Green Chemistry


Visible-Light-Initiated Regioselective Sulfonylation/Cyclization of 1,6-Enynes under Photocatalyst- and Additive-Free Conditions ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC03769A, Paper xiao-xiao meng, Qing-Qing Kang, Jun-Yao Zhang, Qiang Li, Wenting Wei, Wei-Min He Without employing any photocatalyst and additive, an economical, eco-friendly and practical strategy has been developed for the visible-light-initiated regioselective sulfonylation/cyclization of 1,6-enynes in a biomass-derived green solvent 2-methylTHF from easily... The content of this RSS Feed (c) The Royal Society of Chemistry
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Maleic acid as a dicarboxylic acid hydrotrope for green fractionation of wood at atmospheric pressure and ≤ 100 °C: Mode and utility of lignin esterification ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC04267A, Paper Cheng Cai, Kolby Hirth, Rolland Gleisner, Hongming Lou, Xueqing Qiu, JunYong Zhu This study evaluated maleic acid (MA) as a green hydrotrope for efficient wood fractionation at atmospheric pressure and ≤ 100°C. MA hydrotropic fractionation (MAHF) resulted in esterified lignin with a... The content of this RSS Feed (c) The Royal Society of Chemistry
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Tuning Ca-Al-based catalysts composition for isomerize or epimerize glucose and other sugars ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC02823D, Paper María Ventura, Juan A. Cecilia, Enrique Rodriguez-Castellon, Marcelo E Domine One of the key reactions to achieve good productivity on the transformations of the cellulose-derived from biomass feedstocks is the isomerization of glucose to fructose, being this lastest the platform... The content of this RSS Feed (c) The Royal Society of Chemistry
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Replacing methanol with azeotropic ethanol as the co-solvent for improved chiral separations with supercritical fluid chromatography (SFC) ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC04207E, Paper Daipayan Roy, M. Farooq Wahab, Mohsen Talebi, Daniel W. Armstrong Using azeoptropic ‘190 proof’ ethanol eliminates the use of methanol in chiral super/subcritical fluid chromatography. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Colloidal Co single-atom catalyst: a facile synthesis strategy and high catalytic activity for hydrogen generation ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03477C, Paper Junkai Wang, Zhenxia Huang, Lilin Lu, Quanli Jia, Liang Huang, Shuai Chang, Mingyang Zhang, Zuotai Zhang, Sun Li, Dongsheng He, Wenhao Wu, Shaowei Zhang, Naoki Toshima, Haijun Zhang A facile route for on-demand hydrogen production via simply controlling the mixing process of a KBH4 solution and an aqueous solution of ISOBAM-104 stabilized Co2+ ions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Gas-phase bioproduction of a high-value-added monoterpenoid (E)-geranic acid by metabolically engineered Acinetobacter sp. Tol 5 ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03478A, Paper Atsushi Usami, Masahito Ishikawa, Katsutoshi Hori Here we report the gas-phase bioproduction of (E)-geranic acid, a high-value-added monoterpenoid, from gaseous geraniol by Acinetobacter sp. Tol 5. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Aqueous electrosynthesis of silver indium selenide nanocrystals and their photothermal properties ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03647D, Paper Felipe L. N. Sousa, Brenand A. S. Souza, Anderson C. Jesus, Walter M. Azevedo, Herman S. Mansur, Denilson V. Freitas, Marcelo Navarro The eco-friendly aqueous electrosynthesis of AgIn5Se8 (AISe) nanocrystals (NCs), and their respective core/shell structure AgIn5Se8/ZnS NCs (AISe/ZnS), was carried out by using L-glutathione (GSH) as a stabilizer. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Water Tolerant Nickel-Nitrogen-Doped Carbon Catalyst for Continuous Flow Hydrogenation of Biomass Derived-Compounds ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC03826D, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Francesco Brandi, Marius Bäumel, Valerio Molinari, Irina shekova, Iver Lauermann, Tobias Heil, Markus Antonietti, Majd Al-Naji Hydrogenation reactions in water at elevated temperatures are challenging for heterogeneous catalyst. Thus, we present a simple, cheap, scalable, and sustainable approach for synthesizing an efficient and water-tolerant Ni catalyst... The content of this RSS Feed (c) The Royal Society of Chemistry
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One-step electrodeposition of NixFe3-xO4/Ni hybrid nanosheet arrays as highly active and robust electrocatalysts for oxygen evolution ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/D0GC00168F, Paper Dongjie Li, Suqin Liu, Guanying Ye, Weiwei Zhu, Kuangmin ZHAO, Meng Luo, Zhen He The non-precious transition metal oxide-based materials have shown a promising prospect as the electrocatalysts for the oxygen evolution reaction (OER). Herein, we report a template-free and annealing-free one-step electrodeposition approach... The content of this RSS Feed (c) The Royal Society of Chemistry
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Electrochemical-Induced Regioselective C-3 Thiomethylation of Imidazopyridines via a Three-Component Cross-Coupling Strategy ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC04068D, Communication Jiangwei Wen, Cong Niu, Kelu Yan, Xingda Cheng, Ruike Gong, Mengqian Li, Yongqiang Guo, Jianjing Yang, Hua Wang The electrochemical-induced regioselective C-3 thiomethylation of imidazopyridines has been initially accomplished via a three-component cross-coupling strategy using thiocyanate as the sulfur and methanol as methyl reagent. This protocol provides a... The content of this RSS Feed (c) The Royal Society of Chemistry
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Enzymatic One-Pot Synthesis of Renewable and Biodegradable Surfactants in Supercritical Carbon Dioxide (scCO2). ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC04011K, Paper Mariana d’Almeida Gamiero, Amy Rose Goddard, Vincenzo Taresco, Steven M Howdle We seek to expand the opportunities to exploit glycerol, a largely untapped renewable feedstock, by exploiting enzymatic catalysis in supercritical carbon dioxide (scCO2). This work highlights a promising and clean... The content of this RSS Feed (c) The Royal Society of Chemistry
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Effective separation of surfactant-stabilized crude oil-in-water emulsions by waste brick powders-coated membrane under corrosive conditions ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC04178H, Paper Guogui Shi, Yongqian Shen, Peng Mu, Qingtao Wang, Yaoxia Yang, Siyi Ma, Jian Li Crude oil spill accidents have occurred frequently, not only seriously destroying the marine ecological environment and threatening human health for a long time, but also generating a great loss of... The content of this RSS Feed (c) The Royal Society of Chemistry
