Green Chemistry


Efficient organic semiconductors synthesis by Suzuki-Miyaura coupling in aromatic micellar medium ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01071H, Paper Alessandro Sanzone, Sara Mattiello, Giulia Maria Garavaglia, Adiel Mauro Calascibetta, Chiara Ceriani, Mauro Sassi, Luca Beverina Micellar catalysis enable carrying out Suzuki-Miyaura couplings in water under exceptionally mild conditions. Extension of such protocol to the sustainable synthesis of highly conjugated, poorly soluble materials like [1]benzothieno[3,2-b][1]benzothiophene (BTBT)... The content of this RSS Feed (c) The Royal Society of Chemistry
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Converting H+ from Coordinated Water into H- Enables Super Facile Synthesis of LiBH4 ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01897B, Paper Kang Chen, Liuzhang Ouyang, Hao Zhong Zhong, Jiangwen Liu, Hui Wang, Huaiyu Shao, Yao Zhang, Min Zhu LiBH4 has excellent application potential as an off- or on-board hydrogen carrier for its unparalleled hydrogen capacity (18.5 wt.%). However, the difficulty in recycling “one-pass” LiBH4 and the resulting high... The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal-free quinolylation of the primary amino groups of amino acid derivatives and peptides with dihydrooxazolo[3,2-a]quinoliniums ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01442J, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Peng Liu, Bo Li, Mengyu Xi, Zhaoqiang Chen, Haiguo Sun, Xiajuan Huan, xue-jun Xu, Yong Zhang, Kun Zou, Xiangrui Jiang, Zehong Miao, Jinggen Liu, Jingshan Shen, Kaixian Chen, Weiliang Zhu The chemical modification of primary amino groups of amino acid derivatives and peptides is highly concerned in today’s pharmaceutical industry and chemical biology. However, the reactions with mild and environmental-friendly... The content of this RSS Feed (c) The Royal Society of Chemistry
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Electrochemically Dehydrogenative C-H/P-H Cross-Coupling: Effective Synthesis of Phosphonated Quinoxalin-2(1H)-ones and Xanthenes ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01474H, Paper Kejing Li, Yangye Jiang, Kun Xu, Cheng-Chu Zeng, Baoguo Sun An efficient electrochemical approach for the C(sp2)-H phosphonation of quinoxalin-2(1H)-ones and C(sp3)-H phosphonation of xanthene has been developed. The chemistry was performed in an undivided cell under constant current conditions... The content of this RSS Feed (c) The Royal Society of Chemistry
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Are Lignin-Derived Carbon Fibers Graphitic Enough? ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01806A, Critical Review D. S. Argyropoulos, William J Sagues, Ankush Jain, Dylan Brown, Salonika Aggarwal , Antonio Suarez , Matthew Kollman, Seonghyun Park Single component lignin-derived carbon fibers have been under development for many years, but strength properties are still inferior to those of commercial carbon fibers. The extent of graphitization is an... The content of this RSS Feed (c) The Royal Society of Chemistry
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Towards Cleaner PolarClean: Efficient Synthesis and Extended Applications of the Polar Aprotic Solvent Methyl 5 (Dimethylamino)-2-methyl-5-oxopentanoate ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01958H, Paper Levente Cseri, Gyorgy Szekely As a result of recent efforts in green solvent selection, methyl 5-(dimethylamino)-2-methyl-5-oxopentanoate, sold under the brand name Rhodiasolv PolarClean, has received considerable scientific and industrial attention as a possible non-toxic... The content of this RSS Feed (c) The Royal Society of Chemistry
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Intramolecular Electrochemical Dehydrogenative N–N Bond Formation for the Synthesis of 1,2,4-Triazolo[1,5‑a]pyridines ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01895F, Communication Yong Li, Zenghui Ye, Na Chen, Zhenkun Chen, Fengzhi Zhang A metal and oxidant-free intramolecular dehydrogenative N–N bond formation has been developed under mild and scalable electrolytic conditions. Various valuable 1,2,4-Triazolo[1,5-a]pyridines were synthesized efficiently from the readily available N-(2-pyridyl)amidines. The... The content of this RSS Feed (c) The Royal Society of Chemistry
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One-pot Synthesis of Tetrahydro-pyrrolobenzodiazepines and Tetrahydro-pyrrolobenzodiazepinons Through Sequential 1,3-Dipolar Cycloaddition/N-Alkylation (N-Acylation)/Staudinger/Aza-Wittig Reactions ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01642B, Paper Xiaoming Ma, Xiaofeng Zhang, John Mark Awad, Guoshu Xie, Weiqi Qiu, Wei Zhang A new synthetic method for diastereoselective synthesis of tetrahydro-pyrrolo[1,2-d][1,4]benzodiazepines and tetrahydro-pyrrolo[1,2-d][1,4]diazepinones is developed which involves 1,3-dipolar cycloaddition, N-alkylation or N-acylation and Staudinger/aza-Wittig reactions. This one-pot and three-step synthesis of four... The content of this RSS Feed (c) The Royal Society of Chemistry
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Cu+-Cu0 bicomponent CuNPs@ZIF-8 for high-selective hydrogenation of biomass derived 5-hydroxymethyl-furfural ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01331H, Communication Yunchao Feng, Guihua Yan, Ting Wang, Wenlong Jia, Xianhai Zeng, Jonathan Sperry, Yong Sun, Xing Tang, Tingzhou Lei, Lu Lin 99% yield of 2,5-dihydroxymethylfuran (DHMF) was achieved from biomass derived 5-hydroxymethylfurfural (HMF) with a novel CuNPs@ZIF-8 using a relative lower hydrogen pressure and shorter reaction time. The coexistence of Cu+... The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of 2-Substituted Indoles through Cyclization and Demethylation of 2-Alkynyldimethylanilines by Ethanol ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01880H, Paper Guangkuan Zhao, Christelle Roudaut, Vincent Gandon, Mouad ALAMI, Olivier Provot Herein, we demonstrated for the first time that 2-alkynyldimethylamines easily cyclize in EtOH according to a 5-endo-dig annulation into 2-substituted indoles without the aid of any additive or any metal... The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal-free, visible-light-promoted oxidative radical cyclization of N-biarylglycine esters: one-pot construction of phenanthridine-6-carboxylates in water ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01557D, Paper Palani Natarajan, Deachen Chuskit, Pri Ya A metal-free, visible-light (blue LED: h = 42515 nm) photoredox-catalyzed intramolecular cyclization reaction of N-biarylglycine esters to phenanthridine-6-carboxylates in water under open air atmosphere at ambient condition has been developed.... The content of this RSS Feed (c) The Royal Society of Chemistry
