Chem. Commun.



Self-assembled Peptidic Nanomillipede to Fabricate Tuneable Hybrid Hydrogel ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02967B, Communication Jianhui Liu, Rong Ni, Ying Chau Peptidic ‘nanomillipede’, consisting of worm-like nanoscale ‘body’ and cysteine-terminated ‘legs’, was synthesized, tuned (with ultrasound) and utilized to crosslink the vinyl sulfone-modified dextran to form hybrid hydrogels with soft-tissue mimicking... The content of this RSS Feed (c) The Royal Society of Chemistry
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(H3O)HCs2Nb(IO3)9 and SrNbO(IO3)5: A Facile Synthetic Method of Using Hydrofluoric Acid as Solubilizer ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02774B, Communication Fei Fei Mao, Chun-Li Hu, Jin Chen, Ruling Tang, BaoLin Wu, Jiang-Gao Mao By using hydrofluoric acid as solubilizer, the first alkali-metal niobium iodate and an alkali-earth metal niobium iodate, i.e. (H3O)HCs2Nb(IO3)9 and SrNbO(IO3)5, have been obtained. An obvious cation-controlled polarity shift is... The content of this RSS Feed (c) The Royal Society of Chemistry
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Total synthesis and antimalarial activity of mortiamides A-D ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02864A, Communication Christopher Bérubé, Dominic Gagnon, Alexandre Borgia, Dave Richard, Normand Voyer Mortiamides A-D (1-4) are head-to-tail cyclic heptapeptides that were identified from a novel Mortierella sp. isolate obtained from marine sediments from Northern Canada. Herein we report the first total synthesis... The content of this RSS Feed (c) The Royal Society of Chemistry
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Ratiometric fluorescent detecting trace water in organic solvent based on bimetallic lanthanide metal-organic frameworks ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02324K, Communication Bei-Bei Li, Wenjing Wang, Zixiao Hong, El-Sayed M. El-Sayed, Daqiang Yuan Here we report a new sensor Tb97.11Eu2.89-L1 that achieves ratiometric detection of trace water in CH3CN. As the water content increases from 0% to 2.5% (v/v%), Tb97.11Eu2.89-L1 exhibits an excellent... The content of this RSS Feed (c) The Royal Society of Chemistry
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Correction: Synthesis of polyoxometalate clusters using carbohydrates as reducing agents leads to isomer-selection ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC90217A, Correction Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Eric Janusson, Noël de Kler, Laia Vilà-Nadal, De-Liang Long, Leroy Cronin To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Understanding the strain effect of Au@Pd nanocatalysts by in situ surface-enhanced Raman spectroscopy ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02639H, Communication Jie Wei, Yu-Jin Zhang, Si-Na Qin, Weimin Yang, Hua Zhang, Zhilin Yang, Zhong-qun Tian, Jian-Feng Li A gap-mode configuration was developed for the in-situ SERS study of the structure-activity relationship of Au@Pd core-shell nanocatalysts, which show much better performance in the selective oxidation of benzyl alcohol... The content of this RSS Feed (c) The Royal Society of Chemistry
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Vanadium carbide: an efficient, robust, and versatile cocatalyst for photocatalytic hydrogen evolution under visible light ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC03230D, Communication Lei Tian, Shixiong Min, Yonggang Lei, Shasha Chen, Fang Wang Herein, we report that vanadim carbide (VC) can efficiently catalyze photocatalytic H2 evolution with excellent stability in a dye-sensitized system under visible light irradiaiton (≥420 nm) and also serve as... The content of this RSS Feed (c) The Royal Society of Chemistry
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Single, Double, and Triple Intercluster Bonds. Analyses of M2Au36(SR)24 (M=Au, Pd, Pt) as 14-, 12- and 10-ve Superatomic Molecules ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02970B, Communication Alvaro Muñoz-Castro Archetypal molecules bearing single-, double- and triple-bonds are a crucial building block for more complex and extended networks. In this letter, we describe the bonding picture of experimentally characterized species... The content of this RSS Feed (c) The Royal Society of Chemistry
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Orchestrated catalytic double rollover annulation: Rapid access to N-enriched cationic and neutral PAHs ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02710F, Communication Pirudhan Karak, Champak Dutta, Tanoy Dutta, Apurba Lal Koner, Joyanta Choudhury Nitrogen-enriched polycyclic aromatic hydrocarbons (N-PAHs) are recognized as attractive organic electronic materials potentially applied in materials science and bio-imaging. However, straightforward and expeditious synthesis of these promising luminescent molecules with... The content of this RSS Feed (c) The Royal Society of Chemistry
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Uranium Capture Strategy based on Self-assembly in Hydroxyl-functionalized Ionic Liquids Extraction System ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02823D, Communication Bai-Hua Chen, Kaige Wu, Yanqiu Yang, Ning Wang, Yi Liu, Shuanglin Hu, Jing Wang, Jun Wen, Sheng Hu, Qingde Chen, Xinghai Shen, Shuming peng A novel and efficient uranium capture strategy based on self-assembly is developed in ionic liquid extraction system, by which one-step separation and solidification of uranium are realized. It not only... The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of fused B,N-heterocycles by alkyne cleavage, NHC ring-expansion and C–H activation at a diboryne ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02657F, Communication Tobias Brückner, Merle Arrowsmith, Merlin Heß, Kai Hammond, Marcel Müller, Holger Braunschweig The addition of alkynes to a saturated N-heterocyclic carbene (NHC)-supported diboryne results in spontaneous cycloaddition, with complete BB and CC triple bond cleavage, NHC ring-expansion and activation of a variety of C–H bonds, leading to the formation of complex mixtures of fused B,N-heterocycles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Plasma-treated Ti3+-doped sodium titanate nanosheet arrays on titanium foil as a lithiophilic current collector for a stable lithium metal anode ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02536G, Communication Qi Zhang, Jingyi Luan, Dan Sun, Yougen Tang, Haiyan Wang Ar/H2 plasma-treated Ti3+-doped sodium titanate nanosheet arrays on titanium foil can induce a uniform lithium deposition. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Direct oxidative dearomatization of indoles: access to structurally diverse 2,2-disubstituted indolin-3-ones ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02956G, Communication Xigong Liu, Xue Yan, Yingde Tang, Cheng-Shi Jiang, Jin-Hai Yu, Kaiming Wang, Hua Zhang Described is an efficient oxidative dearomatization of indoles with TEMPO oxoammonium salt and a broad range of nucleophiles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Bifunctional nickel oxide-based nanosheets for highly efficient overall urea splitting ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02507C, Communication Fengchi Wu, Gang Ou, Jun Yang, Henan Li, Yanxia Gao, Fuming Chen, Ye Wang, Yumeng Shi 2D Ni0.9Fe0.1Ox nanosheet assembled porous and hollow microspheres were synthesized for efficient overall urea splitting. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ring-opening cyclization of spirocyclopropanes with stabilized sulfonium ylides for the construction of a chromane skeleton ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC03023A, Communication Hisanori Nambu, Yuta Onuki, Naoki Ono, Kiyoshi Tsuge, Takayuki Yakura A regioselective ring-opening cyclization of spirocyclopropanes with sulfonium ylides afforded 2,3-trans-hexahydrobenzopyran-5-ones in high yields without the formation of any diastereoisomers. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ultrasensitive detection of long non-coding RNAs based on duplex-specific nuclease-actuated cyclic enzymatic repairing-mediated signal amplification ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02939G, Communication Yan Zhang, Xin-yan Wang, Xianwei Su, Chun-yang Zhang We develop a new method for sensitive detection of long noncoding RNAs using duplex-specific nuclease-actuated cyclic enzymatic repairing-mediated signal amplification. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Chain length effect in the functionalization of polyoxometalates with α,ω-alkyldiphosphonates ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02854D, Communication Zhiwei Liu, Wei Wang, Jinkui Tang, Weiqi Li, Weiye Yin, Xikui Fang Varying the alkylene tethers in hybrids of polyoxometalates and α,ω-alkyldiphosphonates, even just by a single methylene group, has met with strong structural and magnetic responses. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A Golgi-targeted off–on fluorescent probe for real-time monitoring of pH changes in vivo ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02511A, Communication Li Fan, Xiaodong Wang, Jinyin Ge, Feng Li, Caihong Zhang, Bo Lin, Shaomin Shuang, Chuan Dong A Golgi-targeted small-molecular fluorescent probe RSG has been rationally designed for real-time monitoring of Golgi pH changes in vivo. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A painted layer for high-rate and high-capacity solid-state lithium–metal batteries ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02394A, Communication Bin Sun, Yang Jin, Jialiang Lang, Kai Liu, Minghao Fang, Hui Wu Based on a garnet solid electrolyte, an electron/ion dual-conductive framework established by a spraying method enabled an alloy anode that realized a high-rate operation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Fluorinated porous molecular crystals: vapor-triggered on–off switching of luminescence and porosity ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02309G, Communication Hiroshi Sasaki, Hiroaki Imoto, Takashi Kitao, Takashi Uemura, Takashi Yumura, Kensuke Naka Fluorinated porous molecular crystals (PMCs) were fabricated from platinum(II) dihalide complexes with 9-pentafluorophenyl-9-arsafluorene. The diiodide complex formed a PMC exhibiting open–close switching of porosity as well as on–off switching of luminescence. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ultrabroad-band, red sufficient, solid white emission from carbon quantum dot aggregation for single component warm white light emitting diodes with a 91 high color rendering index ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC01794A, Communication Ting Meng, Ting Yuan, Xiaohong Li, Yunchao Li, Louzhen Fan, Shihe Yang An ultrabroad-band solid white emission from carbon quantum dot aggregation with a full width at half maximum over 200 nm throughout the entire visible light window and, even better, with a sufficient red component is first reported. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ultralong micro-belts of luminescent lead halide-based perovskites ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02668A, Communication Parul Bansal, Prasenjit Kar Ultralong micro-belts of MAPbI3 show bright and stable fluorescence in solution. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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MOF-derived Co1.11Te2 with half-metallic characteristic for efficient photochemical conversion of CO2 under visible-light irradiation ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02728A, Communication Yong Xu, Jiang Mo, Guanqun Xie, DaWei Ding, Shujiang Ding, Xiaoxia Wang, Chen Li Material of Co1.11Te2, prepared by using MOF as self-template, showed excellent catalytic performance in the photoconversion of CO2 to CO. Experimental and theoretical evidences demonstrate that Co1.11Te2 has half-metallic nature,... The content of this RSS Feed (c) The Royal Society of Chemistry
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Flexible and multifunctional metal-organic framework as matrix for analysis of small molecules using laser desorption/ionization mass spectrometry ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02611H, Communication Wen Ma, Shuting Xu, Wanpeng Ai, Cheng Lin , Yu Bai, Huwei Liu Variety of functional metal-organic frameworks (MOFs) were prepared via a universal method and served as matrices in small molecules analysis using laser desorption/ionization mass spectrometry. Among them, cysteine-MOF was found... The content of this RSS Feed (c) The Royal Society of Chemistry
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Brighter Near-IR Emission of Single-walled Carbon Nanotubes Modified with a Cross-linked Polymer Coating ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02712B, Communication Tsuyohiko Fujigaya, Yukiko Nagai, Masako Yudasaka, Hiromichi Kataura Photoluminescence (PL) in near-IR (NIR) region is attractive feature of single-walled carbon nanotubes (SWNTs). In this study, an effect of chemical structure of cross-linked polymer coating around SWNTs for NIR... The content of this RSS Feed (c) The Royal Society of Chemistry
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Crackled Nanocapsules: “Imperfect” Structure for Enzyme Immobilization ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02797A, Communication Qian Huo, Jingjing Zhao, Weiran Li, Dong Yang, Songping Zhang, Jiafu Shi, Zhongyi Jiang Herein, the first example of crackled organosilica nanocapsules (CONs) is reported to directly immobilize enzymes without any further chemical modification. Enzymes are adsorbed on both the exterior and interior surface... The content of this RSS Feed (c) The Royal Society of Chemistry