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Borate chemistry inspired by cell walls converts soy protein into high-strength, antibacterial, flame-retardant adhesive ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC03875B, Paper Weidong Gu, feng li, Xiaorong Liu, Qiang Gao, Shanshan Gong, Jianzhang Li, Sheldon Q. Shi Urea formaldehyde, phenolic, and melamine formaldehyde resins are currently the most common wood adhesives. However, these modern wood adhesives have toxicity problems and most of the raw materials come from... The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalyst-free selective N-formylation and N-methylation of amines using CO2 as a sustainable C1 source ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC03637G, Communication Qizhuang Zou, Guangcai Long, Tianxiang Zhao, Xingbang Hu We herein describe a catalyst-free selective N-formylation and N-methylation of amines using CO2 as a sustainable C1 source. By tuning reaction solvent and temperature, the selective synthesis of formamides and... The content of this RSS Feed (c) The Royal Society of Chemistry
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Lipase-catalyzed ring-opening copolymerization of ω-pentadecalactone and δ-valerolactone by reactive extrusion ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC04111G, Communication Changcun Li, Shuaijun Pan, Weijian Xu, Yanbing Lu, Peipei Wang, Fuming Zhang, Richard Alan Gross This work demonstrates the synthesis of poly(ω-pentadecalactone-co-δ-valeroLactone) with high molecular weight (Mn = 71.3 kDa) and low polydispersity (Đ = 1.67) within 6 hours by reactive extrusion (REX) using a lipase catalyst (Novozyme-435). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Selective hydrogenation of 5-hydroxymethylfurfural and its acetal with 1,3-propanediol to 2,5-bis(hydroxymethyl)furan using supported rhenium-promoted nickel catalysts in water ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03856F, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Jan J. Wiesfeld, Minjune Kim, Kiyotaka Nakajima, Emiel J. M. Hensen High BHMF yield is achieved by protecting the formyl group of 5-HMF and subsequently balancing its rate of deprotection during the hydrogenation reaction. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A mild, general, and metal-free method for site-specific deuteration induced by visible light using D2O as the source of deuterium atoms ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC04096J, Communication Shuai Shi, Ruining Li, Liangming Rao, Zhankui Sun Visible light induced desulfurization–deuteration method was developed using D2O as the source of deuterium atoms. This radical approach features mild conditions, broad substrate scope, highly efficient D-incorporation and excellent functional group compatibility. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Correction: Efficient separation of immiscible oil/water mixtures using a perforated lotus leaf ()
Green Chem., 2020, 22,565-566 DOI: 10.1039/C9GC90121C, Correction Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Chunhui Zhang, Yuheng Zhang, Xiao Xiao, Guoliang Liu, Zhe Xu, Bing Wang, Cunming Yu, Robin H. A. Ras, Lei Jiang The content of this RSS Feed (c) The Royal Society of Chemistry
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Correction: Pentanoic acid from γ-valerolactone and formic acid using bifunctional catalysis ()
Green Chem., 2020, 22,564-564 DOI: 10.1039/C9GC90122A, Correction Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Majd Al-Naji, Joost Van Aelst, Yuhe Liao, Martin d'Halluin, Zhipeng Tian, Chenguang Wang, Roger Gläser, Bert F. Sels The content of this RSS Feed (c) The Royal Society of Chemistry
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Correction: Sulfonated graphitic carbon nitride as a highly selective and efficient heterogeneous catalyst for the conversion of biomass-derived saccharides to 5-hydroxymethylfurfural in green solvents ()
Green Chem., 2020, 22,563-563 DOI: 10.1039/C9GC90120E, Correction Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Tripti Chhabra, Ashish Bahuguna, Sandeep Singh Dhankhar, C. M. Nagaraja, Venkata Krishnan The content of this RSS Feed (c) The Royal Society of Chemistry
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Solid state thermomechanical engineering of high-quality pharmaceutical salts via solvent free continuous processing ()
Green Chem., 2020, 22,540-549 DOI: 10.1039/C9GC03528A, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Md Sadeque Hossain Mithu, Steven A. Ross, Bruce D. Alexander, Dennis Douroumis Solvent-free, continuous processing of high-quality pharmaceutical salts through via hot-melt extrusion as an alternative to solvent based approaches. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ball milling: an efficient and green approach for asymmetric organic syntheses ()
Green Chem., 2020, 22,302-315 DOI: 10.1039/C9GC03414E, Critical Review Ilya N. Egorov, Sougata Santra, Dmitry S. Kopchuk, Igor S. Kovalev, Grigory V. Zyryanov, Adinath Majee, Brindaban C. Ranu, Vladimir L. Rusinov, Oleg N. Chupakhin Mechanochemical approaches in an organic synthesis have received increased interest because of their wide applications in green methodologies. The content of this RSS Feed (c) The Royal Society of Chemistry
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(Non-)Kolbe electrolysis in biomass valorization – a discussion of potential applications ()
Green Chem., 2020, 22,286-301 DOI: 10.1039/C9GC03264A, Perspective Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. F. Joschka Holzhäuser, Joel B. Mensah, Regina Palkovits The bio-availability of organic acids as platform chemicals and the potential of electrochemistry to directly integrate renewable energy into new value chains drive (Non-)Kolbe electrolysis to become an attractive tool in future electro-bio-refinery. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthetic fungal multifunctional cellulases for enhanced biomass conversion ()
Green Chem., 2020, 22,478-489 DOI: 10.1039/C9GC03062J, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Roman Brunecky, Venkataramanan Subramanian, John M. Yarbrough, Bryon S. Donohoe, Todd B. Vinzant, Todd A. Vanderwall, Brandon C. Knott, Yogesh B. Chaudhari, Yannick J. Bomble, Michael E. Himmel, Stephen R. Decker Synthetic multifunctional enzymes exhibit superior performance to their non-multifunctional enzyme components and exhibit novel cellulose deconstruction mechanisms. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of 1,2-amino alcohols by decarboxylative coupling of amino acid derived α-amino radicals to carbonyl compounds via visible-light photocatalyst in water ()