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Sustainable hydrogenation of Aliphatic Acyclic Primary Amides to Primary Amines with Recyclable Heterogeneous Ruthenium-Tungsten Catalysts ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01310E, Paper Robin Coeck, Sarah Berden, Dirk E. De Vos The hydrogenation of amides is a straightforward method to produce (possibly bio-based) amines. However current amide hydrogenation catalysts have only been validated in a rather limited range of toxic solvents... The content of this RSS Feed (c) The Royal Society of Chemistry
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Reactions of α-Haloacroleins with Azides: Highly Regioselective Synthesis of Formyl Triazoles ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01129C, Paper Lizhu Gao, Dongsheng Zhang, Yingzhu Fan, Zhongliang Yan, Yi Nie, Xingquan Xiong A general metal-free route to 1,4-disubstituted and 1,4,5-trisubstituted 1,2,3-triazoles was developed. α-Haloacroleins reacted with organic azides in water and in organic solvents at room temperature to produce 1,4-disubstituted triazoles (up... The content of this RSS Feed (c) The Royal Society of Chemistry
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Continuous separation of cytochrome-c PEGylated conjugates by fast Centrifugal Partition Chromatography ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01063G, Communication João Santos, Ana M. Ferreira, Mafalda Almeida, Paula Quinteiro, Ana Dias, Joao A. P. Coutinho, Mara G Freire, Carlota Oliveira Rangel Yagui, Sónia P.M. Ventura Herein, it is shown the effective use of aqueous biphasic systems (ABS) in Fast Centrifugal Partition Chromatography (FCPC) for the purification of PEGylated cytochrome c conjugates. High recoveries (between 88%... The content of this RSS Feed (c) The Royal Society of Chemistry
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Ligand-free Suzuki–Miyaura coupling reaction of aryl chloride using a continuous irradiation type microwave and palladium nanoparticle catalyst: Effect of a co-existing solid ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01043B, Paper Makito YAMADA, Yasunori SHIO, Toshiki Akiyama, Tetsuo Honma, Yuuta Ohki, Naoyuki Takahashi, Kenichi Murai, Mitsuhiro Arisawa We have explored the effect of a co-existing metal in the ligand-free Suzuki–Miyaura coupling reaction of an aryl chloride, which is promoted by a “continuous irradiation type microwave” and “palladium... The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalytic dehydration of levoglucosan to levoglucosenone using Brønsted solid acid catalysts in tetrahydrofuran ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01526D, Paper Oscar Oyola-Rivera, Jiayue He, George Huber, James Dumesic, Nelson Cardona-Martínez We studied the production of levoglucosenone (LGO) via levoglucosan (LGA) dehydration using Brønsted solid acid catalysts in tetrahydrofuran (THF). The use of propylsulfonic acid functionalized silica catalysts increased the production... The content of this RSS Feed (c) The Royal Society of Chemistry
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Continuous flow upgrading of glycerol toward oxiranes and active pharmaceutical ingredients thereof ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01819K, Paper Romain Morodo, Romaric Gérardy, Guillaume Petit, Jean-Christophe M Monbaliu A robust continuous flow procedure for the transformation of biobased glycerol into high value-added oxiranes (epichlorohydrin and glycidol) is presented. The flow procedure features a central hydrochlorination/dechlorination sequence and provides... The content of this RSS Feed (c) The Royal Society of Chemistry
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Base-free conversion of glycerol to methyl lactate using a multifunctional catalytic system consisting of Au–Pd nanoparticles on carbon nanotubes and Sn-MCM-41-XS ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01521C, Paper Zhenchen Tang, Dina G. Boer, Ali Syariati, Mihaela Enache, Petra Rudolf, Hero J. Heeres, Paolo P. Pescarmona Base-free, multifunctional heterogenous catalytic systems for the highly efficient conversion of glycerol into methyl lactate. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Multicomponent synthesis of sulfonamides from triarylbismuthines, nitro compounds and sodium metabisulfite in deep eutectic solvents ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01541H, Paper Xavier Marset, Javier Torregrosa-Crespo, Rosa M. Martínez-Espinosa, Gabriela Guillena, Diego J. Ramón A sustainable synthesis of sulfonamides using a copper-catalysed process starting from triarylbismuthines, Na2S2O5 and nitro compounds in a Deep Eutectic Solvent (DES) as a reaction medium is described. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A visible-light-induced intermolecular [3 + 2] alkenylation–cyclization strategy: metal-free construction of pyrrolo[2,1,5-cd]indolizine rings ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01766F, Communication Yaofeng Liang, Lili Teng, Yajun Wang, Qiuxing He, Hua Cao An intermolecular [3 + 2] alkenylation–cyclization of indolizines with electron-deficient alkenes was developed using rose bengal as an organo-photocatalyst. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Chitin in ionic liquids: historical insights into the polymer's dissolution and isolation. A review ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01830A, Critical Review Julia L. Shamshina This comprehensive review provides an analysis of findings related to chitin dissolution in ionic liquids based on the polymer's quality. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Environmental sustainability of cellulose-supported solid ionic liquids for CO2 capture ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC00732F, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Pelayo García-Gutiérrez, Rosa M. Cuéllar-Franca, Dan Reed, George Dowson, Peter Styring, Adisa Azapagic The life cycle environmental impacts of cellulose-supported solid ionic liquids are estimated in comparison with a range of other CO2 sorbents. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Bifunctional phase-transfer catalysts for fixation of CO2 with epoxides under ambient pressure ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC02058F, Paper Yuedan Li, Dongxiao Cui, Jun-Chao Zhu, Ping Huang, Zhuang Tian, Yan-Yan Jia, Ping-An Wang A series of achiral and chiral bifunctional phase-transfer catalysts with a quaternary onium center and hydrogen-bonding donor group were prepared for fixation of CO2 with commercially available epoxides under mild... The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of copper catalysts for click chemistry from distillery wastewater using magnetically recoverable bionanoparticles ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC00270G, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Richard L. Kimber, Fabio Parmeggiani, Nimisha Joshi, Alexander M. Rakowski, Sarah J. Haigh, Nicholas J. Turner, Jonathan R. Lloyd Biogenic magnetite nanoparticles were employed to recover copper from whisky distillery wastewaters, generating an efficient and reusable click chemistry catalyst. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Organic aluminum hydrides catalyze nitrile hydroboration ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01659G, Communication Wenqing Liu, Yi Ding, Da Jin, Qiumiao Shen, Ben Yan, Xiaoli Ma, Zhi Yang The eco-friendly and highly efficient catalytic hydroboration of nitriles has been elucidated by using organic aluminum hydrides. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A palladium-catalyzed three-component cascade S-transfer reaction in ionic liquids ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01718F, Paper Jianxiao Li, Yaodan Wu, Miao Hu, Can Li, Meng Li, Dandan He, Huanfeng Jiang A palladium-catalyzed three component cascade S-transfer reaction for the assembly of functionalized 4-sulfenylisoxazoles in ionic liquids was described. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Efficient microbial synthesis of key steroidal intermediates from bio-renewable phytosterols by genetically modified Mycobacterium fortuitum strains ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01267B, Paper Na Liu, Jinhui Feng, Rui Zhang, Xi Chen, Xuemei Li, Peiyuan Yao, Qiaqing Wu, Yanhe Ma, Dunming Zhu Two genetically modified strains of Mycobacterium fortuitum ATCC 6841 were created and applied to the transformation of phytosterols into HIP and HIL in high yields with no detectable by-products. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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AuPd-nNiO as an effective catalyst for the base-free oxidation of HMF under mild reaction conditions ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01283D, Paper Danilo Bonincontro, Alice Lolli, Alberto Villa, Laura Prati, Nikolaos Dimitratos, Gabriel M. Veith, Lidia E. Chinchilla, Gianlugi A. Botton, Fabrizio Cavani, Stefania Albonetti AuPd nanoparticles supported on NiO exhibit high activity and stability in the base free oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Altered carbon assimilation and cellulose accessibility to maximize bioethanol yield under low-cost biomass processing in corn brittle stalk ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01237K, Paper Leiming Wu, Shengqiu Feng, Jun Deng, Bin Yu, Youmei Wang, Boyang He, Hao Peng, Qian Li, Ruofei Hu, Liangcai Peng Although cellulosic ethanol has been regarded as a perfect additive for transportation fuels, lignocellulose recalcitrance fundamentally determines an expensive bioethanol process unacceptable for commercial production. Here, this study collected the... The content of this RSS Feed (c) The Royal Society of Chemistry
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Visible-Light-Promoted Mutual Transformation of Hydrazines and Azo Compounds ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01618J, Paper Xianya Wang, xianjin Wang, Chungu Xia, Lipeng Wu Azo compounds are widely used in the pharmaceutical and chemical industries. Here, we report the use of a non-metal photo-redox catalyst, Eosin Y, to synthesize azo compounds from hydrazine derivatives.... The content of this RSS Feed (c) The Royal Society of Chemistry
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Zwitterionic amphiphiles: aggregation behaviors and their applications ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01808E, Tutorial Review Aoli Wu, Yanan Gao, Liqiang Zheng Zwitterionic amphiphiles with covalently bonded anionic and cationic groups exhibit electrical neutral properties but extremely high polarity. Under most circumstances, their charge densities can be simply and reversibly modulated by... The content of this RSS Feed (c) The Royal Society of Chemistry
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Temperature-responsive ionic liquids to set up a method for the simultaneous extraction and in situ preconcentration of hydrophilic and lipophilic compounds from medicinal plan matrices ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC00995G, Paper Tong Wang, Qing Wang, Ping Li, Hua Yang In this work, we developed a novel and green method for simultaneous extraction and in-situ preconcentration of both lipophilic and hydrophilic compounds from complex matrix by using a switchable temperature-responsive... The content of this RSS Feed (c) The Royal Society of Chemistry
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Selective Hydrothermal Reductions Using Geomimicry ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC00636B, Paper Christiana Bockisch, Edward D Lorance, Garrett Shaver, Lynda Williams, Hilairy Hartnett, Everett Shock, Ian R Gould Reduction of carbon-carbon -bonds has been demonstrated using iron powder as the reductant and simple powdered nickel as the catalyst in water as the solvent at 250°C and the saturated... The content of this RSS Feed (c) The Royal Society of Chemistry
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Preparation of 5-Methylfurfural from Starch in One Step by Iodide Mediated Metal-Free Hydrogenolysis ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01645G, Paper Weiran Yang, Peng Yang, Xianghua Li, Tian Gao, Teng Li Starch is available in large quantities and in cheap price, especially those from stale rice, root and tube crop etc., which is desirable to be converted to value-added products. A... The content of this RSS Feed (c) The Royal Society of Chemistry
