Green Chemistry


Biofabrication of supported metal nanoparticles: exploring the bioinspiration strategy to mitigate the environmental challenges ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02291K, Tutorial Review Thanusu Parandhaman, Manash Deep Dey, Sujoy K. Das Biosynthesis of metal nanoparticles (MNPs) has recently emerged as a novel ecofriendly process for the preparation of supported MNPs to alleviate the environmental challenges. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Simple synthesis of a swellable porous β-cyclodextrin-based polymer in the aqueous phase for the rapid removal of organic micro-pollutants from water ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02422K, Paper Guizhou Xu, Xianchuan Xie, Long Qin, Xuejiao Hu, Delin Zhang, Jun Xu, Dawei Li, Xiaowen Ji, Yu Huang, Yizhou Tu, Lu Jiang, Dongyang Wei Simple synthesis of a swellable porous β-cyclodextrin-based polymer in the aqueous phase for the rapid removal of organic micro-pollutants from water. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Readily recyclable carbon fiber reinforced composites based on degradable thermosets: A Review ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01760G, Tutorial Review Binbo Wang, Songqi Ma, Shifeng Yan, Jin Zhu Carbon fiber reinforced polymer (CFRP) is a structural composite widely used in automobile, aerospace and sporting goods, etc. because of its high strength-to-weight ratio, excellent fatigue and corrosion resistances. However,... The content of this RSS Feed (c) The Royal Society of Chemistry
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Kinetics and Mechanism for Hydrothermal Conversion of Polyhydroxybutyrate (PHB) for Wastewater Valorization ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC02507C, Paper Yalin Li, Timothy J. Strathmann Conventional wastewater treatment processes can be tailored to recover organic carbon from wastewater as intracellular polyhydroxybutyrate (PHB) polymer granules while simultaneously meeting effluent discharge standards. Traditional applications of PHB as... The content of this RSS Feed (c) The Royal Society of Chemistry
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Upgrading of levulinic acid into diverse N-containing functional chemicals ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02415H, Critical Review Zhimin Xue, Dongkun Yu, Xinhui Zhao, Tiancheng Mu This review provides a holistic overview for the upgrading of levulinic acid into various N-containing functional chemicals. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Calcium-catalyzed regioselective dehydrative cross-coupling of propargylic alcohols with 1,3-dicarbonyl compounds ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02635E, Communication Peizhong Xie, Xiangyang Wo, Xiaobo Yang, Xinying Cai, Shuangshuang Li, Cuiqing Gao, Weishan Fu, Zuolian Sun, Teck-Peng Loh A calcium-catalyzed in situ dehydrative cross-coupling reaction of propargylic alcohols with 1,3-dicarbonyl compounds was developed at room temperature under solvent-free conditions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Recycling of Vat and Reactive Dyed Textile Waste to New Colored Man-Made Cellulose Fibers ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC02776A, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Simone Haslinger, Yingfeng Wang, Marja Rissanen, Miriam Beatrice Lossa, Marjaana Tanttu, Elina Ilen, Marjo Määttänen, Ali Harlin, Michael Hummel, Herbert Sixta The chemical upcycling of dyed pre- and postconsumer cotton waste is fostered by studying the spinability and color fastness of seven vat and reactive dyes (i.e Indanthren Blue BC 3%,... The content of this RSS Feed (c) The Royal Society of Chemistry
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Merrifield resin-supported quinone as the Efficient Biomimetic Catalyst for Metal-Free, Base-Free, Chemoselective Synthesis of 2,4,6-Trisubstituted Pyridines ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC02409C, Paper Qing Yang, Yilin Zhang, Wei Zeng, Zheng-Chao Duan, Xinxin Sang, Dawei Wang Metal-free, base-free, biomimetic and chemoselective synthesis of 2,4,6-trisubstituted pyridines was developed under mild conditions for the first time. The heterogeneous biomimetic catalyst – recoverable Merrifield resin-supported quinone, was fully characterized... The content of this RSS Feed (c) The Royal Society of Chemistry
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Transition-metal-free selective pyrimidines and pyridines formation from aromatic ketones, aldehydes and ammonium salts ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02077B, Communication Jinjin Chen, Huanxin Meng, Feng Zhang, Fuhong Xiao, Guo-Jun Deng Pyrimidines and pyridines could be selectively formed from aromatic ketones, aldehydes and ammonium salts under transition-metal-free conditions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A biocatalytic redox cascade approach for one-pot deracemization of carboxyl-substituted tetrahydroisoquinolines by stereoinversion ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02795E, Paper Shuyun Ju, Mingxin Qian, Jing Li, Gang Xu, Lirong Yang, Jianping Wu We describe a biocatalytic redox cascade reaction for one-pot enantioselective synthesis of (S)-carboxyl substituted tetrahydroisoquinolines. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A roadmap for renewable C2–C3 glycols production: a process engineering approach ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02949D, Critical Review Andressa Neves Marchesan, Marina Pinho Oncken, Rubens Maciel Filho, Maria Regina Wolf Maciel A review of strategies and challenges for chemical and biochemical production and purification of C2–C3 glycols from renewable sources. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Poly-quasi-eutectic solvents (PQESs): versatile solvents for dissolving metal oxides ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02604E, Paper Jingyun Jiang, Xiyue Bai, Xinhui Zhao, Wenjun Chen, Tingting Yu, Yan Li, Tiancheng Mu Versatile poly-quasi-eutectic solvents (PQESs), which own excellent metal oxide dissolution performance, have been synthesized. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Environmentally benign process on selective recovery of valuable metals from spent lithium-ion batteries by using conventional sulfation roasting ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01350D, Paper Jiao Lin, Chunwei Liu, Hongbin Cao, Yongxia Yang, Renjie Chen, Li Li, Zhi Sun Recycling of spent lithium-ion batteries (LIBs) has attracted intensive attention owing to their potential environmental risk and importance to supply of critical metals. Sulfation roasting as a traditional technologies is... The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of Rutaecarpine Alkaloids via Electrochemical Cross Dehydrogenation Coupling Reaction ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC03028J, Communication Qian-Yu Li, Shi-Yan Cheng, Hai-Tao Tang, Ying-Ming Pan Substrates are directly oxidized at the anode without using any metal catalyst and oxidant to obtain a series of nitrogen heterocyclic compounds, including benzimidazoles and quinolinones. These compounds are highly... The content of this RSS Feed (c) The Royal Society of Chemistry
