Chem. Commun.

Enantioselective organocatalytic intramolecular Morita-Baylis-Hillman (IMBH) reaction of dienones, and elaboration of the IMBH adducts to fluorenones ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02524F, Communication Bishnupada Satpathi, Siddhant V. Wagulde , S. S. V. Ramasastry An enantioselective organocatalytic intramolecular Morita-Baylis-Hillman (IMBH) reaction of dienones is reported for the first time. This has been achieved by incorporating entropy and synergy considerations during the substrate design. The... The content of this RSS Feed (c) The Royal Society of Chemistry
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Exploring a wider range of Mg-Ca-Zn metallic glass as biocompatible alloys using combinatorial sputtering ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02733H, Communication Jinyang Li, Forrest S Gittleson, Yanhui Liu, Jingbei Liu, Ayomiposi Michelle Loye, Lyndsey McMillon-Brown, Themis Kyriakides, Jan Schroers , Andre Taylor In order to bypass the limitation of bulk metallic glasses fabrication, we synthesized thin film metallic glasses to study the corrosion characteristics of a wide atomic % composition range, Mg(35.9-63%)Ca(4.1-21%)Zn(17.9-58.3%),... The content of this RSS Feed (c) The Royal Society of Chemistry
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Genetic and Chemical Characterisation of the Cornexistin Pathway Provides Further Insight into Maleidride Biosynthesis ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03303F, Communication Katherine Williams, Agnieszka Szwalbe, Claire Louise Dickson, Tim Desson, Nicholas P Mulholland, Jason L Vincent, John Clough, Andrew M Bailey, Craig Philip Butts, Christine L Willis, Thomas J Simpson, Russell Cox The biosynthesis of the herbicide cornexistin in the fungus Paecilomyces variotii was investigated by full sequencing of its genome, knockout of key genes within its biosynthetic gene cluster and isolation... The content of this RSS Feed (c) The Royal Society of Chemistry
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Stabilizing amyloid-[small beta] peptide by the N-terminus capture is capable of preventing and eliminating amyloid-[small beta] oligomers ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03102E, Communication Gesi Wen, Daoyuan Chen, Wenjing Qin, Binhua Zhou, Youqiao Wang, Ziyi Liu, Jun Du, Qiang Zhou, Junmin Quan, Xianzhang Bu A novel strategy to prevent and eliminate amyloid-[small beta] (A[small beta]) oligomers from either the early aggregation or the fibril dissolution pathway is described. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Naphthalene-fused Dimer of an Anti-aromatic Expanded Isophlorin ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC04050D, Communication Baddigam Kiran Reddy, Jeff Rawson, Santosh C Gadekar, Paul Kogerler, Venkataramanarao Govindan Anand We report the first synthesis of a covalent expanded isophlorin dimer from two 24-[small pi] doubly S-confused sapphyrin-like pentathiaisophlorins. It exhibits marginal peripheral aromaticity rather than strong global diatropicity or paratropicity... The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly Productive CO2 Hydrogenation to Methanol - A Tandem Catalytic Approach via Amide Intermediates ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC04613H, Communication Duncan Wass, Matthew Everett A new system for CO2 reduction to methanol has been demonstrated using homogeneous ruthenium catalysts with a range of amine auxiliaries. Modification of this amine has a profound effect on... The content of this RSS Feed (c) The Royal Society of Chemistry
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Ultrasensitive surface-enhanced Raman scattering detection of urea by highly ordered Au/Cu hybrid nanostructure arrays ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03523C, Communication Kun Chen, xinyi zhang, Doug MacFarlane We report a simple approach to fabricate cost-effective and highly sensitive surface-enhanced Raman scattering substrates based on Au/Cu hybrid nanostructure arrays for the detection of urea, an important molecule in... The content of this RSS Feed (c) The Royal Society of Chemistry
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Cationic silyldiazenido complexes of the Fe(diphosphine)2(N2) platform: structural and electronic models for an elusive first intermediate in N2 fixation ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC04188H, Communication Adam D. Piascik, Peter J. Hill, Andrew D. Crawford, Laurence R. Doyle, Jennifer C. Green, Andrew E. Ashley Functionalisation of Fe-bound dinitrogen affords novel cationic silyldiazenido complexes, which are structural surrogates for unstable protonated intermediates in N2 fixation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Superacid-promoted synthesis of highly porous hypercrosslinked polycarbazoles for efficient CO2 capture ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03620E, Communication Xiang Zhu, Shunmin Ding, Carter W. Abney, Katie L. Browning, Robert L. Sacci, Gabriel M. Veith, Chengcheng Tian, Sheng Dai A superacid-promoted "knitting" strategy has been developed for the generation of hypercrosslinked nanoporous polycarbazoles for efficient CO2 capture. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A visible-light-activated rhodium complex in enantioselective conjugate addition of [small alpha]-amino radicals with Michael acceptors ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03650G, Communication Shao-Xia Lin, Gui-Jun Sun, Qiang Kang An efficient enantioselective conjugate addition of photogenerated [small alpha]-amino radicals to Michael acceptors catalyzed by a single and newly prepared chiral-at-metal rhodium complex was established. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Solventless mechanochemical preparation of novel magnetic bioconjugates ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03975A, Communication Daily Rodriguez-Padron, Alain R. Puente-Santiago, Alina M. Balu, Antonio A. Romero, Rafael Luque A solventless mechanochemical approach was employed to obtain a bioconjugate (BSA-DA-Fe2O3) based on bovine serum albumin (BSA) and dopamine (DA) coated iron oxide magnetic nanoparticles. BSA molecules retained their native-like structure after the mechanochemical synthesis. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Photoredox-catalysed chloro-, bromo- and trifluoromethylthio-trifluoromethylation of unactivated alkenes with sodium triflinate ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01903C, Communication Jing Fang, Zhong-Kui Wang, Shu-Wei Wu, Wei-Guo Shen, Gui-Zhen Ao, Feng Liu A convenient and practical protocol is developed for radical vicinal difunctionalization of unactivated alkenes under transition-metal-free conditions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Adaptability of the metal(III,IV) 1,2,3-trioxobenzene rod secondary building unit for the production of chemically stable and catalytically active MOFs ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC04215A, Communication Georges Mouchaham, Brian Abeykoon, Monica Gimenez-Marques, Sergio Navalon, Andrea Santiago-Portillo, Maame Affram, Nathalie Guillou, Charlotte Martineau, Hermenegildo Garcia, Alexandra Fateeva, Thomas Devic Metal-1,2,3-trioxobenzene rod secondary building units are robust enough to adapt to cations of various charges. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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An enantioselective cascade for simultaneous generation of five quaternary stereocenters from fully substituted enones ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03995F, Communication Shu-Mei Yang, Ganapuram Madhusudhan Reddy, Tzu-Ping Wang, Yu-Sheng Yeh, Min Wang, Wenwei Lin A highly stereoselective organocatalytic cascade is developed for efficient synthesis of polycyclic compounds bearing five quaternary stereocenters. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Generation of highly luminescent micro rings by optical irradiation ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01409K, Communication Jiwoong Kwon, Doyk Hwang, Jong Woo Lee, Inhae Zoh, Jooyoun Kang, Seong Keun Kim We report light-induced generation of a circular, highly luminescent and robust microstructure strongly adhered to a glass surface. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Transition-metal-free synthesis of [small beta]-trifluoromethylated enamines with trifluoromethanesulfinate ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03125D, Communication Huanfeng Jiang, Wei Huang, Yue Yu, Songjian Yi, Jiawei Li, Wanqing Wu Direct olefinic C-H trifluoromethylation of enamines is developed under transition metal-free conditions by using Langlois' reagent (NaSO2CF3). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Intermix of metal nanoparticles-single wall carbon nanotubes ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03696E, Communication Feng Xu, Qin Lu, Lin Ye, S. C. Edman Tsang Separated metal islands with no inter-atomic mixing on single walled carbon nanotubes exhibit electrocatalytic properties comparable to corresponding nanoalloy structures. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Exceptional bi-step switching of quadratic nonlinear optical properties in a one-dimensional channel compound ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02625K, Communication Sijie Liu, Zhihua Sun, Chengmin Ji, Lina Li, Sangen Zhao, Junhua Luo A new solid-state channel compound shows exceptional bi-step switching between three distinct nonlinear optical states. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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ESIPT-Active Organic Compounds with White Luminescence Based on Crystallization-Induced Keto Emission (CIKE) ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03758A, Communication Hongyu Zhang, Huapeng Liu, Xiao Cheng, houyu Zhang, Yue Wang, Shigehiro Yamaguchi Structurally simple pyrazole derivatives that exhibit excited-state intramolecular proton transfer (ESIPT) were synthesized. While these compounds displayed deep violet fluorescence in solution, in the crystalline state they showed white emission... The content of this RSS Feed (c) The Royal Society of Chemistry
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Copper-catalyzed radical cascade oxyalkylation of olefinic amides with simple alkanes: highly efficient access to benzoxazines ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC04213B, Communication Jie Wang, Ruoyu Sang, Xiaolong Chong, Yinuo Zhao, Wenjie Fan, Zejiang Li, Jincan Zhao A copper-catalyzed C(sp3)-H bond functionalization of simple alkanes with olefinic amides was developed for the efficient synthesis of important benzoxazine derivatives. It involves new C-C and C-O bond formation in... The content of this RSS Feed (c) The Royal Society of Chemistry
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Improving bioassay sensitivity through immobilization of bio-probes onto reactive micelles ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02057K, Communication Gloria Jimenez-Sanchez, Celine Terrat, Bernard Verrier, Didier Gigmes, Thomas Trimaille Antigen probe (p24) immobilized onto N-succinimidyl ester based micelles was used as solid phase coating in HIV-1 ELISA test, and induced a significant improvement in antibody detection sensitivity as compared... The content of this RSS Feed (c) The Royal Society of Chemistry
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Collision cross section predictions using 2-dimensional molecular descriptors ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC04257D, Communication M. T. Soper-Hopper, A. S. Petrov, J. N. Howard, S.-S. Yu, J. G. Forsythe, M. A. Grover, F. M. Fernandez This work demonstrates the first collision cross section predictions calculated without 3-dimensional information and their application to prebiotic building blocks. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Real-Time Activity Monitoring of New Delhi Metallo-[small beta]-Lactamase-1 in Living Bacterial Cells by UV-Vis Spectroscopy ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02774E, Communication Ke-Wu Yang, Yajun Zhou, Ying Ge, Yuejuan Zhang We report an UV-Vis method monitoring the hydrolysis of the [small beta]-lactam antibiotics inside living bacterial cells. Cell-based studies demonstrated that the hydrolysis of cefazolin was inhibited by three known NDM-1... The content of this RSS Feed (c) The Royal Society of Chemistry
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Aromatic stacking - the key step in the nucleation of aromatic benzoic acids. ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02423A, Communication Aurora Cruz-Cabeza, Roger J Davey, Sharlinda Salimsachithanantha, Rebecca Smith, Sin Kim Tang, Thomas Vetter, Yan Xiao Crystal nucleation from solution is of central importance in the chemical and biological sciences. Linking nucleation kinetics to the properties of solutes and solvents remains a grand-challenge in physical chemistry.... The content of this RSS Feed (c) The Royal Society of Chemistry