Green Chem., 2020, 22,336-341 DOI: 10.1039/C9GC03470F, Communication Shulei Pan, Min Jiang, Jinjin Hu, Ruigang Xu, Xiaofei Zeng, Guofu Zhong A general and efficient visible-light photoredox-catalyzed decarboxylative radical coupling reaction of N-aryl amino acids with aldehydes or ketones for the synthesis of 1,2-amino alcohols in water at room temperature is described. The content of this RSS Feed (c) The Royal Society of Chemistry
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Structure-performance correlations of cross-linked boronic acid polymers as adsorbents for recovery of fructose from glucose–fructose mixtures ()
Green Chem., 2020, 22,550-562 DOI: 10.1039/C9GC03151K, Paper Guido Schroer, Jeff Deischter, Tobias Zensen, Jan Kraus, Ann-Christin Pöppler, Long Qi, Susannah Scott, Irina Delidovich This article addresses the utilization of cross-linked phenylboronic-acid polymers for fructose separation from glucose–fructose mixtures focusing particularly on structure-sorption relationships. The content of this RSS Feed (c) The Royal Society of Chemistry
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Solvometallurgical process for extraction of copper from chalcopyrite and other sulfidic ore minerals ()
Green Chem., 2020, 22,417-426 DOI: 10.1039/C9GC02983D, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Xiaohua Li, Wouter Monnens, Zheng Li, Jan Fransaer, Koen Binnemans Copper is extracted from sulfidic ores by a leaching-electrodeposition system, thereby producing metallic copper and regenerating the oxidizing agent FeCl3. The content of this RSS Feed (c) The Royal Society of Chemistry
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Photochemical oxidation of benzylic primary and secondary alcohols utilizing air as the oxidant ()
Green Chem., 2020, 22,471-477 DOI: 10.1039/C9GC03000J, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Nikolaos F. Nikitas, Dimitrios Ioannis Tzaras, Ierasia Triandafillidi, Christoforos G. Kokotos A mild and green photochemical protocol for the oxidation of alcohols to aldehydes and ketones was developed. The content of this RSS Feed (c) The Royal Society of Chemistry
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Iron-catalyzed cross-dehydrogenative coupling of indolin-2-ones with active methylenes for direct carbon–carbon double bond formation ()
Green Chem., 2020, 22,332-335 DOI: 10.1039/C9GC03639C, Communication Zhi-Yu Tan, Ke-Xin Wu, Lu-Shan Huang, Run-Shi Wu, Zheng-Yu Du, Da-Zhen Xu A novel iron-catalyzed cross-dehydrogenative coupling of two different C(sp3)–H bonds to synthesize olefins by using air as an ideal oxidant. The content of this RSS Feed (c) The Royal Society of Chemistry
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Continuous photochemical benzylic bromination using in situ generated Br2: process intensification towards optimal PMI and throughput ()
Green Chem., 2020, 22,448-454 DOI: 10.1039/C9GC03662H, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Alexander Steiner, Jason D. Williams, Oscar de Frutos, Juan A. Rincón, Carlos Mateos, C. Oliver Kappe Using a Br2 generator in flow process intensified conditions has been developed for photochemical benzylic bromination on a kg scale. The content of this RSS Feed (c) The Royal Society of Chemistry
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Solvent effect on xylose conversion under catalyst-free conditions: insights from molecular dynamics simulation and experiments ()
Green Chem., 2020, 22,532-539 DOI: 10.1039/C9GC03624E, Paper Qixuan Lin, Shouwei Liao, Libo Li, Weiying Li, Fengxia Yue, Feng Peng, Junli Ren In this study, experiments and molecular dynamics simulations were combined to get insights into the role of solvent during the process of xylose conversion under catalyst-free conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
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In water alkylation of amines with alcohols through a borrowing hydrogen process catalysed by ruthenium nanoparticles ()
Green Chem., 2020, 22,327-331 DOI: 10.1039/C9GC03351C, Communication Caterina Risi, Massimo Calamante, Elena Cini, Valentina Faltoni, Elena Petricci, Filippo Rosati, Maurizio Taddei Secondary amines are obtained with low environmental impact with a minimal amount of surfactants and organic solvents (biomass derived) employed only for product separation. The content of this RSS Feed (c) The Royal Society of Chemistry
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Degradable dual superlyophobic lignocellulosic fibers for high-efficiency oil/water separation ()
Green Chem., 2020, 22,504-512 DOI: 10.1039/C9GC03861B, Paper Lei Kang, Bin Wang, Jinsong Zeng, Zheng Cheng, Jinpeng Li, Jun Xu, Wenhua Gao, Kefu Chen A degradable dual lignocellulosic fiber with superwetting characteristics was successfully fabricated by a strategically adjusted condensation reaction of melamine and formaldehyde, maintaining high efficiency for oil/water mixture separation. The content of this RSS Feed (c) The Royal Society of Chemistry
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General sulfone construction via sulfur dioxide surrogate control ()
Green Chem., 2020, 22,322-326 DOI: 10.1039/C9GC03841H, Communication Shihao Chen, Yaping Li, Ming Wang, Xuefeng Jiang A highly efficient one-step synthesis of alkyl–alkyl and aryl–alkyl sulfones with tuneable masked “SO2” sources is described. The content of this RSS Feed (c) The Royal Society of Chemistry
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Electrochemical valorization of carboxylates in aqueous solution for the production of biofuels, fine chemicals, and hydrogen ()
Green Chem., 2020, 22,525-531 DOI: 10.1039/C9GC03007G, Paper Gang Yuan, Li Wang, Xiangwen Zhang, Rafael Luque, Qingfa Wang Naturally separated biofuels, hydrogen, and fine chemicals are simultaneously produced in aqueous solutions of biomass-derived carboxylates using aqueous substitution synthesized anodes. The content of this RSS Feed (c) The Royal Society of Chemistry
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Heterogeneous visible-light-induced Meerwein hydration reaction of alkenes in water using mpg-C3N4 as a recyclable photocatalyst ()
Green Chem., 2020, 22,411-416 DOI: 10.1039/C9GC03679B, Paper Jingjing Wang, Linshuang Xue, Mei Hong, Bangqing Ni, Tengfei Niu This work developed a visible-light promoted Meerwein hydration reaction by using mpg-C3N4 as recyclable photocatalyst in aqueous solution. The content of this RSS Feed (c) The Royal Society of Chemistry
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The direct transformation of bioethanol fermentation residues for production of high-quality resins ()
