Journal of the American Society

Amorphous Metal Polysulfides: Electrode Materials with Unique Insertion/Extraction Reactions (Mon, 26 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03909
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Chirality Control of Electron Transfer in Quantum Dot Assemblies (Mon, 26 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04639
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Crystalline Nanochannels with Pendant Azobenzene Groups: Steric or Polar Effects on Gas Adsorption and Diffusion? (Mon, 26 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b02979
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Practical, Broadly Applicable, α-Selective, Z-Selective, Diastereoselective, and Enantioselective Addition of Allylboron Compounds to Mono-, Di-, Tri-, and Polyfluoroalkyl Ketones (Sat, 24 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b05011
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A Mononuclear Nonheme Iron(V)-Imido Complex (Fri, 23 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04695
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Spectroscopic Characterization, Computational Investigation, and Comparisons of ECX– (E = As, P, and N; X = S and O) Anions (Fri, 23 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b02984
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An OFF–ON Two-Photon Fluorescent Probe for Tracking Cell Senescence in Vivo (Fri, 23 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04985
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Terpene Cyclizations inside a Supramolecular Catalyst: Leaving-Group-Controlled Product Selectivity and Mechanistic Studies (Fri, 23 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04480
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Salicylideneanilines-Based Covalent Organic Frameworks as Chemoselective Molecular Sieves (Fri, 23 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b02696
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Anion- and Solvent-Induced Rotary Dynamics and Sensing in a Perylene Diimide [3]Catenane (Fri, 23 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04295
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Nickel-Catalyzed C–H Silylation of Arenes with Vinylsilanes: Rapid and Reversible β-Si Elimination (Fri, 23 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b05574
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Fluoromodules Consisting of a Promiscuous RNA Aptamer and Red or Blue Fluorogenic Cyanine Dyes: Selection, Characterization, and Bioimaging (Fri, 23 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04211
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Porphyrin Arch-Tapes: Synthesis, Contorted Structures, and Full Conjugation (Fri, 23 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b05332
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Synthesis and Exciton Dynamics of Donor-Orthogonal Acceptor Conjugated Polymers: Reducing the Singlet–Triplet Energy Gap (Fri, 23 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03327
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Cucurbit[7]uril Enables Multi-Stimuli-Responsive Release from the Self-Assembled Hydrophobic Phase of a Metal Organic Polyhedron (Fri, 23 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b05154
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Catalytic Dehydrogenative C–C Coupling by a Pincer-Ligated Iridium Complex (Fri, 23 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03433
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Three-Dimensional Localization of an Individual Fluorescent Molecule with Angstrom Precision (Fri, 23 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03899
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Emerging β-Sheet Rich Conformations in Supercompact Huntingtin Exon-1 Mutant Structures (Fri, 23 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b00838
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Very Large-Sized Transition Metal Dichalcogenides Monolayers from Fast Exfoliation by Manual Shaking (Fri, 23 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04332
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Powering a CO2 Reduction Catalyst with Visible Light through Multiple Sub-picosecond Electron Transfers from a Quantum Dot (Fri, 23 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03134
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Nonclassical Single-State Reactivity of an Oxo-Iron(IV) Complex Confined to Triplet Pathways (Thu, 22 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03255
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Common and Potentially Prebiotic Origin for Precursors of Nucleotide Synthesis and Activation (Thu, 22 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b01562
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Understanding the Oxygen Evolution Reaction Mechanism on CoOx using Operando Ambient-Pressure X-ray Photoelectron Spectroscopy (Thu, 22 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03211
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The In Vivo Potential-Regulated Protective Protein of Nitrogenase in Azotobacter vinelandii Supports Aerobic Bioelectrochemical Dinitrogen Reduction In Vitro (Thu, 22 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04893
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Crystal Structural Effect of AuCu Alloy Nanoparticles on Catalytic CO Oxidation (Thu, 22 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b01784
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Intracellular Transfer Hydrogenation Mediated by Unprotected Organoiridium Catalysts (Thu, 22 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03872
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Nickel Sequestration by the Host-Defense Protein Human Calprotectin (Thu, 22 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b01212
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Controlled Dopant Migration in CdS/ZnS Core/Shell Quantum Dots (Thu, 22 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b02320
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Copper Binding Sites in the Manganese-Oxidizing Mnx Protein Complex Investigated by Electron Paramagnetic Resonance Spectroscopy (Thu, 22 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b02277
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Programmable Assembly of Peptide Amphiphile via Noncovalent-to-Covalent Bond Conversion (Thu, 22 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03878
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General Synthetic Route toward Highly Dispersed Metal Clusters Enabled by Poly(ionic liquid)s (Wed, 21 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03357
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Water Dynamics from the Surface to the Interior of a Supramolecular Nanostructure (Wed, 21 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b02969
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Pushing the Limits of Oxygen Balance in 1,3,4-Oxadiazoles (Wed, 21 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b05158