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TixCe1−xO2 nanocomposites: a monolithic catalyst for the direct conversion of carbon dioxide and methanol to dimethyl carbonate ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC00811J, Paper Yongdong Chen, Hong Wang, Zhaoxian Qin, Shanli Tian, Zhongbin Ye, Lin Ye, Hadi Abroshan, Gao Li Dimethyl carbonate (DMC) is widely employed as a versatile reagent and solvent for green organic synthesis and fuel additives. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A fundamental understanding of whole biomass dissolution in ionic liquid for regeneration of fiber by solution-spinning ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC00774A, Paper Ngoc A. Nguyen, Keonhee Kim, Christopher C. Bowland, Jong K. Keum, Logan T. Kearney, Nicolas André, Nicole Labbé, Amit K. Naskar Molecular interactions, chain alignment and entanglement of the hybrid poplar biomass in ionic liquid were investigated for fiber manufacturing. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A comparative study of secondary depolymerization methods on oxidized lignins ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01663E, Paper Yang Song, Ali Hussain Motagamwala, Steven D. Karlen, James A. Dumesic, John Ralph, Justin K. Mobley, Mark Crocker DDQ oxidized lignins were used as substrates to assess the effectiveness of secondary depolymerization methods for the production of aromatics. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ru Catalyzed Methanol Homologation with CO2 and H2 in Ionic Liquid ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01185D, Paper Bernard Baffour Baffour Asare Bediako, Qingli Qian, Jingjing Zhang, Ying Wang, Xiao-jun Shen, Jinbiao Shi, Meng Cui, Guanying Yang, Zhen Wang, Shengrui Tong, Buxing Han Synthesis of ethanol from cheap and renewable CO2 is of great importance, but is still a challenge. Because it involves CO2 hydrogenation with simultaneous C-C bond formation, synergy of two... The content of this RSS Feed (c) The Royal Society of Chemistry
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Direct Anodic (Thio)Acetalization of Aldehydes with Alcohols(thiols) under Neutral Conditions and Computational Insight into the Electrochemical Acetals Formation ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01554J, Communication kedong yuan, Yi Ding, Caiyan Liu, Yongli Shen, Zihui Xiao, Xue Han, Hui Yang A versatile protocol for acetals/thioacetals production by means of direct electrochemical oxidation is developed under neutral conditions, providing (thiol)acetals with good functional group tolerance and wide scope from both aldehydes... The content of this RSS Feed (c) The Royal Society of Chemistry
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Facile fabrication of homogeneous cellulose/polylactic acid composite film with improved biocompatible, biodegradable and mechanical properties ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01918A, Paper Airong Xu, Yongxin Wang, Jiayu Gao, Jianji Wang Fabricating homogeneous cellulose/polylactic acid (C/PLA) composite material remains a challenge because hydrophilic cellulose and hydrophobic PLA are not mutually soluble and they are also insoluble in the same solvent. Here,... The content of this RSS Feed (c) The Royal Society of Chemistry
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Isolation of molybdenum(VI) from simulated leachates of irradiated uranium-aluminum targets using diluted and undiluted sulfate ionic liquids ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01626K, Paper Stijn Raiguel, Wim Dehaen, Koen Binnemans A method is presented to separate molybdenum from other elements commonly present in oxidative alkaline leachates of irradiated uranium-aluminum targets for the production of molybdenum-99. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Electrochemically enabled chemoselective sulfonylation and hydrazination of indoles ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01201J, Communication Yu-Zhen Zhang, Zu-Yu Mo, Heng-Shan Wang, Xiao-An Wen, Hai-Tao Tang, Ying-Ming Pan We have developed electrochemically enabled chemoselective sulfonylation and hydrazination of C2,C3-unsubstituted indoles with arylsulfonyl hydrazide. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Electrochemical synthesis of enaminones via a decarboxylative coupling reaction ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01098J, Communication Xianqiang Kong, Yulong Liu, Long Lin, Qianjin Chen, Bo Xu Metal-free and oxidant-free n-Bu4NI as a redox catalyst and electrolyte. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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An improved catalytic pyrolysis concept for renewable aromatics from biomass involving a recycling strategy for co-produced polycyclic aromatic hydrocarbons ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01485C, Communication Homer C. Genuino, Inouk Muizebelt, André Heeres, Niels J. Schenk, Jos G. M. Winkelman, Hero J. Heeres Catalytic pyrolysis of crude glycerol over a shaped H-ZSM-5 zeolite catalyst with (partial) recycling of the product oil was studied with the incentive to improve benzene, toluene, and xylene (BTX) yields. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly efficient and practical aerobic oxidation of alcohols by inorganic-ligand supported copper catalysis ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01248F, Paper Zheyu Wei, Shi Ru, Qixin Zhao, Han Yu, Gang Zhang, Yongge Wei An inorganic-ligand supported copper catalyst which can effectively catalyze the aerobic oxidation of alcohols to afford aldehydes or ketones with excellent selectivity and yields. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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The Periodic Table of the Elements of Green and Sustainable Chemistry ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01293A, Perspective Paul Anastas, Julie Zimmerman Achieving a sustainable future will only be possible through the intersection of the best science and technology in combination with the societal, economic, policy, cultural, moral, and ethical ecosystem. Green... The content of this RSS Feed (c) The Royal Society of Chemistry
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Tuning the Catalytic Performance for the Semi-hydrogenation of Alkynols by Selectively Poisoning the Active Sites of Pd Catalysts ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC01356C, Paper ShanJun Mao, Bowen Zhao, Zhe Wang, Yutong Gong, Lü Guofeng, Xiao Ma, Lili Yu, Yong Wang Semi-hydrogenation of alkynols to alkenols with Pd-based catalysts, is of great significance in fine chemical industries. Industrial Lindlar catalysts, employing Pb to modify the Pd nanoparticles for higher selectivity toward... The content of this RSS Feed (c) The Royal Society of Chemistry
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Unlocking the response of lignin structure for improved carbon fiber production and mechanical strength ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01632E, Paper Ran Zhang, Qing Du, Lei Wang, Ze Zheng, Li Guo, Xiaoyu Zhang, Xiangliang Yang, Hongbo Yu Soda lignin, a more linear polymer, blended with PAN could produce more carbon fibers with doubled tensile stress. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly active niobium-loaded montmorillonite catalysts for the production of 5-hydroxymethylfurfural from glucose ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01225G, Paper Guo Qiu, Chongpin Huang, Xiuliang Sun, Biaohua Chen Niobium-loaded montmorillonite was employed as a highly efficient catalyst for the catalytic conversion of glucose to 5-HMF in a biphasic solvent. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Correction: Boosting the activity of catalytic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over nitrogen-doped manganese oxide catalysts ()