Green Chem., 2020, 22,439-447 DOI: 10.1039/C9GC03568K, Paper Bo Pang, Xue-Fei Cao, Shao-Ni Sun, Xi-Luan Wang, Jia-Long Wen, Su Shiung Lam, Tong-Qi Yuan, Run-Cang Sun The direct transformation of bioethanol fermentation residues for production of high-quality green resins. The content of this RSS Feed (c) The Royal Society of Chemistry
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A palladium-catalyzed oxidative aminocarbonylation reaction of alkynone O-methyloximes with amines and CO in PEG-400 ()
Green Chem., 2020, 22,465-470 DOI: 10.1039/C9GC03562A, Paper Jianxiao Li, Junsheng Yu, Wenfang Xiong, Hao Tang, Miao Hu, Wanqing Wu, Huanfeng Jiang A palladium-catalyzed oxidative aminocarbonylation of alkynone O-methyloximes with amines and CO using PEG-400 as an environmentally benign medium was accomplished. The content of this RSS Feed (c) The Royal Society of Chemistry
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Complete waste recycling strategies for improving the accessibility of rice protein films ()
Green Chem., 2020, 22,490-503 DOI: 10.1039/C9GC03354H, Paper Chengxin He, Yu Hu, Yong Wang, Yang Liao, Hua Xiong, Cordelia Selomulya, Juwu Hu, Qiang Zhao Waste recycling-Green chemistry technologies for the preparation of fully environment-friendly rice protein films with improved accessibility have been developed. The content of this RSS Feed (c) The Royal Society of Chemistry
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Waste minimized synthesis of pharmaceutically active compounds via heterogeneous manganese catalysed C–H oxidation in flow ()
Green Chem., 2020, 22,397-403 DOI: 10.1039/C9GC02961C, Paper Francesco Ferlin, Pilar María Luque Navarro, Yanlong Gu, Daniela Lanari, Luigi Vaccaro Herein, we present our results on the development of a continuous flow protocol enabling the waste minimised synthesis of relevant pharmaceuticals and natural compounds. The content of this RSS Feed (c) The Royal Society of Chemistry
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Selective oxidation of (hetero)sulfides with molecular oxygen under clean conditions ()
Green Chem., 2020, 22,433-438 DOI: 10.1039/C9GC03713F, Paper Kai-Jian Liu, Ji-Hui Deng, Jie Yang, Shao-Feng Gong, Ying-Wu Lin, Jun-Yi He, Zhong Cao, Wei-Min He The first example of selective oxidation of sulfides to sulfones and sulfoxides using molecular oxygen under clean conditions was established. The desired products could be easily collected through recrystallization in large-scale preparation. The content of this RSS Feed (c) The Royal Society of Chemistry
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Sustainable catalytic protocols for the solvent free epoxidation and anti-dihydroxylation of the alkene bonds of biorenewable terpene feedstocks using H2O2 as oxidant ()
Green Chem., 2020, 22,513-524 DOI: 10.1039/C9GC03208H, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. William B. Cunningham, Joshua D. Tibbetts, Marc Hutchby, Katarzyna A. Maltby, Matthew G. Davidson, Ulrich Hintermair, Pawel Plucinski, Steven D. Bull Solvent free catalytic epoxidation of biorenewable terpene feedstocks, including untreated crude sulfate turpentine. The content of this RSS Feed (c) The Royal Society of Chemistry
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A sustainable preparation of catalytically active and antibacterial cellulose metal nanocomposites via ball milling of cellulose ()
Green Chem., 2020, 22,455-464 DOI: 10.1039/C9GC02781E, Paper Joanna Kwiczak-Yiğitbaşı, Özge Laçin, Mine Demir, Recep Erdem Ahan, Urartu Özgür Şafak Şeker, Bilge Baytekin Mechanochemical production of cellulose–metal NP composites requires no capping or reducing agents, and yields antibacterial and catalytically active materials. The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal- and solvent-free direct C–H thiolation of aromatic compounds with sulfonyl chlorides ()
Green Chem., 2020, 22,427-432 DOI: 10.1039/C9GC03384J, Paper Feng Zhao, Qi Tan, Dahan Wang, Guo-Jun Deng A simple method for the direct thiolation of aromatic compounds using sulfonyl chlorides was developed under metal- and solvent-free conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Micro versus nanochannels: carbon micro-sieve tubes from biological phloem tissues for lithium–oxygen batteries ()
Green Chem., 2020, 22,388-396 DOI: 10.1039/C9GC03284C, Paper Zhuang Sun, Yuchen Zhang, Bin Sun, Chushu Yang, Tao Zhang Microscale sieve-tube carbon from biological phloem tissue goes much beyond nanoscale channel carbon, avoiding clogging and alleviating stability issues. The content of this RSS Feed (c) The Royal Society of Chemistry
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Continuous flow synthesis of menthol via tandem cyclisation–hydrogenation of citronellal catalysed by scrap catalytic converters ()
Green Chem., 2020, 22,379-387 DOI: 10.1039/C9GC03299A, Paper Alessio Zuliani, Camilla Maria Cova, Roberta Manno, Victor Sebastian, Antonio A. Romero, Rafael Luque A continuous flow synthesis of menthol in a tandem system using catalysts derived from the ceramic core of scrap catalytic converters is reported. The content of this RSS Feed (c) The Royal Society of Chemistry
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A ‘Trojan horse strategy’ for the development of a renewable leather tanning agent produced via an AlCl3-catalyzed cellulose depolymerization ()
Green Chem., 2020, 22,316-321 DOI: 10.1039/C9GC03538A, Communication Zhicheng Jiang, Wei Ding, Shuguang Xu, Javier Remón, Bi Shi, Changwei Hu, James H. Clark The oligosaccharides from AlCl3-catalyzed cellulose depolymerization improve penetration of Al ion into the skin matrix for further crosslinking reaction. The content of this RSS Feed (c) The Royal Society of Chemistry
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Efficient reductive amination of HMF with well dispersed Pd nanoparticles immobilized in a porous MOF/polymer composite ()
Green Chem., 2020, 22,368-378 DOI: 10.1039/C9GC03140E, Paper Vikram V. Karve, Daniel T. Sun, Olga Trukhina, Shuliang Yang, Emad Oveisi, Jeremy Luterbacher, Wendy L. Queen Making heterogeneous catalysis greener by improving nanoparticle stability in a MOF support modified with short polymeric chains. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ultra-fast pyrolysis of lignocellulose using highly tuned microwaves: synergistic effect of a cylindrical cavity resonator and a frequency-auto-tracking solid-state microwave generator ()
Green Chem., 2020, 22,342-351 DOI: 10.1039/C9GC02745A, Paper Shuntaro Tsubaki, Yuki Nakasako, Noriko Ohara, Masateru Nishioka, Satoshi Fujii, Yuji Wada Precisely tuned microwaves facilitate rapid pyrolysis of lignocellulose. The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal-free graphene oxide-catalyzed aza-semipinacol rearrangement to prepare 2-(indol-2-yl)phenols and benzofuro[3,2-b]indolines containing quaternary carbon centers ()