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Reductive catalytic fractionation of black locust bark ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02139F, Paper T. Vangeel, T. Renders, K. Van Aelst, E. Cooreman, S. Van den Bosch, G. Van den Bossche, S.-F. Koelewijn, C. M. Courtin, B. F. Sels During reductive catalytic fractionation of black locust bark, lignin and suberin are simultaneously depolymerized and stabilized. This results in low MW phenolics and long-chain, α,ω-bifunctional aliphatics. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Room temperature, near-quantitative conversion of glucose into formic acid ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02201E, Paper Can Wang, Xi Chen, Man Qi, Jianeng Wu, Gökalp Gözaydın, Ning Yan, Heng Zhong, Fangming Jin Herein, a facile and efficient method was developed to selectively transform glucose into formic acid at room temperature. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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The sustainable room temperature conversion of p-xylene to terephthalic acid using ozone and UV irradiation ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02095K, Paper Kuo Chu Hwang, Arunachalam Sagadevan, Pradip Kundu p-Xylene was oxidatively converted to terephthalic acid at room temperature with ∼98% selectivity in the absence of any catalysts via ozone treatment with concurrent UV irradiation, without the production of global warming gases. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Sustainable strategies based on glycine-betaine analogues ionic liquids for the recovery of monoclonal antibodies from cell culture supernatants ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC02733E, Paper Emanuel V. Capela, Alexandre Santiago, Ana Filipa Rufino, Ana P. M. Tavares, Matheus M. Pereira, Aminou MOHAMADOU, Maria Raquel Aires-Barros, Joao A. P. Coutinho, Ana Azevedo, Mara G Freire Monoclonal antibodies (mAbs) are of crucial interest for therapeutic purposes, particularly in vaccination, immunization, and in the treatment of life-threatening diseases. However, their downstream processing from the complex cell culture... The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly Efficient Catalytic Conversion of Cellulose to Acetol over Ni-Sn Supported on Nanosilica and the Mechanism Study ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC02449B, Paper Xiaohao Liu, Xiaodong Liu, Guangyue Xu, Ying Zhang, Chenguang Wang, Qiang Lu, Longlong Ma Selective conversion of cellulose to high value-added C3 chemicals is a great challenge in biorefinery due to the complicated reaction process. In this work, 61.6% yield of acetol was obtained... The content of this RSS Feed (c) The Royal Society of Chemistry
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Extending the design space in solvent extraction – from supercritical fluids to pressurized liquids using carbon dioxide, ethanol, ethyl lactate, and water in a wide range of proportions ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02140J, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Veronika Pilařová, Said Al Hamimi, Larissa P. Cunico, Lucie Nováková, Charlotta Turner Fast extractions were achieved by the use of green solvents containing compressed carbon dioxide as a viscosity-lowering entrainer. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Transition-metal-free decarboxylative halogenation of 2-picolinic acids with dihalomethane under oxygen conditions ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02407G, Paper Xitao Zhang, Xiujuan Feng, Haixia Zhang, Yoshinori Yamamoto, Ming Bao The reaction of 2-picolinic acids with dihalomethane proceeded smoothly via N-chlorocarbene intermediates to afford 2-halogen-substituted pyridines in satisfactory to excellent yields under oxygen conditions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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One-pot synthesized core/shell structured zeolite@copper catalysts for selective hydrogenation of ethylene carbonate to methanol and ethylene glycol ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01726G, Paper Yu Ding, Jingxia Tian, Wei Chen, Yejun Guan, Hao Xu, Xiaohong Li, Haihong Wu, Peng Wu Novel hierarchical core/shell structured S-1@Cu with balanced Cu0 and Cu+ active species was synthesized via base-assisted hydrothermal chemistry and served as a robust catalyst for selective EC hydrogenation to methanol. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Enzyme-catalysed enantioselective oxidation of alcohols by air exploiting fast electrochemical nicotinamide cycling in electrode nanopores ()
Green Chem., 2019, 21,4958-4963 DOI: 10.1039/C9GC01534E, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Lei Wan, Rachel S. Heath, Bhavin Siritanaratkul, Clare F. Megarity, Adam J. Sills, Matthew P. Thompson, Nicholas J. Turner, Fraser A. Armstrong Enantioselective conversion of alcohols to ketones using air as the oxidant is achieved with high rates and efficiency using an indium tin oxide electrode in which an alcohol dehydrogenase and a NADPH recycling enzyme are confined within nanopores. The content of this RSS Feed (c) The Royal Society of Chemistry
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A biocatalytic cascade for the conversion of fatty acids to fatty amines ()
Green Chem., 2019, 21,4932-4935 DOI: 10.1039/C9GC02260K, Communication Joan Citoler, Sasha R. Derrington, James L. Galman, Han Bevinakatti, Nicholas J. Turner A mild, biocatalytic alternative to the conventional amination of fatty acids through a one-pot tandem cascade performed by a carboxylic acid reductase (CAR) and a transaminase (ω-TA). The content of this RSS Feed (c) The Royal Society of Chemistry
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Biomolecule-derived supported cobalt nanoparticles for hydrogenation of industrial olefins, natural oils and more in water ()
Green Chem., 2019, 21,5104-5112 DOI: 10.1039/C9GC01276A, Paper Anahit Pews-Davtyan, Florian Korbinian Scharnagl, Maximilian Franz Hertrich, Carsten Kreyenschulte, Stephan Bartling, Henrik Lund, Ralf Jackstell, Matthias Beller Biomolecule modified supported cobalt nanoparticles efficiently hydrogenate diverse natural, industrial and functionalized olefins in water under mild conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Photoinduced hydroxylation of arylboronic acids with molecular oxygen under photocatalyst-free conditions ()
