Green Chemistry

Highly Stable Ru/LaCO3OH Catalyst Consisting of Support-coated Ru Nanoparticles in Aqueous-Phase Hydrogenolysis Reactions ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02414B, Paper Bolong Li, Lulu Li, Chen Zhao Hydrothermal reduction under aqueous conditions is widely used to convert biomass into more valuable products. However, the harsh conditions inherent in the process can irreversibly alter the intrinsic structure of... The content of this RSS Feed (c) The Royal Society of Chemistry
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A new selective route towards benzoic acid and derivatives from biomass-derived coumalic acid ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC02041D, Paper Toni Pfennig, Jack M. Carraher, Ashwin Chemburkar, Robert L. Johnson, Austin T. Anderson, Jean-Philippe Tessonnier, Matthew Neurock, Brent H. Shanks The selective production of aromatics from bio-based sources is an area of interest to expand the potential for greener alternatives to petroleum-derived chemicals. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Immobilized bifunctional phosphonium salts as recyclable organocatalysts in the cycloaddition of CO2 and epoxides ()
Green Chem., 2017, 19,4435-4445 DOI: 10.1039/C7GC01782K, Paper J. Steinbauer, L. Longwitz, M. Frank, J. Epping, U. Kragl, T. Werner An immobilized bifunctional phosphonium salt catalyst efficiently catalyzed the synthesis of cyclic carbonates under mild conditions, and was reused up to 15 times. The content of this RSS Feed (c) The Royal Society of Chemistry
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Composition-tunable synthesis of "clean" syngas via a one-step synthesis of metal-free pyridinic-N-enriched self-supported CNTs: the synergy of electrocatalyst pyrolysis temperature and potential ()
Green Chem., 2017, 19,4284-4288 DOI: 10.1039/C7GC01095H, Communication Kai-Hua Liu, Hai-Xia Zhong, Xiao-Yang Yang, Di Bao, Fan-Lu Meng, Jun-Min Yan, Xin-Bo Zhang Exploring efficient and environmentally friendly ways for producing clean syngas is of great significance for realizing an artificial carbon cycle associated with clean and renewable energy. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of ethanol from paraformaldehyde, CO2 and H2 ()
Green Chem., 2017, 19,4396-4401 DOI: 10.1039/C7GC01887H, Paper Jingjing Zhang, Qingli Qian, Meng Cui, Chunjun Chen, Shuaishuai Liu, Buxing Han Ethanol is highly efficiently produced from paraformaldehyde, CO2 and H2 by homogeneous catalysis under mild conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Environmental impact assessment of wheat straw based alkyl polyglucosides produced using novel chemical approaches ()
Green Chem., 2017, 19,4380-4395 DOI: 10.1039/C7GC01719G, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. K. Lokesh, C. West, J. Kuylenstierna, J. Fan, V. Budarin, P. Priecel, J. A. Lopez-Sanchez, J. Clark A comparative environmental life cycle assessment of using low-value wheat straw to produce high value biosurfactants using a novel biorefinery, compared to those produced from palm and wheat, is reported. The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal-free oxidative cyclization of 2-aminobenzothiazoles and cyclic ketones enabled by the combination of elemental sulfur and oxygen ()
Green Chem., 2017, 19,4294-4298 DOI: 10.1039/C7GC02014G, Communication Yanjun Xie, Xiangui Chen, Zhen Wang, Huawen Huang, Bing Yi, Guo-Jun Deng Aerobic cyclization of 2-aminobenzothiazoles and cyclic ketones enabled by the combination of elemental sulfur and oxygen under metal-free conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Photoorganocatalytic synthesis of lactones via a selective C-H activation-alkylation of alcohols ()
Green Chem., 2017, 19,4451-4456 DOI: 10.1039/C7GC01903C, Paper Nikolaos Kaplaneris, Aikaterini Bisticha, Giorgos N. Papadopoulos, Dimitris Limnios, Christoforos G. Kokotos Photoorganocatalytic C-H activation of alcohols for the synthesis of lactones. The content of this RSS Feed (c) The Royal Society of Chemistry
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Elemental sulfur as a polyvalent reagent in redox condensation with o-chloronitrobenzenes and benzaldehydes: three-component access to 2-arylbenzothiazoles ()
Green Chem., 2017, 19,4289-4293 DOI: 10.1039/C7GC01825H, Communication Le Anh Nguyen, Quoc Anh Ngo, Pascal Retailleau, Thanh Binh Nguyen Sulfur was found to be a polyvalent reagent in the multicomponent redox condensation with o-chloronitrobenzenes and benzaldehydes to 2-arylbenzothiazoles. The content of this RSS Feed (c) The Royal Society of Chemistry
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Chemisorption of CO2 by chitosan oligosaccharide/DMSO: organic carbamato-carbonato bond formation ()
Green Chem., 2017, 19,4305-4314 DOI: 10.1039/C7GC01830D, Paper Abdussalam K. Qaroush, Khaleel I. Assaf, Sanaa K. Bardaweel, Ala'a Al-Khateeb, Fatima Alsoubani, Esraa Al-Ramahi, Mahmoud Masri, Thomas Bruck, Carsten Troll, Bernhard Rieger, Ala'a F. Eftaiha A novel oligochitosan/DMSO system as a green sorbent for CO2 capturing. The content of this RSS Feed (c) The Royal Society of Chemistry
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Carbon nitride assisted chemoselective C-H bond photo-oxidation of alkylphenolethoxylates in water medium ()
Green Chem., 2017, 19,4299-4304 DOI: 10.1039/C7GC01588G, Communication M. Ilkaeva, I. Krivtsov, E. Bartashevich, S. A. Khainakov, J. R. Garcia, E. Diaz, S. Ordonez H2O2-modified carbon nitride chemoselectively photo-oxidises the methyl group of alkylphenoxylate molecule 2-(4-methylphenoxy)ehanol in water medium. The content of this RSS Feed (c) The Royal Society of Chemistry
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An atom-economical protocol for direct conversion of Baylis-Hillman alcohols to [small beta]-chloro aldehydes in water ()
Green Chem., 2017, 19,4446-4450 DOI: 10.1039/C7GC01483J, Paper Raktani Bikshapathi, Sai Prathima Parvathaneni, Vaidya Jayathirtha Rao This paper describes an atom-economical strategy for the direct conversion of Baylis-Hillman alcohols to [small beta]-chloro aldehydes under metal free conditions with excellent functional group tolerance. The content of this RSS Feed (c) The Royal Society of Chemistry
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Controlling silicone-saccharide interfaces: greening silicones ()
Green Chem., 2017, 19,4373-4379 DOI: 10.1039/C7GC02088K, Paper Benjamin Macphail, Michael A. Brook (Poly)saccharides crosslink silicone boronic acid polymers and stabilize the silicone oil/water interface. The content of this RSS Feed (c) The Royal Society of Chemistry