Green Chem., 2020, 22,404-410 DOI: 10.1039/C9GC03345A, Paper Hong-Ping Zhao, Gui-Chao Liang, Shu-Min Nie, Xiuqiang Lu, Cheng-Xue Pan, Xin-Xian Zhong, Gui-Fa Su, Dong-Liang Mo A metal-free, heterogeneous, inexpensive, and environmentally friendly graphene oxide-catalyzed aza-semipinacol rearrangement was developed to prepare various 2-(indol-2-yl)phenols and benzofuro[3,2-b]indolines in good to excellent yields. The content of this RSS Feed (c) The Royal Society of Chemistry
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An environment-friendly approach to produce nanostructured germanium anodes for lithium-ion batteries ()
Green Chem., 2020, 22,359-367 DOI: 10.1039/C9GC02348H, Paper Evgeniya A. Saverina, Visweshwar Sivasankaran, Roman R. Kapaev, Alexey S. Galushko, Valentine P. Ananikov, Mikhail P. Egorov, Viatcheslav V. Jouikov, Pavel A. Troshin, Mikhail A. Syroeshkin A halogen-free process for the preparation of germanium nano-structured particles from germanium citrate, an easily accessible and environment-friendly precursor formed from germanium dioxide and citric acid in an aqueous medium, is proposed. The content of this RSS Feed (c) The Royal Society of Chemistry
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A new strategy for CO2 utilization with waste plastics: conversion of hydrogen carbonate into formate using polyvinyl chloride in water ()
Green Chem., 2020, 22,352-358 DOI: 10.1039/C9GC02484K, Paper Lihui Lu, Heng Zhong, Tianfu Wang, Jianeng Wu, Fangming Jin, Toshiaki Yoshioka A new and green approach for hydrogen carbonate reduction and PVC dechlorination in water in a single step. The content of this RSS Feed (c) The Royal Society of Chemistry
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Greening Fmoc/tBu Solid-Phase Peptide Synthesis ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC03982A, Critical Review Fernando Albericio, Othman Al Musaimi, Beatriz G. de la Torre Peptides are gaining considerable attention as potential drugs. The so-called Fmoc/tBu Solid-Phase Synthesis is the method of choice for the synthesis of these molecules in both research and industrial settings.... The content of this RSS Feed (c) The Royal Society of Chemistry
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Site-selective 1,3-Double Functionalization of Arenes Using para-Quinol, C-N, and C-C/C-P Three-Component Coupling ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC04103F, Communication Saddam Husen, Anil Chauhan, Ravindra Kumar A catalytic and site-selective approach has been demonstrated for dual functionalization of arenes via cross-coupling reactions of p-quinols with amines and isocyanides/phosphites. The strategy enables to yield a series of... The content of this RSS Feed (c) The Royal Society of Chemistry
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Selective Hydrodeoxygenation of Lignin Phenols to Alcohols in Aqueous Phase over Hierarchical Nb2O5-Supported Ni Catalyst ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC03842F, Paper Wenjing Song, Yanyan He, Sitong Lai, Weikun Lai, Xiaodong Yi, Weimin Yang, Xingmao Jiang It is a challenge to promote aqueous-phase precise conversion of renewable lignin to valuable chemical building blocks via engineering transition metal catalyst. Motivated by water effect in promoting the catalytic... The content of this RSS Feed (c) The Royal Society of Chemistry
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Waterborne isocyanate-free polyurethane epoxy hybrid coatings synthesized from sustainable fatty acid diamine ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC03335A, Paper Cheng Zhang, Haoran Wang, Qixin Zhou The coatings industry is increasingly aware of the need to protect the environment and is constantly striving to ensure the safety of the industry and the health of consumers, which... The content of this RSS Feed (c) The Royal Society of Chemistry
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Scrap waste automotive converters as efficient catalysts for the continuous-flow hydrogenations of biomass-derived chemicals ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC04091A, Paper Camilla Cova, Alessio Zuliani, Roberta Manno, Victor Sebastian, Rafael Luque The catalytic activity of the scrap ceramic-core of automotive catalytic converters (SCATs) was investigated in the continuous-flow hydrogenation of different biomass derived chemicals. The waste SCATs powders were deeply characterized... The content of this RSS Feed (c) The Royal Society of Chemistry
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Regio/Site-Selective Alkylation of Substrates Containing the Cis-, 1,2- or 1,3-Diol with Ferric Chloride and Dipivaloylmethane as the Catalytic System ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC04126E, Communication Jian Lv, Yu Liu, Jia-Jia Zhu, Dapeng Zou, Hai Dong In this study, we reported the regio/site-selective alkylation of diols and polyols with FeCl3 as a key catalyst. A catalytic system consisting of FeCl3 (0.01 – 0.1 equiv) and dipivaloylmethane... The content of this RSS Feed (c) The Royal Society of Chemistry
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Solvent-free tactics to realize substitution of I- for IO3- in BiOIO3 photocatalyst with opposite charge transferring path ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC03731D, Paper Jing Xie, Yali Cao, Jindou Hu, Yakun Tang, Dianzen Jia Substitutional doping was an effective way to improve photocatalytic activity, while individual ion is substituted for atomic group has always been difficult to achieve. Herein, a simple in situ solvent-free... The content of this RSS Feed (c) The Royal Society of Chemistry
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Thermal [2 + 2]-cycloaddition between silylalkynes and allenylphenols followed by the nucleophilic addition of water: metal-free and economical synthesis of arylcyclobutenals ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC04184B, Paper Shohei Ohno, Ramon Francisco Avena, Hiroshi Aoyama, Hiromichi Fujioka, Mitsuhiro Arisawa A novel thermal [2 + 2]-cycloaddition between silylalkynes and allenylphenols to form a cyclobutachromene intermediate, followed by the nucleophilic addition of water to yield functionalized arylcyclobutenals. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Smart and sustainable design of latent catalyst-containing benzoxazine-bio-resins and application studies ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03504D, Paper Kan Zhang, Yuqi Liu, Mengchao Han, Pablo Froimowicz A fully bio-based benzoxazine containing latent catalytic system is designed and successfully synthesized and it can be used as both an initiator and a beneficial property modifier of other thermosetting systems, especially for fire related properties. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Temperature-controlled regioselective thiolation of 2-indolylmethanols under aqueous micellar conditions ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC04155A, Communication Shengzhen Zhu, Yu Zhang, Jinyue Luo, Fei Wang, Xiaoji Cao, Shenlin Huang Micelle-assisted, temperature-enabled regiodivergent thiolation of 2-indolylmethanols in water under mild conditions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Fully bio-derived CO2 polymers for non-isocyanate based polyurethane synthesis ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03488A, Paper Sarah-Elisabeth Dechent, Arjan W. Kleij, Gerrit A. Luinstra The synthesis of partly carbonated polybutadienes (PC-PBDs) was developed starting from partly epoxidized polybutadienes (PE-PBDs) and CO2 as renewable feedstock. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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An excellent anode renders protic ionic liquids sustainable in metal electrodeposition ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC04169A, Communication Yi-Ting Chen, Hsing-Yin Chen, Yu-Shan Chien, Min-Chieh Chuang, Po-Yu Chen The decomposition of ionic liquids at the anode during metal electrodeposition is substituted by the OER to extend the lives of ionic liquids. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Generation of Ironized and Multivitamin-loaded Liposomes Using Venturi-based Rapid Expansion of Supercritical Solution (Vent-RESS) ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC04018H, Paper Farrokh Sharifi, Apartim Jash, Alireza Abbaspourrad, Syed Rizvi Ironized Multivitamin loaded liposomes were generated via Supercritical CO2 (SC-CO2) as a green solvent without using any organic solvent. We coupled the Venturi effect and rapid expansion of supercritical solvent... The content of this RSS Feed (c) The Royal Society of Chemistry
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Recycling non-food-grade tree gum wastes into nanoporous carbon for sustainable energy harvester ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC04310A, Paper Abhilash Venkateshaiah, Jun Young Cheong, Sung-Ho Shin, Akshay Kumar K. P , Tae Gwang Yun, Jaehyeong Bae, Stanislaw Wacławek, Miroslav Cernik, Seema Agarwal, Andreas Greiner, Vinod vellora thekkaepadil, Il-Doo Kim, Rajender S Varma The disposal of natural wastes has become a global problem and the use of lower-grade gums is very limited, owing to their impurities as well as sticky nature. Rather than... The content of this RSS Feed (c) The Royal Society of Chemistry
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Selective Conversion of Lignin to Ethylbenzene ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC04246F, Paper Zhicheng Luo, Shufang Qin, Shuang Chen, Yingshuang Hui, Chen Zhao Lignin, an abundant renewable aromatic resource, has a complex structure composed of various C9 propyl phenol units with cross-linked C-C, ester and ether linkages. Herein, we report a two-step process... The content of this RSS Feed (c) The Royal Society of Chemistry
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CO2 hydrogenation to formic acid over heterogenized ruthenium catalysts using a fixed bed reactor with separation units ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC03685G, Paper Kwangho Park, Gunniya Hariyanandam Gunasekar, Seong-Hoon Kim, Hongjin Park, Samhwan Kim, Kiyoung Park, Kwang-Deog Jung, Sungho Yoon Along with the mitigation of CO2 emission, recently, the CO2-derived formic acid process has drawn attention as a promising platform for the renewable-energy-derived hydrogen storage cycle by using formic acid... The content of this RSS Feed (c) The Royal Society of Chemistry
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A more sustainable and highly practicable synthesis of aliphatic isocyanides ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC04070F, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. K. A. Waibel, R. Nickisch, N. Möhl, R. Seim, M. A. R. Meier A more sustainable and easier applicable synthesis of aliphatic isocyanides in DMC is introduced using non-hazardous p-toluenesulfonyl chloride as dehydration reagent. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A fully biomass based monomer from itaconic acid and eugenol to build degradable thermosets via thiol–ene click chemistry ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03931G, Paper Yazhou Tian, Qiong Wang, Jue Cheng, Junying Zhang A fully biomass based monomer (EUIT) was designed and synthesized from itaconic acid (IA) and eugenol (EU). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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The salt-free nickel-catalysed α-allylation reaction of ketones with allyl alcohol and diallylether ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03619A, Paper Bouchaib Mouhsine, Abdallah Karim, Clément Dumont, Mathieu Sauthier The alpha-allylation of ketones will allyl alcohol was performed thanks to the use of nickel-based catalysts. No base nor additive needed! To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Freeze–thaw repetition as an auxiliary method to promote efficient separation of hemicellulose from poplar ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03792F, Paper Huixia Zhu, Qianli Ma, Jie Sheng, Rendang Yang The application of freeze–thaw repetition as a pretreatment method in hydrothermal treatment and green upgradation of poplar biomass has been investigated. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Greener synthesis of lignin nanoparticles and their applications ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC02835H, Critical Review Siavash Iravani, Rajender S. Varma Greener synthesis of lignin nanoparticles and their important biomedical applications are discussed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly dispersed Ni2P nanoparticles on N,P-codoped carbon for efficient cross-dehydrogenative coupling to access alkynyl thioethers ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC04137K, Communication Tao Song, Peng Ren, Jianliang Xiao, Youzhu Yuan, Yong Yang A Ni2P nanoparticle dispersed on N,P-codoped carbon material was developed for efficient synthesis of alkynyl thioethers via a cross-dehydrogenative coupling (CDC) strategy under base- and ligand-free conditions using air as the oxidant. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A cytochrome c-urea functionalized dipeptide conjugate: an efficient HBD framework to synthesize 4H-pyrans via one-pot multicomponent reaction ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03512E, Paper Sanjeev Saini, Mayank, Navneet Kaur, Narinder Singh This work is focused on the development of an efficient and green protocol for the one-pot multicomponent synthesis of a series of 4H-pyran derivatives. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Introducing the Tishchenko reaction into sustainable polymer chemistry ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03926K, Communication Tianhua Ren, Qin Chen, Changbo Zhao, Qiang Zheng, Haibo Xie, Michael North The combination of the Williamson and Tishchenko reactions produced a series of new α,ω-diene functionalized carboxylic ester, by which serials of polyesters have been prepared successfully. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Pd@COF-QA: A phase transfer composite catalyst for aqueous Suzuki-Miyaura coupling reaction ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC03718G, Communication Yu-Bin Dong, Jian-Cheng Wang, Cong-Xue Liu, Xuan Kan, Xiaowei Wu, Jinlan Kan A Pd NP loaded and paraffin-chain quaternary ammonium salt decorated covalent framework Pd@COF-QA and its chitosan aerogel-based continuous flow-through reactor, which can be an excellent phase transfer catalyst to promote... The content of this RSS Feed (c) The Royal Society of Chemistry
