Chem. Commun.



Highly Stereoselective Synthesis of Aryl/Heteroaryl-C-Nucleosides via the Merger of Photoredox and Nickel Catalysis ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07184A, Communication Yingying Ma, Shihui Liu, Yifan Xi, Hongrui Li, Kai Yang, Zhihao Cheng, Wei Wang, Yongqiang Zhang A photoredox/nickel dual-catalyzed decarboxylative cross-coupling reaction of anomeric ribosyl/deoxyribosyl acids with aryl/heteroaryl bromides has been developed. The reaction proceeds smoothly under visible-light irradiation and features the using of cost-effective and... The content of this RSS Feed (c) The Royal Society of Chemistry
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Chemo-Enzymatic Three-Step Conversion of Glucose to Kojic Acid ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07405H, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Robert Lassfolk, Anu Suonpää, Klara Birik, Reko Leino Glucosone is a reactive carbohydrate produced from D-glucose by selective oxidation of O2. The high reactivity of glucosone makes it ideal for further conversion to valuable small molecules and building... The content of this RSS Feed (c) The Royal Society of Chemistry
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Fabrication of uniform Ru-doped NiFe2O4 nanosheets as efficient hydrogen evolution electrocatalyst ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07651D, Communication Siqi Niu, Siwei Li, Jing Hu, Yuzhi Li, Yunchen Du, Xijiang Han, Ping Xu Here we demonstrate the synthesis of uniform Ru-doped NiFe2O4 nanosheets with robust hydrogen evolution reaction (HER) activity in alkaline solution, with an extremely low overpotential of 18 mV versus reversible... The content of this RSS Feed (c) The Royal Society of Chemistry
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Bromine-bridged Dy2 single-molecule magnet: magnetic anisotropy driven by cis/trans stereoisomers ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07552F, Communication Min Li, Haipeng Wu, Zhengqiang Xia, Vincent Montigaud, Olivier Cador, Boris Le Guennic, Hongshan Ke, Wenyuan Wang, Gang Xie, Sanping Chen We report the first bromine-bridged dinuclear [Dy(Cy3PO)2(µ-Br)(Br)2]2·2C7H8 single-molecule magnet with an effective energy barrier of 684 K and magnetic hysteresis below 3 K. The asymmetric DyIII centres present two unique... The content of this RSS Feed (c) The Royal Society of Chemistry
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Extremely Twisted and Bent Pyrene-Fused N-Heterocyclic Germylenes ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC08703F, Communication Kelsie Krantz, Sarah Weisflog, Wenlong Yang, Diane Amanda Dickie, Nathan Frey, Charles Edwin Webster, Robert J Gilliard The first examples of pyrene-fused Janus-type N-heterocyclic germylenes (NHGe) are reported. Remarkably, the pyrene linker and the germanium containing rings are extremely twisted, with “twist angles” up to 64°. Coordination... The content of this RSS Feed (c) The Royal Society of Chemistry
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Multitasking Polyamine/Ferrioxalate Nano-Sized Assemblies: Thermo-, Photo-, and Redox-Responsive Soft Materials Made Easy ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC06942A, Communication Santiago Herrera, Maximiliano Agazzi, María Lorena Cortez, Waldemar Alejandro Marmisollé, Mario Tagliazucchi, Omar Azzaroni Responsive nanomaterials have emerged as key components in materials sciences. Herein, we report the one-step preparation of multi-stimuli responsive polyamine-salt aggregates (PSA) by ionically crosslinking polyethylenimine with potassium ferrioxalate (FeOx).... The content of this RSS Feed (c) The Royal Society of Chemistry
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Asymmetric coupling of Au nanospheres on TiO2 nanochannels membrane for NIR-gated artificial ionic nanochannels ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC08317K, Communication Lingling Yang, Kuanzhi Xu, Junli Guo, Huijie Xu, Zhenqing Dai, Zhida Gao, Yan-Yan Song Au nanoparticles were asymmetrically fabricated at one tip of TiO2 nanochannels by combining the photocatalytic reaction and limited penetration of light. Using the asymmetrical nanochannel-based membrane as a plasma absorber,... The content of this RSS Feed (c) The Royal Society of Chemistry
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Planarity of Terphenyl Rings Possessing o-Carborane Cages: Turning on Intramolecular-Charge-Transfer-Based Emission ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07729D, Communication Hyunhee So, Jaeho Kim, Ji Hye Lee, Hyonseok Hwang, Duk Keun An, Kang Mun Lee To clarify the relationship between planarity and intramolecular charge transfer (ICT), two o-carboranyl compounds (TCB and FCB) containing different ortho-type terphenyl rings, namely, perfectly distorted or planar phenyl rings, were... The content of this RSS Feed (c) The Royal Society of Chemistry
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Stable cycling of Na metal anodes in a carbonate electrolyte ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07419H, Communication Shiyang Wang, Wenbin Cai, Zhihao Sun, Fanyang Huang, Yulin Jie, Yang Liu, Yawei Chen, Bo Peng, Ruiguo Cao, Genqiang Zhang, Shuhong Jiao NaAsF6 enables stable cycling of Na metal anodes in a carbonate electrolyte with a high coulombic efficiency of 97% for 400 cycles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Porosity-driven large amplitude dynamics for nitroaromatic sensing with fluorescent films of alternating D–π–A molecules ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07227F, Communication Jean-Pierre Malval, Marion Cranney, Sylvain Achelle, Huriye Akdas-Kiliç, Jean-Luc Fillaut, Nolwenn Cabon, Françoise Robin-le Guen, Olivier Soppera, Yann Molard Very large amplitude nitroaromatic sensing dynamics are observed upon a structural change within an alternating D–π–A chromophore initially configured to promote densely cofacial self-packing at a macromolecular scale. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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An intramolecular Heck reaction of enol ethers involving β-alkoxyl elimination followed by the β-hydride elimination process: access to (Z)-ortho-formyl/keto-cinnamates ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC08133J, Communication Manman Sun, Haibo Wu, Haijian Wu, Zhiming Wang A highly regio- and stereoselective intramolecular Heck reaction of enol ethers involving β-alkoxyl elimination followed by the β-hydride elimination process has been developed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Hydrophilicity and oxophilicity of the isolated CaMn4O5 cationic cluster modeling inorganic core of the oxygen-evolving complex ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07818E, Communication Yufei Zhang, Daigo Masuzaki, Fumitaka Mafuné Isolated CaMn4O5+ was hardly formed in the presence of oxygen, whereas CaMn4O4(OH)2+ was formed stably in the presence of water. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Deformation of stable and toxic hIAPP oligomers by liposomes with distinct nanomechanical features and reduced cytotoxicity ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC06264E, Communication Liwei Zhang, Qingyu Chen, Ping Li, Liang Yuan, Yonghai Feng, Jie Wang, Xiaobo Mao, Lei Liu Nanoliposomes can induce hIAPP oligomers to undergo fibrillation with distinct mechanical properties and reduced cytotoxicity. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalytic asymmetric cycloaddition of unsymmetrical EWG-activated alkenes to fully substituted pyrrolidines bearing three different carbonyl groups ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07738C, Communication Shi-Lu Wu, Ning Li, Guan-Wu Yin, Zheng Xu, Fei Ye, Li Li, Yu-Ming Cui, Li-Wen Xu A unique 1,3-dipolar [3+2] cycloaddition of alkyl 4-oxo-4-arylbut-2-enoates bearing two different electron-withdrawing groups could be completed easily via silver catalysis in good yields and enantioselectivity. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Fe ions modulated formation of hollow NiFe oxyphosphide spheres with enhanced oxygen evolution performance ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07747B, Communication Yu Jia, Wei Cai, Xiaoyu Li, Xin-Yao Yu, Zhanglian Hong Hollow NiFe oxyphosphide spheres are synthesized based on a facile template-engaged strategy with different Fe ions as modulators and exhibit excellent alkaline OER performance. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A tri-functional metal–organic framework heterogeneous catalyst for efficient conversion of CO2 under mild and co-catalyst free conditions ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC08236K, Communication Dingxuan Ma, Yaowen Zhang, Shaoshao Jiao, Jixin Li, Kang Liu, Zhan Shi A novel tri-functional MOF catalyst was achieved by PSM method. Because of the synergistic effect of Lewis acid, Brønsted acid and Br− anion, MIL-IMAc-Br− displayed an efficient catalytic performance for CO2 conversion. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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The hydrophobically-tagged MDM2–p53 interaction inhibitor Nutlin-3a-HT is more potent against tumor cells than Nutlin-3a ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07795B, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Florian Nietzold, Stefan Rubner, Thorsten Berg The hydrophobically-tagged MDM2–p53-interaction inhibitor Nutlin-3a-HT reduces MDM2 levels upon p53 reactivation, and is more potent against tumor cells than Nutlin-3a. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Cooperative enhancement of antibacterial activity of sanguinarine drug through p-sulfonatocalix[6]arene functionalized silver nanoparticles ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07378G, Communication Chahat Mehra, Ravisha Gala, Aarti Kakatkar, Vivekanand Kumar, Raman Khurana, Suchandra Chatterjee, N. Naveen Kumar, Nilotpal Barooah, Achikanath C. Bhasikuttan, Jyotirmayee Mohanty The amelioration of antibacterial efficacy along with the reduced minimum inhibitory concentration (MIC) of sanguinarine (SGR) drug have been demonstrated through the uptake of SGR by p-sulfonatocalix[6]arene functionalized silver nanoparticles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Atropisomer-based construction of macrocyclic hosts that selectively recognize tryptophan from standard amino acids ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07646H, Communication Fei Yang, Caiping Liu, Di Yin, Yanqing Xu, Mingyan Wu, Wei Wei A syn-atropisomer precursor was employed to construct trapezoid-shape macrocycles, which can selectively recognize tryptophan from 20 standard amino acids. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Quantum chemical prediction of a superelectrophilic dianion and its binding with noble gas atoms ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC08049J, Communication Meenakshi Joshi, Tapan K Ghanty A counterintuitive superelectrophilic dianion with a positive charge as well as lowest occupied molecular orbital (LUMO) localized on free-Be1 in Dianion1 embedded in the negatively charged framework, forms stable [NgBeB11(CN)11]2− compounds. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Smart engineering of a dual-DNA machine with a high signal-to-noise ratio for one-pot robust and sensitive miRNA signaling ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07442B, Communication Panzhu Qin, Li Yao, Jianguo Xu, Guodong Liu, Wei Chen A target triggered dual-DNA machine composed of RCA and SDA was developed for robust and one-pot determination of miRNA. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalytic reduction of dinitrogen to tris(trimethylsilyl)amine using rhodium complexes with a pyrrole-based PNP-type pincer ligand ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC06896A, Communication Ryosuke Kawakami, Shogo Kuriyama, Hiromasa Tanaka, Kazuya Arashiba, Asuka Konomi, Kazunari Nakajima, Kazunari Yoshizawa, Yoshiaki Nishibayashi Rhodium complexes bearing an anionic pyrrole-based PNP-type pincer ligand are synthesised and found to work as effective catalysts for the transformation of molecular dinitrogen into tris(trimethylsilyl)amine under mild reaction conditions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Stereoselective three-component cascade synthesis of α-substituted 2,4-dienamides from gem-difluorochloro ethanes ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07100H, Communication Shyamsundar Das, Nakeun Ko, Eunsung Lee, Sang Eun Kim, Byung Chul Lee Herein, we describe a new transition metal-free Claisen rearrangement for the synthesis of α-substituted 2,4-dienamide. This one-pot, stereoselective three-component cascade reaction affords various polysubstituted 2,4-dienamides in good yields. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Yolk–shell hierarchical catalyst with tremella-like molybdenum sulfide on transition metal (Co, Ni and Fe) sulfide for electrochemical water splitting ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC06244K, Communication Tao Yang, Lisi Yin, Maoshuai He, Wenxian Wei, Guojian Cao, Xinran Ding, Yihui Wang, Ziming Zhao, Tingting Yu, Hong Zhao, Dongen Zhang Tremella-like MoS2 nano-sheets were directly synthesized on transition metal sulfides, displaying extreme activities towards hydrogen/oxygen evolution in alkaline condition. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Reverse capture for selectively and sensitively revealing the N-glycome of serum exosomes ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC06742F, Communication Jing Lv, Zhenxin Wang, Feng Li, Ying Zhang, Haojie Lu The N-glycome of human serum exosome is reported and its perspective as a source of biomarker discovery is revealed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Organoaluminum cation for carbonyl activation ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC08272G, Communication Ramkumar Kannan, Raju Chambenahalli, Sandeep Kumar, Athul Krishna, Alex P Andrews, Eluvathingal D Jemmis, Ajay Venugopal In search of stable, yet reactive aluminum Lewis acids, we have isolated an organoaluminum cation, [(Me2NC6H4)2Al(C4H8O)2]+, coordinated with two labile tetrahydrofuran ligands. Its catalytic performance in aldehyde dimerization reveals turn-over... The content of this RSS Feed (c) The Royal Society of Chemistry