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Halides Tuning Subcellular-Targeting in Two-Photon Emissive Complexes via Different Uptake Mechanisms ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03640J, Communication Xiaohe Tian, Yingzhong Zhu, Qiong Zhang, Ruilong Zhang, Jieying Wu, Yupeng Tian We reported a simple and universal strategy by tuning halides (Cl, Br and I) in terpyridine-Zn(II) complexes to achieve different subcellular organelles targeting (nucleolus, nucleus and intracellular membrane system, respectively)... The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalyst-free N-formylation of amines using BH3NH3 and CO2 at mild conditions ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03860G, Communication Tianxiang Zhao, Gaowen Zhai, JIan Liang, Ping Li, Xingbang Hu, You-Ting Wu Catalyst-free N-formylation of amines using CO2 as the C1 source and BH3NH3 as the reductant is developed for the first time. The corresponding formylated products of both primary and secondary... The content of this RSS Feed (c) The Royal Society of Chemistry
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An NHC-phosphinidenyl as a synthon for new group 13/15 compounds ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC04422D, Communication Otfried Lemp, Markus Balmer, Kevin Reiter, Florian Weigend, Carsten von Hanisch The deprotonated parent phosphinidene SIMesPK (SIMes = 1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene) was used as a synthon for new group 13/15 cycles and cage compounds such as [SIMesPGatBu2]2. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis and characterization of catalytically active thiazolium gold(I)-carbenes ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03791K, Communication Clement C. Dince, Roy A. Meoded, Donald Hilvert Thiazolium gold(I)-carbenes have been found to catalyze 5-endo-dig carbocyclization of an acetylenic dicarbonyl compound in organic solvents and hydroalkoxylation of an allene in aqueous buffer. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Contributors to the Emerging Investigators issue 2017 ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC90241G, Profile To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Immobilization of catalytic virus-like particles in a flow reactor ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03024J, Communication A. Liu, L. Yang, C. H.-H. Traulsen, J. J. L. M. Cornelissen A functional microfluidic reactor is constructed by the immobilization of gold containing virus-based protein cages that catalyze the reduction of nitro-arenes with high efficiency. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Computational design of cephradine synthase in a new scaffold identified from structural databases ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02270K, Communication Xiaoqiang Huang, Jing Xue, Yushan Zhu A new protein scaffold was identified and redesigned to catalyze the synthesis of [small beta]-lactam antibiotic cephradine. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Orthogonal electronic coupling in multicentre arylamine mixed-valence compounds based on a dibenzofulvene-thiophene conjugated bridge ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03156D, Communication A. Beneduci, G. A. Corrente, E. Fabiano, V. Maltese, S. Cospito, G. Ciccarella, G. Chidichimo, G. Gigli, A.-L. Capodilupo Novel H-shaped tetrarylamine mixed valence compounds showing orthogonal electronic coupling generate voltage-dependent electro-optical modulation in the near infrared region. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Double duplex invasion of DNA induced by ultrafast photo-cross-linking using 3-cyanovinylcarbazole for antigene methods ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01746D, Communication Shigetaka Nakamura, Hayato Kawabata, Kenzo Fujimoto New photoresponsive antigene probes containing CNVK and CNU have a high double-duplex invasion capability upon photoirradiation because of the inhibition of photo-cross-linking between the probes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ferrocene-BODIPYmerocyanine dyads: new NIR absorbing platforms with optical properties susceptible to protonation ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03332J, Communication Yuriy V. Zatsikha, Natalia O. Didukh, Dion Nemez, Adrien C. Schlachter, Paul-Ludovic Karsenti, Yuriy P. Kovtun, Pierre D. Harvey, Victor N. Nemykin Ferrocene-BODIPYmerocyanine dyads 5 and 6 were synthesized and characterized by spectroscopy, electrochemistry, and DFT calculations. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Dissolution behaviour and activation of selenium in phosphonium based ionic liquids ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03564K, Communication Tao Zhang, Kai Schwedtmann, Jan J. Weigand, Thomas Doert, Michael Ruck The dissolution behaviour of grey selenium in phosphonium based ionic liquids (ILs) has been investigated for the first time by 31P and 77Se nuclear magnetic resonance (NMR) experiments. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A freestanding NiSx porous film as a binder-free electrode for Mg-ion batteries ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03517A, Communication K. Liang, K. Marcus, L. Guo, Z. Li, L. Zhou, Y. Li, S. T. De Oliveira, N. Orlovskaya, Y.-H. Sohn, Yang Yang A freestanding NiSx porous film delivers high volumetric Mg-ion storage capacity. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Differential detection and quantification of cyclic AMP and other adenosine phosphates in live cells ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02935G, Communication Sujoy Das, Himadri Sekhar Sarkar, Md Raihan Uddin, Kari Rissanen, Sukhendu Mandal, Prithidipa Sahoo A 'turn on' chemosensor (NpRD) has been developed for the selective and differential detection of cyclic AMP in human blood cells. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Field effects to slow magnetic relaxation in a mononuclear Ni(II) complex ()
Chem. Commun., 2017, 53,6930-6932 DOI: 10.1039/C7CC03275G, Communication D. Lomjansky, J. Moncol', C. Rajnak, J. Titis, R. Boca A mononuclear Ni(II) complex [Ni(NCS)2(nqu)2(H2O)2][middle dot]2nqu (nqu - 5-nitroquinoline) shows a field induced slow magnetic relaxation with three relaxation domains. The relaxation time for the low-frequency mode is as slow as [small tau] = 0.3 s at T = 1.9 K and BDC = 0.4 T. The content of this RSS Feed (c) The Royal Society of Chemistry
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A nitrile-stabilized ammonium ylide as a masked C-C[double bond, length as m-dash]N synthon in heterocyclization with amidine-imine: 3-component assembly to fused pyrimidine scaffolds ()
