Green Chemistry

Glucose promoted facile reduction of azides to amines in aqueous alkaline conditions ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC01593C, Communication Nisha Chandna, Fatehjeet Kaur, Shobhna Kumar, Nidhi Jain A quick and efficient method for reduction of azides to amines in water using D-glucose and KOH as a green reagent is reported. The protocol is simple, inexpensive, scalable, and... The content of this RSS Feed (c) The Royal Society of Chemistry
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Conversion of C5 carbohydrates into furfural catalyzed by a Lewis acidic ionic liquid in renewable [gamma]-valerolactone ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01298E, Paper Shurong Wang, Yuan Zhao, Haizhou Lin, Jingping Chen, Lingjun Zhu, Zhongyang Luo For the purpose of building a green reaction system to produce furfural (FF), the conversion of xylose and arabinose was investigated in an aqueous reaction system including a Lewis acidic ionic liquid as a catalyst and renewable [gamma]-valerolactone (GVL) as a co-solvent. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Sustainable functionalization of cellulose and starch with diallyl carbonate in ionic liquids ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC01978E, Paper zafer soyler, Michael A. R. Meier A functional and environmentally benign alkoxycarbonylation reagent, diallyl carbonate (DAC), was employed for the sustainable and catalyst-free allyloxycarbonylation of cellulose under homogenous conditions using 1-butyl-3-methylimidazolium chloride (BMIMCI) as a solvent.... The content of this RSS Feed (c) The Royal Society of Chemistry
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A two-phase system for the clean and high yield synthesis of furylmethane derivatives over -SO3H functionalized ionic liquids ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01654A, Paper S. H. Shinde, C. V. Rode A new and effective unique two-phase reaction system for the high yield production of tri(furyl)methane from furfural and furan. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Valuable new platform chemicals obtained by valorisation of a model succinic acid and bio-succinic acid with an ionic liquid and high-pressure carbon dioxide ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC00952F, Paper Daniel Silva, Ewa Bogel-Lukasik Biomass and catalysis form a bridge between bio-based industry and the current process technology. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal-exchanged magnetic [small beta]-zeolites: valorization of lignocellulosic biomass-derived compounds to platform chemicals ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01178D, Paper Erlen Y. C. Jorge, Thiago de M. Lima, Carolina G. S. Lima, Lucas Marchini, William N. Castelblanco, Daniel G. Rivera, Ernesto A. Urquieta-Gonzalez, Rajender S. Varma, Marcio W. Paixao An array of Pd, Fe and Ir exchanged [small beta]-zeolites were synthesized, fully characterized, and their catalytic activity evaluated in converting bio-derived compounds to value-added platform chemicals. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Recent progress on fluorination in aqueous media ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01566F, Tutorial Review Lian Yang, Tao Dong, Hrishikesh M. Revankar, Cheng-Pan Zhang Advances of fluorination in aqueous media during the last few decades are summarized in this review. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly porous graphitic biomass carbon as advanced electrode materials for supercapacitors ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC01681F, Paper Youning Gong, Delong Li, Chengzhi Luo, Qiang Fu, Chunxu Pan In this work, we established a one-step strategy to synthesize three-dimensional porous graphitic biomass carbon (PGBC) from bamboo char (BC), and studied its electrochemical performace as electrode materials for supercapacitors.... The content of this RSS Feed (c) The Royal Society of Chemistry
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Selective reductive amination of aldehydes from nitro compounds catalyzed by molybdenum sulfide clusters ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC01603D, Communication Elena Pedrajas, Ivan Sorribes, Kathrin Junge, Matthias Beller, Rosa Llusar Secondary amines are selectively obtained from low value starting materials using hydrogen and a non-noble metal based catalyst. Reductive amination of aldehydes from nitroarenes or nitroalkanes is efficiently catalyzed by... The content of this RSS Feed (c) The Royal Society of Chemistry
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Tandem deprotection/coupling for peptide synthesis in water at room temperature ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC01575E, Communication Margery Cortes-Clerget, Jean-Yves Berthon, Isabelle Krolikewicz-Renimel, Laurent Chaisemartin, Bruce Howard Lipshutz A tandem deprotection/coupling sequence is reported for solution-phase peptide synthesis in water under micellar catalysis conditions using the designer surfactant TPGS-750-M. Cbz deprotection followed by peptide coupling in the presence... The content of this RSS Feed (c) The Royal Society of Chemistry
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Activation of (Salen)CoI Complex by Phosphorane for Carbon Dioxide Transformation at Ambient Temperature and Pressure ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC01458A, Paper Feng Zhou, Shi-Liang Xie, Xiao-Tong Gao, Rong Zhang, Cui-Hong Wang, Guang-Qiang Yin, Jian Zhou We report the activation of (salen)CoI complex 3g by a phosphorane to form a bifunctional catalyst for the reaction of carbon dioxide with terminal epoxides or aziridines at ambient temperature... The content of this RSS Feed (c) The Royal Society of Chemistry
