyajit Ghosh We report the design of a series of nonhalogenated and halogenated molecular crystals with the specific structural features, which are essential for pronounced elasticity. These feature involve (a) isotropic weak... The content of this RSS Feed (c) The Royal Society of Chemistry
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Self-assembled reversed bilayers directed by pnictogen bonding to form vesicles in solution. ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC05187A, Communication Shiva Moaven, Jingze Yu, Maythe Vega, Daniel K Unruh, Anthony Frank Cozzolino Artificial vesicles can aid in the study and understanding of biological cell membranes. This study employs pnictogen bonding to actively direct the self-assembly of a true reversed bilayer. Antimony(III) alkoxide... The content of this RSS Feed (c) The Royal Society of Chemistry
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Silver-catalyzed stereoselective formation of glycosides using glycosyl ynenoates as donors ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC02494D, Communication Xu Dong, Li Chen, Zhitong Zheng, Xu Ma, Zaigang Luo, Liming Zhang A silver-catalyzed glycosylation reaction is developed by employing a readily accessible and stable glycosyl ynenoate donor and is mostly high yielding. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A Portal to a Class of Novel Sultones Functionalized Pyridines via an Annulative SuFEx Process Employing Earth Abundant Nickel Catalyst ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04032J, Communication Xing Chen, Gao feng Zha, Wan-Yin Fang, K. P. Rakesh, Hua-Li Qin An efficient Nickel catalyzed annulative process for synthesis of a class of structurally unique heterocycles containing pharmaceutically important moieties of both pyridines and sultones was developed by using SuFEx Chemistry.... The content of this RSS Feed (c) The Royal Society of Chemistry
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Oximinotrifluoromethylation of Unactivated Alkenes under Ambient Conditions ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC05186K, Communication Na Wang, Jian Wang, Yu-Long Guo, Lei Li, Yan Sun, Zhuang Li, Hong-Xia Zhang, Zhen Guo, Zhong-Liang Li, Xin-Yuan Liu An efficient protocol for oximinotrifluoromethylation of unactivated alkenes was developed via trifluoromethyl radical-induced intramolecular remote oximino migration under mild reaction conditions, providing a wide range of β-trifluoromethylated oximes. Other fluoroalkyl... The content of this RSS Feed (c) The Royal Society of Chemistry
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Disilanylene-bridged BODIPY-based D-σ-A architectures: a novel promising series of NLO chromophores ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04962A, Communication Xianghui Zheng, Wei Du, Lizhi Gai, Xu-Qiong Xiao, Zhifang Li, Li-Wen Xu, Yupeng Tian, Mitsuo Kira, Hua Lu The synthesis and optical properties of a novel series of disilanylene-bridged BODIPY-based D-σ-A chromophores are reported. Si−Si σ-electrons are useful and impressible for tunable optical properties. The electron-donating group facilitates... The content of this RSS Feed (c) The Royal Society of Chemistry
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Iridium complex-based probe for photoluminescence lifetime imaging of human carboxylesterase 2 in living cells ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04481C, Communication Zihe Yan, Jinyu Wang, Yanxin Zhang, Sichun Zhang, Juan Qiao, Xinrong Zhang A novel photoluminescence lifetime probe (Ir-TB) has been developed for the detection and imaging of hCE2 in living cells. Large lifetime increase by around 300 ns after the enzymatic reaction... The content of this RSS Feed (c) The Royal Society of Chemistry
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Iodine catalyzed reduction of quinolines under mild reaction conditions ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04262D, Communication Chun-Hua Yang, Xixi Chen, Huimin Li, Wenbo Wei, Zhantao Yang, Junbiao Chang A reduction of quinolines to synthetically versatile tetrahydroquinoline molecules with I2 and HBpin is described. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Structural differences between toxic and nontoxic HypF-N oligomers ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03446J, Communication Claudia Capitini, Jayneil R. Patel, Antonino Natalello, Cristiano D’Andrea, Annalisa Relini, James A. Jarvis, Leila Birolo, Alessia Peduzzo, Michele Vendruscolo, Paolo Matteini, Christopher M. Dobson, Alfonso De Simone, Fabrizio Chiti We have studied two misfolded oligomeric forms of the protein HypF-N, which show similar morphologies but very different toxicities. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Enhancement of photoredox catalytic properties of porphyrinic metal–organic frameworks based on titanium incorporation via post-synthetic modification ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04891F, Communication Junhui He, Yajun Zhang, Juan He, Xiaoliang Zeng, Xiandeng Hou, Zhou Long PCN-224 is endowed with greatly enhanced photocatalytic performance for both oxidation and reduction via incorporation of titanium as a metal node. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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“Calix[4]-box” cages promote the formation of amide bonds in water in the absence of coupling reagents ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04561E, Communication Wei-Xu Feng, Liya Dai, Shao-Ping Zheng, Arie van der Lee, Cheng-Yong Su, Mihail Barboiu Calix[4]box cages promote template synthesis via accelerated amide bond formation upon encapsulation in water. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Two-dimensional tellurium nanosheets for photoacoustic imaging-guided photodynamic therapy ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04653K, Communication Yan Lin, Ying Wu, Rong Wang, Guo Tao, Pei-Fu Luo, Xiang Lin, Guoming Huang, Juan Li, Huang-Hao Yang Two-dimensional Te nanosheets were developed as a nanoplatform for photoacoustic imaging-guided photodynamic cancer therapy. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of amphiphilic graphitic silver nanoparticles with inherent internal standards: an efficient strategy for reliable quantitative SERS analysis in common fluids ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04388D, Communication Zhi-Ling Song, Xin Dai, Mengru Li, Zhen Song, Zhuo Chen, Xiliang Luo An efficient strategy for reliable quantitative SERS analysis in fluids by amphiphilic functionalization of graphitic silver nanoparticles with internal standards. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Evidence for the synthesis of an unusual high spin (S = 7/2) [Cu–3Fe–4S] cluster in the radical-SAM enzyme RSAD2 (viperin) ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03565B, Communication K. Honarmand Ebrahimi, C. Silveira, S. Todorovic We demonstrate the synthesis of an unusual high spin [Cu–3Fe–4S] cluster in the radical S-adenosylmethionine enzyme RSAD2 (also known as viperin). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Tailored transition metal-doped nickel phosphide nanoparticles for the electrochemical oxygen evolution reaction (OER) ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03870H, Communication Ho-Wing Man, Chui-Shan Tsang, Molly Meng-Jung Li, Jiaying Mo, Bolong Huang, Lawrence Yoon Suk Lee, Yun-chung Leung, Kwok-Yin Wong, Shik Chi Edman Tsang Foreign transition metals are doped into the nickel phosphide nanoparticles through a simple wet-chemical process to show a high level of doping without significant distortion of crystal structure and morphology, which endows excellent activity in the electrochemical oxygen evolution reaction. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Schiff-base coordination complexes with plutonium(IV) and cerium(IV) ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03571G, Communication Bonnie E. Klamm, Cory J. Windorff, Matthew L. Marsh, David S. Meeker, Thomas E. Albrecht-Schmitt The synthesis and characterization of a Pu(IV) salen complex reveals the stabilization of the +4 oxidation state with respect to that observed with Ce(IV). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Remote activation of nanoparticulate biomimetic activity by light triggered pH-jump ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC04279A, Communication Xiaopei Wang, Ao Gong, Wenhao Luo, Haiqing Wang, Changxu Lin, Xiang Yang Liu, Youhui Lin By incorporating flash photolysis reagents, a facile and versatile method for the photo-regulation of pH-dependent activities of artificial enzymes is presented. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Bimetallic sulfide nanoparticles confined by dual-carbon nanostructures as anodes for lithium-/sodium-ion batteries ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04318C, Communication Jinmeng Lv, Daxun Bai, Lan Yang, Ying Guo, Hong Yan, Sailong Xu Bimetallic sulfide ((Ni0.3Co0.7)9S8) nanoparticles confined by dual-carbon nanostructures are prepared by pyrolyzing a mixture of surfactant-intercalated layered double hydroxide and melamine, and deliver a highly reversible capacity and decent rate... The content of this RSS Feed (c) The Royal Society of Chemistry
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Enantioselective Aliphatic C-H Bond Oxidation Catalyzed by Bioinspired Complexes ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC03165G, Feature Article Michela Milan, Massimo Bietti, Miquel Costas Enantioselective oxidation of aliphatic C-H bonds simultaneoulsy installs functionality and chirality into hydrocarbon units, converting in a single step readily available, rather inert and unexpensive hydrocarbons into precious building blocks... The content of this RSS Feed (c) The Royal Society of Chemistry
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Electronic modulation of carbon encapsulated NiSe composite through Fe doping for synergistic oxygen evolution ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04866E, Communication Bo Xu, Zhiming Chen, Xiaodong Yang, Xiaomei Wang, Yucheng Huang, Cuncheng Li Fe-doped NiSe encapsulated in carbon is synthesized through a simple method using filter paper as sacrificial support and carbon source, exhibiting remarkable OER performance. The doping of Fe modulates the... The content of this RSS Feed (c) The Royal Society of Chemistry
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Stronger Host-guest Binding Does Not Necessarily Give Brighter Particles: A Case Study on a Polymeric AIEE-tunable and Size-tunable Suprasphere ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04905J, Communication Linxian Xu, Rongrong Wang, Wei Cui, Lingyun Wang, Herbert Meier, Hao Tang, Derong Cao The supraspheres were prepared from a pillar[5]arene-based linear polymer (the host) and several multitopic guests. According to host-guest binding studies in the nanosystems, the optical and structural properties (fluorescence capability,... The content of this RSS Feed (c) The Royal Society of Chemistry