Green Chem., 2019, 21,4971-4975 DOI: 10.1039/C9GC02229E, Communication Yu-Ting Xu, Chen-Yuan Li, Xiao-Bo Huang, Wen-Xia Gao, Yun-Bing Zhou, Miao-Chang Liu, Hua-Yue Wu We disclose a photoinduced aerobic hydroxylation of boronic acids under photocatalyst-free conditions, providing a green entry to phenols and alcohols. The content of this RSS Feed (c) The Royal Society of Chemistry
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Electrochemical oxidative cyclization of olefinic carbonyls with diselenides ()
Green Chem., 2019, 21,4976-4980 DOI: 10.1039/C9GC02665G, Communication Zhipeng Guan, Yunkun Wang, Huamin Wang, Yange Huang, Siyuan Wang, Hongding Tang, Heng Zhang, Aiwen Lei The tandem cyclization of olefinic carbonyls with easily accessible diselenides facilitated by electrochemical oxidation has been successfully developed, which provides an environmentally friendly method for the construction of C–Se and C–O bonds simultaneously. The content of this RSS Feed (c) The Royal Society of Chemistry
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Correction: Catalytic synthesis of distillate-range ethers and olefins from ethanol through Guerbet coupling and etherification ()
Green Chem., 2019, 21,5128-5129 DOI: 10.1039/C9GC90076D, Correction Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Nathaniel M. Eagan, Benjamin M. Moore, Daniel J. McClelland, Ashley M. Wittrig, Emmanuel Canales, Michael P. Lanci, George W. Huber The content of this RSS Feed (c) The Royal Society of Chemistry
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Plants and plant-based polymers as scaffolds for tissue engineering ()
Green Chem., 2019, 21,4839-4867 DOI: 10.1039/C9GC02391G, Critical Review Siavash Iravani, Rajender S. Varma Plants and plant-based polymers used in the fabrication of greener scaffolds and their collective role for tissue engineering applications are highlighted. The content of this RSS Feed (c) The Royal Society of Chemistry
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Sustainable valorization of lignin with levulinic acid and its application in polyimine thermosets ()
Green Chem., 2019, 21,4964-4970 DOI: 10.1039/C9GC02384D, Communication Kaifeng Huang, Songqi Ma, Sheng Wang, Qiong Li, Zhijun Wu, Jingcheng Liu, Ren Liu, Jin Zhu Valorization of lignin with renewable levulinic acid incorporated active ketone groups and could be utilized to produce high-performance polymers. The content of this RSS Feed (c) The Royal Society of Chemistry
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Unravelling donor–acceptor film morphology formation for environmentally-friendly OPV ink formulations ()
Green Chem., 2019, 21,5090-5103 DOI: 10.1039/C9GC02288K, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Natalie P. Holmes, Holly Munday, Matthew G. Barr, Lars Thomsen, Matthew A. Marcus, A. L. David Kilcoyne, Adam Fahy, Jan van Stam, Paul C. Dastoor, Ellen Moons Realising bicontinuous interpenetrating network morphologies – with nanoscale phase separation – for donor–acceptor material systems processed from environmentally-friendlier ink formulations. The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalytic asymmetric synthesis of chiral phenols in ethanol with recyclable rhodium catalyst ()
Green Chem., 2019, 21,4946-4950 DOI: 10.1039/C9GC02420D, Communication Jian Yao, Na Liu, Long Yin, Junhao Xing, Tao Lu, Xiaowei Dou A general method to access diverse chiral phenols in ethanol using a recyclable catalyst was developed. The content of this RSS Feed (c) The Royal Society of Chemistry
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Graphene-based advanced nanoplatforms and biocomposites from environmentally friendly and biomimetic approaches ()
Green Chem., 2019, 21,4887-4918 DOI: 10.1039/C9GC02266J, Tutorial Review Lang Ma, Mi Zhou, Chao He, Shuang Li, Xin Fan, Chuanxiong Nie, Hongrong Luo, Li Qiu, Chong Cheng Environmentally friendly and biomimetic approaches to fabricate graphene-based advanced nanoplatforms and biocomposites for biomedical applications are summarized in this review. The content of this RSS Feed (c) The Royal Society of Chemistry
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Production of high-yield short-chain oligomers from cellulose via selective hydrolysis in molten salt hydrates and separation ()
Green Chem., 2019, 21,5030-5038 DOI: 10.1039/C9GC02297J, Paper Qiyu Liu, Qiaozhi Ma, Sanket Sabnis, Weiqing Zheng, Dionisios G. Vlachos, Wei Fan, Wenzhi Li, Longlong Ma Stepwise process of cellulose being hydrolyzed into oligomers in MSH followed by product separation. The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalytic hydrogenation of dihydrolevoglucosenone to levoglucosanol with a hydrotalcite/mixed oxide copper catalyst ()
Green Chem., 2019, 21,5000-5007 DOI: 10.1039/C9GC00564A, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Mario De bruyn, Canan Sener, Davi D. Petrolini, Daniel J. McClelland, Jiayue He, Madelyn R. Ball, Yifei Liu, Leandro Martins, James A. Dumesic, George W. Huber, Bert M. Weckhuysen Levoglucosanol (LGOL) is a critical intermediate for the bio-based production of hexane-1,2,5,6-tetrol, 1,2,6-hexanetriol, and 1,6-hexanediol. The content of this RSS Feed (c) The Royal Society of Chemistry
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Future green chemistry and sustainability needs in polymeric coatings ()
Green Chem., 2019, 21,4919-4926 DOI: 10.1039/C9GC02462J, Perspective Michael F. Cunningham, J. David Campbell, Zhenwen Fu, James Bohling, J. Gary Leroux, Warren Mabee, Tobias Robert Challenges and opportunities for paints and coatings. The content of this RSS Feed (c) The Royal Society of Chemistry
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Zwitterionic-surfactant modified LAPONITE®s for removal of ions (Cs+, Sr2+ and Co2+) from aqueous solutions as a sustainable recovery method for radionuclides from aqueous wastes ()
Green Chem., 2019, 21,5118-5127 DOI: 10.1039/C9GC02243K, Paper Thomas Thiebault, Jocelyne Brendlé, Grégoire Augé, Lionel Limousy A green and efficient adsorbent for the recovery and further storage of radionuclides was developed by the intercalation of a biodegradable amphoteric surfacant onto synthetic clay minerals. The content of this RSS Feed (c) The Royal Society of Chemistry
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Two birds with one stone: one-pot simultaneous synthesis of 2,2,2-trifluoroethylphenanthridines and benzochromenones featuring the utilization of the byproduct of Togni's reagent ()