Chem. Commun., 2017, 53,6941-6944 DOI: 10.1039/C7CC02946B, Communication Sankar K. Guchhait, Meenu Saini, Divyani Sumkaria, Vikas Chaudhary The title ylides possessing a unique reactivity-pattern and nitrile's dual role cyclo-condense with amidine-amine via a pathway of electronically-assisted nucleophilic substitutions and Hofmann elimination. The content of this RSS Feed (c) The Royal Society of Chemistry
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Copper nanoparticles socketed in situ into copper phyllosilicate nanotubes with enhanced performance for chemoselective hydrogenation of esters ()
Chem. Commun., 2017, 53,6933-6936 DOI: 10.1039/C7CC02093G, Communication Xiaoxiao Gong, Meiling Wang, Huihuang Fang, Xiaoqi Qian, Linmin Ye, Xinping Duan, Youzhu Yuan Copper nanoparticles exsoluted in situ under a reducing atmosphere at elevated temperatures are socketed into the parent copper phyllosilicate nanotubes and exhibit excellent catalytic performance and superior stability for the selective hydrogenation of various esters to alcohols. The content of this RSS Feed (c) The Royal Society of Chemistry
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Water mediated proton conduction in a sulfonated microporous organic polymer ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02117H, Communication C. Klumpen, S. Godrich, G. Papastavrou, J. Senker High proton conductivity mediated by water molecules adsorbed within the micro- and mesopores of the sulfonated porous polymer PAF-1. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Palladium-catalyzed intermolecular carbonylative cross-coupling of heteroaryl C(sp2)-H bonds with amines: an efficient strategy for oxidative aminocarbonylation of azoles ()
Chem. Commun., 2017, 53,6914-6917 DOI: 10.1039/C7CC03274A, Communication Qi Xing, Hui Lv, Chungu Xia, Fuwei Li We report the first intermolecular carbonylative cross-coupling of heteroaryl C(sp2)-H bonds with amines using oxygen as the green oxidant. The content of this RSS Feed (c) The Royal Society of Chemistry
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Strong metal-support interaction between Pt and SiO2 following high-temperature reduction: a catalytic interface for propane dehydrogenation ()
Chem. Commun., 2017, 53,6937-6940 DOI: 10.1039/C7CC03859C, Communication Lidan Deng, Hiroki Miura, Tetsuya Shishido, Saburo Hosokawa, Kentaro Teramura, Tsunehiro Tanaka Pt/SiO2 directly reduced in H2 at 1073 K exhibited a high catalytic activity in propane dehydrogenation, primarily attributed to the electronic modification of Pt nanoparticles by the SMSI effect. The content of this RSS Feed (c) The Royal Society of Chemistry
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Palladium and visible-light mediated carbonylative Suzuki-Miyaura coupling of unactivated alkyl halides and aryl boronic acids ()
Chem. Commun., 2017, 53,6895-6898 DOI: 10.1039/C7CC02763J, Communication Sara Roslin, Luke R. Odell An efficient carbonylative coupling of aryl boronic acids and unactivated alkyl halides under visible-light irradiation and low CO-pressure is presented. The content of this RSS Feed (c) The Royal Society of Chemistry
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A supramolecular assembly based on an engineered hemoprotein exhibiting a thermal stimulus-driven conversion to a new distinct supramolecular structure ()
Chem. Commun., 2017, 53,6879-6882 DOI: 10.1039/C7CC02678A, Communication Koji Oohora, Yoshitaka Onuma, Yuta Tanaka, Akira Onoda, Takashi Hayashi An engineered hemoprotein monomer forms a stable fiber-type assembly and metastable micelle-type assembly induced by transient thermal stimulus. The content of this RSS Feed (c) The Royal Society of Chemistry
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Thermal ring-opening polymerization of an unsymmetrical silicon-bridged [1]ferrocenophane in coordination nanochannels ()
Chem. Commun., 2017, 53,6945-6948 DOI: 10.1039/C7CC03391E, Communication Yuichiro Kobayashi, Kayako Honjo, Susumu Kitagawa, Jessica Gwyther, Ian Manners, Takashi Uemura Thermal ring-opening polymerization of the unsymmetrically substituted [1]ferrocenophane was performed in one-dimensional nanochannels of porous coordination polymers (PCPs). The content of this RSS Feed (c) The Royal Society of Chemistry
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Pt-Cu hierarchical quasi great dodecahedrons with abundant twinning defects for hydrogen evolution ()
Chem. Commun., 2017, 53,6922-6925 DOI: 10.1039/C7CC03643D, Communication Ruijie Huang, Zhongti Sun, Sheng Chen, Siyu Wu, Zeqi Shen, Xiaojun Wu, Jie Zeng Hierarchical metal nanostructures which exhibit an open structure and a high density of twin defects accessible to reactants hold great promise in catalysis. The content of this RSS Feed (c) The Royal Society of Chemistry
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The efficient synthesis and purification of amyloid-[small beta](1-42) using an oligoethylene glycol-containing photocleavable lysine tag ()
Chem. Commun., 2017, 53,6903-6905 DOI: 10.1039/C7CC03147E, Communication John A. Karas, Asif Noor, Christine Schieber, Timothy U. Connell, Frances Separovic, Paul S. Donnelly An oligoethylene glycol-containing photocleavable lysine tag was developed to facilitate the efficient synthesis and purification of the A[small beta]42 peptide. The content of this RSS Feed (c) The Royal Society of Chemistry
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A ferrocene based switchable molecular folding ruler ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03358C, Communication Synove O. Scottwell, Jonathan E. Barnsley, C. John McAdam, Keith C. Gordon, James D. Crowley A bis(ferrocene) three tiered molecular folding ruler can be induced to undergo a large scale extension and contraction process using either chemical or better electrochemical methods. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Cobaloxime-catalyzed hydration of terminal alkynes without acidic promoters ()
Chem. Commun., 2017, 53,6926-6929 DOI: 10.1039/C7CC03919K, Communication Shengtai Hou, Hongjian Yang, Bin Cheng, Hongbin Zhai, Yun Li Cobaloxime [Co(dmgBF2)2[middle dot]2H2O], an inexpensive first-row transition-metal complex, catalyzed hydration of terminal alkynes gave the corresponding methyl ketones in good to excellent yields under neutral conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Enantioselective synthesis of tetrahydrocyclopenta[b]indole bearing a chiral quaternary carbon center via Pd(II)-SPRIX-catalyzed C-H activation ()