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Synergizing graphene oxide with microwave irradiation for efficient cellulose depolymerization into glucose ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01691C, Paper Elaine G. Mission, Armando T. Quitain, Mitsuru Sasaki, Tetsuya Kida Schematic representation of the depolymerization of cellulose into glucose through the synergy of microwave and graphene oxide resulting to 61 wt% yield in one hour without pretreatment. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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One-pot conversion of biomass-derived xylose to furfuralcohol by a chemo-enzymatic sequential acid-catalyzed dehydration and bioreduction ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01256J, Paper Yucai He, Yun Ding, Cuiluan Ma, Junhua Di, Chunxia Jiang, Aitao Li One-pot furfuralcohol (FOL) production via dehydration of corncob-derived xylose followed by bioreduction of furfural has been described. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ecocatalyzed Suzuki cross coupling of heteroaryl compounds ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01672G, Paper Guillaume Clave, Franck Pelissier, Stephane Campidelli, Claude Grison A bio-based EcoPd was developed for the Suzuki cross coupling of heteroaryl compounds. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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One-pot and catalyst-free synthesis of pyrroloquinolinediones and quinolinedicarboxylates ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01380A, Paper Xiaofeng Zhang, Gagan Dhawan, Alex Muthengi, Shuai Liu, Wei Wang, Marc Legris, Wei Zhang A method for the catalyst-free synthesis of pyrroloquinolinediones and quinolinedicarboxylates is developed through a one-pot synthesis involving denitrogenation of azide, benzisoxazole formation, aza-Diels-Alder cycloaddition, and dehydrative aromatization. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A Versatile CO-assisted Direct Reductive Amination of 5-Hydroxymethylfurfural Catalyzed by Supported Gold ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC01579H, Paper Ming-Ming Zhu, Lei Tao, Qi Zhang, Jing Dong, Yong-Mei Liu, Heyong He, Yong Cao Reductive amination (RA) constitutes an attractive and practical strategy for discovering protocols capable of converting biomass into valuable N-containing compounds. Described herein is a versatile and sustainable RA of 5-hydroxymethyl-furfural... The content of this RSS Feed (c) The Royal Society of Chemistry
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ON THE STRUCTURE OF SOFTWOOD KRAFT LIGNIN ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC01812F, Paper Claudia Crestini, Heiko Lange, Marco Sette, D. S. Argyropoulos Two constitutional structural schemes are proposed attempting to unify and rationalize a series of focused NMR and chromatographic determinations aimed at providing an integrated picture for the structure of softwood... The content of this RSS Feed (c) The Royal Society of Chemistry
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Lignin Transformations for High Value Applications: Towards Targeted Modifications Using Green Chemistry ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC01479A, Critical Review Sebastien Gillet, Mario Aguedo, Laurene Petitjean, Ana Rita C. Morais, Andre M da Costa Lopes, Rafal Marcin Lukasik, Paul Anastas Lignin represents a considerable source of renewable and bio-based carbon. Pulping processes enable lignin, together with all components of the lignocellulosic biomass, to enter valorizable streams. A current key objective... The content of this RSS Feed (c) The Royal Society of Chemistry
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Facile and sustainable synthesis of sodium lignosulfonate derived hierarchical porous carbons for supercapacitors with high volumetric energy density ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC01434A, Paper Jie Pang, Wenfeng Zhang, Jinliang Zhang, Gaoping Cao, Mingfang Han, Yusheng Yang Interconnected hierarchical porous carbon was successfully prepared by directly carbonization of industrial waste sodium lignosulfonate without additional templating and activation agent. The as-prepared carbon sample shows a moderate specific surface... The content of this RSS Feed (c) The Royal Society of Chemistry
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The carbon nanotube formation parameter space: data mining and mechanistic understanding for efficient resource use ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01421J, Paper Wenbo Shi, Ke Xue, Eric R. Meshot, Desiree L. Plata Data-mining of the carbon nanotube growth parameters informed strategies to reduce energy and resource consumption for chemical vapor deposition processes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Sustainable barrier materials based on polysaccharide polyelectrolyte complexes ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC00991G, Paper Snehasish Basu, Adam Plucinski, Jeffrey M. Catchmark There is a need for sustainable, ecologically compatible barrier materials as a replacement for petroleum derived compounds for packaging and other applications that generate significant land and ocean pollution. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A continuous flow process for the production of 2,5-dimethylfuran from fructose using (non-noble metal based) heterogeneous catalysis ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01055A, Paper Max Braun, Markus Antonietti A simple and continuous flow process set-up for the production of 2,5-dimethylfuran from fructose using (non-noble metal based) heterogeneous catalysis. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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[small beta]-Amino acid derived gemini surfactants from diformylfuran (DFF) with particularly low critical micelle concentration (CMC) ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01534H, Paper Quentin Girka, Nicolas Hausser, Boris Estrine, Norbert Hoffmann, Jean Le Bras, Sinisa Marinkovic, Jacques Muzart Starting from diformylfuran (DFF) obtained from biomass, a new family of gemini surfactants has been synthesized. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Hydrophilic mesoporous poly(ionic liquid)-supported Au-Pd alloy nanoparticles towards aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid under mild conditions ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01116D, Paper Qian Wang, Wei Hou, Shuai Li, Jingyan Xie, Jing Li, Yu Zhou, Jun Wang Au-Pd nanoalloy in hydrophilic mesoporous poly(ionic liquid) shows high activity for oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid with atmospheric O2. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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A straightforward one-pot synthesis of bioactive N-aryl oxazolidin-2-ones via a highly efficient Fe3O4@SiO2-supported acetate-based butylimidazolium ionic liquid nanocatalyst under metal- and solvent-free conditions ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01414G, Paper Radhika Gupta, Manavi Yadav, Rashmi Gaur, Gunjan Arora, Rakesh Kumar Sharma A supported ionic liquid-based magnetic nanocatalyst has been fabricated for the formation of pharmaceutically important N-aryl oxazolidin-2-ones. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Immobilization engineering - How to design advanced sol-gel systems for biocatalysis? ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC00896A, Paper Diana Weiser, Flora Nagy, Gergely Banoczi, Mark Olah, Attila Farkas, Andras Szilagyi, Krisztina Laszlo, Akos Gellert, Gyorgy Marosi, Sandor Kemeny, Laszlo Poppe Immobilization engineering approach using bioinformatics and experimental design tools was applied to improve sol-gel enzyme entrapment methodology. This strategy was used for immobilization of lipase B from Candida antarctica (CaLB),... The content of this RSS Feed (c) The Royal Society of Chemistry