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Ultrathin and Ion-Selective Janus Membranes for High-Performance Osmotic Energy Conversion (Wed, 21 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b02794
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Manganese-Catalyzed Aminomethylation of Aromatic Compounds with Methanol as a Sustainable C1 Building Block (Wed, 21 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b05253
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High-Throughput Selective Capture of Single Circulating Tumor Cells by Dielectrophoresis at a Wireless Electrode Array (Wed, 21 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03288
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Oxidative Cleavage of the CN Bond on Al(I) (Wed, 21 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04841
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Local Structures and Heterogeneity of Silica-Supported M(III) Sites Evidenced by EPR, IR, NMR, and Luminescence Spectroscopies (Wed, 21 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b02179
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Molecular Recognition in Asymmetric Counteranion Catalysis: Understanding Chiral Phosphate-Mediated Desymmetrization (Wed, 21 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b02468
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Domino Direct Arylation and Cross-Aldol for Rapid Construction of Extended Polycyclic π-Scaffolds (Tue, 20 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03412
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4S-Hydroxylation of Insulin at ProB28 Accelerates Hexamer Dissociation and Delays Fibrillation (Tue, 20 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b00794
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Excitonic Circular Dichroism of Chiral Quantum Rods (Tue, 20 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04224
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Simple and Efficient Generation of Aryl Radicals from Aryl Triflates: Synthesis of Aryl Boronates and Aryl Iodides at Room Temperature (Tue, 20 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03538
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Transient Formation and Reactivity of a High-Valent Nickel(IV) Oxido Complex (Tue, 20 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04158
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Carbohydrate Bis-acetal-Based Substrates as Tunable Fluorescence-Quenched Probes for Monitoring exo-Glycosidase Activity (Tue, 20 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b01948
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Development of a Clinically Viable Heroin Vaccine (Tue, 20 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03334
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Photochemical Hexadehydro-Diels–Alder Reaction (Tue, 20 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03832
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Chirality Dependent Potency Enhancement and Structural Impact of Glycol Nucleic Acid Modification on siRNA (Mon, 19 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b02694
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Enantioselective Cycloaddition of Styrenes with Aldimines Catalyzed by a Chiral Magnesium Potassium Binaphthyldisulfonate Cluster as a Chiral Brønsted Acid Catalyst (Mon, 19 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04795
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Sensitive Phonon-Based Probe for Structure Identification of 1T′ MoTe2 (Mon, 19 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03445
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Stable Chloro- and Bromoxenate Cage Anions; [X3(XeO3)3]3– and [X4(XeO3)4]4– (X = Cl or Br) (Mon, 19 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04067
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Distribution of Catalytic Species as an Indicator To Overcome Reproducibility Problems (Mon, 19 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b05045
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Enantioselective Copper-Catalyzed Oxy-Alkynylation of Diazo Compounds (Mon, 19 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04756
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[2]Rotaxane Formation by Transition State Stabilization (Mon, 19 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b05640
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Electrochemistry and Electrochemiluminescence of Organometal Halide Perovskite Nanocrystals in Aqueous Medium (Mon, 19 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b05073
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Origin of the Intrinsic Fluorescence of the Green Fluorescent Protein (Mon, 19 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04987
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Role of Spatial Constraints of Brønsted Acid Sites for Adsorption and Surface Reactions of Linear Pentenes (Mon, 19 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03690
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Water Vapor Sorption in Hybrid Pillared Square Grid Materials (Mon, 19 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b01682
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Sub-1 nm Nanowire Based Superlattice Showing High Strength and Low Modulus (Mon, 19 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03175
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Ternary Gold Hydrides: Routes to Stable and Potentially Superconducting Compounds (Mon, 19 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04456
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The Origins of Dramatic Differences in Five-Membered vs Six-Membered Chelation of Pd(II) on Efficiency of C(sp3)–H Bond Activation (Mon, 19 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b01801
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Active Targeting of the Nucleus Using Nonpeptidic Boronate Tags (Mon, 19 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b02801
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Regiodivergent Glycosylations of 6-Deoxy-erythronolide B and Oleandomycin-Derived Macrolactones Enabled by Chiral Acid Catalysis (Mon, 19 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03198
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Designing Air-Stable O3-Type Cathode Materials by Combined Structure Modulation for Na-Ion Batteries (Fri, 16 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b05176
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Kinetically Controlled Coassembly of Multichromophoric Peptide Hydrogelators and the Impacts on Energy Transport (Fri, 16 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04006
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Creation of a Synthetic Ligand for Mitochondrial DNA Sequence Recognition and Promoter-Specific Transcription Suppression (Fri, 16 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b05230
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Edge Epitaxy of Two-Dimensional MoSe2 and MoS2 Nanosheets on One-Dimensional Nanowires (Fri, 16 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03752