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Photochemical evolution of hydrogen peroxide on lignins ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC04324A, Communication Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Eva Miglbauer, Maciej Gryszel, Eric Daniel Glowacki Means of sustainable on-demand hydrogen peroxide production are sought after for numerous industrial, agricultural, and environmental applications. Herein we present the capacity of lignin and lignin sulfonate to behave as... The content of this RSS Feed (c) The Royal Society of Chemistry
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Mechanistic insights into lignin dissolution behaviors of recyclable acid hydrotrope, deep eutectic solvent (DES), and ionic liquid (IL) ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC02760B, Paper Hairui Ji, Pingli Lv Currently, the recyclable acid hydrotrope (p-TsOH), deep eutectic solvent (DES, ChCl-Lac), and ionic liquid (IL, [Amim][Cl]) are receiving more attentions due to their better delignification performances. However, very few mechanistic... The content of this RSS Feed (c) The Royal Society of Chemistry
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Hydrogen production from formic acid catalyzed by a phosphine free manganese complex: investigation and mechanistic insights ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC02453K, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Alexander Léval, Anastasiya Agapova, Christoph Steinlechner, Elisabetta Alberico, Henrik Junge, Matthias Beller Formic acid dehydrogenation (FAD) is considered as a promising process in the context of hydrogen storage. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Microwave assisted unprotected Sonogashira reaction in water for the synthesis of multi-replaced aromatic acetylene compounds ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC04051J, Paper Yucheng Tian, Jubo Wang, Xinying Cheng, Kang Liu, Tizhi Wu, Xiaqiu Qiu, Zijian Kuang, Zhiyu Li, Jinlei Bian A microwave-assisted, efficient and rapid Sonogashira reaction was developed for the synthesis of polysubstituted aromatic alkynes. The reaction was environmentally friendly and easy to handle by replacing traditional amine solvents... The content of this RSS Feed (c) The Royal Society of Chemistry
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Visible light assisted reduction of CO2 into formaldehyde by heteroleptic ruthenium metal complex-TiO2 Hybrid in aqueous medium ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC03549D, Paper Alok Kumar, Rajakumar Ananthakrishnan Photocatalytic reductions of CO2 and its simultaneous functionalization is a profound journey to achieve in an ambient condition. In the current research, precedent exists for the formation of HCHO, HCOOH,... The content of this RSS Feed (c) The Royal Society of Chemistry
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Design of nitrogen-doped graphitized 2D hierarchical porous carbons as efficient solid base catalysts for transesterification to biodiesel ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03960K, Paper Weiping Kong, Fujian Liu, Yong Liu 2D graphitized porous carbons decorated with high contents of nitrogen sites such as pyridinic nitrogen were developed, which were used as efficient and reusable solid base catalysts for transesterification to biodiesel. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Recent Advances in Selectively Catalytic Hydrodeoxygenation of Lignin-derived Oxygenates to Arenes ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC02762A, Tutorial Review Jiangho Zhang, Junming Sun, Yong Wang Utilization of the lignin-derived compounds is an important part of biomass valorization. One promising way to achieve this goal is to reduce/eliminate the oxygen content via hydrodeoxygenation (HDO), producing valuable... The content of this RSS Feed (c) The Royal Society of Chemistry
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Photocatalyst- and transition-metal-free α-allylation of N-aryl tetrahydroisoquinolines mediated by visible light ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC04191E, Communication Zhuohua Li, Pengju Ma, Yongzhu Tan, Yufei Liu, Min Gao, Yujun Zhang, Bo Yang, Xuan Huang, Yuan Gao, Junmin Zhang A convenient and efficient α-allylation of N-aryl tetrahydroisoquinolines has been achieved. This transformation can be realized under only visible light irradiation without the aid of transition metals or photocatalysts. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of α-enaminones from cyclic ketones and anilines using oxoammonium salt as an oxygen transfer reagent ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03845K, Communication Biping Xu, Yaping Shang, Xiaoming Jie, Xiaofeng Zhang, Jian Kan, Subhash Laxman Yedage, Weiping Su A convenient synthesis of α-enaminones from cyclic ketones with anilines at room temperature via an oxygen-atom-transfer pathway of oxoammonium salt. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalytic O-H Bond Insertion Reactions Using Surface Modified Sewage Sludge as Catalyst ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC03428E, Paper Zhipeng Zhang, Yang Yu, Fei Huang, Xiangyan Yi, Yao Xu, Yide He, Jonathan Baell, He Huang Developing greener, sustainable catalyst is very important but challenging task in organic synthesis. Herein, for the first time, we choose more economically and greener surface modification of sewage sludge-derived carbonaceous... The content of this RSS Feed (c) The Royal Society of Chemistry