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One-pot Integrated Processing of Biopolymers to Furfurals in Molten Salt Hydrate: Understanding Synergy in Acidity ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC01709J, Paper Sunitha Sadula, Owen Oesterling, Andrew Nardone, Brian Dinkelacker, Basudeb Saha Furfural and 5-hydroxymethylfurfual (HMF), promising renewable platforms for bio-products, manufacturing with high carbon efficiency is a challenge because of their undesired polymerization to humins. Here, we present an integrated process... The content of this RSS Feed (c) The Royal Society of Chemistry
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An introduction to zwitterionic salts ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01523B, Communication Marijana Blesic, Brendan F. Gilmore, John D. Holbrey, Johan Jacquemin, Gaelle Level, Peter Nockemann, Lorenzo Stella Zwitterionic salts: highly hydrophilic materials, incorporating some characteristics of zwitterions, ionic liquids, and inorganic salts with potential applications in the biomedical field and separation technology. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Examples of xylochemistry: colorants and polymers ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01244F, Paper Jonas Kuhlborn, Ann-Kathrin Danner, Holger Frey, Rishab Iyer, Anthony J. Arduengo, Till Opatz The syntheses of indigo dyes and polyamides as representatives of two classes of everyday chemical products based on wood-based starting materials, the so-called xylochemicals, are described. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Application of microwave-assisted heterogeneous catalysis in sustainable synthesis design ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01393K, Critical Review Anne Kokel, Christian Schafer, Bela Torok Recent advances in the application of microwave-assisted heterogeneous catalytic synthesis approaches are reviewed with additional inputs on the energy efficiency and scale-up of microwave-assisted synthesis. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Potassium isopropyl xanthate (PIX): an ultra-efficient palladium scavenger ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01765K, Communication Hong Ren, Christopher A. Strulson, Guy Humphrey, Rong Xiang, Guangtao Li, Donald R. Gauthier, Kevin M. Maloney The increasing employment of palladium-catalyzed reactions in the synthesis of active pharmaceutical ingredients (APIs) has created a pressing need for ultra-efficient palladium removal of the resulting metal contaminants. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Hydrodeoxygenation of cellulose pyrolysis model compounds using molybdenum oxide and low pressure hydrogen ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01477E, Paper Michael W. Nolte, Alireza Saraeian, Brent H. Shanks Low pressure hydrodeoxygenation of cellulose pyrolysis model compounds over MoO3 to form hydrocarbons. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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High-yield preparation of a zwitterionically charged chitin nanofiber and its application in a doubly pH-responsive Pickering emulsion ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01592E, Paper Kai Pang, Beibei Ding, Xiaoting Liu, Hao Wu, Yongxin Duan, Jianming Zhang A rapid and high-yield (up to 85%) preparation of a zwitterionic chitin nanofiber (DE-CO-ChNF) has been demonstrated. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Tandem dehydration-transfer hydrogenation reactions of xylose to furfuryl alcohol over zeolite catalysts ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01288H, Communication Priscilla N. Paulino, Rafael F. Perez, Natalia G. Figueiredo, Marco A. Fraga Dehydration and transfer hydrogenation tandem reactions of xylose to furfuryl alcohol in water/isopropanol were performed on MFI, FAU and BEA zeolites. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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The Hy-MASS concept: hydrothermal microwave assisted selective scissoring of cellulose for in situ production of (meso)porous nanocellulose fibrils and crystals ()
Green Chem., 2017, 19,3408-3417 DOI: 10.1039/C7GC01378G, Paper Eduardo M. de Melo, James H. Clark, Avtar S. Matharu The hydrothermal microwave-assisted selective scissoring (Hy-MASS) of depectinated orange peel residues (OPR) to yield (meso)porous nanocellulose fibrils and crystals simultaneously in the absence of auxiliary reagents and mechanical treatment is reported. The content of this RSS Feed (c) The Royal Society of Chemistry
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Homogeneous and heterogeneous catalytic (dehydrogenative) oxidation of oleochemical 1,2-diols to [small alpha]-hydroxyketones ()
Green Chem., 2017, 19,3390-3399 DOI: 10.1039/C7GC00867H, Paper Nam Duc Vu, Boris Guicheret, Nicolas Duguet, Estelle Metay, Marc Lemaire The preparation of alpha-hydroxyketones derived from fatty acid derivatives has been reported under homogeneous and heterogeneous conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Iridium-catalyzed highly efficient chemoselective reduction of aldehydes in water using formic acid as the hydrogen source ()
Green Chem., 2017, 19,3296-3301 DOI: 10.1039/C7GC01289F, Paper Zhanhui Yang, Zhongpeng Zhu, Renshi Luo, Xiang Qiu, Ji-tian Liu, Jing-Kui Yang, Weiping Tang A highly efficient iridium catalyst is developed for the chemoselective reduction of aldehydes to alcohols in water, using formic acid as a reductant. The content of this RSS Feed (c) The Royal Society of Chemistry
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Integrating lignin valorization and bio-ethanol production: on the role of Ni-Al2O3 catalyst pellets during lignin-first fractionation ()
