Chem. Commun.

A two-photon fluorescent probe for real-time monitoring autophagy by ultrasensitive detection of the change in lysosomal polarity ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00752C, Communication Jiacheng Jiang, Xiaohe Tian, changzhi xu, Shuxin Wang, Yan Feng, Man Chen, Haizhu Yu, Manzhou Zhu, Xiangming Meng The first two-photon probe Lyso-OC for monitoring cell autophagy by detecting the change of lysosomal polarity during the membrane fusion process of autophagy was proposed. Lyso-OC exhibited desired optical properties... The content of this RSS Feed (c) The Royal Society of Chemistry
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Palladium-Catalyzed Cascade Metallo-Ene/Suzuki Coupling Reaction of Allenamides ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00191F, Communication Hanbing Liang, Fachao Yan, Xu Dong, qing Liu, Xiaobing Wei, sheng Liu, Yunhui Dong, Hui Liu A new type of cascade metallo-ene/Suzuki coupling reaction of allenamides catalyzed by palladium has been described. A variety of polyfunctionalized 2,3-dihydropyrrole derivates which are important structural motifs for bioactive molecules,... The content of this RSS Feed (c) The Royal Society of Chemistry
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An Unexpected Use of Ferrocene. A Scanning Electrochemical Microscopy Study of a Toll-Like Receptor Array and Its interaction with E.coli ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00863E, Communication Zhe She, Kristin Topping, Bin Dong, Mohtashim Shamsi, Heinz-Bernhard Kraatz Imaging of toll-like receptors microarrays was achieved using scanning electrochemical microscopy with the successful integration of two ferrocene derivatives in order to enhance the background contrast. This investigation has resulted... The content of this RSS Feed (c) The Royal Society of Chemistry
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GO-Se nanocomposite as an antioxidant nanozyme for cytoprotection ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00045F, Communication Yanyan Huang, Chaoqun Liu, Fang Pu, Zhen Liu, Jinsong Ren, Xiaogang Qu GO-Se nanocomposites are fabricated with excellent glutathione peroxidase (GPx)-like property to protect cells against oxidative stress. Compared with SeNPs, the GO-Se nanozymes exhibit higher GPx-mimic catalytic efficiency. Cell experiments further... The content of this RSS Feed (c) The Royal Society of Chemistry
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The Importance of Solvent Selection in Li-O2 Cells ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C6CC09086A, Communication Daniel Sharon, Daniel Hirshberg, Michal Afri, Aryeh A. Frimer, Doron Aurbach We have examined the effect of glyme selection on the cycling behavior of Li-O2 cells. We conclude that diglyme is the optimal solvent for prolonged cycling. We have also focused... The content of this RSS Feed (c) The Royal Society of Chemistry
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"Activography": A novel, versatile and easily adaptable method for monitoring enzymatic activities in situ ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01081H, Communication Georgios Pampalakis, Eleni Zingkou, Kostas Vekrellis, Georgia Sotiropoulou We developed activography to map enzymatic activities on tissue sections by use of activity-based probes. The assay was validated using a new protease-activity probe on skin biopsies to provide proof-of-concept.... The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis and structure of synthetically pure and deuterated amorphous (basic) calcium carbonates ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C6CC08848A, Communication Hsiu-Wen Wang, Luke L. Daemen, Michael C Cheshire, Michelle K Kidder, Andrew G Stack, Lawrence F. Allard, Joerg C. Neuefeind, Daniel P Olds, Jue Liu, Katharine Page It is generally believed that H2O and OH- are the key species stabilizing and controlling amorphous calcium carbonate "polyamorph" forms, and may in turn control the ultimate crystallization products during... The content of this RSS Feed (c) The Royal Society of Chemistry
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Fe3O4@ZIF-8: A Magnetic Nanocomposite for Highly Efficient UO2(2+) Adsorption and Selective UO2(2+)/Ln(3+) Separation ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C6CC10274C, Communication Xue Min, Weiting Yang, Chaoying Gao, Song Dang, Yuan-Feng Hui, Zhong-Ming Sun The magnetic nanocomposite Fe3O4@ZIF-8 has been firstly used as an excellent adsorbent for fast adsorption and seperation of UO2(2+) ions from aqueous solutions. This material exhibits an unprecedented adsorption capacity... The content of this RSS Feed (c) The Royal Society of Chemistry
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Solvent-free Dense Energetic Metal-organic Framework (EMOF): To Improve Stability and Energetic Performance via in situ Microcalorimetry ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00545H, Communication Yinli Zhang, Sheng Zhang, Lin Sun, Qi Yang, Jing Han, Qing Wei, Gang Xie, Sanping Chen, Shengli Gao It is tremendous challenge to prepare solvent-free dense energetic metal-organic frameworks (EMOFs), hence improve their stability and energetic performance. In this study, based on in situ microcalorimetry, an interpenetrating EMOF... The content of this RSS Feed (c) The Royal Society of Chemistry
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Pure DNA Hydrogel with Stable Catalytic Ability Produced by One-Step Rolling Circle Amplification ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00636E, Communication Yishun Huang, Wanlin Xu, Guoyuan Liu, Leilei Tian A rolling-circle-amplification method was developed to produce DNA hydrogels with horseradish-peroxidase-like catalytic capability. The catalytic hydrogel exhibits highly improved stability at elevated temperatures or during a long-term storage. Integrated with... The content of this RSS Feed (c) The Royal Society of Chemistry