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The potential of decarbonising rice and wheat by incorporating carbon capture, utilisation and storage into fertiliser production ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03746B, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. A. Gonzalez-Diaz, L. Jiang, A. P. Roskilly, A. J. Smallbone This paper evaluates the reduction on greenhouse gas emissions in rice and wheat and their supply chains by incorporating CCUS into fertiliser production mainly from ammonia process, which is the section of fertiliser that produces the most CO2. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Environmentally benign multiphase solid–liquid–gas catalysis ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC04063C, Paper Xueli Bai, Nianze Song, Liang Wen, Xin Huang, Jian Zhang, Yue Zhang, Yongxiang Zhao It is significant for the environment that molecular oxygen replaces conventional heavy metal-containing or toxic oxidants to participate in oxidation reactions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Tandem Selective Reduction of Nitroarenes Catalyzed by Palladium Nanoclusters ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC03957K, Paper Ziqiang Yan, Xiaoyu Xie, Qun Song, Fulei Ma, Xinyu Sui, Ziyu Huo, Mingming Ma We report a catalytic tandem reduction of nitroarenes by sodium borohydride (NaBH4) in aqueous solution at ambient conditions, which can selectively produce five categories of nitrogen-containing compounds: anilines, N-aryl hydroxylamines,... The content of this RSS Feed (c) The Royal Society of Chemistry
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Template-free Synthesis of Graphene-like Carbons as Efficient Carbocatalysts for Selective Oxidation of Alkanes ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC03781K, Paper Xiang Hu, Yuchuan Liu, Haitao Huang, Bao-Bing Huang, Guoliang Chai, Zailai Xie Selective oxidation of aromatic alkanes by C-H activation is one of the key reactions in organic synthesis and chemical industry. It is of particular interest to activate C-H bond to... The content of this RSS Feed (c) The Royal Society of Chemistry
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Facile synthesis of “digestible”, rigid-and-flexible, and bio-based building block for high-performance degradable thermosetting plastics ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC04020J, Paper Binbo Wang, Songqi Ma, Qiong Li, Hua Zhang, Junjie Liu, Rong Wang, Zhiquan Chen, Xiwei Xu, Sheng Wang, na lu, yanlin liu, Shifeng Yan, Jin Zhu Plastics are indispensable in modern society, but non-sustainable sources, releasing hazards during service life, and post-disposal issues put the traditional plastics at risk. Here, we report a “digestible”, rigid-and-flexible and... The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalyst-free vitrimer elastomers based on a dimer acid: robust mechanical performance, adaptability and hydrothermal recyclability ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC04080C, Paper Yingyi Li, Tuan Liu, Shuai Zhang, Lin Shao, Mingen Fei, Hui Yu, Jinwen Zhang This work introduces a feasible method for the preparation of catalyst-free vegetable oil based vitrimer elastomers with excellent mechanical and recycling properties. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Cycloamination strategies for renewable N-heterocycles ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03655E, Critical Review Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Hu Li, Haixin Guo, Zhen Fang, Taku Michael Aida, Richard Lee Smith Efficient amination strategies for synthesis of N-heterocycles from functional molecules (bottom-up) or from biomass (top-down) via sustainable C–N/C–X bond chemistry. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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An Unconventional Sulfur-to-Selenium-to-Carbon Radical Transfer: Chemo-and Regioselective Cyclization of Yne-Ynamides ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC03745D, Communication Shubham Dutta, B. Prabagar, Rajeshwer Vanjari, Vincent Gandon, Akhila Kumar Sahoo An uncommon sulfur→selenium→carbon radical transfer process is employed to develop an unprecedented selenyl radical-mediated regioselective cyclization of yne-tethered-ynamides. Density functional theory studies and HRMS experiments are used to establish a... The content of this RSS Feed (c) The Royal Society of Chemistry
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Electroactivated alkylation of amines with alcohols via both direct and indirect borrowing hydrogen mechanisms ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03747K, Paper Benjamin Appiagyei, Souful Bhatia, Gabriela L. Keeney, Troy Dolmetsch, James E. Jackson Aqueous electrocatalytic alkylation of amines with alcohol; water is the only byproduct. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Total hydrogenation of bio-derived furans over supported Ru subnanoclusters prepared via amino acid-assisted deposition ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC02943E, Paper Yang Qian, Ze-Jun Li, Xian-Long Du, Qi Zhang, Yi Zhao, Yong-Mei Liu, Yong Cao Development of efficient catalyst with reduced noble metal usage is extremely desirable for selective hydrogenations of furan-containing bio-based feedstocks, which represents an attractive and sustainable alternative to petrochemical resources. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Enhancing the electrocatalytic activity of CoO for the oxidation of 5-hydroxymethylfurfural by introducing oxygen vacancies ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03698A, Paper Xin Huang, Jinliang Song, Manli Hua, Zhenbing Xie, Shuaishuai Liu, Tianbin Wu, Guanying Yang, Buxing Han The activity of CoO for the electrocatalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid could be significantly enhanced by introducing oxygen vacancies via Se doping. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ecotoxicological assessment of pharmaceuticals and personal care products using predictive toxicology approaches ()
Green Chem., 2020, Accepted Manuscript DOI: 10.1039/C9GC03265G, Critical Review Supratik Kar, Hans Sanderson, Kunal Roy, Emilio Benfenati, Jerzy Leszczynski The use of active pharmaceutical ingredients (APIs) and personal care products (PCPs) is growing day by day in all over the world. Thus, these materials have appearedas the contaminants of... The content of this RSS Feed (c) The Royal Society of Chemistry
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Towards environmentally benign capture and conversion: heterogeneous metal catalyzed CO2 hydrogenation in CO2 capture solvents ()
Green Chem., 2020, Advance Article DOI: 10.1039/C9GC03449H, Paper Jotheeswari Kothandaraman, David J. Heldebrant The transformation of captured CO2 into value-added chemicals to mitigate increasing CO2 concentration in the atmosphere has gained significant attention recently. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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