Green Chem., 2017, 19,3313-3326 DOI: 10.1039/C7GC01324H, Paper S. Van den Bosch, T. Renders, S. Kennis, S.-F. Koelewijn, G. Van den Bossche, T. Vangeel, A. Deneyer, D. Depuydt, C. M. Courtin, J. M. Thevelein, W. Schutyser, B. F. Sels Elucidation of the catalyst role during reductive catalytic fractionation, enabling the integration of lignin valorization and bio-ethanol production. The content of this RSS Feed (c) The Royal Society of Chemistry
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Porous silica-encapsulated and magnetically recoverable Rh NPs: a highly efficient, stable and green catalyst for catalytic transfer hydrogenation with "slow-release" of stoichiometric hydrazine in water ()
Green Chem., 2017, 19,3400-3407 DOI: 10.1039/C7GC00986K, Paper Junjie Zhou, Yunong Li, Hong-bin Sun, Zhike Tang, Li Qi, Lei Liu, Yongjian Ai, Shuang Li, Zixing Shao, Qionglin Liang A porous core-shell nanocatalyst hydrazine hydrate water system has been developed for the catalytic transfer hydrogenation of nitroarenes. The content of this RSS Feed (c) The Royal Society of Chemistry
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Biological phytic acid as a multifunctional curing agent for elastomers: towards skin-touchable and flame retardant electronic sensors ()
Green Chem., 2017, 19,3418-3427 DOI: 10.1039/C7GC01138E, Paper Quanquan Guo, Jie Cao, Yangyang Han, Yumeng Tang, Xinxing Zhang, Canhui Lu A skin-touchable and flame retardant electronic sensor is fabricated by integrating green chemistry with nanostructure design. The content of this RSS Feed (c) The Royal Society of Chemistry
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Producing wood-based nanomaterials by rapid fractionation of wood at 80 [degree]C using a recyclable acid hydrotrope ()
Green Chem., 2017, 19,3370-3379 DOI: 10.1039/C7GC00669A, Paper Huiyang Bian, Liheng Chen, R. Gleisner, Hongqi Dai, J. Y. Zhu Here we report the unparalleled performance of a novel acid hydrotrope, p-toluenesulfonic acid (p-TsOH), for the rapid and nearly-complete dissolution of wood lignin below the boiling temperature of water. The content of this RSS Feed (c) The Royal Society of Chemistry
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Hydrolytic hydrogenation of chitin to amino sugar alcohol ()
Green Chem., 2017, 19,3350-3356 DOI: 10.1039/C7GC01063J, Paper Hirokazu Kobayashi, Kota Techikawara, Atsushi Fukuoka The most abundant marine biomass, chitin, is converted to an amino sugar alcohol in 52% yield by a two-pot three-step reaction. The content of this RSS Feed (c) The Royal Society of Chemistry
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Suppression of oligomer formation in glucose dehydration by CO2 and tetrahydrofuran ()
Green Chem., 2017, 19,3334-3343 DOI: 10.1039/C7GC01115F, Paper Xing Fu, Jinhang Dai, Xiawei Guo, Jinqiang Tang, Liangfang Zhu, Changwei Hu The synergetic action of tetrahydrofuran (THF) and low-pressure CO2 (1.0 MPa) is favourable for effective inhibition of humin precursor (i.e., oligomer) formation in the conversion of glucose to 5-hydroxymethylfurfural (HMF). The content of this RSS Feed (c) The Royal Society of Chemistry
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The formation of p-toluic acid from coumalic acid: a reaction network analysis ()
Green Chem., 2017, 19,3263-3271 DOI: 10.1039/C7GC01290J, Paper Toni Pfennig, Robert L. Johnson, Brent H. Shanks Diels-Alder cycloaddition of biomass-derived 2-pyrone coumalic acid (CMA) with propylene provides an alternative pathway to produce toluic acid (TA), a precursor to terephthalic acid (TPA) which is a key component in the manufacture of polyethylene terephthalate (PET). The content of this RSS Feed (c) The Royal Society of Chemistry
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Straining flow spinning: production of regenerated silk fibers under a wide range of mild coagulating chemistries ()
Green Chem., 2017, 19,3380-3389 DOI: 10.1039/C7GC01254C, Paper Rodrigo Madurga, Alfonso M. Ganan-Calvo, Gustavo R. Plaza, Gustavo V. Guinea, Manuel Elices, Jose Perez-Rigueiro SFS is a versatile technique that allows spinning with mild chemistries. The content of this RSS Feed (c) The Royal Society of Chemistry
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Selective synthesis of dimethoxyethane via directly catalytic etherification of crude ethylene glycol ()
Green Chem., 2017, 19,3327-3333 DOI: 10.1039/C7GC00659D, Paper Weiqiang Yu, Fang Lu, Qianqian Huang, Rui Lu, Shuai Chen, Jie Xu A potential diesel fuel additive, dimethoxyethane, was highly selectively produced via etherification of crude ethylene glycol over SAPO-34. The content of this RSS Feed (c) The Royal Society of Chemistry
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Valorisation of woody biomass by combining enzymatic saccharification and pyrolysis ()
Green Chem., 2017, 19,3302-3312 DOI: 10.1039/C7GC00936D, Paper Dayanand C. Kalyani, Tomaz Fakin, Svein Jarle Horn, Roman Tschentscher This study shows, by a combination of enzymatic saccharification and pyrolysis, how integrated biochemical and thermochemical processes can be used to valorize woody biomass. The content of this RSS Feed (c) The Royal Society of Chemistry
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Reactive catalytic fast pyrolysis of biomass to produce high-quality bio-crude ()
Green Chem., 2017, 19,3243-3251 DOI: 10.1039/C7GC01088E, Paper Kaige Wang, David C. Dayton, Jonathan E. Peters, Ofei D. Mante Reactive catalytic fast pyrolysis with atmospheric pressure hydrogen improved yield and quality of the resulting bio-crude. The content of this RSS Feed (c) The Royal Society of Chemistry
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Amide-assisted radical strategy: metal-free direct fluorination of arenes in aqueous media ()
Green Chem., 2017, 19,3344-3349 DOI: 10.1039/C7GC00356K, Paper Deqiang Liang, Yanni Li, Shulin Gao, Renlun Li, Xiangguang Li, Baoling Wang, Hai Yang A practical aromatic C-H fluorination. The content of this RSS Feed (c) The Royal Society of Chemistry
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From lignin subunits to aggregates: insights into lignin solubilization ()
Green Chem., 2017, 19,3272-3281 DOI: 10.1039/C7GC00944E, Paper Wenwen Zhao, Ling-Ping Xiao, Guoyong Song, Run-Cang Sun, Lilin He, Seema Singh, Blake A. Simmons, Gang Cheng A fundamental understanding of lignin solubilization offers structural information that would benefit a variety of value added applications. The content of this RSS Feed (c) The Royal Society of Chemistry