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Anion Exchange of a Cationic Cd(II)-based Metal-Organic Framework with potassium ferricyanide towards highly active Fe3C-containing Fe/N/C catalysts for Oxygen Reduction ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02390A, Communication Jia-Wei Huang, Yu-Bin Chen, Xiao Liu, Yi-Chen Huang, Ye-Lin Ding, Yang Xu, Hong-Chang Yao, Hai-Bin Zhu, Hui Yang A highly active and stable Fe3C-containing Fe/N/C catalyst, derived from a cationic Cd(II)-based metal-organic framework involving accurate control over Fe-doping via anion-exchange with potassium ferricyanide, shows superior oxygen reduction performance... The content of this RSS Feed (c) The Royal Society of Chemistry
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TMSOTf Mediated ‘5/6-endo-dig’ Reductive Hydroamination for the Stereoselective Synthesis of Pyrrolidine and Piperidine derivatives ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC03127H, Communication Santosh J. Gharpure, Dharmendra S. Vishwakarma, Raj Kumar Patel TMSOTf mediated 5/6-endo-dig reductive hydroamination cascade on internal alkynylamines gave an expedient, stereoselective access to pyrrolidine and piperidine derivatives. We also demonstrate that protecting group on nitrogen has profound effect... The content of this RSS Feed (c) The Royal Society of Chemistry
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Ru(TAP)32+ uses multivalent binding to accelerate and constrain photo-adduct formation on DNA ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02838B, Communication Willem Vanderlinden, Pauline Julika Kolbeck, Wout Frederickx, Sebastian Ferdinand Konrad, Thomas Nicolaus, Carola Lampe, Alexander S. Urban, Cécile Moucheron, Jan Lipfert Ru(II)-complexes with polyazaaromatic ligands can undergo direct electron transfer with guanine nucleobases on blue light excitation that results in DNA lesions with phototherapeutic potential. Here we use single molecule approaches... The content of this RSS Feed (c) The Royal Society of Chemistry
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Cooperative Activation of X-H (X = H, C, O, N) Bonds by a Pt(0)/Ag(I) Metal-Only Lewis Pair ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC03008E, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Nereida Hidalgo, Celia Maya, Jesús Campos Metal-only Lewis pairs made of Pt(I)/Ag(0) combinations have been previously reported, but their cooperative reactivity remains unexplored. Here we demonstrate that these systems are capable of synergistically activating a wide... The content of this RSS Feed (c) The Royal Society of Chemistry
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Pd-catalyzed enantioselective cyclopropanation of nitriles with mono substituted allyl carbonates enabled by the bulky N-heterocyclic carbene ligand ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC01960J, Communication Gao-Peng Zhang, Shuai Huang, Yang-Jie Jiang, Xiu-Yan Liu, Chang-Hua Ding, Yin Wei, Xue-Long Hou Enantioselective cyclopropanation of nitriles with allyl reagents was realized using Pd/NHC as a catalyst and the reasons for the cyclopropanation were investigated. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Decarboxylative Suzuki–Miyaura coupling of (hetero)aromatic carboxylic acids using iodine as the terminal oxidant ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC01817D, Communication Jacob M. Quibell, Guojian Duan, Gregory J. P. Perry, Igor Larrosa A novel methodology for the decarboxylative Suzuki–Miyaura-type coupling of carboxylic acids with arylboronic acids has been developed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Novel silver-phosphine coordination polymers incorporating a Wurster’s Blue - like radical cation with enhanced photoelectric properties ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC01711A, Communication Mei Yang, Xin-Yi Wu, Hui-Fang Wang, david James Young, Zhi-Gang Ren, Jian-Ping Lang Tetraphosphine ligand dpppda reacts with AgNO3 to generate two 1D coordination polymers containing cubic and chair-like [Ag4(NO3)4] clusters. ESR spectroscopy supported by DFT calculations indicated the presence of dpppda•+, a... The content of this RSS Feed (c) The Royal Society of Chemistry
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Selective and quantitative synthesis of a linear [3]catenane by two component coordination-driven self-assembly ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC03336J, Communication Jatinder Singh, Dong Hwan Kim, Eun-Hee Kim, Nem Singh, Hyunuk Kim, Rizky Hadiputra, Jaehoon Jung, Ki-Whan Chi Here we report the synthesis of a linear [3]catenane comprised of three interlocking rings, by coordination-driven self-assembly. Naphthalene-based acceptor A1 and triazole-based donor L1 were utilized for the self-assembly reaction,... The content of this RSS Feed (c) The Royal Society of Chemistry
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Recent advances in the catalytic asymmetric alkylation of stabilized phosphorous ylides ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02831E, Feature Article Liang-Qiu Lu, Kai Zhang, Wen-Jing Xiao The Wittig reaction is a reliable method for synthesizing alkenes from phosphorous ylides (P-ylides) and carbonyls, and is thus widely applied in medicine and pharmaceutical productions. Among them, asymmetric Wittig... The content of this RSS Feed (c) The Royal Society of Chemistry
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Carbon-incorporated NiO/Co3O4 concave surface microcubes derived from a MOF precursor for overall water splitting ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02037C, Communication Xijun Wei, Yunhuai Zhang, Huichao He, Di Gao, Jingrui Hu, Huarong Peng, Li Peng, Shenghuan Xiao, Peng Xiao Carbon-incorporated NiO/Co3O4 concave surface microcubes (denoted as NCMC) are successfully developed from a precursor of Ni3[Co(CN)6]2 for the first time. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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DNAzyme activated protein-scaffolded CRISPR–Cas9 nanoassembly for genome editing ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC03172C, Communication Xueli Zhu, Meng-Mei Lv, Jin-Wen Liu, Ru-Qin Yu, Jian-Hui Jiang A novel self-assembled protein-scaffolded CRISPR–Cas9 nanosystem for facile and efficient gene editing in a DNAzyme-controlled manner has been developed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Fabrication of red blood cell membrane-camouflaged Cu2−xSe nanoparticles for phototherapy in the second near-infrared window ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC03148K, Communication Zhou Liu, Jinquan Wang, Kangqiang Qiu, Xinxing Liao, Thomas W. Rees, Liangnian Ji, Hui Chao Cu2−xSe nanoparticles (Cu2−xSeNPs) were camouflaged with a red blood cell membrane (RBC) for synergistic photothermal and photodynamic therapy of cancer in the second near-infrared (NIR II) window. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Copper-catalyzed arylstannylation of arynes in a sequence ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02738F, Communication Hideya Tanaka, Hitoshi Kuriki, Teruhiko Kubo, Itaru Osaka, Hiroto Yoshida Diverse ortho-stannylbiaryls and teraryls have been synthesized by copper-catalyzed arylstannylation of arynes, in which the single or dual insertion of arynes into arylstannanes is precisely controllable by simply changing the equivalence of the aryne precursors employed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A DNAzyme-powered cross-catalytic circuit for amplified intracellular imaging ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02637A, Communication Lana Zou, Qiong Wu, Yangjie Zhou, Xue Gong, Xiaoqing Liu, Fuan Wang A heterogeneously cross-catalytic CHA–DNAzyme circuit that integrates built-in molecule-recognition and signal-amplification is assembled through a feedback loop. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Switching the enantioselectivity of nanoporous host materials by light ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02849H, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Anemar Bruno Kanj, Jochen Bürck, Sylvain Grosjean, Stefan Bräse, Lars Heinke A chiral photoswitchable nanoporous material with remote-controllable enantioselective adsorption capacity is presented. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Multi-mass velocity-map imaging studies of photoinduced and electron-induced chemistry ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02426C, Feature Article Claire Vallance Multimass velocity-map imaging promises new mechanistic insights into chemistry relevant to fields ranging from atmospheric chemistry and astrochemistry through to synthetic organic photochemistry and biology. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Bismuth oxychloride nanoflake assemblies as a new anode for potassium ion batteries ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC01937E, Communication Wei Li, Yang Xu, Yulian Dong, Yuhan Wu, Chenglin Zhang, Min Zhou, Qun Fu, Minghong Wu, Yong Lei BiOCl is demonstrated as the first bismuth oxyhalide compound serving as a new anode material for potassium ion batteries. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Total structural determination of [Au1Ag24(Dppm)3(SR)17]2+ comprising an open icosahedral Au1Ag12 core with six free valence electrons ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC00767A, Communication Yangfeng Li, Manman Zhou, Shan Jin, Lin Xiong, Qianqin Yuan, Wenjun Du, Yong Pei, Shuxin Wang, Manzhou Zhu Herein, we report the first silver-rich nanocluster containing an open icosahedral Au1Ag12 core. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Photoswitchable catalysis based on the isomerisation of double bonds ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC01891C, Feature Article Ruth Dorel, Ben L. Feringa Photoswitchable catalysis is a young but rapidly evolving field that offers great potential for non-invasive dynamic control of both activity and selectivity in catalysis. This Feature Article summarises the key developments accomplished over the past years through the incorporation of photoswitchable double bonds into the structure of catalytically competent molecules. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A novel fluorescent assay for the ultrasensitive detection of miRNA-21 with the use of G-quadruplex structures as an immobilization material for a signal indicator ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC01850F, Communication Ze-Zhou Yang, Zhi-Bin Wen, Xin Peng, Ya-Qin Chai, Wen-Bin Liang, Ruo Yuan A fluorescent assay for the ultrasensitive detection of miRNA-21 is based on immobilization of PPIX as signal indicators in massive G-quadruplex structures obtained by target recycling, three-dimensional DNA walker and RCA coupled cascade nucleic acid amplification. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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The application of spatially restricted geometries as a unique route to produce well-defined poly(vinyl pyrrolidones) via free radical polymerisation ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02625H, Communication Magdalena Tarnacka, Paulina Maksym, Andrzej Zięba, Anna Mielańczyk, Monika Geppert-Rybczyńska, Laia Leon-Boigues, Carmen Mijangos, Kamil Kamiński, Marian Paluch We report the metal-free green synthesis of linear poly(vinyl pyrrolidone) of well-defined properties via free-radical polymerisation performed under confinement. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Structural tuning of zinc–porphyrin frameworks via auxiliary nitrogen-containing ligands towards selective adsorption of cationic dyes ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02405K, Communication Xiao-Ning Wang, Jiang-Li Li, Yu-Meng Zhao, Jiandong Pang, Bao Li, Tian-Le Zhang, Hong-Cai Zhou Three novel zinc–porphyrin MOFs have been synthesized by using versatile N-containing ligands. The open Watson–Crick pair in the interior surface in one Zn-MOF has been presented, which could endow the related MOF with excellent selective adsorption of dye molecules. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Enantioselective Synthesis of Multi-Nitrogen-Containing Heterocycles Using Azoalkenes as Key Intermediates ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02371B, Feature Article Liang Wei, Chong Shen, Yuan-Zheng Hu, Hai-Yan Tao, Chun-Jiang Wang Chiral multi-nitrogen-containing heterocycles, such as pyrazole, imidazole and pyridazine, are widely found in naturally occurring organic compounds and pharmaceuticals, and hence, their stereoselective and efficient synthesis is an important issue... The content of this RSS Feed (c) The Royal Society of Chemistry
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One-pot synthesis of mercapto functionalized Zr-MOFs for the enhanced removal of Hg2+ ions from water ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC03481A, Communication Daiwu Lin, Xiao Liu, Renliang Huang, Wei Qi, Rongxin Su, Zhimin He Mercapto functionalized Zr-MOFs have been developed via a one-pot synthesis for selective adsorption of Hg2+ ions. Mercaptoacetic acid (MAA) or alpha lipoic acid (ALA) was used as the modulator and... The content of this RSS Feed (c) The Royal Society of Chemistry