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Exploiting H-transfer as a tool for the catalytic reduction of bio-based building blocks: the gas-phase production of 2-methylfurfural using a FeVO4 catalyst ()
Green Chem., 2017, 19,4412-4422 DOI: 10.1039/C7GC01749A, Paper L. Grazia, D. Bonincontro, A. Lolli, T. Tabanelli, C. Lucarelli, S. Albonetti, F. Cavani A new reductive process in the field of biomass valorisation for the sustainable production of bio-fuel additives and chemicals. The content of this RSS Feed (c) The Royal Society of Chemistry
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Benign-by-design preparation of humin-based iron oxide catalytic nanocomposites ()
Green Chem., 2017, 19,4423-4434 DOI: 10.1039/C7GC01405H, Paper Layla Filiciotto, Alina M. Balu, Antonio A. Romero, Enrique Rodriguez-Castellon, Jan C. van der Waal, Rafael Luque Catalytic nanocomposites can be prepared via solvent-free methodologies using biomass-derived humin by-products and iron salts, found active in the conversion of isoeugenol to vanillin. The content of this RSS Feed (c) The Royal Society of Chemistry
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Isomerization of glucose to fructose catalyzed by lithium bromide in water ()
Green Chem., 2017, 19,4402-4411 DOI: 10.1039/C7GC02145C, Paper Chang Geun Yoo, Ning Li, Melanie Swannell, Xuejun Pan Both Br- and Li+ catalyzed the isomerization of glucose in aqueous lithium bromide solution. The content of this RSS Feed (c) The Royal Society of Chemistry
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Oximes as reusable templates for the synthesis of ureas and carbamates by an in situ generation of carbamoyl oximes ()
Green Chem., 2017, 19,4272-4277 DOI: 10.1039/C7GC01449J, Communication Gopal Chandru Senadi, Mohana Reddy Mutra, Ting-Yi Lu, Jeh-Jeng Wang Oximes have been identified as reusable templates for the synthesis of ureas and carbamates by an in situ generation of carbamoyl oximes under metal-free conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
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A promising catalyst for exclusive para hydroxylation of substituted aromatic hydrocarbons under UV light ()
Green Chem., 2017, 19,4278-4283 DOI: 10.1039/C7GC01653K, Communication Vijay Kumar Das, Satyabrat Gogoi, Boyapati Manoranjan Choudary, Niranjan Karak Herein, we describe a waterborne polymer/carbon dot nanocomposite system as an efficient, resourceful and sustainable photocatalyst for para-selective hydroxylation of substituted aromatic compounds using H2O2 under UV light. The content of this RSS Feed (c) The Royal Society of Chemistry
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A multidisciplinary investigation of the technical and environmental performances of TAML/peroxide elimination of Bisphenol A compounds from water ()
Green Chem., 2017, 19,4234-4262 DOI: 10.1039/C7GC01415E, Critical Review Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Yusuf Onundi, Bethany A. Drake, Ryan T. Malecky, Matthew A. DeNardo, Matthew R. Mills, Soumen Kundu, Alexander D. Ryabov, Evan S. Beach, Colin P. Horwitz, Michael T. Simonich, Lisa Truong, Robert L. Tanguay, L. James Wright, Naresh Singhal, Terrence J. Collins A multidisciplinary investigation of the technical and environmental performances of TAML/peroxide elimination of Bisphenol A compounds from water: destruction, oligomerisation, mechanisms, end product toxicity, and applications. The content of this RSS Feed (c) The Royal Society of Chemistry
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Selective cleavage of ester linkages of anhydride-cured epoxy using a benign method and reuse of the decomposed polymer in new epoxy preparation ()
Green Chem., 2017, 19,4364-4372 DOI: 10.1039/C7GC01737E, Paper Tuan Liu, Xiaolong Guo, Wangcheng Liu, Cheng Hao, Liwei Wang, William C. Hiscox, Chengyun Liu, Can Jin, Junna Xin, Jinwen Zhang This work offers a successful loop-closing strategy for increasing the sustainability and lowering the manufacturing cost of epoxy materials. The content of this RSS Feed (c) The Royal Society of Chemistry
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Proof of concept for continuous enantioselective liquid-liquid extraction in capillary microreactors using 1-octanol as a sustainable solvent ()
Green Chem., 2017, 19,4334-4343 DOI: 10.1039/C7GC01700F, Paper Susanti, Tim G. Meinds, Erik B. Pinxterhuis, Boelo Schuur, Johannes G. de Vries, Ben L. Feringa, Jozef G. M. Winkelman, Jun Yue, Hero J. Heeres Separation of racemates in microreactors using liquid-liquid extraction with 1-octanol as the solvent is successfully demonstrated. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly efficient synchronized production of phenol and 2,5-dimethylfuran through a bimetallic Ni-Cu catalyzed dehydrogenation-hydrogenation coupling process without any external hydrogen and oxygen supply ()
Green Chem., 2017, 19,4353-4363 DOI: 10.1039/C7GC01387F, Paper Wei Li, Guoli Fan, Lan Yang, Feng Li Highly efficient synchronized production of phenol and 2,5-dimethylfuran was achieved via a bimetallic Ni-Cu catalyzed dehydrogenation-hydrogenation coupling process. The content of this RSS Feed (c) The Royal Society of Chemistry
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Glucose promoted facile reduction of azides to amines under aqueous alkaline conditions ()
Green Chem., 2017, 19,4268-4271 DOI: 10.1039/C7GC01593C, Communication Nisha Chandna, Fatehjeet Kaur, Shobhna Kumar, Nidhi Jain A quick and efficient method for the reduction of azides to amines in water using D-glucose and KOH as green reagents is reported. The content of this RSS Feed (c) The Royal Society of Chemistry
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Tandem deprotection/coupling for peptide synthesis in water at room temperature ()
Green Chem., 2017, 19,4263-4267 DOI: 10.1039/C7GC01575E, Communication Margery Cortes-Clerget, Jean-Yves Berthon, Isabelle Krolikiewicz-Renimel, Laurent Chaisemartin, Bruce H. Lipshutz A tandem deprotection/coupling sequence is reported for solution-phase peptide synthesis in water under micellar catalysis conditions using the designer surfactant TPGS-750-M. The content of this RSS Feed (c) The Royal Society of Chemistry
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Lignin transformations for high value applications: towards targeted modifications using green chemistry ()
Green Chem., 2017, 19,4200-4233 DOI: 10.1039/C7GC01479A, Critical Review S. Gillet, M. Aguedo, L. Petitjean, A. R. C. Morais, A. M. da Costa Lopes, R. M. Lukasik, P. T. Anastas We provide a critical review of green processes enabling the fractionation and/or depolymerization of lignin towards value-added products. The content of this RSS Feed (c) The Royal Society of Chemistry