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Ligand-free Suzuki-Miyaura coupling using ruthenium(0) nanoparticles and a continuously irradiating microwave system ()
Green Chem., 2017, 19,3357-3369 DOI: 10.1039/C7GC01166K, Paper Toshiki Akiyama, Takahisa Taniguchi, Nozomi Saito, Ryohei Doi, Tetsuo Honma, Yusuke Tamenori, Yuuta Ohki, Naoyuki Takahashi, Hiromichi Fujioka, Yoshihiro Sato, Mitsuhiro Arisawa A good combination between a continuously irradiating microwave system and recyclable Ru(0) nanoparticle for ligand-free Suzuki-Miyaura coupling. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of isoquinolones via Rh-catalyzed C-H activation of substituted benzamides using air as the sole oxidant in water ()
Green Chem., 2017, 19,3219-3224 DOI: 10.1039/C7GC01221G, Communication Nitinkumar Satyadev Upadhyay, Vijaykumar H. Thorat, Ryota Sato, Pratheepkumar Annamalai, Shih-Ching Chuang, Chien-Hong Cheng We report a new approach for a highly regioselective synthesis of isoquinolones from various substituted benzamides and alkynes. The content of this RSS Feed (c) The Royal Society of Chemistry
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Low temperature aqueous phase hydrogenation of the light oxygenate fraction of bio-oil over supported ruthenium catalysts ()
Green Chem., 2017, 19,3252-3262 DOI: 10.1039/C7GC00367F, Paper Hakon Bergem, Run Xu, Robert C. Brown, George W. Huber Hydroxyacetone undergoes two routes to 1,2 propanediol: (1) a direct hydrogenation route and (2) an acid catalyzed enolization route. The content of this RSS Feed (c) The Royal Society of Chemistry
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Bronsted acidic ionic liquid-catalyzed tandem reaction: an efficient approach towards regioselective synthesis of pyrano[3,2-c]coumarins under solvent-free conditions bearing lower E-factors ()
Green Chem., 2017, 19,3282-3295 DOI: 10.1039/C7GC01158J, Paper Sachinta Mahato, Sougata Santra, Rana Chatterjee, Grigory V. Zyryanov, Alakananda Hajra, Adinath Majee 1-Butane sulfonic acid-3-methylimidazolium tosylate, [BSMIM]OTs, is found to be a remarkable catalyst for the tandem cyclization of 4-hydroxycoumarin with chalcones. The content of this RSS Feed (c) The Royal Society of Chemistry
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Hierarchically porous Sn-[small beta] zeolites via an OSDA-free synthesis ()
Green Chem., 2017, 19,3214-3218 DOI: 10.1039/C7GC01040K, Communication Ji-Kang Yao, Kai-Rui Fu, Yi-Chen Wang, Tian-Duo Li, Hai-Xia Liu, Jin-Gui Wang Hierarchical Sn-[small beta] zeolites were synthesized for the first time without using an organic structure directing agent. The content of this RSS Feed (c) The Royal Society of Chemistry
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Glycerol as a potential renewable raw material for acrylic acid production ()
Green Chem., 2017, 19,3186-3213 DOI: 10.1039/C7GC00358G, Critical Review Daolai Sun, Yasuhiro Yamada, Satoshi Sato, Wataru Ueda Renewable glycerol has potential for use as an alternative raw material for the production of acrylic acid. The content of this RSS Feed (c) The Royal Society of Chemistry
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Heterogeneous catalysts for the cyclization of dicarboxylic acids to cyclic anhydrides as monomers for bioplastic production ()
Green Chem., 2017, 19,3238-3242 DOI: 10.1039/C7GC00538E, Paper Md. N. Rashed, S. M. A. H. Siddiki, Md. A. Ali, Sondomoyee K. Moromi, Abeda S. Touchy, Kenichi Kon, Takashi Toyao, Ken-ichi Shimizu Niobic acid catalyzes the condensation of biomass-derived dicarboxylic acids into cyclic anhydrides, key intermediates of carbon-neutral and biodegradable polyesters. The content of this RSS Feed (c) The Royal Society of Chemistry
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Phase-out-compliant fluorosurfactants: unique methimazolium derivatives including room temperature ionic liquids ()
Green Chem., 2017, 19,3225-3237 DOI: 10.1039/C7GC00571G, Paper M. Hummel, M. Markiewicz, S. Stolte, M. Noisternig, D. E. Braun, T. Gelbrich, U. J. Griesser, G. Partl, B. Naier, K. Wurst, B. Kruger, H. Kopacka, G. Laus, H. Huppertz, H. Schottenberger Fluoroalkylations of the medicinal drug 1-methyl-3H-imidazole-2-thione provide high yields of superior surfactants with reduced toxicity. The content of this RSS Feed (c) The Royal Society of Chemistry
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Bioprivileged molecules: creating value from biomass ()
Green Chem., 2017, 19,3177-3185 DOI: 10.1039/C7GC00296C, Perspective Brent H. Shanks, Peter L. Keeling Bioprivileged molecules generated from biomass can be converted to both novel molecules and drop-in replacements. The content of this RSS Feed (c) The Royal Society of Chemistry
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Role of oxygenates and effect of operating conditions in the deactivation of a Ni supported catalyst during the steam reforming of bio-oil ()
Green Chem., 2017, Accepted Manuscript DOI: 10.1039/C7GC01432E, Paper Aitor Ochoa, Borja Aramburu, Beatriz Valle, D Resasco, Javier Bilbao, Ana G. Gayubo, Pedro Castano This work investigates the correlation of the reaction conditions (temperature and steam-to-carbon ratio (S/C)) and the reaction medium composition with the deactivation behavior of a Ni/La2O3-[small alpha]Al2O3 catalyst used in the... The content of this RSS Feed (c) The Royal Society of Chemistry
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High pressure water-initiated ring opening polymerization for the synthesis of well-defined [small alpha]-hydroxy-[small omega]-(carboxylic acid) polycaprolactones ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01748K, Paper A. Dzienia, P. Maksym, M. Tarnacka, I. Grudzka-Flak, S. Golba, A. Zieba, K. Kaminski, M. Paluch A novel method to produce polyesters of a well-defined chemical structure, and narrow molecular weight distributions by using a combination of high pressure, temperature and water was proposed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Chemical composition and stability of renewable hydrocarbon products generated from a hydropyrolysis vapor upgrading process ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01075C, Paper Liang Zhang, Kening Gong, Jinfeng Lai, Paul Alvey The unique feature of a two-step ex situ hydropyrolysis vapor upgrading process for producing infrastructure-compatible cellulosic biofuels has been demonstrated for the first time using a double fluidized-bed reactor system. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Chemically recyclable polymers: a circular economy approach to sustainability ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01496A, Critical Review Miao Hong, Eugene Y.-X. Chen Developing recyclable polymers provides a solution to materials' end-of-life issues and also an approach to establish a circular materials economy. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Production of levoglucosenone and 5-hydroxymethylfurfural from cellulose in polar aprotic solvent-water mixtures ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01688C, Paper Jiayue He, Mingjie Liu, Kefeng Huang, Theodore W. Walker, Christos T. Maravelias, James A. Dumesic, George W. Huber We demonstrate a process to produce levoglucosenone (LGO) and 5-hydroxymethylfurfural (HMF) from cellulose in up to 65% carbon yield using H2SO4 as catalyst and a solvent consisting of tetrahydrofuran (THF) and H2O. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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2,2,5,5-Tetramethyltetrahydrofuran (TMTHF): a non-polar, non-peroxide forming ether replacement for hazardous hydrocarbon solvents ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01392B, Paper Fergal Byrne, Bart Forier, Greet Bossaert, Charly Hoebers, Thomas J. Farmer, James H. Clark, Andrew J. Hunt An inherently non-peroxide forming ether solvent, 2,2,5,5-tetramethyltetrahydrofuran (2,2,5,5-tetramethyloxolane), has been synthesized from readily available and potentially renewable feedstocks, and its solvation properties have been tested. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Large-scale simultaneous synthesis of highly photoluminescent green amorphous carbon nanodots and yellow crystalline graphene quantum dots at room temperature ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01236E, Paper Meng Li Liu, Lin Yang, Rong Sheng Li, Bin Bin Chen, Hui Liu, Cheng Zhi Huang The room temperature synthesis of highly PL CNDs and GQDs by simply mixing TETA and p-benzoquinone and the origin of their photoluminescence. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Solvent-free implementation of two dissimilar reactions using recyclable CuO nanoparticles under ball-milling conditions: synthesis of new oxindole-triazole pharmacophores ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01284E, Paper M. Vadivelu, S. Sugirdha, P. Dheenkumar, Y. Arun, K. Karthikeyan, C. Praveen A mechanochemical approach for the solvent-free synthesis of oxindole-triazole pharmacophores using recyclable CuO nanoparticles has been developed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Continuous CO2 esterification to diethyl carbonate (DEC) at atmospheric pressure: application of porous membranes for in situ H2O removal ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC00916J, Paper Junhui Wang, Zhengping Hao, Sebastian Wohlrab Carbon dioxide esterification at atmospheric pressure in the presence of dehydrating membranes produces more diethyl carbonate compared to batch processes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Selective phenol hydrogenation to cyclohexanone over alkali-metal-promoted Pd/TiO2 in aqueous media ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01318C, Paper Hu Zhou, Bingbing Han, Tianzhu Liu, Xing Zhong, Guilin Zhuang, Jianguo Wang High conversion of phenol and high selectivity of cyclohexanone could be achieved by using alkali-metal-promoted Pd/TiO2 catalysts under mild conditions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Photoinduced rearrangement of vinyl tosylates to [small beta]-ketosulfones ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01467H, Communication Lili Xie, Xiaomeng Zhen, Shuping Huang, Xiaolong Su, Mai Lin, Yi Li We developed a photoinduced radical fragmentation and rearrangement of vinyl tosylates that enables efficient formation of [small beta]-ketosulfones. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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An environmentally benign double Michael addition reaction of heterocyclic ketene aminals with quinone monoketals for diastereoselective synthesis of highly functionalized morphan derivatives in water ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01435J, Paper Yu-Lu Ma, Kai-Min Wang, Rong Huang, Jun Lin, Sheng-Jiao Yan This effort involved an efficient and concise one-pot procedure for the synthesis of morphans based on quinone monoketals 1 reacting with HKAs 2. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Visible-light-induced selective synthesis of sulfoxides from alkenes and thiols using air as the oxidant ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC01416C, Communication Huanhuan Cui, Wei Wei, Daoshan Yang, Yulong Zhang, Huijuan Zhao, Leilei Wang, Hua Wang A selective synthesis of sulfoxides from alkenes and thiols was established by visible-light photoredox catalysis in air at room temperature. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly efficient conversion of terpenoid biomass to jet-fuel range cycloalkanes in a biphasic tandem catalytic process ()
Green Chem., 2017, Advance Article DOI: 10.1039/C7GC00710H, Paper Xiaokun Yang, Teng Li, Kan Tang, Xinpei Zhou, Mi Lu, Whalmany L. Ounkham, Stephen M. Spain, Brian J. Frost, Hongfei Lin A novel efficient biphasic tandem catalytic process (biTCP) with a high carbon efficiency was developed for synthesizing cycloalkanes that can used to make dense jet fuels from renewable terpenoid biomass (such as 1,8-cineole). To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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Selective hydrogenolysis and hydrogenation using metal catalysts directly modified with metal oxide species ()
Green Chem., 2017, 19,2876-2924 DOI: 10.1039/C7GC00620A, Critical Review Keiichi Tomishige, Yoshinao Nakagawa, Masazumi Tamura Excellent reduction catalysis arises from direct bonds between noble metals and reducible metal oxide. The content of this RSS Feed (c) The Royal Society of Chemistry
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Retraction: Bigger data open innovation: potential applications of value-added products from milk and sustainable valorization of by-products from the dairy industry ()
Green Chem., 2017, 19,3164-3164 DOI: 10.1039/C7GC90062G, Retraction Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. S. Ortega-Requena, S. Rebouillat The content of this RSS Feed (c) The Royal Society of Chemistry
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Iridium(III) homo- and heterogeneous catalysed hydrogen borrowing C-N bond formation ()