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A hepatocyte-targeting near-infrared ratiometric fluorescent probe for monitoring peroxynitrite during drug-induced hepatotoxicity and its remediation ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07017F, Communication Wen-Li Jiang, Yongfei Li, Wen-Xin Wang, Yi-Ting Zhao, Junjie Fei, Chun-Yan Li A novel hepatocyte-targeting near-infrared ratiometric fluorescent probe named Gal-NIR is developed for detecting ONOO−. The probe can target the hepatocyte and assess drug-induced liver injury and its remediation in living cells and mice. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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2D covalent organic frameworks with built-in amide active sites for efficient heterogeneous catalysis ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07500C, Communication Yang Li, Weiben Chen, Ruidong Gao, Ziqiang Zhao, Ting Zhang, Guolong Xing, Long Chen Benzene-1,3,5-tricarboxamides (BTAs) are versatile building blocks for supramolecular assembly due to the strong intermolecular hydrogen bonding. Herein, a BTA based amine, N1,N3,N5-tris(4-aminophenyl)benzene-1,3,5-tricarboxamide (TABTA) was successfully applied to construct two new... The content of this RSS Feed (c) The Royal Society of Chemistry
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Integrating in situ formation of nanozyme with mesoporous polydopamine for combined chemo, photothermal and hypoxia-overcoming photodynamic therapy ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07125C, Communication Xiaochun Hu, Yonglin Lu, Xiaoke Shi, Tianming Yao, Chunyan Dong, Shuo Shi Based on the Pt nanozyme modified mesoporous polydopamine in situ, a multi-functional nanoplatform was established, which could overcome the tumour hypoxia by catalyzing overexpressed H2O2 in tumour cells to enhance... The content of this RSS Feed (c) The Royal Society of Chemistry
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Halogenated Tetraphenylethene with Enhanced Aggregation-Induced Emission: Anomalous Anti-Heavy-Atom Effect and Self-Reversible Mechanochromism ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07045A, Communication Pengfei Xu, Qianqian  Qiu, Xinru Ye, Mengru Wei, Wenbin Xi, Hui Feng, Zhaosheng Qian Halogenated tetraphenlyethene derivatives show a unique anti-heavy-atom effect that introducing heavy halogens like bromine greatly improve fluorescence quantum yields upon aggregation, contrary to classic heavy-atom effect. A unique self-reversible mechanochromism... The content of this RSS Feed (c) The Royal Society of Chemistry
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Tryptophan-Glucosamine Conjugates Modulate Tau-Derived PHF6 aggregation at Low concentrations ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC06868F, Communication Ashim Paul, Wen-Hao Li, Guru KrishnaKumar Viswanathan, elad arad, Satabdee Mohapatra, Gao Li, Raz Jelinek, Ehud Gazit, Yanmei Li, Daniel Segal Glycosylation of amyloidogenic proteins enhances their solubility and reduces propensity for aggregation. We therefore, prepared Tryptophan-glucosamine conjugates to modulate aggregation of tau-derived PHF6-peptide. Combined in-vitro and in-silico approaches indicated that... The content of this RSS Feed (c) The Royal Society of Chemistry
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Fabrication of silver chalcogenolate clusters hybrid membranes with enhanced structural stability and luminescence efficiency ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07797A, Communication Yi-Man Wang, Jiangwei Zhang, Qian-You Wang, Hai-Yang Li, Xi-Yan Dong, Shan Wang, Shuang-Quan Zang The present study reports the fabrication of silver chalcogenolate clusters hybrid membrane (SCCs membrane) through self-assembling of SCCs, and then covalently cross-linking of the modified SCCs assembled materials. This strategy... The content of this RSS Feed (c) The Royal Society of Chemistry
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Nickel-catalyzed Electrochemical Reductive Decarboxylative Coupling of N-Hydroxyphthalimide Esters with Quinoxalinones ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07840A, Communication Fei Lian, Kun Xu, Wei Meng, Haonan Zhang, Zhoumei Tan, Cheng-Chu Zeng Reported herein is the first example of electrochemically enabled, NiCl2-catalyzed reductive decarboxylative coupling of N hydroxyphthalimide (NHP) esters with quinoxalinones. A range of primary, secondary, tertiary aliphatic carboxylic acids and... The content of this RSS Feed (c) The Royal Society of Chemistry
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Fe-N/C single-atom catalysts exhibiting multienzyme activity and ROS scavenging ability in cells ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07408B, Communication Mingju Lu, Chao Wang, Yongqi Ding, Meihong Peng, Wang Zhang, Kai Li, Wei Wei, Yuqing Lin Fe-N/C single atom catalysts (SACs) exhibit peroxidase-like, oxidase-like, catalase-like, and glutathione peroxidase-like activity. Fe-N/C SACs are successfully applied to control the intracellular H2O2 level. This study not only explores the... The content of this RSS Feed (c) The Royal Society of Chemistry
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Magnetic frustration in the high-pressure Mn2MnTeO6 (Mn3TeO6–II) double perovskite. ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07733B, Communication Angel M. Arevalo-Lopez, Elena Solana, Cintli Aguilar-Maldonado, Clemens Ritter, Olivier Mentré, Paul Attfield A new double perovskite Mn2MnTeO6 has been obtained by high pressure phase transformation of a corundum-related precursor. It is antiferromagnetic below 36 K and develops a magnetic structure with magnetic... The content of this RSS Feed (c) The Royal Society of Chemistry
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Rational Design and Action Mechanisms of Chemically Innovative Organoselenium in Cancer Therapy ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07683B, Feature Article Zhen Chen, Haoqiang Lai, Liyuan Hou, Tianfeng Chen Organo-seleno compounds (org-Se) have been widely used in antitumor, antivirus, antiinflammation, antioxidation and other biological fields. As such, they have made an important contribution in overcoming various kinds of diseases... The content of this RSS Feed (c) The Royal Society of Chemistry