Chem. Commun., 2017, 53,6887-6890 DOI: 10.1039/C7CC03199H, Communication Mohamed Ahmed Abozeid, Shiho Sairenji, Shinobu Takizawa, Makoto Fujita, Hiroaki Sasai Pd(II)-SPRIX promotes the first highly enantioselective cyclization of 3-alkenylindoles into the corresponding indoles bearing a chiral quaternary carbon center via C-H activation and an assisting effect by the allyl substituent. The content of this RSS Feed (c) The Royal Society of Chemistry
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A single quantum dot-based nanosensor for the signal-on detection of DNA methyltransferase ()
Chem. Commun., 2017, 53,6868-6871 DOI: 10.1039/C7CC03736H, Communication Fei Ma, Wen-jing Liu, Bo Tang, Chun-yang Zhang We develop a single quantum dot-based nanosensor for the signal-on detection of DNA methyltransferase with high sensitivity and good selectivity. The content of this RSS Feed (c) The Royal Society of Chemistry
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Achieving the highest efficiency using a BODIPY core decorated with dithiafulvalene wings for small molecule based solution-processed organic solar cells ()
Chem. Commun., 2017, 53,6953-6956 DOI: 10.1039/C7CC03363J, Communication R. Srinivasa Rao, Anirban Bagui, G. Hanumantha Rao, Vinay Gupta, Surya Prakash Singh A novel boron dipyrromethene based dye, coded as BODIPY-DTF, decorated with dithiafulvalene wings has been developed for solar cell application. The content of this RSS Feed (c) The Royal Society of Chemistry
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Potential of polymethacrylate pseudo crown ethers as solid state polymer electrolytes ()
Chem. Commun., 2017, 53,6899-6902 DOI: 10.1039/C7CC02385E, Communication S. Moins, J. C. Martins, A. Krumpmann, V. Lemaur, J. Cornil, N. Delbosc, A. Decroly, Ph. Dubois, R. Lazzaroni, J.-F. Gohy, O. Coulembier The association of kinetic studies, DFT calculations and 1H-7Li NMR analyses allowed the control of the cyclo-ATRP of PEG9DMA and the production of polymethacrylate pseudo crown-ethers of various molar masses. The content of this RSS Feed (c) The Royal Society of Chemistry
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An excellent rechargeable PP14TFSI ionic liquid dual-ion battery ()
Chem. Commun., 2017, 53,6891-6894 DOI: 10.1039/C7CC02534C, Communication Jiaxin Fan, Zhixiong Zhang, Yinhua Liu, Aiye Wang, Li Li, Wenhui Yuan PP14TFSI dual-ion cells exhibit superior performance of a 4.4 V discharge plateau and 600 cycles without capacity decay. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly enantioselective synthesis of fused bicyclic dihydropyranones via low-loading N-heterocyclic carbene organocatalysis ()
Chem. Commun., 2017, 53,6875-6878 DOI: 10.1039/C7CC02921G, Communication Jun-Long Li, Lu Fu, Jiao Wu, Kai-Chuan Yang, Qing-Zhu Li, Xiao-Jun Gou, Cheng Peng, Bo Han, Xu-Dong Shen A NHC catalyzed highly diastereo and enantioselective [4+2] cycloaddition has been achieved with extremely low catalyst loadings, including the lowest loading ever reported for NHC organocatalysis (0.025 mol%, 250 ppm). The content of this RSS Feed (c) The Royal Society of Chemistry
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Efficient energy-level modification of novel pyran-annulated perylene diimides for photocatalytic water splitting ()
Chem. Commun., 2017, 53,6918-6921 DOI: 10.1039/C7CC03682E, Communication Ran Wang, Gang Li, Andong Zhang, Wen Wang, Guanwei Cui, Jianfeng Zhao, Zhiqiang Shi, Bo Tang This work reports a facile method to prepare pyran-annulated perylene diimides, which are used as photocatalysts in photocatalytic water splitting. The content of this RSS Feed (c) The Royal Society of Chemistry
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A host-guest system based on collagen-like triple-helix hybridization ()
Chem. Commun., 2017, 53,6856-6859 DOI: 10.1039/C7CC03055J, Communication N. Delsuc, S. Uchinomiya, A. Ojida, I. Hamachi A peptide recognition strategy based on triple helix hybridization leads to a host-guest system showing high affinity and selectivity in an aqueous medium. The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal free mild and selective aldehyde cyanosilylation by a neutral penta-coordinate silicon compound ()
Chem. Commun., 2017, 53,6910-6913 DOI: 10.1039/C7CC03948D, Communication V. S. V. S. N. Swamy, Milan Kumar Bisai, Tamal Das, Sakya S. Sen This study demonstrates the first example of the use of a penta-coordinate Si(IV) hydride (PhC(NtBu)2SiH(CH3)Cl) as a catalyst for the cyanosilylation of a variety of aldehydes under mild conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
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A dielectric anomaly observed for doubly reduced mixed-valence polyoxometalate ()
Chem. Commun., 2017, 53,6824-6827 DOI: 10.1039/C7CC03361C, Communication Ippei Nakamura, Ryo Tsunashima, Sadafumi Nishihara, Katsuya Inoue, Tomoyuki Akutagawa A doubly reduced mixed-valence Keggin cluster exhibited a dielectric anomaly that originated from dipole relaxation. The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal-free radical oxidative alkoxycarbonylation and imidation of alkanes ()
Chem. Commun., 2017, 53,6852-6855 DOI: 10.1039/C7CC03671J, Communication Lijun Lu, Danyang Cheng, Yuanfeng Zhan, Renyi Shi, Chien-Wei Chiang, Aiwen Lei The metal-free radical oxidative carbonylation of alkanes proceeded to give the corresponding esters and imides in good to high yields. The content of this RSS Feed (c) The Royal Society of Chemistry
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Modified biovectors for the tuneable activation of anti-platelet carbon monoxide release ()
Chem. Commun., 2017, 53,6840-6843 DOI: 10.1039/C7CC03642F, Communication Lucas Prieto, Jeremie Rossier, Katarzyna Derszniak, Jakub Dybas, Rene M. Oetterli, Emmanuel Kottelat, Stefan Chlopicki, Felix Zelder, Fabio Zobi This communication describes the anti-platelet effects of a new class of cis-rhenium(II)-dicarbonyl-vitamin B12 complexes (B12-ReCORMs) with tuneable CO releasing properties. The content of this RSS Feed (c) The Royal Society of Chemistry
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A highly enantioselective access to chiral chromanones and thiochromanones via copper-catalyzed asymmetric conjugated reduction of chromones and thiochromones ()
Chem. Commun., 2017, 53,6844-6847 DOI: 10.1039/C7CC03939E, Communication Donglu Xiong, Wenxi Zhou, Zhiwu Lu, Suping Zeng, Jun (Joelle) Wang The chromanone scaffold is a privileged structure in heterocyclic chemistry and drug discovery. The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal-free formal carbon-halogen bond insertion: facile syntheses of 3-halo 3,3[prime or minute]-disubstituted oxindoles and spirooxindole-[gamma]-butyrolactones ()