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Orthogonal switching in four-state azobenzene mixed-dimers ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00504K, Communication Fangli Zhao, Lutz Grubert, Stefan Hecht, David Bleger Azobenzene mixed-dimer rods have been prepared, whose four isomers can be orthogonally addressed with light and electrons. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Self-assembly of cucurbit[7]uril based triangular [4]molecular necklaces and their fluorescence properties ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC10328F, Communication Soumen K. Samanta, Kimberly G. Brady, Lyle Isaacs We report the synthesis of rigid rod (bis)dipyridinium ligand 1 and its self-assembly in the presence of M(en)(NO3)2 (M = Pd, Pt) and cucurbit[7]uril or motor 2 (M2) to yield triangular [4]molecular necklaces 7-10. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Oxygen reduction catalyzed by a water-soluble binuclear copper(II) complex from a neutral aqueous solution ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC09206C, Communication Chengyu Liu, Haitao Lei, Zongyao Zhang, Fangfang Chen, Rui Cao A water-soluble binuclear CuII complex of a polypyridine-polyamide ligand can catalyze oxygen reduction to water from neutral aqueous solutions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Mn(IV) and Mn(V)-radical species supported by the redox non-innocent bis(2-amino-3,5-di-tert-butylphenyl)amine pincer ligand ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00516D, Communication Nicolas Leconte, Jules Moutet, Khrystyna Herasymchuk, Ryan M. Clarke, Christian Philouze, Dominique Luneau, Tim Storr, Fabrice Thomas The electron-rich pincer ligand 1 has been synthesized and chelated to manganese, affording 2 in high yield. Complex 2 comprises two iminosemiquinone radicals coordinated to a Mn(IV) ion. Its two electron oxidation produces 22+, which is a stable Mn(V)-iminosemiquinone radical complex. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Asymmetric hydroarylation of vinyl ethers catalyzed by a hydroxoiridium complex: azoles as effective directing groups ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00238F, Communication Daisuke Yamauchi, Takahiro Nishimura, Hideki Yorimitsu Asymmetric hydroarylation of vinyl ethers using azoles as directing groups was realized by use of a hydroxoiridium/chiral phosphine catalyst. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Stable amphiphilic supramolecular self-assembly based on cyclodextrin and carborane for the efficient photodynamic therapy ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC10059G, Communication Hejian Xiong, Dongfang Zhou, Xiaohua Zheng, Yanxin Qi, Yongheng Wang, Xiabin Jing, Yubin Huang We synthesized stable supramolecular nanoparticles based on the high affinity of carboranes and [small beta]-cyclodextrin for efficient photodynamic therapy. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Coupling Polymorphic Nanostructured Carbon Nitrides into an Isotype Heterojunction with Boosted Photocatalytic H2 Evolution ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00356K, Communication Jianhai Wang, Yile Chen, Yanfei Shen, Songqin Liu, Yuanjian Zhang Heterojunction photocatalyst that was made of single substrate was reported. The very similar chemical and crystalline structures make the heterointerfaces of carbon nitride (CN) natively compatible. Moreover, the varieties in... The content of this RSS Feed (c) The Royal Society of Chemistry
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A mitochondria-targeting supramolecular photosensitizer based on pillar[5]arene for photodynamic therapy ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00950J, Communication Leilei Rui, Yudong Xue, Yong Wang, Yun Gao, Weian Zhang A mitochondria-targeting supramolecular photosensitizer system TPP-QASs/WP5/DTAB was constructed based on host-guest inclusion complex. The supramolecular system could efficiently release and activate TPP-QASs in an acidic environment, which demonstrated to preferentially... The content of this RSS Feed (c) The Royal Society of Chemistry
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Pt nanoparticles immobilized in a mesostructured silica: a non-leaching catalyst for 1-octene hydrosilylation ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C6CC10154B, Communication Thomas Galeandro-Diamant, Reine Sayah, Marie-Line Zanota, Sebastien Marrot, Laurent Veyre, Chloe Thieuleux, Valerie Meille A catalyst containing small (ca. 2.5 nm) and cristalline Pt nanoparticles embedded into the walls of a mesostructured silica was found highly active in alkene hydrosilylation reaching TONs of ca.... The content of this RSS Feed (c) The Royal Society of Chemistry
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Rigidly linking cyclometallated Ir(III) and Pt(II) centres: an efficient approach to strongly absorbing and highly phosphorescent red emitters ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00656J, Communication Graeme Turnbull, J. A. Gareth Williams, Valery N. Kozhevnikov Appending a cyclometallated platinum unit onto each of the three ligands of the archetypal fac-Ir(ppy)3 complex leads to a highly efficient red emitter with a short luminescence decay time. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Selective separation of americium from europium using 2,9-bis(triazine)-1,10-phenanthrolines in ionic liquids: a new twist on an old story ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC09823A, Communication Neil J. Williams, Jeremy Dehaudt, Vyacheslav S. Bryantsev, Huimin Luo, Carter W. Abney, Sheng Dai Am(III) is efficiently extracted from Eu(III) in a single contact with a bis(triazine)-1,10-phenanthroline dissolved in an ionic liquid. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Isolation of a chiral anthracene cation radical: X-ray crystallography and computational interrogation of its racemization ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC10307C, Communication Maxim V. Ivanov, Khushabu Thakur, Anshul Bhatnagar, Rajendra Rathore Chiral cation-radicals hold significant promise as charge-transfer materials, chiroptical switches, and catalysts for enantioselective synthesis. Herein we identify a chiral anthracene derivative that forms a robust cation-radical salt as established by X-ray crystallography and DFT calculations. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Quantifying and understanding the steric properties of N-heterocyclic carbenes ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00255F, Feature Article Adrian Gomez-Suarez, David J. Nelson, Steven P. Nolan This Feature Article presents and discusses the use of different methods to quantify and explore the steric impact of N-heterocyclic carbene (NHC) ligands. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Iron(II)-catalyzed sulfur directed C(sp3)-H bond amination/C-S cross coupling reaction ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC10303K, Communication Fang-Fang Duan, Shi-Qian Song, Run-Sheng Xu An efficient iron(II)-catalyzed sulfur directed C(sp3)-H bond amination/C-S cross coupling reaction has been developed, and the mechanism corresponds to a Fe(II)/Fe(III) catalytic cycle. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Bronsted acid-catalyzed [small alpha]-halogenation of ynamides from halogenated solvents and pyridine-N-oxides ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC10286G, Communication Seung Woo Kim, Tae-Woong Um, Seunghoon Shin The keteniminium ions generated from the protonation of ynamides formed reversible adducts with counter anions and pyridine-N-oxides as well as halogenated solvents. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Oxidative couplings on tryptophan-based diketopiperazines leading to fused and bridged chemotypes ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00555E, Communication Lorena Mendive-Tapia, Arantxa Albornoz-Grados, Alexandra Bertran, Fernando Albericio, Rodolfo Lavilla Selective C-C and C-N oxidative couplings on tryptophan-based diketopiperazines allow the direct access to two novel scaffolds. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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The bifunctional catalytic role of water clusters in the formation of acid rain ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC09616F, Communication Eduardo Romero-Montalvo, Jose Manuel Guevara-Vela, Wilmer Esteban Vallejo Narvaez, Aurora Costales, Angel Martin Pendas, Marcos Hernandez-Rodriguez, Tomas Rocha-Rinza Modern bonding analyses indicate that water clusters in the formation of H2SO4 in acid rain (left) resemble bifunctional organocatalysts (right). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Comparative analysis of triarylamine and phenothiazine sensitizer donor units in dye-sensitized solar cells ()
Chem. Commun., 2017, 53,2367-2370 DOI: 10.1039/C6CC09178D, Communication Valerie A. Chiykowski, Brian Lam, Chuan Du, Curtis P. Berlinguette The performance of a homologous set of dyes that differ only in the donor fragments, namely phenothiazine (PTZ) and triarylamine (TPA) units, was evaluated in dye-sensitized solar cells (DSSCs). The content of this RSS Feed (c) The Royal Society of Chemistry
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Electrochemical probing of hydrogelation induced by the self-assembly of a donor-acceptor complex comprising pyranine and viologen ()
Chem. Commun., 2017, 53,2371-2374 DOI: 10.1039/C6CC09465A, Communication Sougata Datta, Nilanjan Dey, Santanu Bhattacharya We report the electrochemical analysis of a donor-acceptor type two-component hydrogelation by an electroactive co-assembly of pyranine and n-dodecyl methyl viologen. The content of this RSS Feed (c) The Royal Society of Chemistry
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A facile approach for the synthesis of hydroxyl-rich microporous organic networks for efficient CO2 capture and H2 storage ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC09660C, Communication Sujan Mondal, Sudipta K. Kundu, Asim Bhaumik A new series of porous organic networks (PONs) with N-donor sites and free hydroxyl groups in the backbone have been synthesized under high vacuum sealed tube conditions. These PONs possess high BET surface area and showed excellent H2 and CO2 storage capacities. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Hybrid methylammonium lead halide perovskite nanocrystals confined in gyroidal silica templates ()
Chem. Commun., 2017, 53,2359-2362 DOI: 10.1039/C6CC10245J, Communication Victor Malgras, Joel Henzie, Toshiaki Takei, Yusuke Yamauchi We synthesized confined hybrid methylammonium lead halide nanocrystals in a gyroidal mesoporous silica template in order to provide high material diffusion and space for solvent escape. The content of this RSS Feed (c) The Royal Society of Chemistry
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Tailor-made synthesis of fully alkylated/arylated nicotinates by FeCl3-mediated condensation of enamino esters with enones ()
Chem. Commun., 2017, 53,2390-2393 DOI: 10.1039/C7CC00051K, Communication Sho Hirai, Yurie Horikawa, Haruyasu Asahara, Nagatoshi Nishiwaki A synthetic method for fully alkylated/arylated nicotinates was achieved by FeCl3-mediated condensation of enamino esters and enones. The content of this RSS Feed (c) The Royal Society of Chemistry
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Palladium-catalyzed domino Heck/intermolecular cross-coupling: efficient synthesis of 4-alkylated isoquinoline derivatives ()
Chem. Commun., 2017, 53,2386-2389 DOI: 10.1039/C6CC10075A, Communication Tuanli Yao, Tao Liu, Changhui Zhang The first example of a [sigma]-alkylpalladium(II) intermediate promoting cyclization of alkynes containing a proximate nucleophilic center is presented. The content of this RSS Feed (c) The Royal Society of Chemistry
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Mixing cations with different alkyl chain lengths markedly depresses the melting point in deep eutectic solvents formed from alkylammonium bromide salts and urea ()
Chem. Commun., 2017, 53,2375-2377 DOI: 10.1039/C7CC00201G, Communication Zhengfei Chen, Tamar L. Greaves, Gregory G. Warr, Rob Atkin Mixing cations with different alkyl chain lengths markedly depresses the freezing point in deep eutectic solvents. The content of this RSS Feed (c) The Royal Society of Chemistry
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A catalytic intramolecular nitrene insertion into a copper(I)-N-heterocyclic carbene bond yielding fused nitrogen heterocycles ()
Chem. Commun., 2017, 53,2402-2405 DOI: 10.1039/C6CC09160A, Communication Kevin Fauche, Lionel Nauton, Laurent Jouffret, Federico Cisnetti, Arnaud Gautier We report a catalytic NHC-imido/nitrene cyclization allowing an easy access to diverse nitrogen-rich heterocyclic scaffolds. The content of this RSS Feed (c) The Royal Society of Chemistry
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Robust superhydrophobic diamond microspheres for no-loss transport of corrosive liquid microdroplets ()
Chem. Commun., 2017, 53,2355-2358 DOI: 10.1039/C6CC09806A, Communication Qiang Wang, Jie Bai, Bing Dai, Zhenhuai Yang, Shuai Guo, Lei Yang, Yurong He, Jiecai Han, Jiaqi Zhu A superhydrophobic composite film with a high adhesive force and chemical stability based on diamond microspheres is created via a simple bonding process. The content of this RSS Feed (c) The Royal Society of Chemistry
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Cu1.8S-Passivated carbon dots for enhancing photocatalytic activity ()
Chem. Commun., 2017, 53,2343-2346 DOI: 10.1039/C6CC09508A, Communication Qing Chang, Xuejun Han, Chaorui Xue, Jinlong Yang, Shengliang Hu Carbon dots are passivated by a small amount of Cu1.8S and show excellent photocatalytic activities in redox processes. The content of this RSS Feed (c) The Royal Society of Chemistry
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Two microporous Fe-based MOFs with multiple active sites for selective gas adsorption ()