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Outer surface interactions to drive cucurbit[8]uril-based supramolecular frameworks: possible application in gold recovery ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07147D, Communication Li-Xia Chen, Ming Liu, Yun-Qian Zhang, Qian-Jiang Zhu, Jing-Xin Liu, Bi-Xue Zhu, Zhu Tao Q[8]-based honeycomb-like frameworks could be obtained in [AuCl4]− free aqueous HNO3 solution, aqueous HCl and HNO3 solutions that contain [AuCl4]−. These frameworks exhibit a high selectivity for imprisoning [AuCl4]−. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Unexpected α,α′-difluoroethers from Ag(I)F and N-bromosuccinimide reactions of dibenzo[a,e]cyclooctatetraene ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC06426E, Communication Zeguo Fang, Roscoe Z. Gillatt, Alexandra M. Z. Slawin, David B. Cordes, Cameron L. Carpenter-Warren, David O'Hagan An unexpected reaction of dibenzo[a,e]cyclooctatetraene with Ag(I)F and N-bromosuccinamide generates bridged bicyclic α,α′-difluoroether isomers. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A bright NIR-II fluorescent probe for breast carcinoma imaging and image-guided surgery ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07694H, Communication Xiaodong Zeng, Liru Xie, Deliang Chen, Shanshan Li, Jinxia Nong, Bo Wang, Lin Tang, Qianqian Li, Yang Li, Zixin Deng, Xuechuan Hong, Mingfu Wu, Yuling Xiao A bright NIR-II fluorescent probe was synthesized for xenograft breast tumor and chemically induced spontaneous breast carcinoma imaging and image-guided surgery. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A hierarchical composite of GeO2 nanotubes/N-doped carbon microspheres with high-rate and super-durable performance for lithium-ion batteries ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC06921F, Communication Lijing Han, Jing Tang, Qiaohua Wei, Congrong Chen, Mingdeng Wei A new composite of hierarchical microspheres assembled by GeO2 tubes/nitrogen doped carbon was fabricated for the first time and showed a promising electrochemical performance. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Template-free synthesis and metalation of hierarchical covalent organic framework spheres for photothermal therapy ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07809F, Communication Yanshu Shi, Sainan Liu, Zhixiang Zhang, Ying Liu, Maolin Pang Room temperature synthesized hierarchical COF spheres were metalated with Fe3+ and utilized for photothermal therapy. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A high performance tungsten bronze electrode in a mixed electrolyte and applications in supercapacitors ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC06845G, Communication Zhen Sun, Xiao-Guang Sang, Yu Song, Di Guo, Dong-Yang Feng, Xiaoqi Sun, Xiao-Xia Liu A Na2SO4/H2SO4 mixed electrolyte is demonstrated to provide an excellent potential window and cycle life for a tungsten bronze pseudocapacitive electrode. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Visible light-induced palladium-catalyzed ring opening β-H elimination and addition of cyclobutanone oxime esters ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC08077E, Communication Wei-Long Xing, Rui Shang, Guang-Zu Wang, Yao Fu A photo-excited Pd(0) complex activates cyclobutanone oxime esters to induce radical ring opening for the generation of products of β-H elimination and addition with silyl enol ether. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highlights from Faraday Discussion 301: Nanolithography of Biointerfaces, London, UK, July 3–5 2019 ()
Chem. Commun., 2019, 55,13631-13637 DOI: 10.1039/C9CC90421B, Conference Report Clare S. Mahon, Mia L. Huang In this report, we will give an overview of the topics and discussions covered during the 2019 Faraday Discussion on the Nanolithography of Biointerfaces, and highlight the content of each session. The content of this RSS Feed (c) The Royal Society of Chemistry
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Enantioselective palladium-catalyzed diarylation of unactivated alkenes ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07036B, Communication Baihang Ju, Shigui Chen, Wangqing Kong Enantioselective Pd-catalyzed diarylation of unactivated alkenes between arenediazonium salts and arylboronic acids has been developed. This method provides an efficient route to dihydrobenzofurans with all-carbon quaternary centers in good yields with 88–99% ee. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Retraction: Visible-light-induced oxidative difunctionalization of styrenes: synthesis of α-trifluoromethylthio-substituted ketones ()
Chem. Commun., 2019, 55,13777-13777 DOI: 10.1039/C9CC90479D, Retraction Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Arvind Kumar Yadav, Krishna Nand Singh The content of this RSS Feed (c) The Royal Society of Chemistry
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An intermolecular C–H oxidizing strategy to access highly fused carbazole skeletons from simple naphthylamines ()
Chem. Commun., 2019, 55,13749-13752 DOI: 10.1039/C9CC05240B, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Christian K. Rank, Alexander W. Jones, Tatjana Wall, Patrick Di Martino-Fumo, Sarah Schröck, Markus Gerhards, Frederic W. Patureau Highly π-extended hetero-cyclic/aromatic skeletons are of great importance as they can be utilized in many organic material based technologies. The content of this RSS Feed (c) The Royal Society of Chemistry
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Palladium-catalyzed regioselective C–H alkynylation of indoles with haloalkynes: access to functionalized 7-alkynylindoles ()
Chem. Commun., 2019, 55,13769-13772 DOI: 10.1039/C9CC07263B, Communication Songjia Fang, Guangbin Jiang, Meng Li, Zhenying Liu, Huanfeng Jiang, Wanqing Wu A palladium-catalyzed exclusively selective alkynylation of indoles has been reported, affording concise access to 7-alkynylindoles from readily available starting materials. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of C-terminal glycopeptides via oxime resin aminolysis ()
Chem. Commun., 2019, 55,13741-13744 DOI: 10.1039/C9CC07481C, Communication Thomas Tremblay, Gabrielle Robert-Scott, Christopher Bérubé, Antoine Carpentier, Normand Voyer, Denis Giguère We developed a general solid-phase approach to complex C-terminal glycopeptides. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ti3C2/BiVO4 Schottky junction as a signal indicator for ultrasensitive photoelectrochemical detection of VEGF165 ()
Chem. Commun., 2019, 55,13729-13732 DOI: 10.1039/C9CC07108C, Communication Yaling Liu, Hongmei Zeng, Yaqin Chai, Ruo Yuan, Hongyan Liu A “signal-on” photoelectrochemical (PEC) biosensor was developed for ultrasensitive detection of vascular endothelial growth factor 165 (VEGF165) based on Ti3C2/BiVO4 Schottky junction. The content of this RSS Feed (c) The Royal Society of Chemistry