Chem. Commun., 2017, 53,6860-6863 DOI: 10.1039/C7CC03765A, Communication Rong Zhou, Rongfang Liu, Kai Zhang, Ling Han, Honghui Zhang, Wenchao Gao, Ruifeng Li A metal-free carbon-heteroatom bond insertion of isatins into allylic and benzylic bromides/chlorides is reported. The content of this RSS Feed (c) The Royal Society of Chemistry
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A novel indeno[1,2-b]pyridinone derivative, a DNA intercalative human topoisomerase II[small alpha] catalytic inhibitor, for caspase 3-independent anticancer activity ()
Chem. Commun., 2017, 53,6864-6867 DOI: 10.1039/C7CC02372C, Communication K. H. Jeon, C. Park, T. M. Kadayat, A. Shrestha, E. S. Lee, Y. Kwon A novel 2-(furan-2-yl)-4-(pyridin-2-yl)-5H-indeno[1,2-b]pyridin-5-one (TI-1-190) was synthesized using a simple microwave-assisted method and its mode of action was systematically characterized. The content of this RSS Feed (c) The Royal Society of Chemistry
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Investigation of zinc ion storage of transition metal oxides, sulfides, and borides in zinc ion battery systems ()
Chem. Commun., 2017, 53,6872-6874 DOI: 10.1039/C7CC01064H, Communication Wenbao Liu, Jianwu Hao, Chengjun Xu, Jian Mou, Liubing Dong, Fuyi Jiang, Zhuang Kang, Junlin Wu, Baozheng Jiang, Feiyu Kang MnS has the capability of storing zinc ions with high capacity and long cycle performance. The content of this RSS Feed (c) The Royal Society of Chemistry
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Incorporation studies of clickable ceramides in Jurkat cell plasma membranes ()
Chem. Commun., 2017, 53,6836-6839 DOI: 10.1039/C7CC01220A, Communication T. Walter, J. Schlegel, A. Burgert, A. Kurz, J. Seibel, M. Sauer The acyl chain length and the azide position strongly influence the accessibility of the DBCO-dye, which was studied via TCEP quenching and anisotropy experiments. The content of this RSS Feed (c) The Royal Society of Chemistry
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Electrochemical performance of MXenes as K-ion battery anodes ()
Chem. Commun., 2017, 53,6883-6886 DOI: 10.1039/C7CC02026K, Communication Michael Naguib, Ryan A. Adams, Yunpu Zhao, Dmitry Zemlyanov, Arvind Varma, Jagjit Nanda, Vilas G. Pol Herein, we report on the electrochemical performance of two-dimensional transition metal carbonitrides as novel promising electrode materials in K-ion batteries. The content of this RSS Feed (c) The Royal Society of Chemistry
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Developing a ferroelectric nanohybrid for enhanced photocatalysis ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02548C, Communication Zhipeng Wang, Jianmin Song, Feng Gao, Ran Su, Dawei Zhang, Yang Liu, Congcong Xu, Xiaojie Lou, Yaodong Yang We develop a ferroelectric nanohybrid that improves photocatalytic efficiency by reducing the recombination of holes and electron charge carriers. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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One-dimensional silicon nanoshuttles simultaneously featuring fluorescent and magnetic properties ()
Chem. Commun., 2017, 53,6957-6960 DOI: 10.1039/C7CC02964K, Communication Bin Song, Yiling Zhong, Houyu Wang, Yuanyuan Su, Yao He Fluorescent and magnetic one-dimensional silicon nanoshuttles are prepared in situ through a metal ions-assisted microwave synthetic strategy. The content of this RSS Feed (c) The Royal Society of Chemistry
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Exploration of organic-inorganic hybrid perovskites for surface-enhanced infrared spectroscopy of small molecules ()
Chem. Commun., 2017, 53,6949-6952 DOI: 10.1039/C7CC02782F, Communication Jia Chen, Zhi-Hong Mo, Xiao Yang, Hai-Ling Zhou, Qin Gao Organic-inorganic hybrid perovskites allow the infrared absorption of small molecules to be efficiently enhanced. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ruthenium(II)-catalyzed intermolecular synthesis of 2-arylindolines through C-H activation/oxidative cyclization cascade ()
Chem. Commun., 2017, 53,6906-6909 DOI: 10.1039/C7CC03053C, Communication Manash Kumar Manna, Samir Kumar Bhunia, Ranjan Jana A novel ruthenium(II)-catalyzed, pyrimidine-directed synthesis of 2-arylindolines with unbiased vinyl arenes via interrupted Heck manifold is reported. The content of this RSS Feed (c) The Royal Society of Chemistry
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Dual gold/photoredox-catalyzed bis-arylative cyclization of chiral homopropargyl sulfonamides with diazonium salts: rapid access to enantioenriched 2,3-dihydropyrroles ()
Chem. Commun., 2017, 53,6848-6851 DOI: 10.1039/C7CC03262E, Communication Ze-Shu Wang, Tong-De Tan, Cai-Ming Wang, Ding-Qiang Yuan, Te Zhang, Pengfei Zhu, Chunyin Zhu, Jin-Mei Zhou, Long-Wu Ye A novel dual gold/photoredox-catalyzed bis-arylative cyclization of chiral homopropargyl sulfonamides with diazonium salts is presented. The content of this RSS Feed (c) The Royal Society of Chemistry
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Silver-mediated radical 5-exo-dig cyclization of 2-alkynylbenzonitriles: synthesis of phosphinylated 1-indenones ()
Chem. Commun., 2017, 53,6828-6831 DOI: 10.1039/C7CC01666B, Communication Xiao-Tong Zhu, Qi Zhao, Feng Liu, Ai-Fang Wang, Pei-Jun Cai, Wen-Juan Hao, Shu-Jiang Tu, Bo Jiang A new silver-mediated 5-exo-dig cyclization of 2-alkynylbenzonitriles with disubstituted phosphine oxide and H2O has been developed. The content of this RSS Feed (c) The Royal Society of Chemistry
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Conversion of methanol to hydrocarbons over zeolite ZSM-23 (MTT): exceptional effects of particle size on catalyst lifetime ()
Chem. Commun., 2017, 53,6816-6819 DOI: 10.1039/C6CC10118F, Communication A. Molino, K. A. Lukaszuk, D. Rojo-Gama, K. P. Lillerud, U. Olsbye, S. Bordiga, S. Svelle, P. Beato A variety of synthetic procedures have been used to obtain zeolite ZSM-23 (MTT) catalysts with crystallite sizes ranging from the micrometer to nanometer scale. The content of this RSS Feed (c) The Royal Society of Chemistry
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Transcriptional regulatory proteins as biosensing tools ()
Chem. Commun., 2017, 53,6820-6823 DOI: 10.1039/C6CC09512G, Communication Kendrick Turner, Smita Joel, Jessika Feliciano, Agatha Feltus, Patrizia Pasini, Daniel Wynn, Peter Dau, Emre Dikici, Sapna K. Deo, Sylvia Daunert We have developed sensing systems employing different classes of transcriptional regulatory proteins genetically and chemically modified to incorporate a fluorescent reporter molecule for detection of arsenic, hydroxylated polychlorinated biphenyls (OH-PCBs), and cyclic AMP (cAMP). The content of this RSS Feed (c) The Royal Society of Chemistry