Green Chem., 2019, 21,5113-5117 DOI: 10.1039/C9GC02001B, Paper Cai Gao, Bin Li, Xueyang Geng, Qianting Zhou, Xinying Zhang, Xuesen Fan A one-pot simultaneous synthesis of 2,2,2-trifluoroethylphenanthridines and benzochromenones featuring the utilization of the byproduct of Togni's reagent is presented. The content of this RSS Feed (c) The Royal Society of Chemistry
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Directional synergistic conversion of lignocellulosic biomass with matching-solvents for added-value chemicals ()
Green Chem., 2019, 21,4951-4957 DOI: 10.1039/C9GC02365H, Communication Junfeng Feng, Le Zhang, Jianchun Jiang, Chungyun Hse, Todd F. Shupe, Hui Pan Directional and synergistic conversion of cellulose and hemicellulose in biomass with matching-solvents for high added-value chemicals. The content of this RSS Feed (c) The Royal Society of Chemistry
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Improving the performance of supported ionic liquid phase (SILP) catalysts for the ultra-low-temperature water–gas shift reaction using metal salt additives ()
Green Chem., 2019, 21,5008-5018 DOI: 10.1039/C9GC02153A, Paper Patrick Wolf, Manfred Aubermann, Moritz Wolf, Tanja Bauer, Dominik Blaumeiser, Robert Stepic, Christian R. Wick, David M. Smith, Ana-Sunčana Smith, Peter Wasserscheid, Jörg Libuda, Marco Haumann Addition of CuCl to supported ionic liquid phase (SILP) catalysts enhances the activity in the low temperature water–gas shift (WGS) reaction. The content of this RSS Feed (c) The Royal Society of Chemistry
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Electrochemical oxidative annulation of amines and aldehydes or ketones to synthesize polysubstituted pyrroles ()
Green Chem., 2019, 21,4941-4945 DOI: 10.1039/C9GC02118C, Communication Xinlong Gao, Pan Wang, Qingqing Wang, Jingting Chen, Aiwen Lei A general and practical protocol to synthesize polysubstituted pyrroles has been established by electrooxidative annulation of amines and aldehydes or ketones. The content of this RSS Feed (c) The Royal Society of Chemistry
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A facile and mild strategy to fabricate an underwater superoleophobic and underoil superhydrophobic mesh with outstanding anti-viscous oil-fouling properties for switchable high viscosity oil/water separation ()
Green Chem., 2019, 21,5080-5089 DOI: 10.1039/C9GC02129A, Paper Jin Zhang, Lu Zhang, Jianguo Zhao, Wenshan Qu, Zhenxing Wang Underwater superoleophobic and underoil superhydrophobic mesh has been prepared for switchable high viscosity oil/water separation. The content of this RSS Feed (c) The Royal Society of Chemistry
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How to assess the potential of emerging green technologies? Towards a prospective environmental and techno-economic assessment framework ()
Green Chem., 2019, 21,4868-4886 DOI: 10.1039/C9GC02223F, Tutorial Review Gwenny Thomassen, Miet Van Dael, Steven Van Passel, Fengqi You The prospective environmental techno-economic assessment framework is proposed, gathering best practices to assess the potential of emerging green chemical technologies. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of spiro[2,3-dihydrofuran-3,3′-oxindole] derivatives via a multi-component cascade reaction of α-diazo esters, water, isatins and malononitrile/ethyl cyanoacetate ()
Green Chem., 2019, 21,4936-4940 DOI: 10.1039/C9GC01751H, Communication Taoda Shi, Shenghan Teng, Yajie Wei, Xin Guo, Wenhao Hu We report a green synthesis of spiro[2,3-dihydrofuran-3,3′-oxindole] derivatives which are of potential value in medicinal chemistry. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ru/hydroxyapatite as a dual-functional catalyst for efficient transfer hydrogenolytic cleavage of aromatic ether bonds without additional bases ()
Green Chem., 2019, 21,5073-5079 DOI: 10.1039/C9GC02336D, Paper Manli Hua, Jinliang Song, Chao Xie, Haoran Wu, Yue Hu, Xin Huang, Buxing Han Transfer hydrogenolytic cleavage of aromatic ether bonds could be efficiently carried out by employing Ru/hydroxyapatite as a dual-functional catalyst without additional bases. The content of this RSS Feed (c) The Royal Society of Chemistry
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The use of bicarbonate for microalgae cultivation and its carbon footprint analysis ()
Green Chem., 2019, 21,5053-5062 DOI: 10.1039/C9GC01107B, Paper Ga-Yeong Kim, Kosan Roh, Jong-In Han A new bicarbonate-based microalgae cultivation system coupled with an electrochemical CO2 absorption process to improve carbon utilization efficiency. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly selective conversion of natural oil to alcohols or alkanes over a Pd stabilized CuZnAl catalyst under mild conditions ()
Green Chem., 2019, 21,5046-5052 DOI: 10.1039/C9GC02379H, Paper Ziwei Guo, Feng Zhou, Hao Wang, Xiaohao Liu, Guangyue Xu, Ying Zhang, Yao Fu A novel and green catalytic system based on a Pd stabilized CuZnAl catalyst was designed for one-pot conversion of natural oil components to the corresponding alcohols or long-chain linear and branched alkanes with high selectivity and atom economy. The content of this RSS Feed (c) The Royal Society of Chemistry
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Enhanced photocatalytic performance for oxidation of glucose to value-added organic acids in water using iron thioporphyrazine modified SnO2 ()
Green Chem., 2019, 21,5019-5029 DOI: 10.1039/C9GC01647C, Paper Quanquan Zhang, Yanchun Ge, Changjun Yang, Bingguang Zhang, Kejian Deng Photocatalytic oxidation of glucose to value-added organic acids in water was realized by SnO2/FePz(SBu)8 using atmospheric air as the oxidant. The content of this RSS Feed (c) The Royal Society of Chemistry
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Carbon fibres from renewable resources: the role of the lignin molecular structure in its blendability with biobased poly(ethylene terephthalate) ()
Green Chem., 2019, 21,5063-5072 DOI: 10.1039/C9GC02041A, Paper Anne Beaucamp, Yan Wang, Mario Culebras, Maurice N. Collins Understanding the blending chemistry at the molecular level to improve lignin valorisation. The content of this RSS Feed (c) The Royal Society of Chemistry
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Direct one-step synthesis of a formally fully bio-based polymer from cellulose and cinnamon flavor ()
Green Chem., 2019, 21,4927-4931 DOI: 10.1039/C9GC01333D, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Daisuke Hirose, Samuel Budi Wardhana Kusuma, Daiki Ina, Naoki Wada, Kenji Takahashi Direct fully bio-based polymer synthesis by cellulose modification involving simply mixing cellulose and cinnamaldehyde “cinnamon flavor” in an ionic liquid. The content of this RSS Feed (c) The Royal Society of Chemistry