Green Chem., 2017, 19,3142-3151 DOI: 10.1039/C7GC01007A, Paper Chin M. Wong, Roy T. McBurney, Samantha C. Binding, Matthew B. Peterson, Vinicius R. Goncales, J. Justin Gooding, Barbara A. Messerle Ir(III) complexes were found to be highly active catalysts for the hydrogen borrowing coupling of amines and alcohols. The content of this RSS Feed (c) The Royal Society of Chemistry
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A solid acetylene reagent with enhanced reactivity: fluoride-mediated functionalization of alcohols and phenols ()
Green Chem., 2017, 19,3032-3041 DOI: 10.1039/C7GC00724H, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Georg Werner, Konstantin S. Rodygin, Anton A. Kostin, Evgeniy G. Gordeev, Alexey S. Kashin, Valentine P. Ananikov The direct vinylation of an OH group in alcohols and phenols was carried out utilizing an easy-to-use CaC2/KF solid acetylene reagent. The content of this RSS Feed (c) The Royal Society of Chemistry
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Highly effective C-C bond cleavage of lignin model compounds ()
Green Chem., 2017, 19,3135-3141 DOI: 10.1039/C7GC00844A, Paper Yinling Wang, Qianyi Wang, Jianghua He, Yuetao Zhang Baeyer-Villiger oxidation is employed to effectively cleave the C-C bonds in lignin model compounds, affording multifunctional esters and phenols in excellent yields. The content of this RSS Feed (c) The Royal Society of Chemistry
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An environmentally friendly protocol for oxidative halocyclization of tryptamine and tryptophol derivatives ()
Green Chem., 2017, 19,2952-2956 DOI: 10.1039/C7GC01341H, Communication Jun Xu, Rongbiao Tong An environmentally friendly protocol for halocyclization of tryptamine/tryptophol derivatives was developed and demonstrated with 28 examples and synthesis of protubonines. The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal-free synthesis of ketones by visible-light induced aerobic oxidative radical addition of aryl hydrazines to alkenes ()
Green Chem., 2017, 19,2941-2944 DOI: 10.1039/C7GC01083D, Communication Ya Ding, Wenkai Zhang, Hao Li, Yunge Meng, Te Zhang, Qiu-Yun Chen, Chunyin Zhu A green and cost-effective method has been developed for the conversion of alkenes to ketones under metal-free conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
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cis,cis-Muconic acid isomerization and catalytic conversion to biobased cyclic-C6-1,4-diacid monomers ()
Green Chem., 2017, 19,3042-3050 DOI: 10.1039/C7GC00658F, Paper Jack M. Carraher, Toni Pfennig, Radhika G. Rao, Brent H. Shanks, Jean-Philippe Tessonnier Renewable monomers from biologically-produced intermediates: unlocking the isomerization of cis,trans- to trans,trans-muconic acid for the production of renewable 1,4-cyclohexanedicarboxylic acid and terephthalic acid. The content of this RSS Feed (c) The Royal Society of Chemistry
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Increasing global access to the high-volume HIV drug nevirapine through process intensification ()
Green Chem., 2017, 19,2986-2991 DOI: 10.1039/C7GC00937B, Paper Jenson Verghese, Caleb J. Kong, Daniel Rivalti, Eric C. Yu, Rudy Krack, Jesus Alcazar, Julie B. Manley, D. Tyler McQuade, Saeed Ahmad, Katherine Belecki, B. Frank Gupton Fundamental elements of process intensification were applied to generate efficient batch and continuous syntheses of the high-volume HIV drug nevirapine. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of 2-substituted quinazolines by CsOH-mediated direct aerobic oxidative cyclocondensation of 2-aminoarylmethanols with nitriles in air ()
Green Chem., 2017, 19,2945-2951 DOI: 10.1039/C7GC00977A, Communication Song Yao, Kaijing Zhou, Jiabing Wang, Hongen Cao, Lei Yu, Jianzhang Wu, Peihong Qiu, Qing Xu An atom-efficient synthesis of 2-substituted quinazolines is developed by a CsOH-mediated aerobic oxidative reaction of 2-aminoarylmethanols and nitriles in air. The content of this RSS Feed (c) The Royal Society of Chemistry
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Valorisation of agricultural waste with an adsorption/nanofiltration hybrid process: from materials to sustainable process design ()
Green Chem., 2017, 19,3116-3125 DOI: 10.1039/C7GC00912G, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Christos Didaskalou, Sibel Buyuktiryaki, Rustem Kecili, Claudio P. Fonte, Gyorgy Szekely A continuous oleuropein isolation process using imprinted materials coupled with nanofiltration-based solvent recovery utilising olive leaf waste. The content of this RSS Feed (c) The Royal Society of Chemistry
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Synthesis of potential bisphenol A substitutes by isomerising metathesis of renewable raw materials ()
Green Chem., 2017, 19,3051-3060 DOI: 10.1039/C7GC00553A, Paper A. S. Trita, L. C. Over, J. Pollini, S. Baader, S. Riegsinger, M. A. R. Meier, L. J. Goo[German sz ligature}en Plant-derived alkenyl arenes were converted into polymer building blocks with low estrogenic activity via isomerising metathesis. The content of this RSS Feed (c) The Royal Society of Chemistry
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One-pot integrated biofuel production using low-cost biocompatible protic ionic liquids ()
Green Chem., 2017, 19,3152-3163 DOI: 10.1039/C7GC01179B, Paper Jian Sun, N. V. S. N. Murthy Konda, Ramakrishnan Parthasarathi, Tanmoy Dutta, Marat Valiev, Feng Xu, Blake A. Simmons, Seema Singh We present an inexpensive and biocompatible protic ionic liquid that enables one-pot integrated cellulosic ethanol production without any pH adjustments and without water-wash or solid-liquid separations. The content of this RSS Feed (c) The Royal Society of Chemistry
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Aqueous 1,3-dipolar cycloadditions promoted by copper nanoparticles in polydiacetylene micelles ()
Green Chem., 2017, 19,3112-3115 DOI: 10.1039/C7GC01017F, Paper Damien Clarisse, Praveen Prakash, Valerie Geertsen, Frederic Miserque, Edmond Gravel, Eric Doris A colloidal catalyst was assembled from copper nanoparticles to efficiently promote alkyne-azide cycloadditions in water. The content of this RSS Feed (c) The Royal Society of Chemistry
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One-pot sustainable synthesis of tertiary alcohols by combining ruthenium-catalysed isomerisation of allylic alcohols and chemoselective addition of polar organometallic reagents in deep eutectic solvents ()