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Thermodynamic control of quantum defects on single-walled carbon nanotubes ()
Chem. Commun., 2019, 55,13757-13760 DOI: 10.1039/C9CC05623H, Communication Yutaka Maeda, Hiyori Murakoshi, Haruto Tambo, Pei Zhao, Kiyonori Kuroda, Michio Yamada, Xiang Zhao, Shigeru Nagase, Masahiro Ehara We designed and synthesized SWNT quantum defects, the band gaps of which can be tuned by thermal treatment. Theoretical calculations suggest that the change in the PL spectra can be explained by isomerization from kinetic to thermodynamic products. The content of this RSS Feed (c) The Royal Society of Chemistry
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A paper-based chemosensor for highly specific, ultrasensitive, and instantaneous visual detection of toxic phosgene ()
Chem. Commun., 2019, 55,13753-13756 DOI: 10.1039/C9CC07437F, Communication Lintao Zeng, Hongyan Zeng, Shuangfei Wang, Shan Wang, Ji-Ting Hou, Juyoung Yoon A chemosensor containing an o-hydroxyaniline unit as the reaction site was developed for colorimetric and fluorimetric detection of phosgene, which showed fast response (15 s), high specificity, and an extremely low detection limit. The content of this RSS Feed (c) The Royal Society of Chemistry
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Visible-light-promoted oxidative halogenation of alkynes ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07655G, Communication Yiming Li, Tao Mou, Lingling Lu, Xuefeng Jiang In nature, halogenation promotes the biological activity of secondary metabolites, especially geminal dihalogenation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synergistic photothermal and photochemical partial oxidation of methane over noble metals incorporated in mesoporous silica ()
Chem. Commun., 2019, 55,13765-13768 DOI: 10.1039/C9CC06170C, Communication Haoyang Jiang, Xiaobo Peng, Akira Yamaguchi, Takeshi Fujita, Hideki Abe, Masahiro Miyauchi We establish a hot-carrier-driven photothermal and photochemical system for partial oxidation of methane using noble metals incorporated in mesoporous silica. The content of this RSS Feed (c) The Royal Society of Chemistry
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An unexpected coupling–reduction tandem reaction for the synthesis of alkenyl-substituted BODIPYs ()
Chem. Commun., 2019, 55,13761-13764 DOI: 10.1039/C9CC07730H, Communication Kun-Xu Teng, Li-Ya Niu, Jie Li, Lu Jia, Qing-Zheng Yang We report an unexpected coupling–reduction tandem reaction as a general and efficient one-pot synthesis of alkenyl-substituted boron dipyrromethene (BODIPY) from chlorinated-BODIPY and alkyne. The content of this RSS Feed (c) The Royal Society of Chemistry
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Digital quantitative detection of serum circulating miRNAs using dual-enhanced magnetobiosensors based on cascaded nucleic acid circuits ()
Chem. Commun., 2019, 55,13733-13736 DOI: 10.1039/C9CC07841J, Communication Chunxue Liu, Yayun An, Yuanfu Zhang, Xia Li, Qingwang Xue, Huaisheng Wang Here, we developed a dual-enhanced magnetobiosensor based on cascaded nucleic acid circuits for sensitive, portable and digital quantitative detection of circulating miRNAs in serum by a personal glucose meter (PGM). The content of this RSS Feed (c) The Royal Society of Chemistry
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A stable AIEgen cis-diarylethene-based ‘ESIPT’ benchmark ()
Chem. Commun., 2019, 55,13713-13716 DOI: 10.1039/C9CC07434A, Communication Tingting Zhang, Liu Wen, Genjiang Liu, Jiaying Yan, Xiang Liu, Kaibo Zheng, Nuonuo Zhang A stable AIEgen locked by the seven-membered ring hydrogen bond and steric hindrance which made ‘ESIPT’ take place. It features a highly fluorescence in aggregate and solid states and large Stokes shift in solution. The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalytic selective mono- and difluoroalkylation using fluorinated silyl enol ethers ()
Chem. Commun., 2019, 55,13638-13648 DOI: 10.1039/C9CC07677H, Feature Article Xiao-Si Hu, Jin-Sheng Yu, Jian Zhou This feature article highlights our recent achievements in catalytic selective mono- and difluoroalkylation using fluorinated silyl enol ethers (FSEEs). The content of this RSS Feed (c) The Royal Society of Chemistry
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Process-tracing study on the post-assembly modification of poly-NHC-based metallosupramolecular cylinders with tunable aggregation-induced emission ()
Chem. Commun., 2019, 55,13689-13692 DOI: 10.1039/C9CC07113J, Communication Yi-Shou Wang, Sha Bai, Yao-Yu Wang, Ying-Feng Han A process-tracing and aggregation-induced emission (AIE) study of a covalent post-assembly modification (PAM) process of the AuI–CNHC cylinders was presented. The content of this RSS Feed (c) The Royal Society of Chemistry
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Multifunctional 1,3-diphenylguanidine for the carboxylative cyclization of homopropargyl amines with CO2 under ambient temperature and pressure ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07671A, Communication Xiao-Tong Gao, Shi-Liang Xie, Feng Zhou, Hai-Hong Wu, Jian Zhou The highly efficient multifunctional DPG promoted carboxylative cyclization of homopropargyl amines with CO2 to form six-membered 2-oxazinones was developed under ambient temperature and pressure. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Versatile, one-pot introduction of nonahalogenated 2-ammonio-decaborate ions as boron cluster scaffolds into organic molecules; host–guest complexation with γ-cyclodextrin ()
Chem. Commun., 2019, 55,13669-13672 DOI: 10.1039/C9CC07678F, Communication Suzan El Anwar, Khaleel I. Assaf, Barbara Begaj, Maksim A. Samsonov, Zdeňka Růžičková, Josef Holub, Dmytro Bavol, Werner M. Nau, Detlef Gabel, Bohumír Grűner A new method for previously inaccessible coupling of halogenated polyhedral ions with organic molecules is presented along with studies on the supramolecular complexation with cyclodextrin. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of gold allyloxysulfonium complexes and elimination to form an α,β-unsaturated aldehyde ()
Chem. Commun., 2019, 55,13745-13748 DOI: 10.1039/C9CC06589J, Communication Nana Kim, Ross A. Widenhoefer Reaction of a cationic gold vinyl carbene/allylic cation complex with sulfoxides forms gold allyloxysulfonium complexes that undergo thermal elimination to form aldehyde. The content of this RSS Feed (c) The Royal Society of Chemistry
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Palladium(II)-catalyzed oxidative C(sp3)–P bond formation via C(sp3)–H bond activation ()
Chem. Commun., 2019, 55,13693-13696 DOI: 10.1039/C9CC07637A, Communication Lijin Chen, Zhenfei Zhou, Saifei Zhang, Xiaoqian Li, Xuebing Ma, Jiaxing Dong A palladium-catalyzed oxidative C(sp3)–H/P–H cross-coupling reaction has been realized via chelation-assisted C(sp3)–H bond activation. The content of this RSS Feed (c) The Royal Society of Chemistry