Chem. Commun., 2017, 53,2394-2397 DOI: 10.1039/C6CC09923H, Communication Yun-Wu Li, Hui Yan, Tong-Liang Hu, Hui-Yan Ma, Da-Cheng Li, Su-Na Wang, Qing-Xia Yao, Jian-Min Dou, Jian Xu, Xian-He Bu Two Fe-based porous MOFs have been constructed from dimeric Fe-clusters and rod-shaped heterobimetallic Fe/Na-chains as SBUs, respectively. Notably, both of them exhibit highly selective CO2 uptake over CH4 and N2 owing to abundant multiple active sites. The content of this RSS Feed (c) The Royal Society of Chemistry
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Acid deprotonation driven by cation migration at biased graphene nanoflake electrodes ()
Chem. Commun., 2017, 53,2351-2354 DOI: 10.1039/C6CC09418J, Communication M. M. Lounasvuori, K. B. Holt Deprotonation of acids at an electrode interface is driven by cation migration in response to the applied potential. The content of this RSS Feed (c) The Royal Society of Chemistry
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First report on bio-catalytic N-formylation of amines using ethyl formate ()
Chem. Commun., 2017, 53,2382-2385 DOI: 10.1039/C6CC07679C, Communication Rupesh E. Patre, Sanjib Mal, Pankaj R. Nilkanth, Sujit K. Ghorai, Sudhindra H. Deshpande, Myriem El Qacemi, Tomas Smejkal, Sitaram Pal, Bhanu N. Manjunath A bio-catalyzed N-formylation reaction of different amines has been developed using ethyl formate as a formylating agent. The content of this RSS Feed (c) The Royal Society of Chemistry
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Long time and distance self-propelling of a PVC sphere on a water surface with an embedded ZnO micro-/nano-structured hollow sphere ()
Chem. Commun., 2017, 53,2347-2350 DOI: 10.1039/C6CC09308F, Communication Lei Wang, Lujia Yu, Liting Yi, Bin Yuan, Yongping Hou, Xiangfu Meng, Jing Liu In this research, a zinc oxide micro-/nano-structured hollow sphere (MNHS) with a large specific surface area is applied as energy storage material to encapsulate poly(vinyl chloride) solution and control the fuel release. The content of this RSS Feed (c) The Royal Society of Chemistry
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Firmly anchored photosensitizer Chlorin e6 to layered double hydroxide nanoflakes for highly efficient photodynamic therapy in vivo ()
Chem. Commun., 2017, 53,2339-2342 DOI: 10.1039/C6CC09510K, Communication Li Yan, Zhigang Wang, Xianfeng Chen, Xiao-Jun Gou, Zhenyu Zhang, Xiaoyue Zhu, Minhuan Lan, Wei Chen, Guangyu Zhu, Wenjun Zhang We covalently conjugate photosensitizer Chlorin e6 (Ce6) to polyethylene glycol modified layered double hydroxides and produce hybrid nanoflakes with excellent in vivo photodynamic therapeutic efficiency and safety profiles. The content of this RSS Feed (c) The Royal Society of Chemistry
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Specific detection of cancer cells through aggregation-induced emission of a light-up bioprobe ()
Chem. Commun., 2017, 53,2398-2401 DOI: 10.1039/C7CC00122C, Communication Jian Chen, Hong Jiang, Huipeng Zhou, Zhenzhen Hu, Niu Niu, Sohail Anjum Shahzad, Cong Yu A specific cancer cell detection method through the aggregation-induced emission of a light-up bioprobe is developed. The content of this RSS Feed (c) The Royal Society of Chemistry
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A facile approach for TiO2-based superhydrophobic-superhydrophilic patterns by UV or solar irradiation without a photomask ()
Chem. Commun., 2017, 53,2363-2366 DOI: 10.1039/C6CC09558E, Communication Zhu Yanqing, Shi jifu, Huang Qizhang, Wang Leilei, Xu Gang A novel and facile approach to produce TiO2-based superhydrophobic-superhydrophilic patterns by UV or solar irradiation without a photomask is presented. The content of this RSS Feed (c) The Royal Society of Chemistry
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Versatile cross-dehydrogenative coupling of heteroaromatics and hydrogen donors via decatungstate photocatalysis ()
Chem. Commun., 2017, 53,2335-2338 DOI: 10.1039/C6CC09725A, Communication Matteo C. Quattrini, Saki Fujii, Keiichi Yamada, Takahide Fukuyama, Davide Ravelli, Maurizio Fagnoni, Ilhyong Ryu A facile sunlight-induced derivatization of heteroaromatics via TBADT photocatalyzed C-H functionalization in amides, ethers, alkanes and aldehydes is described. The content of this RSS Feed (c) The Royal Society of Chemistry
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Pentazadiene: a high-nitrogen linkage in energetic materials ()
Chem. Commun., 2017, 53,2327-2330 DOI: 10.1039/C6CC08179G, Communication Qi Wang, Fuqing Pang, Guilong Wang, Jinglun Huang, Fude Nie, Fu-Xue Chen The N5-linear energetic moiety of pentazadiene, a new high-nitrogen linkage in energetic materials, has been constructed for the first time from a triazene precursor. The content of this RSS Feed (c) The Royal Society of Chemistry
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A rechargeable Al-ion battery: Al/molten AlCl3-urea/graphite ()
Chem. Commun., 2017, 53,2331-2334 DOI: 10.1039/C6CC09825H, Communication Handong Jiao, Chen Wang, Jiguo Tu, Donghua Tian, Shuqiang Jiao A new Al-ion battery with an affordable and nontoxic AlCl3/urea electrolyte. The content of this RSS Feed (c) The Royal Society of Chemistry
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Liquefaction-induced emission enhancement of tetraphenylethene derivatives ()
Chem. Commun., 2017, 53,2378-2381 DOI: 10.1039/C6CC09939D, Communication Takashi Machida, Ryosuke Taniguchi, Tsuyoshi Oura, Kazuki Sada, Kenta Kokado A typical AIE dye, TPE, was liquefied by attaching long and branched alkyl chains. The obtained liquid dye showed intense emission compared to that of the solid dye or TPE. The linkage between TPE and the alkyl chain led to significant differences in their photoluminescent and thermal properties. The content of this RSS Feed (c) The Royal Society of Chemistry
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Bacteria-templated fabrication of a charge heterogeneous polymeric interface for highly specific bacterial recognition ()
Chem. Commun., 2017, 53,2319-2322 DOI: 10.1039/C6CC09242J, Communication Han Bao, Bin Yang, Xingwang Zhang, Lecheng Lei, Zhongjian Li Using bacteria-templated polymerization, a novel bacteria-imprinted polymer (BIP) was fabricated for bacterial recognition. The content of this RSS Feed (c) The Royal Society of Chemistry
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Rhenium(I) complexes of N-heterocyclic carbene ligands that bind to amyloid plaques of Alzheimer's disease ()
Chem. Commun., 2017, 53,2311-2314 DOI: 10.1039/C6CC10066J, Communication Chung Ying Chan, Asif Noor, Catriona A. McLean, Paul S. Donnelly, Peter J. Barnard Rhenium(I) complexes of tridentate N-heterocyclic carbene ligands that bind to amyloid plaques in human brain tissue are reported. The content of this RSS Feed (c) The Royal Society of Chemistry