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Role of oxygenates and effect of operating conditions in the deactivation of a Ni supported catalyst during the steam reforming of bio-oil ()
Green Chem., 2017, 19,4315-4333 DOI: 10.1039/C7GC01432E, Paper Aitor Ochoa, Borja Aramburu, Beatriz Valle, Daniel E. Resasco, Javier Bilbao, Ana G. Gayubo, Pedro Castano This work investigates the correlation of the reaction conditions and the reaction medium composition with the deactivation behavior of a Ni/La2O3-[small alpha]Al2O3 catalyst used in the steam reforming of bio-oil. The content of this RSS Feed (c) The Royal Society of Chemistry
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Selective conversion of bio-derived ethanol to renewable BTX over Ga-ZSM-5 ()
Green Chem., 2017, 19,4344-4352 DOI: 10.1039/C7GC01188A, Paper Zhenglong Li, Andrew W. Lepore, Mariam F. Salazar, Guo Shiou Foo, Brian H. Davison, Zili Wu, Chaitanya K. Narula The exchanged Ga(III) sites are the active sites for promoting BTX formation during ethanol conversion. The content of this RSS Feed (c) The Royal Society of Chemistry
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Bio-based amines through sustainable heterogeneous catalysis ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02299A, Critical Review Michiel Pelckmans, Tom Renders, Stijn Van de Vyver, Bert F Sels The production of amines from biomass is a growing field of interest. Particularly the amination of bio-based alcohols receives a lot of attention. In this review, we discuss recent progress... The content of this RSS Feed (c) The Royal Society of Chemistry
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New Catalyst with Multiple Active Sites for Selective Hydrogenolysis of Cellulose to Ethylene Glycol ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02122D, Paper Mohamed Hamdy, Murad Eissa, sherif keshk Three different metals are successfully incorporated into TUD-1 mesoporous siliceous material for the first time. One-pot synthesis procedure was applied to incorporate isolated Al3+, nanoparticles of WO3, and nanoaprticles of... The content of this RSS Feed (c) The Royal Society of Chemistry
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Phloretic acid as an alternative to the phenolation of aliphatic hydroxyls for the elaboration of polybenzoxazine ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02348K, Paper Acerina Trejo-Machin, Pierre Verge, Laura Puchot, Robert Quintana 3-(4-hydroxyphenyl)propanoic acid, so-called phloretic acid (PA), is a naturally occurring phenolic compound which can be produced from the hydrogenation of p-coumaric acid or synthesized from phloretin, a by-product of apple... The content of this RSS Feed (c) The Royal Society of Chemistry
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Efficient electrosynthesis of phosphinic amides via oxidative cross-coupling between N-H/P-H ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01989K, Communication Yukang Wang, Peng Qian, Ji-Hu Su, Yanan Li, Meixiang Bi, Zhenggen Zha, Zhiyong Wang A facile and efficient approach to phosphinic amides was developed from diarylphosphine oxides and amines via electrosynthesis. A variety of phosphinic amides were obtained in one step with good to excellent yields under mild and metal-free conditions. The corresponding mechanism was investigated. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Self-hydrogen transfer hydrogenolysis of [small beta]-O-4 linkages in lignin catalyzed by MIL-100(Fe) supported Pd-Ni BMNPs ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC02087B, Communication Jia-wei Zhang, Guo-ping Lu, Chun Cai A MIL-100(Fe) supported Pd-Ni BMNP catalyst has been fabricated, and the catalyst exhibits superior catalytic performance toward intramolecular transfer hydrogenolysis of lignin model compounds and organosolv lignin. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Exceptional control on physical properties of a polymeric material through alcoholic solvent-mediated environment-friendly Michael addition reaction ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC02286G, Communication A. M. Rather, N. Jana, S. Begum, H. K. Srivastava, U. Manna An eco-friendly approach to synthesize the polymeric materials with various controlled physical properties is explored in this work through appropriate selection of the reaction medium (i.e. alcoholic solvent). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Mid-chain carboxylic acids by catalytic refining of microalgae oil ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01484H, Paper Julia Zimmerer, Lara Williams, Dennis Pingen, Stefan Mecking Microalgae oil serves as a feedstock for a biorefinery approach to mid-chain (di-) carboxylic acid esters via cross-metathesis and isomerizing alkoxycarbonylation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Water excellent solvent for the synthesis of bifunctionalized cyclopentenones from furfural ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02303K, Paper Monica Nardi, Paola Costanzo, Antonio De Nino, Maria Luisa Di Gioia, Fabrizio Olivito, Giovanni Sindona, Antonio Procopio Chiral cyclopentenones are important precursors in the asymmetric synthesis of target molecules. In particular, C-2 amino cyclopentenones could be utilised as intermediates towards antitumor natural products. On the basis of... The content of this RSS Feed (c) The Royal Society of Chemistry
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Bio-based N-alkyl-2-pyrrolidones by Pd-catalyzed reductive N-alkylation and decarboxylation of glutamic acid ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC01829K, Paper Free De Schouwer, Sander Adriaansen, Laurens Claes, Dirk E. De Vos Environmental regulations boost the search for new safer and less toxic bio-based solvents to replace controversial high-boiling solvents such as N-methyl-2-pyrrolidone and N,N-dimethylformamide in the chemical industry. Recently, N-alkyl-2-pyrrolidones and... The content of this RSS Feed (c) The Royal Society of Chemistry