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Dynamic kinetic asymmetric transformations of β-halo-α-keto esters by N,N′-dioxide/Ni(II)-catalyzed carbonyl-ene reaction ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04993A, Communication Wen Liu, Weidi Cao, Haipeng Hu, Lili Lin, Xiaoming Feng Dynamic kinetic asymmetric transformations of racemic β-halo-α-keto esters through carbonyl-ene reaction were realized by using a chiral N,N′-dioxide-nickel(II) complex, giving the corresponding β-halo-α-hydroxy esters containing two vicinal chiral tri- and... The content of this RSS Feed (c) The Royal Society of Chemistry
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Blue Light-promoted Cross-Coupling of Aryldiazoacetates and Diazocarbonyl Compounds ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04609C, Communication Tiebo Xiao, Mingjing Mei, Yuwei He, Lei Zhou A blue light-promoted cross-coupling of two distinct diazo compounds was described. The reaction produces E-configured trisubstituted alkenes in good yields in the absence of catalysts and additives. The reactive free... The content of this RSS Feed (c) The Royal Society of Chemistry
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Single-molecule magnet behaviour in a dysprosium-triradical complex ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04739A, Communication Zhao-Xin Xiao, Hao Miao, Dong Shao, Haiyan Wei, Yi-Quan Zhang, Xin-Yi Wang The first triradical bridged binuclear penta-spin single-molecule magnet, [Dy2(hfac)6(BTR)], based on a nitronyl nitroxide triradical was synthesized and characterized. Theoretical calculations revealed the Dy-radical antiferromagnetic coupling and radical-radical ferromagnetic coupling.... The content of this RSS Feed (c) The Royal Society of Chemistry
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One-Pot Selective N-Formylation of Nitroarenes to Formamides Catalyzed by Core-Shell Structured Cobalt Nanoparticles ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC05285A, Communication Xiaosu Dong, Zhaozhan Wang, Yanan Duan, Yong Yang One-pot direct N-formylation of readily available nitroarenes with ammonium formate catalyzed by core-shell structured cobalt nanoparticles has been developed. A broad set of nitroarenes was successfully converted to their corresponding... The content of this RSS Feed (c) The Royal Society of Chemistry
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Convenient synthesis of selenyl-indoles via iodide ion-catalyzed electrochemical C-H selenation ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04543G, Communication Xing Zhang, Chen-Guang Wang, Hong Jiang, Lin-Hao Sun Reported herein is a transition metal- and oxidant-free method for the synthesis of selenyl heteroarenes with diselenides through iodide ion-catalyzed electrolytic selenation. This direct C(sp2)-H selenation strategy, with reduced environmental... The content of this RSS Feed (c) The Royal Society of Chemistry
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Peptide self-cleavage at canaline residue: application to a solubilizing tag system for native chemical ligation ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04579H, Communication Shugo Tsuda, Hideki Nishio, Taku Yoshiya Canaline (Can) is a non-proteinogenic amino acid containing an aminooxy group in its side chain. Can-containing peptides can be synthesized by standard Fmoc SPPS using Fmoc-Can(2-Cl-Trt). Here, for the first... The content of this RSS Feed (c) The Royal Society of Chemistry
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Defective Pt nanoparticles encapsulated in mesoporous metal-organic framework for enhanced catalysis ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04485F, Communication Rong Cao, Yuan-Biao Huang, Qiang Wang, Xusheng Wang, Chun-Hui Chen, Xue Yang Highly dispersed ultrafine defective Pt nanoparticles (NPs) encapsulated in the mesopores of MIL-101 were successfully achieved for the first time through a facile chemical dealloying approach. PtCo alloy NPs inside... The content of this RSS Feed (c) The Royal Society of Chemistry
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TfNHNHBoc as a SCF3 source for the sulfenylation of indoles ()
Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04600J, Communication Jing-Yu Guo, Rui-Han Dai, Wen-Cong Xu, Ruo-Xin Wu, Shi-Kai Tian An unprecedented use of trifluoromethanesulfonyl hydrazides as effective SCF3 sources has been established in the sulfenylation of indoles. A range of substituted indoles participated in CuCl-catalyzed oxidative sulfenylation reaction with... The content of this RSS Feed (c) The Royal Society of Chemistry
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Sensitive and label-free discrimination of 5-hydroxymethylcytosine and 5-methylcytosine in DNA by ligation-mediated rolling circle amplification ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03938K, Communication Zi-yue Wang, Meng Wang, Yan Zhang, Chun-yang Zhang We develop a label-free fluorescence method for sensitive discrimination of 5-hydroxymethylcytosine (5hmC) and 5-methylcytosine (5mC) by ligation-mediated rolling circle amplification. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Palladium-catalyzed C(carbonyl)–C bond cleavage of amides: a facile access to phenylcarbamate derivatives with alcohols ()
Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC03954B, Communication Xufei Yan, Huihui Sun, Haifeng Xiang, Da-Gang Yu, Daibing Luo, Xiangge Zhou A sulfur-containing auxiliary enabled palladium-catalyzed C(carbonyl)–C bond activation of amides was reported to form phenylcarbamate derivatives with alcohols. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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