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Effect of cationic groups in poly(arylene ether sulfone) membranes on reverse electrodialysis performance ()
Chem. Commun., 2017, 53,2323-2326 DOI: 10.1039/C6CC08440K, Communication Doo Hee Cho, Kang Hyuck Lee, Young Mi Kim, Sang Hyun Park, Won Hyo Lee, Sang Min Lee, Young Moo Lee Swelling of poly(arylene ether sulfone) anion exchange membranes increases the permselectivity in reverse electrodialysis performance while maintaining the high ion conductivity. The content of this RSS Feed (c) The Royal Society of Chemistry
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Accessing alternative reaction pathways of the intermolecular condensation between homo-propargyl alcohols and terminal alkynes through divergent gold catalysis ()
Chem. Commun., 2017, 53,2315-2318 DOI: 10.1039/C6CC09794D, Communication Courtney A. Smith, Stephen E. Motika, Lukasz Wojtas, Xiaodong Shi An intermolecular condensation of alkynols and terminal alkynes is reported. The content of this RSS Feed (c) The Royal Society of Chemistry
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One-pot Conversion of the Biomass-derived Xylose and Furfural into Levulinate Esters via Acid Catalysis ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC01078H, Communication Xun Hu, Shengjuan Jiang, Liping Wu, Shuai Wang, Chun-Zhu Li Direct conversion of biomass-derived xylose and furfural into levulinic acid, a platform molecule, via acid-catalysis has been accomplished for the first time in dimethoxymethane/methanol. Dimethoxymethane acted as the electrophile to... The content of this RSS Feed (c) The Royal Society of Chemistry
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A novel strategy for high-performance transparent conductive films based on double-walled carbon nanotubes ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C6CC10252B, Communication Yuan He, Hehua Jin, Song Qiu, Qingwen Li High concentration of double-walled carbon nanotubes was dispersed by a carbazole-based conjugated polymer. And the transparent conductive film was fabricated via simple dip-coating using the dispersion, which showed simultaneously a... The content of this RSS Feed (c) The Royal Society of Chemistry
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Localization Matters: A Nuclear Targeting Two-Photon Absorption Iridium Complex Induced Intracellular Immigration and Dual-damage in Photon Dynamic Therapy ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C6CC09470H, Communication Xiaohe Tian, Yingzhong Zhu, Ming-Zhu Zhang, Lei Luo, Jieying Wu, Hongping zhou, Lijuan Guan, Giuseppe Battaglia, Yupeng Tian We present a two-photon (TP, 800nm) PDT cyclometalated Iridium (III) complex (Ir-Es) that targets intracellular nucleus, it is capable of imigrating sequentially from nucleus to mitochondria and inducing dual-damage under... The content of this RSS Feed (c) The Royal Society of Chemistry
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Nucleic acid detection using BRET-beacons based on bioluminescent protein-DNA hybrids ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C6CC10032E, Communication Wouter Engelen, Kayleigh van de Wiel, Lenny Meijer, Bedabrata Saha, Maarten Merkx Bioluminescent molecular beacons have been developed using a modular design approach that relies on BRET between the bright luciferase NanoLuc and a Cy3 acceptor. While classical molecular beacons are hampered... The content of this RSS Feed (c) The Royal Society of Chemistry
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A Versatile Size-Coded Flow Cytometric Bead Assay for Simultaneous Detection of Multiple MicroRNAs Coupled with a Two-Step Cascading Signal Amplification ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00618G, Communication Liying Qiu, Yuecheng Zhang, Chenghui Liu, Zhengping Li A versatile flow cytometric bead assay is developed for sensitive and simultaneous detection of multiple microRNAs that combines an elegant enzyme-mediated cascading signal amplification on magnetic beads with a novel... The content of this RSS Feed (c) The Royal Society of Chemistry
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Molecular and genetic basis for early stage structural diversifications in hapalindole-type alkaloid biogenesis: WelU- protein-directed regiodivergent assembly of 12-epi-fischerindole U and 12-epi-hapalindole C in welwitindolinone producers ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C7CC00782E, Communication Qin Zhu, Xinyu Liu Heterologous expressions and purifications of all WelU proteins from the welwitindolinone pathways in Hapalosiphon welwitschii UTEX B1830 and IC-52-3 led to the discovery that WelU1 and WelU3 selectively assemble 12-epi-fischerindole... The content of this RSS Feed (c) The Royal Society of Chemistry
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Strontium cobalt oxychlorides: enhanced electrocatalysts for oxygen reduction and evolution reactions ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC09890H, Communication Yuto Miyahara, Kohei Miyazaki, Tomokazu Fukutsuka, Takeshi Abe Cobalt-based layered perovskite oxychlorides Sr2CoO3Cl and Sr3Co2O5Cl2 exhibit high oxygen electrochemical activity compared to conventional lanthanum cobalt-based perovskite oxides. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Elucidating light-induced charge accumulation in an artificial analogue of methane monooxygenase enzymes using time-resolved X-ray absorption spectroscopy ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC08748E, Communication Dooshaye Moonshiram, Antonio Picon, Alvaro Vazquez-Mayagoitia, Xiaoyi Zhang, Ming-Feng Tu, Pablo Garrido-Barros, Jean-Pierre Mahy, Frederic Avenier, Ally Aukauloo Probing the light-induced two electron transfer processes at a diiron(III,III) multimolecular photocatalytic system. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Gold-catalyzed ring-expansion through acyl migration to afford furan-fused polycyclic compounds ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00218A, Communication Changyuan Zhang, Huanfeng Jiang, Shifa Zhu A gold-catalyzed ring-expansion reaction of alkynones to access furan-fused polycyclic compounds is reported. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Selective palladium(II)-mediated oxidation of homoallylic N-tert-butanesulfinyl amine derivatives ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00826K, Communication Ana Sirvent, Tatiana Soler, Francisco Foubelo, Miguel Yus The palladium(II)-catalyzed oxidation of N-tert-butanesulfinyl homoallylamine derivatives was substrate dependent and proceeded with high regio- and stereoselectivity. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Selective hydrogenolysis of carbon-oxygen bonds with formic acid over a Au-Pt alloy catalyst ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC09599B, Communication Liang Wang, Jian Zhang, Guoxiong Wang, Wei Zhang, Chengtao Wang, Chaoqun Bian, Feng-Shou Xiao A CeO2-supported Au-Pt alloy catalyst is highly efficient for selective hydrogenolysis of carbon-oxygen species using formic acid as the hydrogen source. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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An unusual nitride network of aluminum-centered octahedra and phosphorus-centered tetrahedra and structure determination from microcrystalline samples ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00233E, Communication Lukas Neudert, Frank Heinke, Thomas Brauniger, Florian J. Pucher, Gavin B. Vaughan, Oliver Oeckler, Wolfgang Schnick Aluminum coordinated by six nitrogen atoms was realized in a new highly condensed network which was obtained via HP-HT synthesis at 5 GPa. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Three in one: prototropy-free highly stable AADD-type self-complementary quadruple hydrogen-bonded molecular duplexes with a built-in fluorophore ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC09478C, Communication Sanjeev Kheria, Suresh Rayavarapu, Amol S. Kotmale, Gangadhar J. Sanjayan This communication reports an effective approach for addressing the prototropy-related problems in heterocycle-based AADD-type self-assembling systems by freezing their hydrogen-bonding codes, by utilizing intramolecular bifurcated hydrogen bonding interactions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Exploring the "fold-in" strategy toward the construction of a highly-strained triazasumanene skeleton ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00329C, Communication Fengkun Chen, Takayuki Tanaka, Atsuhiro Osuka "Fold-in"-type syntheses toward the construction of tribenzotriazasumanene were attempted under oxidative and reductive conditions, which resulted in the formation of two different products. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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An unexpected pathway for hydrodesulfurization of gazole over a CoMoS active phase supported on a mesoporous TiO2 catalyst ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00848A, Communication I. Naboulsi, C. Felipe Linares Aponte, B. Lebeau, S. Brunet, L. Michelin, M. Bonne, J. L. Blin Isomerization and dismutation pathways are identified as the main routes for the hydrodesulfurization of 4,6-dimethylbenzothiophene over a MoS2@mesoporous TiO2 catalyst. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Extraordinary rate capability achieved by a 3D "skeleton/skin" carbon aerogel-polyaniline hybrid with vertically aligned pores ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00121E, Communication Mingkai Liu, Bomin Li, Hang Zhou, Cong Chen, Yuqing Liu, Tianxi Liu A novel "skeleton/skin" CA-PANI hybrid with vertically aligned pores exhibits an excellent rate capability by maintaining 95% of its initial capacitance when the current density is increased from 1 to 100 A g-1. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Utilization of electron-donating [small alpha],[small beta]-unsaturated oximes: regioselective inverse 1,3-dipolar cycloaddition of nitrones ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00505A, Communication Yoshimitsu Hashimoto, Hiromasa Ishiwata, Soko Tachikawa, Shintaro Ban, Nobuyoshi Morita, Osamu Tamura The cycloaddition of nitrones with [small alpha],[small beta]-unsaturated carbonyl compounds (enones) afforded predominantly 4-acylisoxazolidines, whereas the cycloaddition of the corresponding oximes afforded 5-iminoisoxazolidines. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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C[double bond, length as m-dash]N bond formation via palladium-catalyzed carbene insertion into N[double bond, length as m-dash]N bonds: inhibiting the general 1,2-migration process of ylide intermediates ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC10187A, Communication Chuanle Zhu, Pengquan Chen, Rui Zhu, Zhiming Lin, Wanqing Wu, Huanfeng Jiang Inhibiting the general 1,2-migration process of ylide intermediates, a new palladium-catalyzed carbene insertion into N[double bond, length as m-dash]N bonds affords various N,N-disubstituted hydrazones. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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The synthesis of an EDTA-like chelating peptidomimetic building block suitable for solid-phase peptide synthesis ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC10203D, Communication Jan Spengler, Michael Barker, Constanze Schelhorn, Jesus Garcia, Maria J. Macias, Fernando Albericio A novo trifunctional EDTA-like peptidomimetic amino acid is described. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Core-to-core dimers forming switchable mesophase ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC09983A, Communication M. Horcic, J. Svoboda, V. Novotna, D. Pociecha, E. Gorecka We report structurally new type of dimers composed of bent-core molecules connected through their central cores by an alkylene spacer. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Evolution of CH3NO2/Si interfacial chemistry under reaction conditions: a combined experimental and theoretical study ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC09961K, Communication Xueqiang Zhang, Chen-Guang Wang, Wei Ji, Sylwia Ptasinska Dissociative adsorption of CH3NO2 onto a Si(100)-2 [times] 1 surface is studied using ambient-pressure X-ray photoelectron spectroscopy (AP-XPS) and density functional theory (DFT) calculations. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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N-Heterocyclic carbene (NHC)-catalysed atom economical construction of 2,3-disubstituted indoles ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC10292A, Communication Battu Harish, Manyam Subbireddy, Surisetti Suresh N-Heterocyclic carbene (NHC)-catalysed atom economical synthesis of a wide range of 2-substituted indole-3-acetic acid derivatives has been disclosed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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E-Z isomerization of the -C[double bond, length as m-dash]N- bond in anthracene-based acylhydrazone derivatives under visible light ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC08403F, Communication Binglian Bai, Mingang Zhang, Nan Ji, Jue Wei, Haitao Wang, Min Li The E-Z isomerizations of the -C[double bond, length as m-dash]N- group upon visible light irradiation induced the photoresponsive behaviour of AHP-mB8. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Controlled Assembly of Organic Whispering-Gallery-Mode Microlasers as Highly Sensitive Chemical Vapor Sensors ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C6CC08094D, Communication Miaomiao Gao, Cong Wei, Xianqing Lin, Yuan Liu, Fengqin Hu, Yong Sheng Zhao We demonstrate the fabrication of organic high Q active Whispering-Gallery-Mode (WGM) resonators from [small pi]-conjugated polymer by a controlled emulsion-solvent-evaporation method, which can simultaneously act as optical gain and effective resonant... The content of this RSS Feed (c) The Royal Society of Chemistry