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A strategy for generating high-quality cellulose and lignin simultaneously from woody biomass ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC02492D, Paper Xiaoqin Si, Fang Lu, Jiazhi Chen, Rui Lu, Qianqian Huang, Huifang Jiang, Esben Taarning, Jie Xu An efficient strategy was developed for achieving high-quality cellulose and lignin simultaneously from woody biomass using solvent thermal treatment. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Beverage waste derived biomaterials for tissue engineering ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01951C, Communication M. Yates, M. Ramos-Gomez, A. Civantos, V. Ramos, J. L. Lopez-Lacomba, J. V. Sanz Casado, J. Lluis Tarterra, B. Fite Luis, M. A. Martin-Luengo For the first time waste from the beverage manufacturing industry has been valorised as an in vivo tissue engineering scaffold. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Efficient route for the construction of polycyclic systems from bioderived HMF ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC02211E, Paper F. A. Kucherov, K. I. Galkin, E. G. Gordeev, V. P. Ananikov Efficient one-pot synthesis of tricyclic compounds from biobased 5-hydroxymethylfurfural (HMF) is described using a [4 + 2] cycloaddition reaction. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Clean synthesis of furfural oxime through liquid-phase ammoximation of furfural over titanosilicate catalysts ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC02069D, Paper Xinqing Lu, Yejun Guan, Hao Xu, Haihong Wu, Peng Wu The clean synthesis of furfural oxime (FO) has been realized through titanosilicate-catalyzed liquid-phase ammoximation of furfural with ammonia and hydrogen peroxide. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Conversion of HMF to Methyl Cyclopentenolone by the Pd/Nb2O5 and Ca-Al Catalysts via Two-steps Procedure ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02310C, Paper Ying Duan, Min Zheng, Dong-Mi Li, Dongsheng Deng, Lufang Ma, Yanliang Yang The catalytic conversion of HMF to 2-hydroxy-3-methyl-2-cyclopenten-1-one (MCP), which was a valuable edible essence traditionally obtained from adipinic acid, was achieved with 58% isolated yield. This procedure contained two steps:... The content of this RSS Feed (c) The Royal Society of Chemistry
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Microwave-Assisted Hydrothermal Selective Dissolution and Utilisation of Hemicellulose in Phyllostachys heterocycla cv. pubescens ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02300F, Paper Yiping Luo, Jiajun Fan, Vitaliy L. Budarin, Changwei Hu, James Clark A green process for the microwave-assisted hydrothermal selective dissolution and utilisation of hemicellulose in Phyllostachys heterocycla cv. Pubescens (shortened to pubescens) was developed. The process facilitated the efficient dissolution of... The content of this RSS Feed (c) The Royal Society of Chemistry
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Dimethyldioxirane (DMDO) as a valuable oxidant for the synthesis of polyfunctional aromatic imidazolium monomers bearing epoxides. ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02372C, Communication Charline Chardin, Jacques Henri Rouden, Sebastien Livi, Jerome Baudoux Conventional organic salts represent a new paradigm in many areas of research. Despite their great potential, an improvement of their physicochemical properties requires the chemical modification of their intrinsic structure.... The content of this RSS Feed (c) The Royal Society of Chemistry
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A new low impact and efficient synthesis of -nitro esters under solid heterogeneous catalysis ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02241G, Paper Alessandro Palmieri, Serena Gabrielli, Roberto Ballini, Elena Chiurchiu Herein, we report a new efficient and sustainable synthetic protocol for the preparation of -nitro esters starting from cyclic 2-nitro ketones. The method involves the use of polymer bound BEMP... The content of this RSS Feed (c) The Royal Society of Chemistry
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Visible-Light-Induced C-H Sulfenylation Using Sulfinic Acids ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC01891F, Communication Pengfei Sun, Daoshan Yang, Wei Wei, Ming Jiang, Zu-Li Wang, Liyan Zhang, Hui Zhang, Zhenzhen Zhang, Yu Wang, Hua Wang Visible light and Eosin B-catalyzed the direct sulfenylation of sp2 C-H bond with sulfinic acids through a photoredox process has been initially demonstrated at room temperature under transition-metal-free conditions. Diverse... The content of this RSS Feed (c) The Royal Society of Chemistry
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Low molecular weight gelators (LMWGs) for ionic liquids: the role of hydrogen bonding and sterics in the formation of stable low molecular weight ionic liquid gels ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC02053H, Paper Peter McNeice, Yingying Zhao, Jianxun Wang, Gerald F. Donnelly, Patricia C. Marr 3 sugar based low molecular weight gelators are shown to form ionic liquid gels with a diverse range of ionic liquids. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Organic electrolyte solutions as versatile media for the dissolution and regeneration of cellulose ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01776F, Critical Review Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Matthew T. Clough Organic electrolyte solutions - mixtures of a (room-temperature) ionic liquid with a neutral, organic, polar co-solvent - are attracting increasing attention as solvents for the regeneration and derivatisation of cellulose. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Polyethylenimine-cross-linked cellulose nanocrystals for highly efficient recovery of rare earth elements from water and a mechanism study ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01770G, Paper Feiping Zhao, Eveliina Repo, Yang Song, Dulin Yin, Samia Ben Hammouda, Li Chen, Simo Kalliola, Juntao Tang, Kam C. Tam, Mika Sillanpaa PEI acts not only as a cross-linker but also as a chelating agent for RE ions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Sustainable chemistry: how to produce better and more from less? ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02006F, Perspective Philippe Marion, Bastien Bernela, Antoine Piccirilli, Boris Estrine, Norbert Patouillard, Jerome Guilbot, Francois Jerome The International Symposium on Green Chemistry (ISGC) organized in 2013, 2015 and 2017 has gathered many senior and young talented scientists from all around the world (2200 attendees in three... The content of this RSS Feed (c) The Royal Society of Chemistry
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A Highly Efficient Suzuki-Miyaura Methylation of Pyridines Leading to the Drug Pirfenidone and to its CD3 Version (SD-560) ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC01740E, Communication Eliezer Falb, Konstantin Ulanenko, Andrey Tor, Ronen Gottesfeld, Michal Weitman, Michal Afri, Hugo Gottlieb, Alfred Hassner Efficient introduction of methyl or methyl-d3 into aromatic and heteroaromatic systems still presents a synthetic challenge. In particular, we were in search of a non-cryogenic synthesis of the 5-CD3 version... The content of this RSS Feed (c) The Royal Society of Chemistry