Green Chem., 2017, 19,3069-3077 DOI: 10.1039/C7GC00458C, Paper Luciana Cicco, Maria J. Rodriguez-Alvarez, Filippo M. Perna, Joaquin Garcia-Alvarez, Vito Capriati Transition-metal complexes and polarised organometallic reagents play together in Deep Eutectic Solvents. The content of this RSS Feed (c) The Royal Society of Chemistry
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Aqueous phase reforming of glycerol using doped graphenes as metal-free catalysts ()
Green Chem., 2017, 19,3061-3068 DOI: 10.1039/C7GC01058C, Paper Ivan Esteve-Adell, Bertrand Crapart, Ana Primo, Philippe Serp, Hermenegildo Garcia Boron-doped graphene obtained by pyrolysis at 900 [degree]C of the boric acid ester of alginate was found to be the most active graphene among a series of doped and co-doped graphenes to promote the aqueous phase reforming of glycerol at 250 [degree]C. The content of this RSS Feed (c) The Royal Society of Chemistry
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Solar-driven alumina calcination for CO2 mitigation and improved product quality ()
Green Chem., 2017, 19,2992-3005 DOI: 10.1039/C7GC00585G, Paper Dominic Davis, Fabian Muller, Woei L. Saw, Aldo Steinfeld, Graham J. Nathan Demonstrating technical feasibility and potential for process benefits from alumina calcination with concentrated solar thermal energy. The content of this RSS Feed (c) The Royal Society of Chemistry
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A general environmentally friendly access to long chain fatty acid ionic liquids (LCFA-ILs) ()
Green Chem., 2017, 19,3103-3111 DOI: 10.1039/C7GC00830A, Paper A. Mezzetta, L. Guazzelli, M. Seggiani, C. S. Pomelli, M. Puccini, C. Chiappe A general, environmentally friendly, single step synthesis of ammonium, phosphonium, and imidazolium long chain fatty acid ionic liquids (LCFA-ILs) is presented. The content of this RSS Feed (c) The Royal Society of Chemistry
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A scalable carboxylation route to furan-2,5-dicarboxylic acid ()
Green Chem., 2017, 19,2966-2972 DOI: 10.1039/C7GC01059A, Paper Graham R. Dick, Amy D. Frankhouser, Aanindeeta Banerjee, Matthew W. Kanan 2-Furoic acid is converted to furan-2,5-dicarboxylic acid in high yield on a mole scale using carbonate-promoted C-H carboxylation. The content of this RSS Feed (c) The Royal Society of Chemistry
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Multi-electron redox phenazine for ready-to-charge organic batteries ()
Green Chem., 2017, 19,2980-2985 DOI: 10.1039/C7GC00849J, Paper Minah Lee, Jihyun Hong, Byungju Lee, Kyojin Ku, Sechan Lee, Chan Beum Park, Kisuk Kang A new class of multi-electron redox phenazine was proposed to build ready-to-charge sustainable organic batteries. The content of this RSS Feed (c) The Royal Society of Chemistry
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Mild-temperature hydrodeoxygenation of vanillin over porous nitrogen-doped carbon black supported nickel nanoparticles ()
Green Chem., 2017, 19,3126-3134 DOI: 10.1039/C7GC00531H, Paper Renfeng Nie, Huanhuan Yang, Haifu Zhang, Xiaolong Yu, Xinhuan Lu, Dan Zhou, Qinghua Xia N-doped carbon black (NCB) supported Ni NPs exhibited higher activity than most Ni-based catalysts for selective HDO of vanillin at mild conditions, ascribing to higher reducibility, lower oxidation state of Ni NPs and enhanced spillover hydrogen of Ni to NCB. The content of this RSS Feed (c) The Royal Society of Chemistry
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A PEGylated deep eutectic solvent for controllable solvothermal synthesis of porous NiCo2S4 for efficient oxygen evolution reaction ()
Green Chem., 2017, 19,3023-3031 DOI: 10.1039/C7GC01012E, Paper Jingyun Jiang, Chuanyu Yan, Xinhui Zhao, Hongxia Luo, Zhimin Xue, Tiancheng Mu A PEGylated deep eutectic solvent was developed and used for one step solvothermal synthesis of NiCo2S4 for efficient oxygen evolution reaction. The content of this RSS Feed (c) The Royal Society of Chemistry
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Mechanochemical Suzuki polycondensation - from linear to hyperbranched polyphenylenes ()
Green Chem., 2017, 19,2973-2979 DOI: 10.1039/C7GC00693D, Paper S. Gratz, B. Wolfrum, L. Borchardt Mechanochemical Suzuki polycondensation offers a sustainable alternative to classical solvent based approaches, affording high yields and short reaction times. The content of this RSS Feed (c) The Royal Society of Chemistry
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MoO3-TiO2 synergy in oxidative dehydrogenation of lactic acid to pyruvic acid ()
Green Chem., 2017, 19,3014-3022 DOI: 10.1039/C7GC00807D, Paper Open Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Kaituo Liu, Xiaoming Huang, Evgeny A. Pidko, Emiel J. M. Hensen Oxidative dehydrogenation of lactic acid to pyruvic acid can be efficiently carried out using mixed-oxide MoOx/TiO2 heterogeneous catalysts. The content of this RSS Feed (c) The Royal Society of Chemistry
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Revisiting the deoxydehydration of glycerol towards allyl alcohol under continuous-flow conditions ()
Green Chem., 2017, 19,3006-3013 DOI: 10.1039/C7GC00657H, Paper Nelly Ntumba Tshibalonza, Jean-Christophe M. Monbaliu Highly selective flash deoxydehydration of glycerol towards allyl alcohol under continuous-flow conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
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Atom- and step-economical nucleophilic arylation of azaaromatics via electrochemical oxidative cross C-C coupling reactions ()
Green Chem., 2017, 19,2931-2935 DOI: 10.1039/C7GC00789B, Communication O. N. Chupakhin, A. V. Shchepochkin, V. N. Charushin A simple and efficient electrochemical method for the synthesis of asymmetrical bi(het)aryls through direct functionalization of the C(sp2)-H bond in azaaromatics with fragments of (hetero)aromatic nucleophiles has been developed. The content of this RSS Feed (c) The Royal Society of Chemistry
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An economically viable ionic liquid for the fractionation of lignocellulosic biomass ()
Green Chem., 2017, 19,3078-3102 DOI: 10.1039/C7GC00705A, Paper Agnieszka Brandt-Talbot, Florence J. V. Gschwend, Paul S. Fennell, Tijs M. Lammens, Bennett Tan, James Weale, Jason P. Hallett Cost-effective fractionation (pretreatment) of lignocellulosic biomass is necessary to enable its large-scale use as a source of liquid fuels, bio-based materials and bio-derived chemicals. The content of this RSS Feed (c) The Royal Society of Chemistry
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