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Single-component frameworks for heterogeneous catalytic hydrolysis of organophosphorous compounds in pure water ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02236H, Communication Sergio Javier Garibay, Omar K. Farha, Jared Bernard DeCoste Amine modified Zr6-based metal-organic frameworks (MOFs) were synthesized through solvent-assisted linker incorporation (SALI) and utilized as single-component heterogeneous catalysts for the hydrolysis of organophosphorous compounds under solely aqueous conditions at... The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal–catechol complexes mediate ice nucleation ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02987G, Communication Huige Yang, Yunhe Diao, Beili Huang, Kaiyong Li, Jianjun Wang Metal–catechol complexes are constructed to successively mediate ice nucleation by varying the characteristic and valence of metal. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Homo and heteroassembly of amide-based [2]rotaxanes using α,α’-dimethyl-p-xylylenediamines ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02701G, Communication Carmen Lopez-Leonardo, Alberto Martinez-Cuezva, Delia Bautista, Mateo Alajarin, Jose Berna The formation of [2]rotaxanes via a fumaramide-templated clipping reaction using α,α’-dimethyl-p-xylylenediamines is described. This process selectively affords two out of seven possible interlocked isomers due to a noticeable effect of... The content of this RSS Feed (c) The Royal Society of Chemistry
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Unprecedented Water-Controlled Rotator–Stator Conversion of Supramolecular Rotor in Crystals ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC03267C, Communication Rui-Kang Huang, Zhi-Feng Xiao, De-Xuan Liu, Wei-Xiong Zhang, Xiao-Ming Chen The rotational dynamics, dielectric response and phase transitions of a unique crystalline supramolecular rotor are controlled by the existence/absence of guest water molecules making prominent effects on supramolecular interactions. Such... The content of this RSS Feed (c) The Royal Society of Chemistry
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Water Plays a Diverse Role in a Hydrogen-Bonded, Hexameric Supramolecular Assembly ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC03151K, Communication Ankita Katiyar, Julia C. Freire Sovierzoski, Paul B. Calio, Anthony A. Vartia, Ward H Thompson The interactions between water and a hexameric resorcin[4]arene assembly formed in wet chloroform are examined by molecular dynamics simulations of the diffusion coefficients. It is found that the water diffusion... The content of this RSS Feed (c) The Royal Society of Chemistry
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In situ visualization of peroxisomal peroxynitrite in liver of mice with acute liver injury induced by carbon tetrachloride using a new two-photon fluorescent probe ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02483B, Communication Yongqing Zhou, Ping Li, Nannan Fan, Xin Wang, Xiaoning Liu, Lijie Wu, Wen Zhang, Wei Zhang, Changle Ma, Bo Tang We developed a new two-photon fluorescent probe (PX-1) with high selectivity and sensitivity for detecting peroxisomal peroxynitrite. The PX-1 was successfully applied to in situ imaging of peroxynitrite in the... The content of this RSS Feed (c) The Royal Society of Chemistry
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Unusual fluorescence of o-phenylazonaphthol derivatives with aggregation-induced emission and their use in two-photon cell imaging ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC03106E, Communication Yeoju Yoon, Seonyoung Jo, Sang Jun Park, Hwan Myung Kim, Dongwook Kim, Taek Seung Lee o-Phenylazonaphthol (o-PAN) derivatives including 6-bromo-1-((4-bromophenyl)diazenyl) naphthalen-2-ol (AN-Br-OH) and 1-phenylazo-2-naphthol (AN-OH, known as Sudan I (Color Index 12055)) were synthesized to investigate their fluorogenic behaviors, in which their aggregated-induced emission (AIE)... The content of this RSS Feed (c) The Royal Society of Chemistry
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A consecutive process for C–C and C–N bond formation with high enantio-and diastereo-control: direct reductive amination of chiral ketones using hydrogenation catalysts ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC00923J, Communication Sophie H. Gilbert, Virginie Viseur, Matthew L. Clarke A Rh catalyst derived from tri-(2-furyl)phosphine enables the direct reductive amination of 1,3-substituted ketones to occur in high yield and diastereoselectivity. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Temperature-sensitive protein expression in protocells ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02734C, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Haiyang Jia, Michael Heymann, Tobias Härtel, Lei Kai, Petra Schwille We engineered a synthetic temperature regulation toolbox to enable protocells to sense and respond to heat, utilizing RNA thermometers. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Symmetry-guided, divergent assembly of regio-isomeric molecular Janus particles ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02296A, Communication Di Han, Yu Shao, Yang-Dan Tao, Ge Han, Dai-Lin Zhou, Shuguang Yang, Wen-Bin Zhang, Qiang Fu Varying a single regio-configuration diverges the assembly outcome into distinct morphologies as mandated by their molecular symmetries. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Precise ricin A-chain delivery by Golgi-targeting carbon dots ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC01599J, Communication Chun Hong Li, Rong Sheng Li, Chun Mei Li, Cheng Zhi Huang, Shu Jun Zhen The as-prepared CDs–RTA conjugates exhibit enhanced internalization, improved stability against enzymatic digestion and an increased location rate of RTA to the ER, and thus much more RTA could translocate to the cytosol and ribosome to exert toxic effects. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synergistic combination of visible-light photo-catalytic electron and energy transfer facilitating multicomponent synthesis of β-functionalized α,α-diarylethylamines ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02465D, Communication Yanan Wu, Yipin Zhang, Mingjie Jiang, Xunqing Dong, Hitesh B. Jalani, Guigen Li, Hongjian Lu A synthetic strategy which takes advantage of the synergistic combination of electron and energy transfer processes using only one photocatalyst has been developed for the multicomponent synthesis of the α,α-diarylalkylamine skeleton. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Direct readout protonophore induced selective uncoupling and dysfunction of individual mitochondria within cancer cells ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC01483G, Communication Kondapa Naidu Bobba, Anupama Binoy, Seyoung Koo, Divya Nedungadi, Arup Podder, Amit Sharma, Nandita Mishra, Jong Seung Kim, Sankarprasad Bhuniya Endogenous H2S-stimulated protonophores released from MitoDP are a vanguard in creating mitochondria-targeted therapies for reducing mitochondrial activity in cancer cells. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A perovskite La2Ti2O7 nanosheet as an efficient electrocatalyst for artificial N2 fixation to NH3 in acidic media ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02310K, Communication Jiali Yu, Chengbo Li, Bingyue Li, Xiaojuan Zhu, Rong Zhang, Lei Ji, Dianping Tang, Abdullah M. Asiri, Xuping Sun, Quan Li, Shanhu Liu, Yonglan Luo A perovskite La2Ti2O7 nanosheet acts as an efficient electrocatalyst toward N2-to-NH3 fixation, achieving a NH3 yield rate of 25.15 μg h−1 mgcat.−1 and a faradaic efficiency of 4.55%. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalytic asymmetric synthesis of tetrahydrocarbazoles ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02486G, Feature Article Fen Tan, Hong-Gang Cheng This feature article summarises recent advances in catalytic asymmetric synthesis of THCs, with emphases on reaction type and reaction mechanism. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Recognition of plastic nanoparticles using a single gold nanopore fabricated at the tip of a glass nanopipette ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC01358J, Communication Xiao-Lei Nie, Hai-Ling Liu, Zhong-Qin Pan, Saud Asif Ahmed, Qi Shen, Jin-Mei Yang, Jian-Bin Pan, Jie Pang, Cheng-Yong Li, Xing-Hua Xia, Kang Wang A single gold nanopore with high surface enhanced Raman spectroscopy (SERS) activity is fabricated on the tip of a glass nanopipette. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Homogeneous probing of lipase and α-amylase simultaneously by AIEgens ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC01959F, Communication Jie Shi, Qianchun Deng, Ya Li, Zhe Zheng, Huijuan Shangguan, Lu Li, Fenghong Huang, Bo Tang An AIE dual-reactive supramolecular probe has been devised to simultaneously measure endogenous lipase and α-amylase activity in a homogeneous system. Fluorescence quantitative analysis of lipase and α-amylase in real biological samples enables rapid and accurate diagnosis of diseases. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Allylation of aldehydes by dual photoredox and nickel catalysis ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC03344K, Communication Andrea Gualandi, Giacomo Rodeghiero, Adriana Faraone, Filippo Patuzzo, Marianna Marchini, Francesco Calogero, Rossana Perciaccante, Thomas Paul Jansen, Paola Ceroni, Pier Giorgio Cozzi Here we report the application of dual nickel/photoredox catalysis to the allylation of aliphatic, aromatic and heteroaromatic aldehydes by using commercially available reagents. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Rhenium is different: CO tetramerization induced by a divalent lanthanide complex in rhenium carbonyls ()
Chem. Commun., 2019, 55,5765-5768 DOI: 10.1039/C9CC02350J, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Ravi Yadav, Thomas Simler, Michael T. Gamer, Ralf Köppe, Peter W. Roesky The reduction of M2(CO)10 (M = Mn, Re) with different divalent lanthanide (Ln = Sm, Yb) compounds was investigated. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synchronous screening of multiplexed biomarkers of Alzheimer's disease by a length-encoded aerolysin nanopore-integrated triple-helix molecular switch ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC02065A, Communication Zhen Zou, Hua Yang, Qi Yan, Peng Qi, Zhihe Qing, Jing Zheng, Xuan Xu, Lihua Zhang, Feng Feng, Ronghua Yang A label-free triple-helix molecular switch-mediated nanopore sensor is developed for the synchronous screening of biomarkers of Alzheimer's disease. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of polyoxometalate clusters using carbohydrates as reducing agents leads to isomer-selection ()
Chem. Commun., 2019, 55,5797-5800 DOI: 10.1039/C9CC02361E, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Eric Janusson, Noël de Kler, Laia Vilà-Nadal, De-Liang Long, Leroy Cronin By using sugars as the reducing agents, we demonstrate that it is possible to control the self-assembly of polyoxomolybdates through selective preparation of a single heteropolyanion isomer. The content of this RSS Feed (c) The Royal Society of Chemistry
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Acetylcholine-responsive cargo release using acetylcholinesterase-capped nanomaterials ()
Chem. Commun., 2019, 55,5785-5788 DOI: 10.1039/C9CC02602A, Communication Tania M. Godoy-Reyes, Antoni Llopis-Lorente, Alba García-Fernández, Pablo Gaviña, Ana M. Costero, Ramón Martínez-Máñez, Félix Sancenón Mesoporous silica nanoparticles capped with acetylcholinesterase through boronic ester linkages selectively release their cargo in the presence of acetylcholine. The content of this RSS Feed (c) The Royal Society of Chemistry
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A promising engineering strategy for water electro-oxidation iridate catalysts via coordination distortion ()
Chem. Commun., 2019, 55,5801-5804 DOI: 10.1039/C9CC02447F, Communication Wei Sun, Zhiqiang Wang, Zhenhua Zhou, Yiyi Wu, Waqas Qamar Zaman, Muhammad Tariq, Li-mei Cao, Xue-qing Gong, Ji Yang Distorted IrO6 is more conducive to improving OER activity. Specifically, regulating the transformation of the IrO6 octahedron from D4h compression to D4h elongation is very beneficial for reducing the energy of the rate determining step of the OER process. The content of this RSS Feed (c) The Royal Society of Chemistry
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Pressure-dependent guest binding and release on a supramolecular polymer ()
Chem. Commun., 2019, 55,5793-5796 DOI: 10.1039/C9CC02696G, Communication Shumpei Yonezawa, Ramarani Sethy, Gaku Fukuhara, Tsuyoshi Kawai, Takuya Nakashima Pressurization on a supramolecular host–guest system induces the compression of binding pockets, discharging the guest molecules. The content of this RSS Feed (c) The Royal Society of Chemistry
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Bottom-up synthesis of iron and nitrogen dual-doped porous carbon nanosheets for efficient oxygen reduction ()
Chem. Commun., 2019, 55,5789-5792 DOI: 10.1039/C9CC02615K, Communication Peng Du, Fei-Xiang Ma, Fucong Lyu, Kangqiang He, Zebiao Li, Jian Lu, Yang Yang Li Iron and nitrogen co-doped porous carbon nanosheets were fabricated with great convenience for efficient electrocatalysis of the oxygen reduction reaction. The content of this RSS Feed (c) The Royal Society of Chemistry
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Phase transition of spiropyrans: impact of isomerization dynamics at high temperatures ()
Chem. Commun., 2019, 55,5813-5816 DOI: 10.1039/C9CC02141H, Communication Mihael A. Gerkman, Shichen Yuan, Pu Duan, Jennifer Taufan, Klaus Schmidt-Rohr, Grace G. D. Han Temperature-dependent isomerization dynamics between spiropyran and merocyanine forms strongly impact the phase transition of molecular switches. The content of this RSS Feed (c) The Royal Society of Chemistry
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A new approach for the achievement of stable aqueous dispersions of carbon nanotubes ()