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A CaMn4O2 model of the biological oxygen evolving complex: synthesis via cluster expansion on a low symmetry ligand ()
Chem. Commun., 2017, 53,6832-6835 DOI: 10.1039/C7CC02313H, Communication Heui Beom Lee, Emily Y. Tsui, Theodor Agapie A pentanuclear CaMn4O2 cluster with the same metal stoichiometry as the biological OEC was prepared from a tetranuclear Mn precursor. The content of this RSS Feed (c) The Royal Society of Chemistry
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Expeditious Synthesis of Pyrano[2,3,4-de]quinolines via Rh(III)-Catalyzed Cascade C-H Activation/Annulation/Lactonization of Quinolin-4-ol with Alkynes ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC04113F, Communication Gang Liao, Hong Song, Xue-Song Yin, Bing-Feng Shi Rh(III)-Catalyzed cascade C-H activation/annulation/lactonization of quinoline-4-ols and alkynes has been reported. A broad range of tetracyclic pyrano[2,3,4-de]quinolines have been prepared in one-step with good functional group tolerance, excellent site selectivity,... The content of this RSS Feed (c) The Royal Society of Chemistry
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Two-dimensional graphene-like N, Co-codoped carbon nanosheets derived from ZIF-67 polyhedrons for efficient oxygen reduction reaction ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC02848B, Communication Yanan Hou, Zongbin Zhao, Zhengfa Yu, Yongchao Tang, Xuzhen Wang, Jieshan Qiu Two-dimensional graphene-like N, Co-codoped carbon nanosheets (N, Co-CNSs), which exhibit excellent stability, competitive catalytic activity and superior methanol tolerance compared to the commercial Pt/C catalyst, have been successfully fabricated using... The content of this RSS Feed (c) The Royal Society of Chemistry
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Thermal Decomposition Pathways of Nitro-functionalized Metal-Organic Frameworks ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03354K, Communication Kyle Andrew McDonald, Nakeun Ko, Kyungkyou Noh, Jonathan C. Bennion, Jaheon Kim, Adam Matzger The decomposition behavior of high energy metal-organic frameworks (MOFs) with extensive nitration is disclosed. In contrast to the detonation behavior observed in molecular energetic compounds, deflagration transforms cubic MOFs into... The content of this RSS Feed (c) The Royal Society of Chemistry
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Dissipation of Self-assemblies by Fusion of Complementary Gels: An Elegant Strategy for Programmed Enzymatic Reaction ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC04269H, Communication Deep Mandal, Pritam Choudhury, Deblina Sarkar, Prasanta Kumar Das Cholesterol based phenylboronic acid and glucose tailored amphiphiles were developed. These amphiphiles showed gelation in a common solvent DMF-water (2:1 v/v) binary solvent mixture. Interestingly, when these gels were mixed... The content of this RSS Feed (c) The Royal Society of Chemistry
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Niobate nanosheet membranes with enhanced stability for nanofiltration ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03911E, Communication Keizo Nakagawa, Hiroharu Yamashita, Daisuke Saeki, Tomohisa Yoshioka, Takuji Shintani, Eiji Kamio, Hannah Theresa Kreissl, Edman Tsang, Shigeru Sugiyama, Hideto Matsuyama Niobate nanosheets are assembled into thin membranes by a vacuum filtration. The nanosheet membranes have a dense and stable structure in water via chemical cross-linking and show higher permeance and... The content of this RSS Feed (c) The Royal Society of Chemistry
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Chiral N,N'-Dioxide/Co(II)-Promoted Asymmetric 1,3-Dipolar Cycloaddition of Nitrones with Methyleneindolinones ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03575F, Communication Dong Zhang, Chengkai Yin, Yuhang Zhou, Yali Xu, Lili Lin, Xiaohua Liu, Xiaoming Feng A chiral N,N'-dioxide/Co(BF4)2[round bullet, filled]6H2O complex catalytic system has been developed to efficiently catalyze the asymmetric 1,3-dipolar cycloaddition of nitrones with methyleneindolinones. The corresponding chiral multisubsitituted spiroisoxazolidines with three contiguous quaternary-tertiary stereocenters... The content of this RSS Feed (c) The Royal Society of Chemistry
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Asymmetric Radical Alkylation of N-Sulfinimines under Visible Light Photocatalytic Conditions ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03724D, Communication Alberto F. Garrido-Castro, Houcine Chobane, Daaou Mortada, M. Carmen Maestro Rubio, Jose Aleman In this communication, a new photocatalytic strategy for the addition of alkyl-radical derivatives to N-sulfinimines with complete diastereoselectivity and moderate to good yields is presented. This is the first asymmetric... The content of this RSS Feed (c) The Royal Society of Chemistry
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Efficient conversion of N6-threonylcarbamoyladenosine (t6A) into tRNA native hydantoin cyclic form (ct6A) performed at nucleoside and oligoribonucleotide levels ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC03560H, Communication Michal Matuszewski, Katarzyna Debiec, Elzbieta J Sochacka A t6A nucleoside was efficiently and stereospecifically transformed into a hydantoin cyclic form of N6-L-threonylcarbamoyladenosine (ct6A) by the use of polymer bounded carbodiimide (EDC-P) and HOBt. The procedure was succesfully... The content of this RSS Feed (c) The Royal Society of Chemistry