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Confining a bi-enzyme inside the nanochannels of a porous aluminum oxide membrane for accelerating the enzymatic reactions ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00300E, Communication Li Shangguan, Yuanqing Wei, Xu Liu, Jiachao Yu, Songqin Liu An artificial metabolon with high conversion efficiency was constructed by confining a bi-enzyme into porous aluminum oxide nanochannels, which accelerated enzymatic reactions by minimizing the diffusion loss of intermediate species. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Copolymerisation of ethylene with polar monomers by using palladium catalysts bearing an N-heterocyclic carbene-phosphine oxide bidentate ligand ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00002B, Communication W. Tao, S. Akita, R. Nakano, S. Ito, Y. Hoshimoto, S. Ogoshi, K. Nozaki We report the synthesis and characterisation of palladium complexes bearing an N-heterocyclic carbene-phosphine oxide bidentate ligand and their use as catalysts for ethylene polymerisation and ethylene/polar monomer copolymerisation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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[sigma]-Complexation as a Strategy for Designing Copper-Based Light Emitters ()
Chem. Commun., 2017, Accepted Manuscript DOI: 10.1039/C6CC10139A, Communication Yeong-Eun Kim, Jin Kim, Joon Woo Park, Kiyoung Park, Yunho Lee Strongly emissive cuprous complexes containing a stable [sigma]-SiH-Cu motif were prepared. These complexes serve as a proof of principle that [sigma]-complexation can be utilized as a design principle for engineering... The content of this RSS Feed (c) The Royal Society of Chemistry
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Magic size InP and InAs clusters: synthesis, characterization and shell growth ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC09778B, Communication Jiajia Ning, Uri Banin Magic size InP and InAs nanocrystals (MSCs) have been synthesized. Based on InP MSCs, InP/ZnS and InP/ZnSe core/shell nanocrystals can be produced. An emission from interfacial traps can be observed with thicker ZnS shells. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly branched photomechanical crystals ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC08999B, Communication Rabih O. Al-Kaysi, Fei Tong, Maram Al-Haidar, Lingyan Zhu, Christopher J. Bardeen Ultraviolet light exposure causes highly branched microcrystals of 4-fluoroanthracene-9-carboxylic acid to reversibly deform and manipulate objects on a surface. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Hard carbon anodes of sodium-ion batteries: undervalued rate capability ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C7CC00301C, Communication Zhifei Li, Zelang Jian, Xingfeng Wang, Ismael A. Rodriguez-Perez, Clement Bommier, Xiulei Ji The intrinsic high rate capability of hard carbon anodes in sodium-ion batteries is revealed by a three-electrode cell. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Albumin nanoparticle encapsulation of potent cytotoxic therapeutics shows sustained drug release and alleviates cancer drug toxicity ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC08978J, Communication Hangxiang Wang, Jiaping Wu, Li Xu, Ke Xie, Chao Chen, Yuehan Dong We present novel HSA-based nanoassemblies for the formulation of highly potent cytotoxic therapeutic drugs such as maytansinoid DM1. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Photocyclization of photoswitches with high enantioselectivity in human serum albumin in an artificial environment ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC10197F, Communication Koichi Kawamura, Ken Osawa, Yuta Watanobe, Yuri Saeki, Naoki Maruyama, Yasushi Yokoyama Three photochromic bisthienylethenes exhibited 56 to >99% enantiomeric excess in photochemical ring closure upon UV irradiation when incorporated in human serum albumin dissolved in 15% acetonitrile-phosphate buffer solution and incubated for 24 h at -4 [degree]C. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Generation of cycloalkynes through deprotonation of cyclic enol triflates with magnesium bisamides ()
Chem. Commun., 2017, Advance Article DOI: 10.1039/C6CC09920C, Communication Yuto Hioki, Kentaro Okano, Atsunori Mori Magnesium bis(2,2,6,6-tetramethylpiperidide)-mediated deprotonation of readily available cyclic enol triflates allows direct access to cyclohexynes, cycloheptynes, and cyclooctynes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Second sphere ligand modifications enable a recyclable catalyst for oxidant-free alcohol oxidation to carboxylates ()
Chem. Commun., 2017, 53,2287-2289 DOI: 10.1039/C6CC10206A, Communication Eric W. Dahl, Thomas Louis-Goff, Nathaniel K. Szymczak Ruthenium-terpyridine complexes appended with secondary amines impart hydride stability and recyclability toward catalytic dehydrogenative alcohol oxidation to carboxylates. The content of this RSS Feed (c) The Royal Society of Chemistry
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De-orphaning the marine natural product (+/-)-marinopyrrole A by computational target prediction and biochemical validation ()
Chem. Commun., 2017, 53,2272-2274 DOI: 10.1039/C6CC09693J, Communication P. Schneider, G. Schneider A machine-learning method led to the discovery of the macromolecular targets of the natural anticancer compound marinopyrrol A. The content of this RSS Feed (c) The Royal Society of Chemistry
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Gauging circadian variation in ketamine metabolism by real-time breath analysis ()
Chem. Commun., 2017, 53,2264-2267 DOI: 10.1039/C6CC09061C, Communication P. Martinez-Lozano Sinues, M. Kohler, S. A. Brown, R. Zenobi, R. Dallmann Real-time in vivo pharmacokinetics to investigate time-of-day variation in drug metabolism. The content of this RSS Feed (c) The Royal Society of Chemistry