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[Ru(triphos)(CH3CN)3](OTf)2 as a homogeneous catalyst for the hydrogenation of biomass derived 2,5-hexanedione and 2,5-dimethyl-furan in aqueous acidic medium ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01956D, Paper Elnaz Latifi, Austin D. Marchese, Margaret C. W. Hulls, Dmitriy V. Soldatov, Marcel Schlaf In aqueous acidic medium a direct hydrogenation of 2,5-dimethylfuran does not take place with the homogeneous [Ru(triphos)]-system opening a pathway to the more valuable 2,5-hexanediol. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Self-assembly of a bio-based extractant in methyl esters: combination of small angle X-ray scattering experiments and molecular dynamics simulations ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01769C, Paper Donatien Gomes Rodrigues, Ophelie Fadel, Pierre Bauduin, Luc Girard, Philippe Guilbaud, Annabelle L'Hermitte, Anne Rossignol-Castera, Olivier Diat The structure of a bio-based extractant in oils was accessed by combining experiments and molecular dynamics simulations. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Improved monitoring of aqueous samples by the preconcentration of active pharmaceutical ingredients using ionic-liquid-based systems ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01954H, Paper Hugo F. D. Almeida, Mara G. Freire, Isabel M. Marrucho The concentration of active pharmaceutical ingredients up to mg L-1 using ionic-liquid-based strategies allows their more accurate monitoring and an evaluation of their persistence in environmentally related aqueous samples. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Base-free nickel-catalyzed hydroboration of simple alkenes with bis(pinacolato)diboron in an alcoholic solvent ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC02282D, Communication Jiang-Fei Li, Zhen-Zhong Wei, Yong-Qiu Wang, Mengchun Ye A base-free nickel-catalyzed hydroboration of unreactive simple alkenes with bis(pinacolato)diboron using methanol as the hydride source under mild conditions has been developed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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The continuous oxidation of HMF to FDCA and the immobilisation and stabilisation of periplasmic aldehyde oxidase (PaoABC) ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01696D, Paper S. M. McKenna, P. Mines, P. Law, K. Kovacs-Schreiner, W. R. Birmingham, N. J. Turner, S. Leimkuhler, A. J. Carnell One-pot multienzyme continuous cascade for the conversion of HMF to FDCA using HRP to activate GOaseM3-5 in situ. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Efficient eco-clean upgrading of isolated cellulose fibers by polyoxometalate (POM) catalyzed ozonation boosted by enzymes ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02218B, Paper Anatoly A. Shatalov The extremely selective and effective delignification (bleaching) approach for upgrading of isolated cellulose fibers by ozone in the presence of mixed-addenda [small alpha]-Keggin-type polyoxometalates (POM), such as heteropolyanions of series [PMo(12-n)VnO40](3+n)-,... The content of this RSS Feed (c) The Royal Society of Chemistry
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Facile preparation of bio-based polyesters from furandicarboxylic acid and long chain diols via asymmetric monomer strategy ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02081C, Paper yong shen, BinBin Yao, Guang Yu, Yao Fu, Fusheng Liu, Zhibo Li In this study, we propose a novel strategy to prepare furandicarboxylic acid (FDCA) based polyesters by melt polycondensation of asymmetric monomer with terminal methyl ester and hydroxyl groups. A series... The content of this RSS Feed (c) The Royal Society of Chemistry
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Heterogeneous catalysis for bio-based polyester monomers from cellulosic biomass: advances, challenges and prospects ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02040F, Critical Review Rik De Clercq, Michiel Dusselier, Bert F Sels It is a 21st century challenge to develop a more sustainable chemical industry where fossil-based resources are, where possible, preferentially replaced by renewable alternatives. Biobased polymers, in particular those derived... The content of this RSS Feed (c) The Royal Society of Chemistry
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A roadmap towards green packaging: current status and future outlook for polyesters in the packaging industry ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02521A, Tutorial Review muhammad rabnawaz, Ian Wyman, Rafael Auras, Shouyun Cheng Approximately 99% of the plastics produced today are petroleum-based, and the packaging industry alone consumes over 39% of these plastics. In this review, we argue that renewable polyesters can provide... The content of this RSS Feed (c) The Royal Society of Chemistry
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Hydrolysis of cellulose to glucose over carbon catalysts sulfonated via a plasma process in dilute acid ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02143G, Communication Oi Lun Helena Li, Ryuhei Ikura, Takahiro Ishizaki Herein, we reported a novel plasma-sulfonation process of carbon materials under dilute sulfuric acid within several tens of minutes. The total acidic and -SO3H densities were 4.4 mmol g-1 and... The content of this RSS Feed (c) The Royal Society of Chemistry
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Synergistic Maximization of Carbohydrate Output and Lignin Processibility by Combinatorial Pretreatment ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02057K, Paper Zhi-Hua Liu, Michelle Olson, Somnath Dattatray Shinde, Xin Wang, Naijia Hao, Chang Geun Yoo, Samarthya Bhagia , John R. Dunlap , Yunqiao Pu, Katy Kao, Arthur Ragauskas, Mingjie Jin, Joshua S. Yuan Lignocellulosic biorefineries have gained much attention worldwide as a potential solution to the challenges of energy demand and global climate change. However, the industrial implementation of biorefinery has been hindered... The content of this RSS Feed (c) The Royal Society of Chemistry