Green Chem., 2019, 21,3701-3701 DOI: 10.1039/C9GC90058F, Correction Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Qingping Ke, Yangxin Jin, Fei Ruan, Minh Ngoc Ha, Dandan Li, Peixin Cui, Yali Cao, Hao Wang, Tongtong Wang, Van Noi Nguyen, Xinya Han, Xi Wang, Ping Cui The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of amides from acid chlorides and amines in the bio-based solvent Cyrene™ ()
Green Chem., 2019, 21,3675-3681 DOI: 10.1039/C9GC01180C, Paper Thomas W. Bousfield, Katharine P. R. Pearce, Simbarashe B. Nyamini, Athanasios Angelis-Dimakis, Jason E. Camp Cyrene™ as a bio-alternative dipolar aprotic solvent: a waste minimizing and molar efficient protocol for the synthesis of amides from acid chlorides and primary amines in the bio-available solvent Cyrene™ is disclosed. The content of this RSS Feed (c) The Royal Society of Chemistry
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Tough, strong, and biodegradable composite film with excellent UV barrier performance comprising soy protein isolate, hyperbranched polyester, and cardanol derivative ()
Green Chem., 2019, 21,3651-3665 DOI: 10.1039/C9GC01081E, Paper Weidong Gu, Xiaorong Liu, Feng Li, Sheldon Q. Shi, Changlei Xia, Wenrui Zhou, Derong Zhang, Shanshan Gong, Jianzhang Li Tough and biodegradable soy protein isolate film with excellent UV barrier performance by hyperbranched polyester, and cardanol derivative. The content of this RSS Feed (c) The Royal Society of Chemistry
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Mild and facile synthesis of formamide: reduction and functionalization of CO2 using NaBH(OAc)3 under atmospheric pressure ()
Green Chem., 2019, 21,3552-3555 DOI: 10.1039/C9GC01137D, Communication Huan Liu, Zhuang Nie, Jiaan Shao, Wenteng Chen, Yongping Yu An approach for N-formylation of amines was developed using NaBH(OAc)3 as a reductant under an atmospheric pressure of CO2 at 50 °C. The content of this RSS Feed (c) The Royal Society of Chemistry
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Triple copper catalysis for the synthesis of vinyl triazoles ()
Green Chem., 2019, 21,3556-3560 DOI: 10.1039/C9GC01066A, Communication Lucas L. Baldassari, Eduardo A. Cechinatto, Angélica V. Moro Herein, we report our studies on the synthesis of vinyl 1,2,3-triazoles through a one-pot sequence, enabled by the same copper catalyst, of three different reactions: hydroboration involving an alkyne, azidation for a vinyl boronate and azide–alkyne cycloaddition. The content of this RSS Feed (c) The Royal Society of Chemistry
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Combined mild chemical pretreatments for complete cadmium release and cellulosic ethanol co-production distinctive in wheat mutant straw ()
Green Chem., 2019, 21,3693-3700 DOI: 10.1039/C9GC00686A, Paper Liangliang Cheng, Lingqiang Wang, Luyao Wei, Yue Wu, Aftab Alam, Chengbao Xu, Yanting Wang, Yuanyuan Tu, Liangcai Peng, Tao Xia A complete cadmium release and high cellulosic ethanol co-production was achieved in wheat mutant straw in two-step mild chemical pretreatment. The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal-free visible-light induced cyclization/substitution cascade reaction of alkyne-tethered cyclohexadienones and diselenides: access to 5-hydroxy-3-selenyl-4a,8a-dihydro-2H-chromen-6(5H)-ones ()
Green Chem., 2019, 21,3547-3551 DOI: 10.1039/C9GC00570F, Communication Xian-Li Ma, Qian Wang, Xi-Yuan Feng, Zu-Yu Mo, Ying-Ming Pan, Yan-Yan Chen, Mao Xin, Yan-Li Xu A simple and efficient Se-radical triggered cyclization/substitution cascade reaction of alkyne-tethered cyclohexadienones to the product of 3 has been developed. The compounds 3e and 3q showed potent cancer cell-growth inhibition activities. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of bis(indolyl)methanes under dry grinding conditions, promoted by a Lewis acid–surfactant–SiO2-combined nanocatalyst ()
Green Chem., 2019, 21,3542-3546 DOI: 10.1039/C9GC01073D, Communication Zhiqiang Wu, Gang Wang, Shuo Yuan, Dan Wu, Wanyi Liu, Baojun Ma, Shuxian Bi, Haijuan Zhan, Xiaoyan Chen The Lewis acid–surfactant–SiO2-combined (LASSC) nanocatalyst synthesizes BIMs, and has the advantages of being non-toxic, multi-cycle, highly stable and efficient. The content of this RSS Feed (c) The Royal Society of Chemistry
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A simple route to synthesize esterified lignin derivatives ()
Green Chem., 2019, 21,3682-3692 DOI: 10.1039/C9GC00844F, Paper Li-Yang Liu, Qi Hua, Scott Renneckar Developed a simple esterification route to obtain lignin derivatives with tunable Tg's and low E-factor reactions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Visible light promoted PANI@Au:CuO catalyzed sequential amination, azidation and annulation for the preparation of 2-arylbenzimidazoles ()
Green Chem., 2019, 21,3666-3674 DOI: 10.1039/C9GC00350A, Paper Radhika Chopra, Manoj Kumar, Neelam, Vandana Bhalla A protocol describing PANI@Au:CuO photocatalyzed sequential amination/azidation/annulation reactions to prepare 2-aryl benzimidazole derivatives has been developed. The content of this RSS Feed (c) The Royal Society of Chemistry
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Chromium(III) in deep eutectic solvents: towards a sustainable chromium(VI)-free steel plating process ()
Green Chem., 2019, 21,3637-3650 DOI: 10.1039/C9GC00690G, Paper Tim Verdonck, Philippe Verpoort, Joost De Strycker, Ansbert De Cleene, Dipanjan Banerjee, Peter Nockemann, Rik Van Deun, Kristof Van Hecke A sustainable Cr(III) electrolyte was brought one step closer to industrial application by in-depth understanding of the (coordination) chemistry. The content of this RSS Feed (c) The Royal Society of Chemistry
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Allylic oxidation of olefins with a manganese-based metal–organic framework ()
Green Chem., 2019, 21,3629-3636 DOI: 10.1039/C9GC01337G, Paper Jingwen Chen, Minda Chen, Biying Zhang, Renfeng Nie, Ao Huang, Tian Wei Goh, Alexander Volkov, Zhiguo Zhang, Qilong Ren, Wenyu Huang Manganese-based CPF-5 as a highly efficient catalyst for the selective aerobic oxidation of cyclohexene to cyclohexenone under mild conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Visible-light-induced α-oxyamination of 1,3-dicarbonyls with TEMPO via a photo(electro)catalytic process applying a DSSC anode or in a DSSC system ()
Green Chem., 2019, 21,3615-3620 DOI: 10.1039/C9GC01154D, Paper Ming Gong, Jung Keun Kim, Xiuli Zhao, Yabo Li, Jianye Zhang, Mengmeng Huang, Yangjie Wu The photo(electro)catalyzed α-oxyamination of 1,3-dicarbonyls with TEMPO using a DSSC anode or in a DSSC system. The content of this RSS Feed (c) The Royal Society of Chemistry