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Dual colorimetric and fluorogenic probes for visualizing tyrosine phosphatase activity ()
Chem. Commun., 2017, 53,2233-2236 DOI: 10.1039/C6CC09204G, Communication Suvendu Biswas, Brandon S. McCullough, Elena S. Ma, Dollie LaJoie, Colin W. Russell, D. Garrett Brown, June L. Round, Katharine S. Ullman, Matthew A. Mulvey, Amy M. Barrios Two resorufin-based substrates were developed, providing sensitive fluorogenic readouts for PTP activity in vitro and in living cells. The content of this RSS Feed (c) The Royal Society of Chemistry
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A fluorogenic molecular nanoprobe with an engineered internal environment for sensitive and selective detection of biological hydrogen sulfide ()
Chem. Commun., 2017, 53,2275-2278 DOI: 10.1039/C6CC09696D, Communication Myung Kim, Young Hun Seo, Youngsun Kim, Jeongyun Heo, Woo-Dong Jang, Sang Jun Sim, Sehoon Kim A nanoreactor approach based on the amphiphilic molecular assembly enables microscopic imaging of cellular processes and in vitro diagnostics with blood samples through selective and sensitive detection of H2S. The content of this RSS Feed (c) The Royal Society of Chemistry
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Halogen-bond-based cooperative ion-pair recognition by a crown-ether-embedded 5-iodo-1,2,3-triazole ()
Chem. Commun., 2017, 53,2260-2263 DOI: 10.1039/C6CC09749A, Communication Ronny Tepper, Benjamin Schulze, Peter Bellstedt, Jan Heidler, Helmar Gorls, Michael Jager, Ulrich S. Schubert A heteroditopic receptor with an iodo-triazole moiety for simultaneous cation-anion binding through Lewis-basic nitrogen atoms and halogen-bond-donating iodine atoms was designed. The content of this RSS Feed (c) The Royal Society of Chemistry
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Phototactic behavior of self-propelled micrometer-sized oil droplets in a surfactant solution ()
Chem. Commun., 2017, 53,2237-2240 DOI: 10.1039/C6CC09236E, Communication Sho Kaneko, Kouichi Asakura, Taisuke Banno We demonstrate the phototactic behavior of self-propelled micrometer-sized oil droplets in a far-from-equilibrium state. The content of this RSS Feed (c) The Royal Society of Chemistry
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Controlling and tuning the dynamic nature of supramolecular polymers in aqueous solutions ()
Chem. Commun., 2017, 53,2279-2282 DOI: 10.1039/C6CC10046E, Communication Simone I. S. Hendrikse, Sjors P. W. Wijnands, Rene P. M. Lafleur, Maarten J. Pouderoijen, Henk M. Janssen, Patricia Y. W. Dankers, E. W. Meijer Structural and kinetic exchange properties of supramolecular polymers composed of mono- and bivalent ureidopyrimidinone-based monomers are investigated in aqueous solutions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Heterogeneous mesoporous manganese oxide catalyst for aerobic and additive-free oxidative aromatization of N-heterocycles ()
Chem. Commun., 2017, 53,2256-2259 DOI: 10.1039/C6CC09095H, Communication Kankana Mullick, Sourav Biswas, Alfredo M. Angeles-Boza, Steven L. Suib Herein, we report a heterogeneous, aerobic, additive-free and environmentally benign catalytic protocol for oxidative aromatization of saturated nitrogen-heterocycles using a mesoporous manganese oxide material. The content of this RSS Feed (c) The Royal Society of Chemistry
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Electronic perturbation of supramolecular conjugates of porphyrins and phthalocyanines ()
Chem. Commun., 2017, 53,2230-2232 DOI: 10.1039/C6CC09590A, Communication Nozomi Mihara, Yasuyuki Yamada, Shigehisa Akine, Kunihisa Sugimoto, Kentaro Tanaka The redox potential of a supramolecular porphyrin-phthalocyanine heterodimer was perturbed by the stacking of an extra metalloporphyrin to the phthalocyanine. The content of this RSS Feed (c) The Royal Society of Chemistry
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Host-guest interactions and controllable capture and release of proteins based on cationic perylene bisimides ()
Chem. Commun., 2017, 53,2241-2244 DOI: 10.1039/C6CC08811B, Communication Qi Xu, Jia-Li Wang, Ya-Li Luo, Juan-Juan Li, Ke-Rang Wang, Xiao-Liu Li A system of controllable capture and release of protein was constructed by multiple, interconnected supramolecular binding modules based on lactose modified mono-cationic perylene bisimide derivatives, cucurbit[8]uril (CB[8]), 1-adamantanamine (ADA) and peanut agglutinin (PNA) lectins. The content of this RSS Feed (c) The Royal Society of Chemistry
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Large grain growth for hole-conductor-free fully printable perovskite solar cells via polyoxometalate molecular doping ()
Chem. Commun., 2017, 53,2290-2293 DOI: 10.1039/C6CC08516D, Communication Yuzhuo Zhang, Yanju Wang, Zhixia Sun, Fengyan Li, Ran Tao, Zhanbin Jin, Lin Xu Polyoxometalate-induced Ostwald ripening process occurring during the crystal grain growth of perovskite film, achieving a grain size of 30 [small mu ]m. The content of this RSS Feed (c) The Royal Society of Chemistry
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The ability of a fibrous titanium oxophosphate for nitrogen-adsorption above room temperature ()
Chem. Commun., 2017, 53,2249-2251 DOI: 10.1039/C6CC07518E, Communication Jorge Garcia-Glez, Zakariae Amghouz, Ivan da Silva, Conchi O. Ania, Jose B. Parra, Camino Trobajo, Santiago Garcia-Granda Nitrogen-fixation by an inorganic material at above-ambient temperature provoked by a structural change. The content of this RSS Feed (c) The Royal Society of Chemistry
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Palladium-catalyzed aerobic (1+2) annulation of Csp3-H bonds with olefin for the synthesis of 3-azabicyclo[3.1.0]hex-2-ene ()
Chem. Commun., 2017, 53,2294-2297 DOI: 10.1039/C6CC09332A, Communication Kun Wu, Lingkui Meng, Mingming Huai, Zhiliang Huang, Chao Liu, Xiaotian Qi, Aiwen Lei A novel Pd-catalyzed aerobic (1+2) annulation was developed and the palladation of Csp3-H bonds took place twice at the same position. Mechanistic studies by in situ IR revealed that the second C-H palladation and reductive elimination might be slow steps. The content of this RSS Feed (c) The Royal Society of Chemistry
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A red-NIR fluorescent dye detecting nuclear DNA G-quadruplexes: in vitro analysis and cell imaging ()
Chem. Commun., 2017, 53,2268-2271 DOI: 10.1039/C6CC08492C, Communication F. Doria, M. Nadai, M. Zuffo, R. Perrone, M. Freccero, S. N. Richter Light-up of nuclear G-quadruplex DNA in cells by an aggregating and red/NIR emitting dye. The content of this RSS Feed (c) The Royal Society of Chemistry
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