Chem. Commun., 2019, 55,5809-5812 DOI: 10.1039/C9CC01541H, Communication João Paulo V. Damasceno, Aldo J. G. Zarbin A simple and innovative way to achieve highly stable aqueous dispersions of both multi- and single-walled carbon nanotubes is reported. The content of this RSS Feed (c) The Royal Society of Chemistry
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A gold–selenium-bonded nanoprobe for real-time in situ imaging of the upstream and downstream relationship between uPA and MMP-9 in cancer cells ()
Chem. Commun., 2019, 55,5817-5820 DOI: 10.1039/C9CC01454C, Communication Mingming Luan, Mingwan Shi, Wei Pan, Na Li, Bo Tang A novel Au–Se nanoprobe with remarkable anti-interference ability for glutathione was developed for real-time in situ monitoring of the upstream and downstream regulatory relationship between uPA and MMP-9 proteins in the pathway. The content of this RSS Feed (c) The Royal Society of Chemistry
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An ultrathin cuprite film on Pt(111) with high reactivity to CO ()
Chem. Commun., 2019, 55,5825-5828 DOI: 10.1039/C9CC01002E, Communication Wenyuan Wang, Zhilin Wen, Shanwei Hu, Zhe Li, Xiaojun Wu, Junfa Zhu, Xiang Shao A Cu2O(111)-like thin film with a honeycomb structure is grown on Pt(111) whose interface exhibits extremely high reactivity to CO molecules. The content of this RSS Feed (c) The Royal Society of Chemistry
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Efficient and scalable high-quality graphene nanodot fabrication through confined lattice plane electrochemical exfoliation ()
Chem. Commun., 2019, 55,5805-5808 DOI: 10.1039/C9CC02889G, Communication Hui Wang, Kaiyi Zhu, Liwei Yan, Can Wei, Yu Zhang, Chunhong Gong, Jianhui Guo, Jiwei Zhang, Dongmao Zhang, Jingwei Zhang An innovative confined lattice plane electrochemical exfoliation method for efficient and scalable fabrication of graphene nanodots with uniform size distribution. The content of this RSS Feed (c) The Royal Society of Chemistry
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ReGaGe2: an intermetallic compound with semiconducting properties and localized bonding ()
Chem. Commun., 2019, 55,5821-5824 DOI: 10.1039/C9CC02563D, Communication Maxim S. Likhanov, Roman A. Khalaniya, Valeriy Yu. Verchenko, Andrei A. Gippius, Sergei V. Zhurenko, Alexey V. Tkachev, Dina I. Fazlizhanova, Alexey N. Kuznetsov, Andrei V. Shevelkov ReGaGe2 is a new intermetallic compound with semiconducting properties and localized bonding patterns. The content of this RSS Feed (c) The Royal Society of Chemistry
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Enhancing the utility of 1JCH coupling constants in structural studies through optimized DFT analysis ()
Chem. Commun., 2019, 55,5781-5784 DOI: 10.1039/C9CC02469G, Communication Alexei V. Buevich, Josep Saurí, Teodor Parella, Nunziatina De Tommasi, Giuseppe Bifulco, R. Thomas Williamson, Gary E. Martin High accuracy for DFT-predicted 1JCH-couplings can be achieved without ad hoc corrections or empirical scaling by careful selection of the DFT method utilized for geometry optimization and J-coupling calculations. The content of this RSS Feed (c) The Royal Society of Chemistry
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Probing membrane enhanced protein–protein interactions in a minimal redox complex of cytochrome-P450 and P450-reductase ()
Chem. Commun., 2019, 55,5777-5780 DOI: 10.1039/C9CC01630A, Communication Mukesh Mahajan, Thirupathi Ravula, Elke Prade, G. M. Anantharamaiah, Ayyalusamy Ramamoorthy Investigating the interplay in a minimal redox complex of cytochrome-P450 and its reductase is crucial for understanding cytochrome-P450's enzymatic activity. The content of this RSS Feed (c) The Royal Society of Chemistry
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Boosting photocatalytic H2 evolution on g-C3N4 by modifying covalent organic frameworks (COFs) ()
Chem. Commun., 2019, 55,5829-5832 DOI: 10.1039/C9CC02144B, Communication Maolan Luo, Qing Yang, Kewei Liu, Hongmei Cao, Hongjian Yan Modifying g-C3N4 with covalent organic frameworks (COFs) through imine linkage results in a dramatically enhanced visible-light-driven photocatalytic hydrogen evolution, which reached 10.1 mmol g−1 h−1 when 2 wt% Pt and triethanolamine were used as co-catalyst and sacrificial agent, respectively, corresponding to an apparent quantum efficiency (AQE) of 20.7% at 425 nm. The content of this RSS Feed (c) The Royal Society of Chemistry
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4-Hydroxymethyl-substituted oxazolidinone synthesis by tetraarylphosphonium salt-catalyzed reactions of glycidols with isocyanates ()
Chem. Commun., 2019, 55,5761-5764 DOI: 10.1039/C9CC01983A, Communication Yasunori Toda, Shoya Tanaka, Shuto Gomyou, Ayaka Kikuchi, Hiroyuki Suga A tetraarylphosphonium catalyst enables efficient coupling reactions between glycidols and isocyanates to afford 4-hydroxymethyl-substituted oxazolidinones. The content of this RSS Feed (c) The Royal Society of Chemistry
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Enhancing surface-assisted laser desorption ionization mass spectrometry performance by integrating plasmonic hot-electron transfer effect through surface modification ()
Chem. Commun., 2019, 55,5769-5772 DOI: 10.1039/C9CC02541C, Communication Yafeng Li, Peiqi Luo, Xiaohua Cao, Huihui Liu, Jianing Wang, Jiyun Wang, Lingpeng Zhan, Zongxiu Nie Surface-assisted laser desorption ionization mass spectrometry (SALDI MS) performances were enhanced by modifying surfaces to include a plasmonic hot-electron transfer effect. The content of this RSS Feed (c) The Royal Society of Chemistry
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Particle-stabilized Janus emulsions that exhibit pH-tunable stability ()
Chem. Commun., 2019, 55,5773-5776 DOI: 10.1039/C8CC09842E, Communication Tao Li, Andrew B. Schofield, Ke Chen, Job H. J. Thijssen, Jure Dobnikar, Paul S. Clegg A simple and large-scale fabrication approach to create Janus emulsions that can be controlled in size, geometry and stability. The content of this RSS Feed (c) The Royal Society of Chemistry
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A Fluorogenic BODIPY Molecular Rotor as Apoptosis Marker ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC03242H, Communication Pichandi Ashokkumar, Anila Hoskere Ashoka, Mayeul Collot, Amitava Das, Andrey S Klymchenko Based on BODIPY molecular rotor and zinc-dipicolylamine receptor, we designed a fluorogenic probe for detection of apoptosis. Being poorly emissive in solution and with healthy cells, it selectively binds phosphatidylserine... The content of this RSS Feed (c) The Royal Society of Chemistry
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Near-Infrared circularly polarized luminescence from chiral Yb(III)-diketonates ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC03032H, Communication Francesco Zinna, Lorenzo Arrico, Lorenzo Di Bari We report a rare example of near infrared circularly polarized luminescence (NIR-CPL) in the 920-1050 nm region associated to the f-f transitions of Yb diketonate complexes bearing chiral ancillary ligands.... The content of this RSS Feed (c) The Royal Society of Chemistry