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Semithiobambus[6]uril is a transmembrane anion transporter ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC04026A, Communication Chao Lang, Amar Mohite, Xiaoli Deng, Feihu Yang, Zeyuan Dong, Jiayun Xu, Junqiu Liu, Ehud Keinan, Ofer Reany Bambus[6]uril analogs are excellent anion binders but only the sulfur analog is also an effective anion transporter capable of polarizing lipid membranes through selective anion uniport. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Breathing-induced new phase transition in an MIL-53(Al)-NH2 metal-organic framework under high methane pressures ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02743E, Communication Linius Bolinois, Tanay Kundu, Xuerui Wang, Yuxiang Wang, Zhigang Hu, Kenny Koh, Dan Zhao The room temperature methane sorption tests on a flexible MOF reveal a new phase transition to a large pore phase above 45 bar, which is helpful to increase the deliverable capacity for natural gas storage. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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SNAr catalysis enhanced by an aromatic donor-acceptor interaction; facile access to chlorinated polyfluoroarenes ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03996D, Communication Sameera Senaweera, Jimmie D. Weaver The use of TMSCl skews the thermodynamics of the Halex reaction, allowing catalysis and access to functionalized fluoroarenes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Engineering multi-functional bacterial outer membrane vesicles as modular nanodevices for biosensing and bioimaging ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC04246A, Communication Qi Chen, Sharon Rozovsky, Wilfred Chen We report here a one-pot synthesis approach to engineer multi-functionalized OMV-based sensors for both antigen binding and signal generation. A virtually unlimited combination of capturing and reporting moieties can be created for a wide range of biosensing and bioimaging applications. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Chemically induced degradation of CDK9 by a proteolysis targeting chimera (PROTAC) ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03879H, Communication Caroline M. Robb, Jacob I. Contreras, Smit Kour, Margaret A. Taylor, Mohammad Abid, Yogesh A. Sonawane, Muhammad Zahid, Daryl J. Murry, Amarnath Natarajan, Sandeep Rana In this manuscript, for the first time, we report the synthesis of a PROTAC that selectively degrades cyclin dependent kinase 9 (CDK9). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Micro- and nano-patterned conductive graphene-PEG hybrid scaffolds for cardiac tissue engineering ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01988B, Communication Alec S. T. Smith, Hyok Yoo, Hyunjung Yi, Eun Hyun Ahn, Justin H. Lee, Guozheng Shao, Ekaterina Nagornyak, Michael A. Laflamme, Charles E. Murry, Deok-Ho Kim Topographic and graphene-functionalized culture substrates were fabricated to regulate cardiac structure and function through manipulation of micro- and nano-scale mechanical and electroconductive cues. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Carbon dots promoted vanadium flow batteries for all-climate energy storage ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00691H, Communication Ying Zhou, Le Liu, Yi Shen, Lantao Wu, Lihong Yu, Feng Liang, Jingyu Xi VFB with a CDs@GF electrode exhibits outstanding rate performance, superior cycling stability, and broad temperature adaptability from -20 to 60 [degree]C. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Pd(0)-Catalyzed intramolecular arylative dearomatization of [small beta]-naphthols ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC04022A, Communication Ren-Qi Xu, Ping Yang, Shu-Li You An efficient Pd(0)-catalyzed intramolecular arylative dearomatization of [small beta]-naphthols was developed to afford a series of structurally diverse spirocarbocycles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Base-promoted, deborylative secondary alkylation of N-heteroaromatic N-oxides with internal gem-bis[(pinacolato)boryl]alkanes: a facile derivatization of 2,2[prime or minute]-bipyridyl analogues ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03731G, Communication Chiwon Hwang, Woohyun Jo, Seung Hwan Cho A base-promoted, secondary alkylation of N-heteroaromatic N-oxides using internal gem-bis[(pinacolato)boryl]alkanes as alkylation reagents is achieved to form deoxygenated secondary alkylated N-heteroarenes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Recent advances in the computational chemistry of soft porous crystals ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03306K, Feature Article Guillaume Fraux, Francois-Xavier Coudert We highlight recent progress in the field of computational chemistry of nanoporous materials, focusing on methods and studies that address the extraordinary dynamic nature of these systems: the high flexibility of their frameworks, the large-scale structural changes upon external physical or chemical stimulation, and the presence of defects and disorder. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Functionalised cyclodextrin-based metal-organic frameworks ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC03345A, Communication K. J. Hartlieb, A. W. Peters, T. C. Wang, P. Deria, O. K. Farha, J. T. Hupp, J. F. Stoddart A CD-MOF is prepared from amino-functionalized (blue moon) [gamma]-CD, which permanently captures CO2 as a carbamate (red moon). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Wavelength-selective and high-contrast multicolour fluorescence photoswitching in a mixture of photochromic nanoparticles ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02938A, Communication Sanae Ishida, Tuyoshi Fukaminato, Daichi Kitagawa, Seiya Kobatake, Sunnam Kim, Tomonari Ogata, Seiji Kurihara Wavelength-selective and high-contrast multicolour fluorescence photoswitching was successfully demonstrated based on the nonlinear fluorescence quenching in photochromic nanoparticles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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An annealing-free aqueous-processed anatase TiO2 compact layer for efficient planar heterojunction perovskite solar cells ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC01104K, Communication Chengwu Yang, Mingyu Yu, Dichun Chen, Yaqing Zhou, Wei Wang, Yang Li, Tung-Chun Lee, Daqin Yun We report efficient perovskite solar cells (PCE = 18.29 +/- 0.18%) based on TiO2 films synthesised via a facile aqueous, annealing-free route. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Development of air-stable hydrogen evolution catalysts ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02941A, Feature Article Biswajit Mondal, Abhishek Dey Obtaining abundant pure hydrogen by reduction of water has an important implication in the development of clean and renewable energy. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Hexagonal boron nitride supported mesoSiO2-confined Ni catalysts for dry reforming of methane ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC02007D, Communication Yang Cao, Meirong Lu, Jianhui Fang, Liyi Shi, Dengsong Zhang Hexagonal boron nitride supported mesoSiO2-confined Ni catalysts were designed and developed for dry reforming of methane. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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