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Developing a sustainable route to environmentally relevant metal–organic frameworks: ultra-rapid synthesis of MFM-300(Al) using microwave heating ()
Green Chem., 2019, 21,5039-5045 DOI: 10.1039/C9GC02375E, Paper Ieuan Thomas-Hillman, Lee A. Stevens, Marcus Lange, Jens Möllmer, William Lewis, Chris Dodds, Samuel W. Kingman, Andrea Laybourn The synthesis of MFM-300(Al) in aqueous conditions and 10 minutes using microwave heating is reported. The material produced exhibits significantly enhanced uptake of CO2, SO2, and NO2 compared to the 3-day solvothermal route. The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalytic dehydration of levoglucosan to levoglucosenone using Brønsted solid acid catalysts in tetrahydrofuran ()
Green Chem., 2019, 21,4988-4999 DOI: 10.1039/C9GC01526D, Paper Oscar Oyola-Rivera, Jiayue He, George W. Huber, James A. Dumesic, Nelson Cardona-Martínez We explored the production of levoglucosenone from levoglucosan using propylsulfonic acid functionalized silica; 59% selectivity was obtained at 100% conversion. The content of this RSS Feed (c) The Royal Society of Chemistry
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Unlocking the response of lignin structure for improved carbon fiber production and mechanical strength ()
Green Chem., 2019, 21,4981-4987 DOI: 10.1039/C9GC01632E, Paper Ran Zhang, Qing Du, Lei Wang, Ze Zheng, Li Guo, Xiaoyu Zhang, Xiangliang Yang, Hongbo Yu Soda lignin, a more linear polymer, blended with PAN could produce more carbon fibers with doubled tensile stress. The content of this RSS Feed (c) The Royal Society of Chemistry
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Computational Design of an Intramolecular Photocyclization Reaction with State-Selective Reactivity: A Strategy for Indole Synthesis ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC02676B, Communication Jingwei Zhou, Lamei Li, Ming Yan, Wentao Wei Development of efficient and convenient indole synthesis method is of great methodological and pharmaceutical interest. In this work, by developing and applying a de novo visible-light-induction-based design strategy to exploit... The content of this RSS Feed (c) The Royal Society of Chemistry
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Photoinduced cycloaddition of biomass derivatives to high-performance spiro-fuel ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC02790D, Paper Junjian Xie, Lun Pan, Genkuo Nie, Jiawei Xie, Yakun Liu, Chi Ma, Xiangwen Zhang, Ji-Jun Zou Photoinduced conversion of biomass-derived chemicals to high value chemicals and advanced fuels is of great significance but still challenging. Herein, a green and efficient self-sensitized [2+2] cycloaddition process is developed... The content of this RSS Feed (c) The Royal Society of Chemistry
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Efficient catalytic hydrogenation of alkyl levulinates to γ-valerolactone ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01651A, Communication Rosa Padilla, Mike S. B. Jørgensen, Márcio W. Paixão, Martin Nielsen Catalytic hydrogenation of alkyl levulinates to γ-valerolactone is achieved under mild reaction conditions employing pincer PNP-M complexes. High efficacy is demonstrated with TON's exceeding 9000. Furthermore, the feasibility of recycling is shown. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Deep Eutectic Solvents for Cu-catalysed ARGET ATRP under Air Atmosphere. A Sustainable and Efficient Route to poly(methyl methacrylate) using Recyclable Cu(II) Metal Organic Framework ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC02624J, Paper Joaquín García-Álvarez, Alejandro Presa Soto, Gabino A. Carriedo, Luís Quirós-Montes Atom Transfer Radical Polymerisation (ATRP) is one of the most important techniques leading to well-defined polymers with predetermined molecular weight, designed microstructure and tailored-made functionalities. Although ATRP has been extensively... The content of this RSS Feed (c) The Royal Society of Chemistry
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Niobium oxide prepared through a novel supercritical-CO2-assisted method as highly active heterogeneous catalyst for the synthesis of azoxybenzene from aniline ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC02623A, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Yehan Tao, Bhawan Singh, Vanshika Jindal, Zhenchen Tang, Paolo P. Pescarmona High-surface area Nb2O5 nanoparticles were synthesised by a novel supercritical-CO2-assisted method (Nb2O5-scCO2) and were applied for the first time as a heterogeneous catalyst in the oxidative coupling of aniline to... The content of this RSS Feed (c) The Royal Society of Chemistry
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Copper and cobalt co-catalyzed aerobic oxidative cross-dehydrogenative coupling reaction of (benzo)azoles ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02464F, Communication Yanrong Li, Fen Qian, Xia Ge, Tao Liu, Hitesh B. Jalani, Hongjian Lu, Guigen Li The dehydrogenative cross-coupling (CDC) reaction of diversely substituted azoles was realized by copper and cobalt co-catalysis under air conditions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalyst- and Additive-Free Baeyer−Villiger-type Oxidation of α-Iodocyclopentenones to α-Pyrones: Using Air as the Oxidant ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC02725D, Paper Yuanyuan Zhou, Xianxiao Chen, Xiangxiang Ling, Weidong Rao An efficient synthetic approach for the synthesis of α-pyrones via Baeyer−Villiger-type oxidation of α-iodocyclopentenones through a catalyst- and additive-free system using air as an environmentally benign oxidant is described. The... The content of this RSS Feed (c) The Royal Society of Chemistry
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Copper-Free Click Reaction for Synthesis of Redox-Responsive Water-soluble Core Cross-Linked Nanoparticles for Drug Delivery in Cancer Therapy ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01863H, Paper Gargi Biswas, Bikash Chandra Jena, Satyagopal Sahoo, Pousali Samanta, Mahitosh Mandal, Dibakar Dhara Polymer based core cross-linked nanoparticles (CCNPs) have generated a lot of interest as potential stimuli-responsive drug delivery systems. In the present work, we have synthesized smart redox-responsive water soluble polymeric... The content of this RSS Feed (c) The Royal Society of Chemistry
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Cercosporin-Bioinspired Selective Photooxidation Reactions under Mild Conditions ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC02270H, Paper Jia Li, Wenhao Bao, Zhaocheng Tang, Baodang Guo, Shiwei Zhang, Haili Liu, Shuping Huang, Yan Zhang, Yijian Rao The development of an efficient system for selective oxidation of organic substrates to generate more valuable compounds with molecular oxygen is a significant challenge in industrial chemistry. Bioinspired by the... The content of this RSS Feed (c) The Royal Society of Chemistry