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Anhydrous Amorphous Calcium Carbonate is Different from Transient Phase of Biogenic Amorphous Calcium Carbonate ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC00518H, Communication Chieh Tsao, Pao-Tao Yu, Chin-Hsuan Lo, Chung-Kai Chang, Chia-Hsin Wang, Yaw-Wen Yang, Jerry Chun Chung Chan Amorphous calcium carbonate (ACC) is an important precursor phase of biogenic calcite. In this work, an in situ Ca L-edge X-ray absorption spectroscopic study has been carried out to monitor... The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis and Reactivity of [Au(NHC)(Bpin)] Complexes ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC03171E, Communication Steven P Nolan, caroline zinser, Laura Falivene, Fady Nahra, marcel brill, David Bradford Cordes, Alexandra Slawin, Luigi Cavallo, Catherine Cazin A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their unusual reactivity was investigated using computational and experimental methods. The gold-boryl complexes exhibit unexpected high stability and reactivity. The content of this RSS Feed (c) The Royal Society of Chemistry
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Unique Tyr-heme double cross-links in F43Y/T67R myoglobin: an artificial enzyme with a peroxidase activity comparable to that of native peroxidases ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02714A, Communication Can Liu, Hong Yuan, Fei Liao, Chuanwan Wei, Kejie Du, Shu-Qin Gao, Xiangshi Tan, Ying-wu Lin An X-ray crystal structure of F43Y/T67R myoglobin revealed unique Tyr-heme double cross-links between Tyr43 and the heme 4-vinyl group, which represents a novel post-translational modification of heme proteins. Moreover, with... The content of this RSS Feed (c) The Royal Society of Chemistry
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A Palladium/Norbornene Cooperative Catalysis to Access N-Containing Bridged Scaffolds ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC03126J, Communication Qianwen Gao, Ze-Shui Liu, Yu Hua, Lisha Li, Hong-Gang Cheng, Hengjiang Cong, Qianghui Zhou Reported is a palladium/norbornene cooperative catalysis promoted annulation involving an ortho-C‒H amination and intramolecular Heck cascade between aryl iodides and functionalized amination reagents, thereby providing a highly convergent access to... The content of this RSS Feed (c) The Royal Society of Chemistry
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Enhancement of exon skipping activity by reduction in secondary structure content of LNA-based splice-switching oligonucleotides ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C8CC09648A, Communication Takenori Shimo, Keisuke Tachibana, Yuki Kawawaki, Yuuka Watahiki, Taku Ishigaki, Yusuke Nakatsuji, Takashi Hara, Junji Kawakami, Satoshi Obika PAGE and UV melting analysis revealed that longer LNA-based splice-switching oligonucleotides (SSOs) formed secondary structures by themselves, reducing their effective concentration. To avoid such secondary structure formation, we introduced 7-deaza-2’-deoxyguanosine... The content of this RSS Feed (c) The Royal Society of Chemistry
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A single-ion conducting hyperbranched polymer as high performance solid-state electrolyte for lithium ion battery ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02351H, Communication Meng Zhang, Songrui Yu, Yiyong Mai, Shaodong Zhang, Yongfeng Zhou This communication reports a novel hyperbranched polymer with poly(ethylene glycol)9 segments and carboxylate groups. The combined advantages of single-ion conducting and hyperbranched structure make the as-prepared polymers very promising as... The content of this RSS Feed (c) The Royal Society of Chemistry
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Changing the π-bridge from thiophene to thieno[3,2-b]thiophene for D-π-A type polymer enables high performance fullerene-free organic solar cells ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02904D, Communication You Chen, Yanfang Geng, Ailing Tang, Xiaochen Wang, Yanming Sun, Erjun Zhou For photovoltaic polymers with D-π-A backbone, there are a great deal of D and A units, but the choice of π bridge is relatively limited and thiophene (T) is still... The content of this RSS Feed (c) The Royal Society of Chemistry
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Electrochemical 1,4-Reduction of α, β-Unsaturated Ketones with Methanol and Ammonium Chloride as Hydrogen Sources ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02368B, Communication Wujiong Xia, Binbin Huang, Yanan Li, Chao Yang A sustainable, chemoselective 1,4-reduction of α, β-unsaturated ketones by means of an electrochemical method is presented, wherein the extremely inexpensive ammonium chloride (NH4Cl) is applied as the only additive. The... The content of this RSS Feed (c) The Royal Society of Chemistry
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Functionalization of inorganic nanomaterials with pillar[n]arenes ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC03165K, Feature Article Yong Yao, Jiao Chen, Yang Wang, Chenwei Wang, Renhua Long, Tingting Chen Pillar[n]arenes, which consisting of hydroquinone units linked by -CH2- bridges at 2,5-positions, are a relatively new class of synthetic macrocycles since 2008. Their facile preparation and flexible modification properties make... The content of this RSS Feed (c) The Royal Society of Chemistry
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Templated nanoreactors array toward nanoscale-tunable liquid-phase catalysis ()
Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC00834A, Communication Shuo Zhang, Xie Quan, Shuo Chen, Hongtao Yu We demonstrate templated synthesis of arrayed metal oxide-based nanoreactors as candidate platforms for liquid-phase catalysis. Case study on zinc oxide nanotubes revealed the high-level catalytic reactivity and nanoscale-tunable kinetics, either... The content of this RSS Feed (c) The Royal Society of Chemistry
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Inter-ligand energy transfer in dye chromophores attached to high bandgap SiO2 nanoparticles ()
Chem. Commun., 2019, Advance Article DOI: 10.1039/C9CC03412A, Communication Michael B. Price, Andrew Paton, Jeffrey Gorman, Isabella Wagner, Geoffry Laufersky, Kai Chen, Richard H. Friend, Timothy W. Schmidt, Justin M. Hodgkiss, Nathaniel J. L. K. Davis Simple artificial light harvesting networks can be created by the covalent attachment of organic chromophores to silicon dioxide nanoparticles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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