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H2O-controlled selective thiocyanation and alkenylation of ketene dithioacetals under electrochemical oxidation ()
Green Chem., 2019, 21,3597-3601 DOI: 10.1039/C9GC01351B, Paper Jiangwei Wen, Longfei Zhang, Xiaoting Yang, Cong Niu, Shuangfeng Wang, Wei Wei, Xuejun Sun, Jianjing Yang, Hua Wang Efficient and H2O-controlled selective thiocyanation and alkenylation of internal olefins, to afford tetrasubstituted olefins under electrochemical oxidation, has been successfully developed. The content of this RSS Feed (c) The Royal Society of Chemistry
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Extraction and milking of astaxanthin from Haematococcus pluvialis cultures ()
Green Chem., 2019, 21,3621-3628 DOI: 10.1039/C9GC01273G, Paper Chiara Samorì, Laura Pezzolesi, Paola Galletti, Margherita Semeraro, Emilio Tagliavini Natural astaxanthin can be recovered from Haematococcus pluvialis culture without any cell pre-treatment by using human-compatible solvents, and can be re-synthesized by cells if algae-compatible solvents are applied in a milking mode, avoiding a net biomass loss. The content of this RSS Feed (c) The Royal Society of Chemistry
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Cascade utilization of lignocellulosic biomass to high-value products ()
Green Chem., 2019, 21,3499-3535 DOI: 10.1039/C9GC00473D, Tutorial Review Yanrong Liu, Yi Nie, Xingmei Lu, Xiangping Zhang, Hongyan He, Fengjiao Pan, Le Zhou, Xue Liu, Xiaoyan Ji, Suojiang Zhang Sustainable and effective methods for biomass pretreatment and biomass cascade utilization are reviewed in this work. The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalytic production of renewable lubricant base oils from bio-based 2-alkylfurans and enals ()
Green Chem., 2019, 21,3606-3614 DOI: 10.1039/C9GC01044K, Paper Sibao Liu, Basudeb Saha, Dionisios G. Vlachos Lubricant ranged alkanes of controlled branching and molecular size with excellent yields were synthesized by catalytic conjugate addition-hydroxylalkylation/alkylation (CA-HAA) of biomass derived 2-alkylfurans with enals followed by hydrodeoxygenation. The content of this RSS Feed (c) The Royal Society of Chemistry
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Continuous manufacturing – the Green Chemistry promise? ()
Green Chem., 2019, 21,3481-3498 DOI: 10.1039/C9GC00773C, Critical Review Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Luke Rogers, Klavs F. Jensen We review Green Chemistry advances resulting when transitioning to continuous manufacturing with focus on Green Chemistry elements inherent in flow chemistry and related separation processes. The content of this RSS Feed (c) The Royal Society of Chemistry
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Visible-light-induced condensation cyclization to synthesize benzimidazoles using fluorescein as a photocatalyst ()
Green Chem., 2019, 21,3602-3605 DOI: 10.1039/C9GC01359H, Paper Zhuofei Li, He Song, Rui Guo, Minghui Zuo, Chuanfu Hou, Shouneng Sun, Xin He, Zhizhong Sun, Wenyi Chu A mild strategy for visible-light-induced synthesis of benzimidazoles was developed using aromatic aldehydes and o-phenylenediamines as substrates. The content of this RSS Feed (c) The Royal Society of Chemistry
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Fiber-supported Fe(III) complex catalyst in spinning basket reactor for cleaner ring-opening of epoxides with alcohols ()
Green Chem., 2019, 21,3573-3582 DOI: 10.1039/C9GC00987F, Paper Xian-Lei Shi, Benyu Sun, Qianqian Hu, Yongju Chen, Peigao Duan An available, nontoxic, efficient, recyclable and gram-scaleable fiber-supported Fe(III) complex catalyst in spinning basket reactor for cleaner ring-opening reactions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Integration of phosphine ligands and ionic liquids both in structure and properties – a new strategy for separation, recovery, and recycling of homogeneous catalyst ()
Green Chem., 2019, 21,3583-3596 DOI: 10.1039/C9GC00679F, Paper Xin Jin, Jianying Feng, Hongbing Song, Jiajun Yao, Qingqing Ma, Mei Zhang, Cong Yu, Shumei Li, Shitao Yu Integration of phosphine ligand and ionic liquid – a new strategy for separation, recovery, and recycling of homogeneous catalyst. The content of this RSS Feed (c) The Royal Society of Chemistry
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Kinetic and mechanistic insights into hydrogenolysis of lignin to monomers in a continuous flow reactor ()
Green Chem., 2019, 21,3561-3572 DOI: 10.1039/C9GC00986H, Paper Yanding Li, Benginur Demir, Leida M. Vázquez Ramos, Mingjie Chen, James A. Dumesic, John Ralph Phenolic commodity chemicals were produced from lignin with high yield and selectivity in a flow reactor, valorizing the biorefinery process. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly chemo- and regioselective C–P cross-coupling reaction of quinone imine ketals with Ar2P(O)H to construct ortho-amino triarylphosphine derivatives ()
Green Chem., 2019, 21,3536-3541 DOI: 10.1039/C9GC00989B, Communication Teng Liu, Yongqin Li, Feixiang Cheng, Xianfu Shen, Jianjun Liu, Jun Lin The first highly selective C–P cross-coupling reaction of QIKs with Ar2P(O)H to construct ortho-amino triarylphosphine derivatives has been developed. Furthermore, a series of functionalized organophosphorus were accomplished. The content of this RSS Feed (c) The Royal Society of Chemistry
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Functionalization of chitosan with lignin to produce active materials by waste valorization ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01372E, Paper Kevin Crouvisier-Urion, Fernanda Regina da Silva Farias, Sorawit Arunatat, Donnchadh Griffin, Massimiliano Gerometta, Jeancarlo R. Rocca-Smith, Guy Weber, Nicolas Sok, Thomas Karbowiak Active films are produced by a grafting reaction based on the reactivity between chitosan amino groups and lignin hydroxyl groups. This opens a new route for the valorization of lignin, with the possibility of tuning the anti-oxidant activity. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Wealth from waste: blue mussels (Mylitus edulis) offer up a sustainable source of natural and synthetic nacre ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01244C, Paper Jennifer N. Murphy, Céline M. Schneider, Lilo K. Mailänder, Quentin Lepillet, Kelly Hawboldt, Francesca M. Kerton Inner and outer layers of blue mussel shell separate easily via heat treatment allowing isolation of biogenic nacre and calcite. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of jet fuel range high-density polycycloalkanes with polycarbonate waste ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01627A, Communication Hao Tang, Yancheng Hu, Guangyi Li, Aiqin Wang, Guoliang Xu, Cong Yu, Xiaodong Wang, Tao Zhang, Ning Li Jet fuel range high-density C13–C15 cycloalkanes were first synthesized at a high overall yield (∼80%) with polycarbonate waste. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Production of a renewable 1,3-diene containing a functional group from a furfural–acetone adduct in a fixed-bed reactor ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01481K, Paper Yanlong Qi, Shijun Liu, Long Cui, Quanquan Dai, Jianyun He, Wei Dong, Chenxi Bai A renewable functionalized 1,3-diene containing a furan group is firstly produced from furfural and acetone by an alternative approach. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Visible-light-induced deoxygenative C2-sulfonylation of quinoline N-oxides with sulfinic acids ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01175G, Paper Long-Yong Xie, Tai-Gang Fang, Jia-Xi Tan, Bo Zhang, Zhong Cao, Li-Hua Yang, Wei-Min He The first example of direct synthesis of 2-sulfonylquinolines through visible-light-induced deoxygenative C2-sulfonylation of quinoline N-oxides with organic dye as the catalyst and ambient air as the sole oxidant was developed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Controlling metal oxide nanoparticle size and shape with supercritical fluid synthesis ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01619H, Critical Review Mary Kate Mitchell Lane, Julie B. Zimmerman Supercritical fluid nanoparticle synthesis (SCF nano synthesis) can robustly and readily control size and shape of metal oxide nanoparticles, while offering a potentially greener synthetic route through the employment of green solvents. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Anionic surfactants based on intermediates of carbohydrate conversion ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01163C, Paper Lukas Kipshagen, Lukas T. Vömel, Marcel A. Liauw, Anna Klemmer, Alexander Schulz, Christian Kropf, Peter J. C. Hausoul, Regina Palkovits Starting from the bio-based platform chemicals 5-hydroxymethylfurfural (HMF) and furfural, a library of anionic surfactants was synthesized using stoichiometric and catalytic reactions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of high-molecular weight isosorbide-based polycarbonates through efficient activation of endo-hydroxyl groups by an ionic liquid ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01500K, Paper Zhencai Zhang, Fei Xu, Hongyan He, Weilu Ding, Wenjuan Fang, Wei Sun, Zengxi Li, Suojiang Zhang A high-molecular weight bio-based polycarbonate was successfully synthesized by breaking the hydrogen bond of endo-OH group using an ionic liquid. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Thermocatalytic depolymerization of kraft lignin to guaiacols using HZSM-5 in alkaline water–THF co-solvent: a realistic approach ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC00593E, Paper Deepak Raikwar, Saptarshi Majumdar, Debaprasad Shee A study representing depolymerization of kraft lignin in a batch reactor with higher loading attaining high conversion and guaiacol selectivity simultaneously and its correlation with structural modifications. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Cellulolytic enzyme-aided extraction of hemicellulose from switchgrass and its characteristics ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC00252A, Paper Jinhua Ding, Chang Geun Yoo, Yunqiao Pu, Xianzhi Meng, Samarthya Bhagia, Chongwen Yu, Arthur J. Ragauskas To further increase the potential applications of hemicellulose, an eco-friendly promising protocol was introduced to isolate hemicellulose from switchgrass. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Efficient synthesis of enantiopure amines from alcohols using resting E. coli cells and ammonia ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01059A, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Joseline A. Houwman, Tanja Knaus, Magda Costa, Francesco G. Mutti E. coli cells co-expressing alcohol dehydrogenases and an amine dehydrogenase convert alcohols into enantiopure amines at the expense of ammonia. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A 3,4-dihalo-2(5H)-furanone initiated ring-opening reaction of DABCO in the absence of a metal catalyst and additive and its application in a one-pot two-step reaction ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01740B, Communication Han-Qing Wu, Kai Yang, Xiao-Yun Chen, Mani Arulkumar, Neng Wang, Si-Hong Chen, Zhao-Yang Wang An environmental friendly protocol for metal/additive-free synthesis of potential bioactive compounds from 3,4-dihalo-2(5H)-furanone and DABCO is described. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Lithium-mediated ammonia synthesis from water and nitrogen: a membrane-free approach enabled by an immiscible aqueous/organic hybrid electrolyte system ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01338E, Paper Kwiyong Kim, Yifu Chen, Jong-In Han, Hyung Chul Yoon, Wenzhen Li A membrane-free electrochemical cell provides a green and economic way of lithium deposition and its utilization for lithium-mediated ammonia synthesis. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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PET hydrolysing enzymes catalyse bioplastics precursor synthesis under aqueous conditions ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01284B, Paper Daniele Parisi, Christopher Riley, Abhishek S. Srivastava, Hannah V. McCue, James R. Johnson, Andrew J. Carnell Poly(ethylene terephthalate) hydrolase (PETase) was used to catalyse a double transesterification to convert FDCA dimethyl ester to the bioplastics precursor bis-butandiol ester in good yield under aqueous conditions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal-free imidazolium hydrogen carbonate ionic liquids as bifunctional catalysts for the one-pot synthesis of cyclic carbonates from olefins and CO2 ()
Green Chem., 2019, Advance Article DOI: 10.1039/C9GC01088B, Paper Jia Liu, Guoqiang Yang, Ying Liu, Dongsheng Wu, Xingbang Hu, Zhibing Zhang A direct route for the synthesis of cyclic carbonates from olefins and CO2 has been achieved by using imidazolium hydrogen carbonate ionic liquids as bifunctional catalysts in the absence of a solvent. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Carbon Inventory, Carbon Fluxes and Evaluation of Carbon Cycles for a Long-Term Sustainable World ()
Green Chem., 2019, Accepted Manuscript DOI: 10.1039/C9GC00528E, Tutorial Review Patrick Tomkins, Thomas Ernst Müller Carbon is an essential element of life as we know it on earth. The evolution of life has had substantial impact on the distribution of carbon in the various geo-habitats.... The content of this RSS Feed (c) The Royal Society of Chemistry