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An unexpected cascade reaction of 3-hydroxyoxindoles with coumarin-3-carboxylates to construct 2,3-dihydrobenzofuran spirooxindoles ()
Chem. Commun., 2019, 55,13681-13684 DOI: 10.1039/C9CC07114H, Communication Kuan Zhang, Huabin Han, Lele Wang, Ziying Zhang, Qilin Wang, Wenjing Zhang, Zhanwei Bu An unexpected Michael addition-inspired ring-opening/closure cascade reaction of 3-hydroxyoxindoles with coumarin-3-carboxylates was developed. The content of this RSS Feed (c) The Royal Society of Chemistry
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Porous organic polymer supported rhodium as a heterogeneous catalyst for hydroformylation of alkynes to α,β-unsaturated aldehydes ()
Chem. Commun., 2019, 55,13721-13724 DOI: 10.1039/C9CC06834A, Communication Zuyu Liang, Jianbin Chen, Xin Chen, Kai Zhang, Jinhe Lv, Haowen Zhao, Guoying Zhang, Congxia Xie, Lingbo Zong, Xiaofei Jia A novel porous organic polymer supported rhodium catalyst (Rh/POL-BINAPa&PPh3) was developed for the hydroformylation of alkynes to afford α,β-unsaturated aldehydes. The content of this RSS Feed (c) The Royal Society of Chemistry
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Unravelling the mechanism of amyloid-β peptide oligomerization and fibrillation at chiral interfaces ()
Chem. Commun., 2019, 55,13725-13728 DOI: 10.1039/C9CC06980A, Communication Shuai Gong, Jingjing Liu, Mengting Tian, Kang Wang, Shali Cai, Weiyan Wang, Lei Shen The mechanism of how surface chirality affects amyloid-β peptide oligomerization and fibrillation was firstly unravelled at the molecular level. The content of this RSS Feed (c) The Royal Society of Chemistry
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Aptamer recognition-trigged label-free homogeneous electrochemical strategy for an ultrasensitive cancer-derived exosome assay ()
Chem. Commun., 2019, 55,13705-13708 DOI: 10.1039/C9CC07253E, Communication Xuehan Yin, Ting Hou, Bingzheng Huang, Limin Yang, Feng Li An aptamer recognition-trigged label-free homogeneous electrochemical strategy was developed for highly selective and ultrasensitive detection of cancer-derived exosomes. The content of this RSS Feed (c) The Royal Society of Chemistry
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Direct amide synthesis via Ni-mediated aminocarbonylation of arylboronic acids with CO and nitroarenes ()
Chem. Commun., 2019, 55,13709-13712 DOI: 10.1039/C9CC06638A, Communication Ni Shen, Chi Wai Cheung, Jun-An Ma Ni metal-mediated aminocarbonylation based on readily available arylboronic acids, nitroarenes, and carbon monoxide was achieved to prepare a variety of aryl amides. The content of this RSS Feed (c) The Royal Society of Chemistry
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Partial substitution induced centrosymmetric to noncentrosymmetric structure transformation and promising second-order nonlinear optical properties of (K0.38Ba0.81)Ga2Se4 ()
Chem. Commun., 2019, 55,13701-13704 DOI: 10.1039/C9CC07112A, Communication Ya-Nan Li, Yang Chi, Zong-Dong Sun, Huaiguo Xue, Nian-Tzu Suen, Sheng-Ping Guo Novel noncentrosymmetric (K0.38Ba0.81)Ga2Se4 can be obtained from centrosymmetric BaGa2Se4via partial substitution, and it demonstrates promising balanced NLO properties. The content of this RSS Feed (c) The Royal Society of Chemistry
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Assembling a double shell on a diatomite skeleton ternary complex with conductive polypyrrole for the enhancement of supercapacitors ()
Chem. Commun., 2019, 55,13773-13776 DOI: 10.1039/C9CC06791D, Communication Kailin Li, Shihao Feng, Chuan Jing, Yuxiang Chen, Xiaoying Liu, Yuxin Zhang, Liang Zhou Double shell FeOOH/PPy on a diatomite ternary complex was assembled via two-step hydrothermal and in situ polymerization routes. The content of this RSS Feed (c) The Royal Society of Chemistry
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Sensitive discrimination of glycoproteins and cell differentiation with an array sensing platform exploiting pyrene-derived amphiphile/surfactant assemblies ()
Chem. Commun., 2019, 55,13673-13676 DOI: 10.1039/C9CC07515A, Communication Xin Lin, Lifang Gao, Jianhua Wang, Xuwei Chen An array sensing platform exploiting pyrene-derived amphiphile/surfactant assemblies is constructed for sensitive discrimination of glycoproteins and differentiated cell lines. The content of this RSS Feed (c) The Royal Society of Chemistry
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An enantioselective oxidative coupling reaction of 2-naphthol derivatives catalyzed by chiral diphosphine oxide–iron(II) complexes ()
Chem. Commun., 2019, 55,13677-13680 DOI: 10.1039/C9CC07834G, Communication Takahiro Horibe, Keita Nakagawa, Takashi Hazeyama, Kazuki Takeda, Kazuaki Ishihara An enantioselective oxidative coupling of 2-naphthol derivatives is developed with the use of chiral Fe(II)–diphosphine oxide complexes. The content of this RSS Feed (c) The Royal Society of Chemistry
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Palladium/copper-catalyzed multicomponent reactions of propargylic amides, halohydrocarbons and CO2 toward functionalized oxazolidine-2,4-diones ()
Chem. Commun., 2019, 55,13685-13688 DOI: 10.1039/C9CC07027C, Communication Cong Zhou, Yaqun Dong, Jin-Tao Yu, Song Sun, Jiang Cheng Palladium/copper-catalyzed multicomponent reactions of propargylic amides, halohydrocarbons and CO2 toward functionalized oxazolidine-2,4-diones. The content of this RSS Feed (c) The Royal Society of Chemistry
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Stretchable, transparent and imperceptible supercapacitors based on Au@MnO2 nanomesh electrodes ()
Chem. Commun., 2019, 55,13737-13740 DOI: 10.1039/C9CC06263G, Communication Junlong Yang, Tianzeng Hong, Jue Deng, Yan Wang, Fan Lei, Jianming Zhang, Bo Yu, Zhigang Wu, Xinzheng Zhang, Chuan Fei Guo A wearable supercapacitor achieved high transparency of 82.1% and an excellent areal capacitance of 0.53 mF cm−2, together with high stretchability (160% strain). The content of this RSS Feed (c) The Royal Society of Chemistry
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A catalytically relevant intermediate in the synthesis of cyclic polymers from alkynes ()
Chem. Commun., 2019, 55,13697-13700 DOI: 10.1039/C9CC05612B, Communication Christopher D. Roland, Tianyu Zhang, Sudarsan VenkatRamani, Ion Ghiviriga, Adam S. Veige A tungsten metallacyclopentadiene complex is generated upon treating a trianionic pincer tungsten alkylidyne with dipropargyl fluorene. The content of this RSS Feed (c) The Royal Society of Chemistry
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Preparation and crystal structures of the beryllium ammines [Be(NH3)4]X2 (X = Br, I, CN, SCN, N3) and Be(NH3)2X'2 (X' = Cl, Br, I) ()