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Stabilising Ni catalysts for the dehydration-decarboxylation-hydrogenation of citric acid to methylsuccinic acid ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01773A, Paper Jasper Verduyckt, Anton Geers, Birgit Claes, Samuel Eyley, Cedric Van Goethem, Ivo Stassen, Simon Smolders, Rob Ameloot, Ivo Vankelecom, Wim Thielemans, Dirk E. De Vos Ni nanoparticles could be stabilised to enable the Ni catalyzed dehydration-decarboxylation-hydrogenation of citric acid to methylsuccinic acid. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal Free Carbon as a Catalyst for Oxidative Coupling : Solvent Enhance Poly-Coupling with Regioselectivity ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02227A, Communication Ranganath VS Kalluri, Melad Shaikh, KK Atyam, Aanchal Sahu, Mahendra Sahu, SUNIL KUMAR SINGH A heterogeneous, inexpensive and a metal free, environmental friendly graphene oxide (GO), has been developed for the oxidative poly coupling of 2-naphthols in aqeous sodium hydroxide in the presence of... The content of this RSS Feed (c) The Royal Society of Chemistry
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I2-Mediated oxidative bicyclization of 4-pentenamines to prolinol carbamates with CO2 incorporating oxyamination of the C[double bond, length as m-dash]C bond ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01992K, Communication Sheng Wang, Xiaowei Zhang, Chengyao Cao, Chao Chen, Chanjuan Xi A metal-free oxyamination reaction of alkenes with ambient CO2 has been reported. This reaction provided a feasible approach to prepare prolinol carbamates with high efficiency under mild conditions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Nutritional requirements and the impact of yeast extract on the D-lactic acid production by Sporolactobacillus inulinus ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01796K, Paper Silvia Klotz, Anja Kuenz, Ulf Pru[German sz ligature}e For the first time, nutritional requirements including the effects of yeast extract on the D-lactic acid production by Sporolactobacillus inulinus are presented. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Long-term protein packaging in cholinium-based ionic liquids: Improved catalytic activity and enhanced stability of cytochrome C against multiple stresses ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02011B, Paper Meena Bisht, Dibyendu Mondal, Matheus M Pereira, Mara G Freire, Pannuru Venkatesu, Joao A. P. Coutinho There is a considerable interest in the use of structurally stable and catalytically active enzymes, such as cytochrome C (Cyt C), in the pharmaceutical and fine chemical industries. However, harsh... The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalytic fast pyrolysis of biomass: superior selectivity of hierarchical zeolite to aromatics ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02309J, Paper liangyuan Jia, Mira Raad, Soumaya Hamieh, Joumana Toufaily, Tayssir Hamieh, Mohammed Bettahar, guillain mauviel, Mehrad Tarrighi, Ludovic Pinard, Anthony Dufour The catalytic fast pyrolysis of oak over two zeolites (microporous and hierarchical) was investigated in a microfluidized bed reactor (MFBR) at 500 [degree]C and as a function of biomass-to-catalyst ratio.... The content of this RSS Feed (c) The Royal Society of Chemistry
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Emulsion electro-oxidation of kraft lignin ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02115A, Communication Davide Di Marino, Vadim Aniko, Antonio Stocco, Stefanie Kriescher, Matthias Wessling Lignin is one of the most abundant bio-polymers present in nature and its valorization still represents a challenge to an economically feasible biorefinery concept. Lignin's heterogeneity and scarce reactivity represent... The content of this RSS Feed (c) The Royal Society of Chemistry
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Ionic Liquid Catalyzed Probase Method for One-pot Synthesis of [small alpha], [small beta]-Unsaturated Esters from Esters and Aldehydes at Mild Condition ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC02265D, Paper Gang Wang, Yiming Xu, Suojiang Zhang, CHUNSHAN LI, Zengxi Li One-pot synthesis of [small alpha], [small beta]-unsaturated esters from unactivated esters and aldehydes using strong bases, such as sodium alkoxide and potassium tert-butoxide, were reported. However, the ionic liquids (ILs) catalyzed probase... The content of this RSS Feed (c) The Royal Society of Chemistry
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Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01993A, Paper A. P. C. Ribeiro, L. M. D. R. S. Martins, A. J. L. Pombeiro The highly efficient eco-friendly synthesis of methanol directly from carbon dioxide and H2 catalysed by the iron(II) scorpionate catalyst [FeCl2{[small kappa]3-HC(pz)3}] is reported. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal-free base-mediated oxidative annulation cascades to 3-substituted-3-hydroxyoxindole and its 3-spirocyclic derivative ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01783A, Communication Min Liu, Chunxia Zhang, Mingruo Ding, Bencan Tang, Fengzhi Zhang A simple and efficient method was developed for the construction of the medicinally important 3-substituted-3-hydroxyoxindole and its 3-spirocyclic derivatives with readily available aniline derivatives as starting materials. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Preparation of S/N-codoped carbon nanosheets with tunable interlayer distance for high-rate sodium-ion batteries ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01942D, Paper Guoqiang Zou, Hongshuai Hou, Ganggang Zhao, Zhaodong Huang, Peng Ge, Xiaobo Ji In this work, an ultra-thin sheet-like carbon with the co-doping of S and N prepared by a environmentally friendly one-pot method was firstly reported, delivering high-rate capability for SIBs. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Direct use of humic acid mixtures to construct efficient Zr-containing catalysts for Meerwein-Ponndorf-Verley reactions ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01925D, Paper Yufei Sha, Zhenhuan Xiao, Huacong Zhou, Keli Yang, Yinmin Song, Na Li, Runxia He, Keduan Zhi, Quansheng Liu Humic acid (HA) mixtures from lignite could be directly used to construct Zr-HAs catalysts for MPV reaction of carboxyl compounds. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Molybdenum modified nickel phyllosilicates as a high performance bifunctional catalyst for deoxygenation of methyl palmitate to alkanes under mild conditions ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01720K, Paper Long Yan, Xinxin Liu, Jin Deng, Yao Fu A new Mo doping Ni phyllosilicates catalyst (Mo-Ni@PSi) was synthesized and exhibited high catalytic activity under mild reaction condition for the deoxygenation of methyl palmitate. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Nano-flowered Ce@MOR hybrids with modulated acid properties for the vapor-phase dehydration of 1,3-butanediol into butadiene ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC02223A, Paper Lin Fang, Fangli Jing, Jingya Lu, Bingwen Hu, Marc Pera-Titus A series of Ce@MOR hybrids based on CeOx nanoparticles (1-2.5 nm) encapsulated in mordenite exhibited high catalytic activity and selectivity for the vapor-phase dehydration of 1,3-butanediol into butadiene. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Super impact absorbing bio-alloys from inedible plants ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01842H, Communication Jumpei Kawada, Masayuki Kitou, Makoto Mouri, Yuichi Kato, Yoshihide Katagiri, Mitsumasa Matsushita, Toshiyuki Ario, Osamu Kitou, Arimitsu Usuki Injection molded bio-alloys from inedible plants showed a "salami-like structure in a co-continuous phase" and had superior impact strength with good stiffness, making bio-alloys feasible for applications. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Environmental sustainability assessment of a new degreasing formulation for the tanning cycle within leather manufacturing ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01900A, Paper Roberto Rosa, Martina Pini, Paolo Neri, Massimo Corsi, Roberto Bianchini, Marco Bonanni, Anna Maria Ferrari The environmental assessment of the lab-scale preparation of a new lactose derivative-based degreasing formulation, for the leather manufacturing cycle, was performed by using EATOS and LCA methodologies. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of nano- and microstructures from proanthocyanidins, tannic acid and epigallocatechin-3-O-gallate for active delivery ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC02009K, Paper Elisavet D. Bartzoka, Heiko Lange, Pasquale Mosesso, Claudia Crestini Versatile tannin nano- and microstructures have been created via ultrasound treatment and thoroughly characterized for the stimuli responsive delivery of active molecules. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Acidic/amphiphilic silica nanoparticles: new eco-friendly Pickering interfacial catalysis for biodiesel production ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01910F, Paper Bingyu Yang, Loic Leclercq, Jean-Marc Clacens, Veronique Nardello-Rataj Silica nanoparticles have been designed by surface modification to stabilize solventless catalytic Pickering emulsions for effective biodiesel production. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Gold and palladium oxidation/complexation in water by a thioamide-iodine leaching system ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01310H, Paper Francesco Isaia, Maria Carla Aragoni, Massimiliano Arca, Claudia Caltagirone, Carlo Castellano, Greta De Filippo, Alessandra Garau, Vito Lippolis, Tiziana Pivetta This paper concerns the oxidative dissolution ability of a thioamide/iodine leaching system in water towards gold, palladium and silver metals by using reaction conditions safe for the health and environment. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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New insights into the catalytic reduction of aliphatic nitro compounds with hypophosphites under ultrasonic irradiation ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01622K, Paper S. Letort, M. Lejeune, N. Kardos, E. Metay, F. Popowycz, M. Lemaire, M. Draye This work proposes an efficient process allowing the reduction of nitro compounds to the corresponding amines in water, at 70 [degree]C with a quantitative conversion and a maximal yield in only 15 min thanks to the ultrasonic activation. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Zirconocene-catalyzed direct (trans)esterification of acyl acids (esters) and alcohols in a strict 1 : 1 ratio under solvent-free conditions ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC02174G, Paper Zhi Tang, Qiutao Jiang, Lifen Peng, Xinhua Xu, Jie Li, Renhua Qiu, Chak-Tong Au A highly efficient way for the direct (trans)esterification of acyl acids (esters) and alcohols in a strict 1 : 1 ratio using a zirconocene complex (1, 1 mol%), a strong Lewis acid of good water tolerance, as a catalyst under solvent-free conditions has been developed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalyst-free multi-component cascade C-H-functionalization in water using molecular oxygen: an approach to 1,3-oxazines ()
Green Chem., 2017, 19,4036-4042 DOI: 10.1039/C7GC01494E, Communication Mohit L. Deb, Choitanya D. Pegu, Paran J. Borpatra, Prakash J. Saikia, Pranjal K. Baruah Synthesis of 1,3-oxazines via catalyst free C-H functionalization using molecular oxygen in water. The content of this RSS Feed (c) The Royal Society of Chemistry
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Correction: Catalytic hydrogenolysis of kraft lignin to monomers at high yield in alkaline water ()
Green Chem., 2017, 19,4186-4186 DOI: 10.1039/C7GC90089A, Correction Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Shi-Chao Qi, Jun-ichiro Hayashi, Shinji Kudo, Lu Zhang The content of this RSS Feed (c) The Royal Society of Chemistry
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An environmentally benign and selective electrochemical oxidation of sulfides and thiols in a continuous-flow microreactor ()
Green Chem., 2017, 19,4061-4066 DOI: 10.1039/C7GC01973D, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Gabriele Laudadio, Natan J. W. Straathof, Menno D. Lanting, Benny Knoops, Volker Hessel, Timothy Noel A practical and environmentally benign electrochemical oxidation of thioethers and thiols in a commercially-available continuous-flow microreactor is presented. The content of this RSS Feed (c) The Royal Society of Chemistry
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A straightforward thiol-ene click reaction to modify lignocellulosic scaffolds in water ()
Green Chem., 2017, 19,4017-4022 DOI: 10.1039/C7GC01601H, Communication S. Kostic, J. K. Berg, K. Casdorff, V. Merk, I. Burgert, E. Cabane A cost-effective approach to functionalize lignocellulosic material is presented: cyclodextrin catalyzed thiol-ene click reaction in water. The content of this RSS Feed (c) The Royal Society of Chemistry
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Environmentally sound textile dyeing technology with nanofibrillated cellulose ()
Green Chem., 2017, 19,4031-4035 DOI: 10.1039/C7GC01662J, Communication Yunsang Kim, Lauren Tolbert McCoy, Eliza Lee, Hansol Lee, Raha Saremi, Corbin Feit, Ian R. Hardin, Suraj Sharma, Sudhagar Mani, Sergiy Minko Sustainable textile dyeing technology using nanofibrillated cellulose is developed that would significantly reduce wastewater and potential environmental costs. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of CO2-responsive cellulose nanocrystals by surface-initiated Cu(0)-mediated polymerisation ()