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Achmatowicz rearrangement enables hydrogenolysis–free gas-phase synthesis of pentane-1,2,5-triol from furfuryl alcohol ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC02888A, Paper Svilen Simeonov, Hristina Lazarova, Maya Marinova, Margarita Popova Highly efficient synthesis of pentane-1,2,5 triol, a promising member of the biorenewable C5 alcohols, has been achieved by gas-phase hydrogenation of the derived from furfuryl alcohol Achmatowizc intermediate. The hydrogenations... The content of this RSS Feed (c) The Royal Society of Chemistry
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Engineering of a fungal laccase to develop a robust, versatile and highly-expressed biocatalyst for sustainable chemistry ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02475A, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Felipe de Salas, Pablo Aza, Joan F. Gilabert, Gerard Santiago, Sibel Kilic, Mehmet E. Sener, Jesper Vind, Víctor Guallar, Angel T. Martínez, Susana Camarero From laccase design to application of the overexpressed biocatalyst in an industrial environment for eco-friendly synthesis of polyaniline and dyes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly transparent, healable, and durable anti-fogging coating by combining hydrophilic pectin and tannic acid with poly(ethylene terephthalate) ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02454A, Paper Tao Zhang, Lanlan Fang, Nan Lin, Jiajun Wang, Yongguang Wang, Tao Wu, Pingan Song A highly transparent and healable anti-fogging coating was constructed via a facile dip-coating method from bio-derived pectin and tannic acid. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Methanesulfonic acid: a sustainable acidic solvent for recovering metals from the jarosite residue of the zinc industry ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02238D, Paper Thupten Palden, Bieke Onghena, Mercedes Regadío, Koen Binnemans Leaching the industrial jarosite residue with pure methanesulfonic acid resulted in a solid–liquid separation of iron from dissolved lead and zinc by precipitation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ru@UiO-66(Ce) catalyzed acceptorless dehydrogenation of primary amines to nitriles: the roles of Lewis acid–base pairs in the reaction ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02181G, Paper Guo-Ping Lu, Xinxin Li, Lixiang Zhong, Shuzhou Li, Fei Chen UiO-66(Ce)-encapsulated ruthenium nanoparticles (Ru@UiO-66(Ce)) was designed and used for dehydrogenation of primary amines to nitriles in water without any hydrogen acceptors and additives. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Boronic acid-promoted site-selective Fischer esterifications of sugar alcohols ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC00901A, Paper Sanjay Manhas, Yu Chen Lin, Grace Wang, Luke T. Kyne, Mark S. Taylor Phenylboronic acid mediates selective monoesterifications of sugar alcohols by direct condensation with fatty acids, providing access to useful, bio-derived amphiphiles. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of dibenzocycloketones by acyl radical cyclization from aromatic carboxylic acids using methylene blue as a photocatalyst ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02380A, Paper Hongshuo Jiang, Guijie Mao, Hongfeng Wu, Qi An, Minghui Zuo, Weihao Guo, Chunzhao Xu, Zhizhong Sun, Wenyi Chu An efficient intramolecular radical cyclization reaction via photoredox catalysis was developed for the synthesis of dibenzocycloketone derivatives using methylene blue as a photosensitizer. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Hydrogen Peroxide as Oxidant in Biomass-to-Chemical Processes with Industrial Interest ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC02445J, Tutorial Review Siew Ping Teong, Xiukai Li, Yugen Zhang Production of chemicals and fuels from renewable biomass is a hot topic of current research. Theoretically, most of the fuels and chemicals from petroleum resource could be synthesised from biomass.... The content of this RSS Feed (c) The Royal Society of Chemistry
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[4+4]-Cycloaddition of Isoprene for the Production of High-Performance Bio-Based Jet Fuel ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC02404B, Paper Kyle Rosenkoetter, C. Rose Kennedy, Paul Chirik, Benjamin Grant Harvey Isoprene was efficiently converted to 1,6-dimethyl-1,5-cyclooctadiene (DMCOD) by selective [4+4]-cycloaddition with a catalyst formed by in situ reduction of [(MePI)FeCl(μ-Cl)]2 (MePI = [2-(2,6-(CH3)2-C6H3–N=C(CH3))–C4H5N]). DMCOD was isolated in 92% yield, at... The content of this RSS Feed (c) The Royal Society of Chemistry
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Tailoring diesel bioblendstock from integrated catalytic upgrading of carboxylic acids: a “fuel property first” approach ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01820D, Paper Xiangchen Huo, Nabila A. Huq, Jim Stunkel, Nicholas S. Cleveland, Anne K. Starace, Amy E. Settle, Allyson M. York, Robert S. Nelson, David G. Brandner, Lisa Fouts, Peter C. St. John, Earl D. Christensen, Jon Luecke, J. Hunter Mack, Charles S. McEnally, Patrick A. Cherry, Lisa D. Pfefferle, Timothy J. Strathmann, Davinia Salvachúa, Seonah Kim, Robert L. McCormick, Gregg T. Beckham, Derek R. Vardon Applying a rational design approach to produce a high-quality, low-sooting hydrocarbon diesel blendstock from lignocellulosic biomass-derived short-chain carboxylic acids. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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The selective hydrogenation of furfural over intermetallic compounds with outstanding catalytic performance ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01119F, Paper Yusen Yang, Lifang Chen, Yudi Chen, Wei Liu, Haisong Feng, Bin Wang, Xin Zhang, Min Wei An intermetallic compound (Ni3Sn2) was prepared from a hydrotalcite precursor, which exhibited outstanding hydrogenation selectivity from furfural to furfuryl alcohol. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Unsymmetrical triazolyl-naphthyridinyl-pyridine bridged highly active copper complexes supported on reduced graphene oxide and their application in water ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02086A, Paper Wenkang Hu, Yilin Zhang, Haiyan Zhu, Dongdong Ye, Dawei Wang A clean method for the synthesis of functionalized quinolines in water with a recoverable copper catalyst was developed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Co-catalysis over a tri-functional ligand modified Pd-catalyst for hydroxycarbonylation of terminal alkynes towards α,β-unsaturated carboxylic acids ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01887E, Paper Da Yang, Huan Liu, Lei Liu, Wen-Di Guo, Yong Lu, Ye Liu An amphiphilic tri-functional ligand (L1) containing a phosphonium cation, a phosphino-fragment and a hydrophilic sulfonate anion enabled Pd(OAc)2 to co-catalyze hydroxycarbonylation of terminal alkynes towards α,β-unsaturated carboxylic acids. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Sustainable hydrogenation of aliphatic acyclic primary amides to primary amines with recyclable heterogeneous ruthenium–tungsten catalysts ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01310E, Paper Robin Coeck, Sarah Berden, Dirk E. De Vos Hydrogenation of primary aliphatic amides was achieved in CPME with a novel RuWOx/MgAl2O4 catalyst with yields up to 83%. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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GVL pulping facilitates nanocellulose production from woody biomass ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01490J, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Mingjie Chen, Qianli Ma, J. Y. Zhu, David Martin Alonso, Troy Runge Nanocellulose was extracted from wood by green GVL pulping without bleaching, but with no impact on the properties of nanocellulose. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Continuous flow/waste-minimized synthesis of benzoxazoles catalysed by heterogeneous manganese systems ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01641D, Paper Francesco Ferlin, Mitchell K. van der Hulst, Stefano Santoro, Daniela Lanari, Luigi Vaccaro Herein, we present our results on the development of a waste minimized protocol for the synthesis of 2-arylbenzoxazoles in continuous flow by combining safe solvent and heterogeneous manganese-based catalyst. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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In situ product recovery of bio-based ethyl esters via hybrid extraction-distillation ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01844A, Paper Patrick O. Saboe, Hanna R. Monroe, William E. Michener, Lorenz P. Manker, Stefan J. Haugen, Gregg T. Beckham, Eric M. Karp In situ product recovery (ISPR) of bio-based chemicals from microbial cultivation is a means to improve titer, rate, and yield because it alleviates end product inhibition. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Homogeneous versus heterogeneous catalysis in Cu2O-nanoparticle-catalyzed C–C coupling reactions ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01930H, Paper Ravi Teja Addanki Tirumala, Andishaeh P. Dadgar, Farshid Mohammadparast, Sundaram Bhardwaj Ramakrishnan, Tong Mou, Bin Wang, Marimuthu Andiappan Copper based nanocatalysts have recently emerged as attractive catalysts for a diversity of bond formations, such as C–C, C–N, C–O, C–S, and C–Se. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Cleavage of lignin C–O bonds over a heterogeneous rhenium catalyst through hydrogen transfer reactions ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01710K, Paper Bo Zhang, Zaojuan Qi, Xinxin Li, Jianwei Ji, Leilei Zhang, Hua Wang, Xiaoyan Liu, Changzhi Li ReOx/AC exhibits high catalytic activity and selectivity for the C–O bond cleavage of lignin via hydrogen transfer reactions in isopropanol. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Novel deep eutectic solvents with different functional groups towards highly efficient dissolution of lignin ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02306B, Paper Qiaoling Liu, Xinhui Zhao, Dongkun Yu, Haitao Yu, Yibin Zhang, Zhimin Xue, Tiancheng Mu Two types of novel deep eutectic solvents with different functional groups were designed for highly efficient dissolution of different types of lignin. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Valorization of monosaccharides towards fructopyrazines in a new sustainable and efficient eutectic medium ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC02176K, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Svitlana Filonenko, Antje Voelkel, Markus Antonietti A new green and efficient approach for valorization of monosaccharides into value added chemicals by forming a eutectic medium between reactants. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Biomass-derived phosphorus-doped carbon materials as efficient metal-free catalysts for selective aerobic oxidation of alcohols ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01910C, Paper Xiwei Hu, Mengying Fan, Yangyang Zhu, Qian Zhu, Qiang Song, Zhengping Dong Heteroatom-doped carbon materials (HDCMs) with abundant active functional groups and stable structural characteristics are promising catalysts for eco-friendly metal-free catalysis. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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An N-heterocyclic carbene-functionalised covalent organic framework with atomically dispersed palladium for coupling reactions under mild conditions ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01993F, Paper Junjuan Yang, Yuanyuan Wu, Xiaowei Wu, Wenjing Liu, Yaofang Wang, Junwen Wang We report a heterogeneous catalyst based on N-heterocyclic carbene-functionalized covalent organic framework, which shows high activity in the C–C cross coupling reaction at room temperature in pure/ethanol aqueous solvent even with multiple reuse. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Continuous flow solvent free organic synthesis involving solids (reactants/products) using screw reactor ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC02447F, Paper Brijesh M. Sharma, Ranjit S. Atapalkar, Amol Kulkarni Here we report for the first-time various organic transformations such as aldol condensation, oxidation, nucleophilic substitutions, protection, acylations and coupling reactions using mechanochemical approach at controlled temperature using a single... The content of this RSS Feed (c) The Royal Society of Chemistry
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Sustainable recycling of intact carbon fibres from end-of-service-life composites ()
Green Chem., 2019, 21,4757-4768 DOI: 10.1039/C9GC01847F, Paper Pi-yu Chen, Chun Pei, Ji-Hua Zhu, Meini Su, Feng Xing We demonstrate a sustainable recycling method to reclaim intact carbon fibres from end-of-service-life cement-based composites. The content of this RSS Feed (c) The Royal Society of Chemistry
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Transesterification of soybean oil using a switchable-hydrophilicity solvent, 2-(dibutylamino)ethanol ()