Chem. Commun., 2019, 55,13649-13652 DOI: 10.1039/C9CC07712J, Communication Matthias Müller, Magnus R. Buchner Ammine complexes of beryllium halides and pseudo-halides have been synthesized through the reaction of metallic beryllium with ammonium salts in liquid ammonia or in the solid state. The content of this RSS Feed (c) The Royal Society of Chemistry
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Direct synthesis of dilithium tetraphenylporphyrin: facile reaction of a free-base porphyrin with vapor-deposited lithium ()
Chem. Commun., 2019, 55,13665-13668 DOI: 10.1039/C9CC07170A, Communication Maik Schöniger, Stefan R. Kachel, Jan Herritsch, Philipp Schröder, Mark Hutter, J. Michael Gottfried A dilithium porphyrin was synthesized by vapor-deposition of metallic lithium onto solid free-base porphyrin. The content of this RSS Feed (c) The Royal Society of Chemistry
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Buchwald Hartwig diversification of unprotected halotryptophans, halotryptophan containing tripeptides and the natural product barettin in aqueous conditions ()
Chem. Commun., 2019, 55,13653-13656 DOI: 10.1039/C9CC02554E, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Yohann J. G. Renault, Rosemary Lynch, Enrico Marelli, Sunil V. Sharma, Cristina Pubill-Ulldemolins, Joshua A. Sharp, Christopher Cartmell, Paco Cárdenas, Rebecca J. M. Goss Providing a tool to enhance natural product diversification, we report the first Buchwald Hartwig late stage modification in water of short peptides and the natural product barettin. The content of this RSS Feed (c) The Royal Society of Chemistry
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An amphipathic cell penetrating peptide aids cell penetration of cyclosporin A and increases its therapeutic effect in an in vivo mouse model for dry eye disease ()
Chem. Commun., 2019, 55,13657-13660 DOI: 10.1039/C9CC05960A, Communication Soonsil Hyun, Lan Li, Kyung Chul Yoon, Jaehoon Yu The use of CPP, LK-3, increases the cell penetration of cyclosporine A (CsA) at nanomolar concentrations and therapeutic efficacy. The content of this RSS Feed (c) The Royal Society of Chemistry
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Handy fluorescent paper device based on a curcumin derivative for ultrafast detection of peroxide-based explosives ()
Chem. Commun., 2019, 55,13661-13664 DOI: 10.1039/C9CC06737J, Communication Qiu-Hong Zhu, Guo-Hao Zhang, Wen-Li Yuan, Shuang-Long Wang, Ling He, Fang Yong, Guo-Hong Tao A useful and inexpensive fluorescent paper-based device was fabricated for ultrafast sensing of peroxide-based explosives. The content of this RSS Feed (c) The Royal Society of Chemistry
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Stabilization of a 4.5 V Cr4+/Cr3+ redox reaction in NASICON-type Na3Cr2(PO4)3 by Ti substitution ()
Chem. Commun., 2019, 55,13717-13720 DOI: 10.1039/C9CC04860J, Communication Kosuke Kawai, Daisuke Asakura, Shin-ichi Nishimura, Atsuo Yamada NASICON-type Na2CrTi(PO4)3 offers a stable redox reaction of Cr4+/Cr3+ at 4.5 V vs. Na/Na+. The content of this RSS Feed (c) The Royal Society of Chemistry
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Lead-Free Silver-Antimony Halide Double Perovskite Quantum Dots with Superior Blue Photoluminescence ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07397C, Communication Kexin Lv, Shaopeng Qi, Guoning Liu, Yongbing Lou, Jinxi Chen, Yixin Zhao A novel all-inorganic Sb-based lead-free double perovskite Cs2AgSbX6 (X=Cl, Br, I) quantum dots exhibited excellent air stability and strong blue emission with photoluminescence quantum yields of 31.33% was firstly surfactant... The content of this RSS Feed (c) The Royal Society of Chemistry
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Real-Time Monitoring of Solid-Phase Peptide Synthesis Using a Variable Bed Flow Reactor ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC08421E, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Eric T. Sletten, Manuel Nuno, Duncan Guthrie, Peter Seeberger On-resin aggregation and incomplete amide bond formation are major challenges for solid-phase peptide synthesis that are difficult to be monitored in real-time. Incorporation of a pressure-based variable bed flow reactor... The content of this RSS Feed (c) The Royal Society of Chemistry
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Facile Synthesis of 9H-Pyrrolo[1,2-a]indoles Via Brønsted Acid Catalyzed Cascade Reaction ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07228D, Communication kunhua xu, wenming chen, jin lin, guifang chen, biao wang, Tian Xu An efficient Brønsted acid catalyzed Friedel-Crafts alkenylation/1,6-addition/condensation cascade reaction has been developed. The protocol enables effective access to various highly functionalized 9H-pyrrolo[1,2-a]indoles in moderate to high yields. Mechanistic studies indicate... The content of this RSS Feed (c) The Royal Society of Chemistry
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Thermoresponsive drug delivery to mitochondria in vivo ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07538K, Communication Lifo Ruan, Mengxue Zhou, Jun Chen, Hui Huang, Jiayu Zhang, Hongyan Sun, Zhifang Chai, Yi Hu Mitochondrial targeting of drugs largely relies on delocalized lipophilic cations. Nevertheless, mitochondrial membrane potentials in cancer cells are inconstant, which could compromise stable mitochondrial targeting. Herein, we further validated a... The content of this RSS Feed (c) The Royal Society of Chemistry
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Modelling hemoproteins: Porphyrins and cyclodextrins as sources of inspiration ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07545C, Feature Article Maxime Vonesch, Jennifer Wytko, Hiroaki Kitagishi, Koji Kano, Jean Weiss The association of hydrophobic cavities with porphyrin derivatives has been used to mimic hemoprotein structures. The most employed cavity in this field is the β-cyclodextrin (β-CD) and scaffolds combining β-CDs... The content of this RSS Feed (c) The Royal Society of Chemistry
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Mass spectrometric detection of enantioselectivity in three-component complexation, copper(II)-chiral tetradentate ligand-free amino acid in solution ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07231D, Communication Takashi Nakakoji, Hirofumi Sato, Daisuke Ono, Hiroyuki Miyake, Satoshi Shinoda, Hiroshi Tsukube, Hideya Kawasaki, Ryuichi Arakawa, Motohiro Shizuma Enantioselective coordination of a free amino acid as the second ligand of a Cu(II) complex with a novel chiral tetradentate ligand was evaluated quantitatively in a short measurement time by ESI-MS/deuterium-labelled quasienantiomers. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Dendritic copper: a high-efficiency electrocatalyst for N2 fixation to NH3 under ambient conditions ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC08234D, Communication Chengbo Li, Shiyong Mou, Xiaojuan Zhu, Fengyi Wang, Yuting Wang, Yanxia Qiao, Xifeng Shi, Yonglan Luo, Baozhan Zheng, Quan Li, Xuping Sun The artificial N2 fixation to NH3 is dominated by the traditional Haber-Bosch process, which consumes large amounts of energy and natural gas with low energy efficiency and a large amount... The content of this RSS Feed (c) The Royal Society of Chemistry