Green Chem., 2017, 19,4141-4152 DOI: 10.1039/C7GC01798G, Paper Joaquin Arredondo, Philip G. Jessop, Pascale Champagne, Jean Bouchard, Michael F. Cunningham CNC was converted into a CO2-responsive composite nanomaterial by grafting PDMAEMA and PDEAEMA on its surface using a grafting-from approach via surface-initiated copper(0)-mediated polymerisation. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of 3-alkoxypropan-1,2-diols from glycidol: experimental and theoretical studies for the optimization of the synthesis of glycerol derived solvents ()
Green Chem., 2017, 19,4176-4185 DOI: 10.1039/C7GC01583F, Paper A. Leal-Duaso, M. Caballero, A. Urriolabeitia, J. A. Mayoral, J. I. Garcia, E. Pires Optimized green synthesis of glyceryl monoethers from alcohols and glycidol through experimental and computational studies. The content of this RSS Feed (c) The Royal Society of Chemistry
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Three-component synthesis of 2-heteroaryl-benzothiazoles under metal-free conditions ()
Green Chem., 2017, 19,4043-4047 DOI: 10.1039/C7GC01932G, Communication Guozheng Li, Hao Xie, Jinjin Chen, Yanjun Guo, Guo-Jun Deng 2-Heteroaryl-benzothiazole derivatives were selectively prepared from anilines, 2-methylquinolines and elemental sulfur under metal-free conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Designing the thermal behaviour of aqueous biphasic systems composed of ammonium-based zwitterions ()
Green Chem., 2017, 19,4012-4016 DOI: 10.1039/C7GC02262J, Communication Ana M. Ferreira, Helena Passos, Akiyoshi Okafuji, Mara G. Freire, Joao A. P. Coutinho, Hiroyuki Ohno The design of the thermal behaviour - from an upper critical solution temperature (UCST) to a lower critical solution temperature (LCST) - of aqueous biphasic systems composed of water-soluble ammonium-based zwitterions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Insight into forced hydrogen re-arrangement and altered reaction pathways in a protocol for CO2 catalytic processing of oleic acid into C8-C15 alkanes ()
Green Chem., 2017, 19,4157-4168 DOI: 10.1039/C7GC01853C, Paper Shiyou Xing, Pengmei Lv, Haoran Yuan, Lingmei Yang, Zhongming Wang, Zhenhong Yuan, Yong Chen A protocol for CO2 enhanced processing of oleic acid for C8-C15 alkane production is proposed where intrinsic hydrogen in oleic acids is re-arranged in final liquid products. The content of this RSS Feed (c) The Royal Society of Chemistry
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Efficient and sustainable solvents for lignin dissolution: aqueous choline carboxylate solutions ()
Green Chem., 2017, 19,4067-4073 DOI: 10.1039/C7GC01886J, Paper Airong Xu, Xin Guo, Yibo Zhang, Zhiyong Li, Jianji Wang Aqueous choline carboxylate ILs with environment-friendliness, low viscosity and economical advantages have been used for efficient dissolution of lignin at room temperature. The content of this RSS Feed (c) The Royal Society of Chemistry
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Catalytic hydroboration of aldehydes, ketones, alkynes and alkenes initiated by NaOH ()
Green Chem., 2017, 19,4169-4175 DOI: 10.1039/C7GC01632H, Paper Yile Wu, Changkai Shan, Jianxi Ying, Jue Su, Jun Zhu, Liu Leo Liu, Yufen Zhao Commercially available NaOH powder is shown to be an efficient transition-metal-free initiator for the catalytic hydroboration of aldehydes, ketones, alkynes and alkenes with HBpin and 9-BBN under mild conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Joint tuning of nanostructured Cu-oxide morphology and local electrolyte programs high-rate CO2 reduction to C2H4 ()
Green Chem., 2017, 19,4023-4030 DOI: 10.1039/C7GC01677H, Communication Yuanjie Pang, Thomas Burdyny, Cao-Thang Dinh, Md Golam Kibria, James Zhangming Fan, Min Liu, Edward H. Sargent, David Sinton Electrochemical ethylene production rates are enhanced by pushing favourable local electrolyte conditions to occur at higher current densities and lower relative overpotentials. The content of this RSS Feed (c) The Royal Society of Chemistry
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An efficient approach for the synthesis of 5-hydroxy-chromeno[2,3-b]pyridines under catalyst and solvent free conditions ()
Green Chem., 2017, 19,4153-4156 DOI: 10.1039/C7GC01463E, Paper Shruti Gupta, Jitender M. Khurana An efficient and sustainable method has been developed for the synthesis of novel 5-hydroxy-chromeno[2,3-b]pyridines by the reaction of 3-formylchromone, aromatic amines and malononitrile under catalyst and solvent-free conditions by simply stirring the components magnetically or by grinding at room temperature. The content of this RSS Feed (c) The Royal Society of Chemistry
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The effect of room temperature ionic liquids on the selective biocatalytic hydrolysis of chitin via sequential or simultaneous strategies ()
Green Chem., 2017, 19,4122-4131 DOI: 10.1039/C7GC01471F, Paper E. Husson, C. Hadad, G. Huet, S. Laclef, D. Lesur, V. Lambertyn, A. Jamali, S. Gottis, C. Sarazin, A. Nguyen Van Nhien N-Acetylglucosamine and N,N[prime or minute]-diacetylchitobiose are efficiently and selectively produced from chitin biomass by using RTILs and chitinases. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly porous graphitic biomass carbon as advanced electrode materials for supercapacitors ()
Green Chem., 2017, 19,4132-4140 DOI: 10.1039/C7GC01681F, Paper Youning Gong, Delong Li, Chengzhi Luo, Qiang Fu, Chunxu Pan 3D porous graphitic biomass carbon as advanced supercapacitor electrode materials synthesized by a low-cost and effective one-step method. The content of this RSS Feed (c) The Royal Society of Chemistry
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On the structure of softwood kraft lignin ()
Green Chem., 2017, 19,4104-4121 DOI: 10.1039/C7GC01812F, Paper Claudia Crestini, Heiko Lange, Marco Sette, Dimitris S. Argyropoulos Two constitutional structural schemes are proposed attempting to unify and rationalize a series of focused NMR and chromatographic determinations aimed at providing an integrated picture for the structure of softwood kraft lignin. The content of this RSS Feed (c) The Royal Society of Chemistry
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An introduction to zwitterionic salts ()
Green Chem., 2017, 19,4007-4011 DOI: 10.1039/C7GC01523B, Communication Marijana Blesic, Brendan F. Gilmore, John D. Holbrey, Johan Jacquemin, Gaelle Level, Peter Nockemann, Lorenzo Stella Zwitterionic salts: highly hydrophilic materials, incorporating some characteristics of zwitterions, ionic liquids, and inorganic salts with potential applications in the biomedical field and separation technology. The content of this RSS Feed (c) The Royal Society of Chemistry
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