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A tunable precious metal-free system for selective oxidative esterification of biobased 5-(hydroxymethyl)furfural ()
Green Chem., 2019, 21,3464-3468 DOI: 10.1039/C9GC00840C, Paper Kirill S. Kozlov, Leonid V. Romashov, Valentine P. Ananikov Oxidative esterification of biomass-derived 5-(hydroxymethyl) furfural (HMF) and furfural and their derivatives has been performed using a simple MnO2/NaCN system. The content of this RSS Feed (c) The Royal Society of Chemistry
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Efficient transformation of CO2 to cyclic carbonates using bifunctional protic ionic liquids under mild conditions ()
Green Chem., 2019, 21,3456-3463 DOI: 10.1039/C9GC01165J, Paper Xianglei Meng, Zhaoyang Ju, Suojiang Zhang, Xiaodong Liang, Nicolas von Solms, Xiaochun Zhang, Xiangping Zhang Bifunctional protic ionic liquids were prepared and they showed high activity for conversion of CO2 with epoxides at mild temperature (30–50 °C) and 1 bar CO2. The content of this RSS Feed (c) The Royal Society of Chemistry
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Flow-based enzymatic synthesis of melatonin and other high value tryptamine derivatives: a five-minute intensified process ()
Green Chem., 2019, 21,3263-3266 DOI: 10.1039/C9GC01374A, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Martina Letizia Contente, Stefano Farris, Lucia Tamborini, Francesco Molinari, Francesca Paradisi To increase the uptake of biocatalytic processes by industry, it is essential to demonstrate the reliability of enzyme-based methodologies directly applied to the production of high value products. The content of this RSS Feed (c) The Royal Society of Chemistry
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Sustainable bioproduction of the blue pigment indigoidine: Expanding the range of heterologous products in R. toruloides to include non-ribosomal peptides ()
Green Chem., 2019, 21,3394-3406 DOI: 10.1039/C9GC00920E, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Maren Wehrs, John M. Gladden, Yuzhong Liu, Lukas Platz, Jan-Philip Prahl, Jadie Moon, Gabriella Papa, Eric Sundstrom, Gina M. Geiselman, Deepti Tanjore, Jay D. Keasling, Todd R. Pray, Blake A. Simmons, Aindrila Mukhopadhyay Development of R. toruloides as a production host for the sustainable production of the NRP indigoidine. The content of this RSS Feed (c) The Royal Society of Chemistry
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A facile strategy for photoactive nanocellulose-based antimicrobial materials ()
Green Chem., 2019, 21,3424-3435 DOI: 10.1039/C9GC00551J, Paper David Ramirez Alvarado, Dimitris S. Argyropoulos, Frank Scholle, Bharadwaja S. T. Peddinti, Reza A. Ghiladi Anti-infective materials based upon renewable nanocellulose–porphyrin conjugates photodynamically inactivated four strains of drug-resistant bacteria and two viruses by 99.999+%. The content of this RSS Feed (c) The Royal Society of Chemistry
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Opportunities and perspectives for green chemistry in semiconductor technologies ()
Green Chem., 2019, 21,3250-3255 DOI: 10.1039/C9GC01058K, Perspective Francesca Iacopi, Monique McIntosh Semiconductor technologies offer a plethora of technological challenges and opportunities for a more extensive implementation of green chemistry principles. The content of this RSS Feed (c) The Royal Society of Chemistry
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Biocatalytic synthesis of panthenyl monoacyl esters in ionic liquids and deep eutectic solvents ()
Green Chem., 2019, 21,3353-3361 DOI: 10.1039/C9GC01076A, Paper Pedro Lozano, Elena Alvarez, Susana Nieto, Rocio Villa, Juana M. Bernal, Antonio Donaire The enzymatic synthesis of panthenyl monoacyl esters was carried out by the direct esterification of fatty acids (e.g. lauric acid) with panthenol in sponge-like ionic liquids, as well as in deep eutectic mixtures, resulting in highly selective processes (i.e. near to 100% for the panthenyl monolaurate case). The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly efficient electrochemical conversion of CO2 and NaCl to CO and NaClO ()
Green Chem., 2019, 21,3256-3262 DOI: 10.1039/C9GC01099H, Communication Fengjiao Quan, Guangming Zhan, Huan Shang, Yahui Huang, Falong Jia, Lizhi Zhang, Zhihui Ai Cathodic CO2 reduction and anodic salt oxidation are coupled for simultaneous production of CO and NaClO in high efficiencies. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ambient and aerobic carbon–carbon bond cleavage toward α-ketoester synthesis by transition-metal-free photocatalysis ()
Green Chem., 2019, 21,3436-3441 DOI: 10.1039/C9GC01357A, Paper Qing Yu, Yating Zhang, Jie-Ping Wan With a low loading of Rose Bengal (1 mol%) and green LED irradiation, α-ketoesters are efficiently synthesized with excellent product diversity and selectivity via the ambient cleavage of the enaminone CC double bond. The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalytic synthesis of distillate-range ethers and olefins from ethanol through Guerbet coupling and etherification ()
Green Chem., 2019, 21,3300-3318 DOI: 10.1039/C9GC01290G, Paper Nathaniel M. Eagan, Benjamin M. Moore, Daniel J. McClelland, Ashley M. Wittrig, Emmanuel Canales, Michael P. Lanci, George W. Huber Ethanol can be converted to heavy diesel ethers and jet fuel precursor olefins through sequential Guerbet coupling and dehydration. The content of this RSS Feed (c) The Royal Society of Chemistry
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System-level analysis and life cycle assessment of CO2 and fossil-based formic acid strategies ()
Green Chem., 2019, 21,3442-3455 DOI: 10.1039/C9GC01280J, Paper Yuchan Ahn, Jaewon Byun, Dongin Kim, Beom-Sik Kim, Cheol-Seung Lee, Jeehoon Han A cradle-to-gate life cycle assessment provides comprehensive insights into diverse environmental impacts and possible improvements in producing two formic acids. The content of this RSS Feed (c) The Royal Society of Chemistry
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Visible-light-induced radical cyclization of N-allylbenzamides with CF3SO2Na to trifluoromethylated dihydroisoquinolinones in water at room temperature ()
Green Chem., 2019, 21,3362-3369 DOI: 10.1039/C9GC00938H, Paper Long Zou, Pinhua Li, Bin Wang, Lei Wang An efficient strategy for the preparation of trifluoromethylated dihydroisoquinolinones via visible-light induced radical cyclization of N-allylbenzamides with CF3SO2Na was developed. The content of this RSS Feed (c) The Royal Society of Chemistry
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