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Sodium chromium hexacyanoferrate as a potential cathode material for aqueous sodium-ion batteries ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC06350A, Communication Dominika Baster, Emad Oveisi, Pierre Mettraux, Surbhi Agrawal, Hubert Girault Sodium chromium hexacyanoferrate (NaCrHCF) is here obtained using a facile co-precipitation method at room temperature. The powder was investigated in terms of potential use as a cathode material for aqueous... The content of this RSS Feed (c) The Royal Society of Chemistry
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Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC08630G, Communication Rajendra S. Ghadwal, Mahendra Sharma, Beate Neumann, Georg Stammler, Diego M Andrada The first terminal arsinidene complexes [{(NHC)C(Ph)}As]Fe(CO)4 (NHC = IPr = C{(NDipp)CH}2 5, Me-IPr = C{(NDipp)CMe}2 6; Dipp = 2,6-iPr2C6H3) with a two-coordinated arsenic atom have been reported as crystalline solids.... The content of this RSS Feed (c) The Royal Society of Chemistry
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Through-Space π-Delocalization in a Conjugated Macrocycle Consisting of [2.2]Paracyclophane ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC06492C, Communication Yayu Wu, Gui-lin Zhuang, Shengsheng Cui, Yu Zhou, Jinyi Wang, Qiang Huang, Pingwu Du Herein we report the synthesis and characterization of a [2.2]paracyclophane-containing macrocycle (PCMC) as a new through-space conjugated macrocycle using only benzene groups as the skeleton. For comparison, diphenylmethane-containing nanohoop macrocycle... The content of this RSS Feed (c) The Royal Society of Chemistry
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Reversible Chirality Inversion of Circularly Polarized Luminescence in a Photo-invertible Helical Cholesteric Superstructure ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC08090B, Communication Jinghui Qiao, Siyang Lin, Juntao Li, Jiajun Tian, Jinbao Guo A photo-invertible helical cholesteric superstructure was constructed by doping a novel chiral fluorescence photoswitch and a static dopant with opposite handedness into a nematic host, the handedness of circularly polarized... The content of this RSS Feed (c) The Royal Society of Chemistry
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The Effect of Polymeric Binders in the Sulfur Cathode on the Cycling Performance for Lithium-Sulfur Batteries ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07061C, Communication Ji-Yong Eom, Seong-In Kim, Vitalii Ri, Chunjoong Kim Recently, great advance of the Li-S battery technology enables its penetration to the power source of the mid- and large-sized devices, which require high energy and power density that cannot... The content of this RSS Feed (c) The Royal Society of Chemistry
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Achieving Long-lived thermally activated delayed fluorescence in the atmospheric aqueous environment by nanoencapsulation ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC07704A, Communication Yingnan Wu, Long Jiao, Fengling Song, Miaomiao Chen, Dapeng Liu, Wei Yang, Yuming Sun, Gaobo Hong, Lingge Liu, Xiaojun Peng The fluorescent silica nanoparticles which encapsulated dye DCF-BYT with thermally activated delayed fluorescence (TADF) were fabricated in a simple synthetic method. Even in the atmospheric aqueous environment, the obtained DCF-BYT... The content of this RSS Feed (c) The Royal Society of Chemistry
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Covalently linked donor–acceptor dyad for efficient single material organic solar cells ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07179B, Communication Sebastian Lucas, Tim Leydecker, Paolo Samorì, Elena Mena-Osteritz, Peter Bäuerle A novel covalently linked donor–acceptor dyad comprising a dithienopyrrol-based oligomeric donor and a fullerene acceptor was synthesized and characterized. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A nonaqueous all organic semisolid flow battery ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07937H, Communication Xueqi Xing, Qinghua Liu, Jiang Li, Zhihua Han, Baoguo Wang, John P. Lemmon A proof-of-principle of a nonaqueous all organic semisolid flow battery with a cell voltage of 2.35 V was demonstrated. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly specific and sensitive detection of microRNAs by tandem signal amplification based on duplex-specific nuclease and strand displacement ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC06790F, Communication Qing Liu, Peng-Jian Kang, Zeng-Ping Chen, Cai-Xia Shi, Yao Chen, Ru-Qin Yu A platform for microRNA detection was developed based on understanding the hydrolysis patterns of duplex-specific nuclease against probe DNAs. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Intensified interzeolite transformation: ultrafast synthesis of active and stable Ti-Beta zeolites without solvents ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07423F, Communication Zhiguo Zhu, Hao Xu, Bowen Wang, Jinpeng Yin, Jingang Jiang, Hongying Lü, Peng Wu Nanosized Ti-Beta zeolite with highly stable isolated Ti(IV) is synthesized in an ultrafast manner by intensified interzeolite transformation from a Ti-MWW source under solvent-free conditions at an elevated temperature. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Rapid access to (cycloalkyl)tellurophene oligomer mixtures and the first poly(3-aryltellurophene) ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC07512G, Communication Bruno T. Luppi, Robert McDonald, Michael J. Ferguson, Lingzi Sang, Eric Rivard New poly- and oligotellurophenes bearing cycloalkyl and 3-aryl substituents have been reported, with narrow band gaps approaching 1.3 eV observed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Iridium(III) complexes of 1,2,4-triazines as potential bioorthogonal reagents: metal coordination facilitates luminogenic reaction with strained cyclooctynes ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC06828G, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Valery N. Kozhevnikov, Michael E. Deary, Theodora Mantso, Mihalis I. Panayiotidis, Mark T. Sims Unprecedented Ir(III) complexes of 5-(2-pyridyl)-1,2,4-triazine are described. The metal coordination drastically increases the speed of the Inverse Electron Demand Diels Alder reaction with strained bicyclooctyne BCN. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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