Green Chem., 2019, 21,4786-4791 DOI: 10.1039/C9GC00241C, Paper Kelsey J. Viner, Hannah M. Roy, Roland Lee, Ouwen He, Pascale Champagne, Philip G. Jessop Employing 2-dibutylaminoethanol as both base and solvent for transesterification produces biodiesel and glycerol uncontaminated with metal salts and allows the base/solvent to be easily re-used. The content of this RSS Feed (c) The Royal Society of Chemistry
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UV grafting: surface modification of cellulose nanofibers without the use of organic solvents ()
Green Chem., 2019, 21,4619-4624 DOI: 10.1039/C9GC02035G, Communication Xianpeng Yang, Ting-Hsuan Ku, Subir K. Biswas, Hiroyuki Yano, Kentaro Abe Polymers were grafted from the surfaces of cellulose nanofibers by UV irradiation with an organic solvent-free process. The content of this RSS Feed (c) The Royal Society of Chemistry
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Sustainable access to biobased biphenol epoxy resins by electrochemical dehydrogenative dimerization of eugenol ()
Green Chem., 2019, 21,4815-4823 DOI: 10.1039/C9GC02068C, Paper Goswinus H. M. de Kruijff, Thorsten Goschler, Nicole Beiser, Andreas Stenglein, Oliver M. Türk, Siegfried R. Waldvogel Limited fossil resources require innovative monomers and polymers derived from renewable feedstocks such as plant biomass. The content of this RSS Feed (c) The Royal Society of Chemistry
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Solvation of carbohydrates in five choline chloride-based deep eutectic solvents and the implication for cellulose solubility ()
Green Chem., 2019, 21,4673-4682 DOI: 10.1039/C9GC00559E, Paper Riina Häkkinen, Andrew Abbott Most organic solvents cannot dissolve carbohydrates due to the lack of hydrogen bonding ability of the solvent. The content of this RSS Feed (c) The Royal Society of Chemistry
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Confinement of Brønsted acidic ionic liquids into covalent organic frameworks as a catalyst for dehydrative formation of isosorbide from sorbitol ()
Green Chem., 2019, 21,4792-4799 DOI: 10.1039/C9GC02126D, Paper Yi-Ran Du, Bao-Hua Xu, Jia-Sheng Pan, Yi-Wei Wu, Xiao-Ming Peng, Yao-Feng Wang, Suo-Jiang Zhang The confinement of BILs into 2D COFs using a one-pot self-assembly strategy was achieved. The resulted mesoporous hybrids were successfully applied as the catalyst for a quantitative transformation of sorbitol to isosorbide. The content of this RSS Feed (c) The Royal Society of Chemistry
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Electrochemical oxidative cyclization of activated alkynes with diselenides or disulfides: access to functionalized coumarins or quinolinones ()
Green Chem., 2019, 21,4706-4711 DOI: 10.1039/C9GC02131K, Paper Jiawei Hua, Zheng Fang, Jia Xu, Mixue Bian, ChengKou Liu, Wei He, Ning Zhu, Zhao Yang, Kai Guo A direct electrochemical oxidative cyclization of activated alkynes with diselenides or disulfides toward functionalized coumarins and quinolinones has been developed. The content of this RSS Feed (c) The Royal Society of Chemistry
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Centrifugal fractionation of softwood extracts improves the biorefinery workflow and yields functional emulsifiers ()
Green Chem., 2019, 21,4691-4705 DOI: 10.1039/C9GC02007A, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Fabio Valoppi, Maarit H. Lahtinen, Mamata Bhattarai, Satu J. Kirjoranta, Venla K. Juntti, Leena J. Peltonen, Petri O. Kilpeläinen, Kirsi S. Mikkonen Centrifuging softwood extracts separated the hemicellulose-rich fraction and lignin-rich micro- and nanoparticles. The hemicellulose-rich fraction and lignin-rich nanoparticles formed stable emulsions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Rapid flow-through fractionation of biomass to preserve labile aryl ether bonds in native lignin ()
Green Chem., 2019, 21,4625-4632 DOI: 10.1039/C9GC02315A, Communication Hao Zhou, Jia Yun Xu, Yingjuan Fu, Haiguang Zhang, Zaiwu Yuan, Menghua Qin, Zhaojiang Wang Effective isolation of lignin containing native aryl ether linkages. The content of this RSS Feed (c) The Royal Society of Chemistry
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The highly efficient air oxidation of aryl and alkyl boronic acids by a microwave-assisted protocol under transition metal-free conditions ()
Green Chem., 2019, 21,4614-4618 DOI: 10.1039/C9GC01965K, Communication Weiyan Yin, Xizhi Pan, Wenxi Leng, Jian Chen, Haifeng He A rapid, green and efficient microwave-assisted protocol is developed for the air oxidation of boronic acids to phenols and alcohols under transition metal-free conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Photosystem ratio imbalance promotes direct sustainable H2 production in Chlamydomonas reinhardtii ()
Green Chem., 2019, 21,4683-4690 DOI: 10.1039/C9GC01416K, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Pilla Sankara Krishna, Stenbjörn Styring, Fikret Mamedov Changes in the photosystem I/photosystem II ratio promote sustainable H2 production in C. reinhardtii in a standard TAP medium. The content of this RSS Feed (c) The Royal Society of Chemistry
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Scale-up biopolymer-chelated fabrication of cobalt nanoparticles encapsulated in N-enriched graphene shells for biofuel upgrade with formic acid ()
Green Chem., 2019, 21,4732-4747 DOI: 10.1039/C9GC01720H, Paper Shenghui Zhou, Fanglin Dai, Chao Dang, Ming Wang, Detao Liu, Fachuang Lu, Haisong Qi Carboxymethyl cellulose-derived Co nanocatalysts sheathed in N-doped graphene exhibited an excellent catalytic activity for base-free transfer hydrodeoxygenation of vanillin with formic acid. The content of this RSS Feed (c) The Royal Society of Chemistry
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Application of the Cu(I)/TEMPO/O2 catalytic system for aerobic oxidative dehydrogenative aromatization of pyrrolidines ()
Green Chem., 2019, 21,4609-4613 DOI: 10.1039/C9GC01932D, Communication Zheng Luo, Yan Liu, Chao Wang, Danjun Fang, Junyu Zhou, Huayou Hu A Cu(I)/TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy)-catalyzed aerobic oxidative dehydrogenative aromatization reaction of fully saturated pyrrolidines to synthesize multi-substituted pyrroles was developed for the first time. The content of this RSS Feed (c) The Royal Society of Chemistry
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Biofactories: engineered nanoparticles via genetically engineered organisms ()
Green Chem., 2019, 21,4583-4603 DOI: 10.1039/C9GC01759C, Critical Review Siavash Iravani, Rajender S. Varma Latest advances in nanoparticle biosynthesis are highlighted with specific emphasis on the deployment of genetically engineered organisms and associated challenges. The content of this RSS Feed (c) The Royal Society of Chemistry
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