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Synthesis of Luminescent Platinum(II) 2,6-Bis(N-dodecylbenzimidazol-2′-yl)pyridine Foldamers and Their Supramolecular Assembly and Metallogel Formation (Fri, 16 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03635
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Uncatalyzed Carboboration of Seven-Membered-Ring trans-Alkenes: Formation of Air-Stable Trialkylboranes (Fri, 16 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03986
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Chiral Covalent Organic Frameworks with High Chemical Stability for Heterogeneous Asymmetric Catalysis (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04008
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Ultrathin Two-Dimensional Covalent Organic Framework Nanosheets: Preparation and Application in Highly Sensitive and Selective DNA Detection (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04096
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Reversible Generation of Labile Secondary Carbocations from Alcohols in the Nanospace of H-Mordenite and Their Long-Lasting Preservation at Ambient Temperature (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03336
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Evidence for Anisotropic Electronic Coupling of Charge Transfer States in Weakly Interacting Organic Semiconductor Mixtures (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b01622
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Insight into the Complexity of the i-Motif and G-Quadruplex DNA Structures Formed in the KRAS Promoter and Subsequent Drug-Induced Gene Repression (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b02046
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Pressure-Enabled Synthesis of Hetero-Dimers and Hetero-Rods through Intraparticle Coalescence and Interparticle Fusion of Quantum-Dot-Au Satellite Nanocrystals (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04018
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Regio- and Stereospecific Copper-Catalyzed Substitution Reaction of Propargylic Ammonium Salts with Aryl Grignard Reagents (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b05273
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CuH-Catalyzed Regioselective Intramolecular Hydroamination for the Synthesis of Alkyl-Substituted Chiral Aziridines (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04816
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Switchable Chiral Selection of Aspartic Acids by Dynamic States of Brushite (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03116
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Molecular Recognition and Chirality Sensing of Epoxides in Water Using Endo-Functionalized Molecular Tubes (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b05021
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Electrocatalytic Water Oxidation by a Homogeneous Copper Catalyst Disfavors Single-Site Mechanisms (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03278
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Unprecedented Ferroelectric–Antiferroelectric–Paraelectric Phase Transitions Discovered in an Organic–Inorganic Hybrid Perovskite (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04693
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3D Porphyrin-Based Covalent Organic Frameworks (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04141
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Formation of Germa-ketenimine on the Ge(100) Surface by Adsorption of tert-Butyl Isocyanide (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04755
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Catalytic Enantioselective [3 + 2] Cycloaddition of α-Keto Ester Enolates and Nitrile Oxides (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03782
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Control of Heme Coordination and Catalytic Activity by Conformational Changes in Peptide–Amphiphile Assemblies (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b01588
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Alkylated Selenophene-Based Ladder-Type Monomers via a Facile Route for High-Performance Thin-Film Transistor Applications (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03099
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Supramolecular Construction of an Aldehyde–Cyclobutane via the Solid State: Combining Reversible Imine Formation and Metal–Organic Self-Assembly (Thu, 15 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04420
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Type II Anion Relay Chemistry: Conformational Constraints To Achieve Effective [1,5]-Vinyl Brook Rearrangements (Wed, 14 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04149
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Near-Infrared Optical Imaging of Necrotic Cells by Photostable Lanthanide-Based Metallacrowns (Wed, 14 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b01587
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Covalency in Americium(III) Hexachloride (Wed, 14 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03755
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Hypervalent Iodine/Triflate Hybrid Benzdiyne Equivalents: Access to Controlled Synthesis of Polycyclic Aromatic Compounds (Wed, 14 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04483
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Correction to “Effects of Additives on the Morphology of Solution Phase Aggregates formed by Active Layer Components of High-Efficiency Organic Solar Cells” (Wed, 14 Jun 2017)
Journal of the American Chemical Society DOI: 10.1021/jacs.7b00277
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Design of Modular Protein Tags for Orthogonal Covalent Bond Formation at Specific DNA Sequences (Wed, 14 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b01640
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Engineering High-Potential Photo-oxidants with Panchromatic Absorption (Wed, 14 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04400
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Dioxygen: What Makes This Triplet Diradical Kinetically Persistent? (Wed, 14 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b04232
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Ligand and Metal Based Multielectron Redox Chemistry of Cobalt Supported by Tetradentate Schiff Bases (Wed, 14 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03604
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Oxime-Based and Catalyst-Free Dynamic Covalent Polyurethanes (Tue, 13 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b03967
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Correction to “Molecular Cobalt Complexes with Pendant Amines for Selective Electrocatalytic Reduction of Carbon Dioxide to Formic Acid” (Mon, 12 Jun 2017)
Journal of the American Chemical Society DOI: 10.1021/jacs.7b05505
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Thiazolothiazole Fluorophores Exhibiting Strong Fluorescence and Viologen-Like Reversible Electrochromism (Fri, 02 Jun 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b01005
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Observation of Photovoltaic Action from Photoacid-Modified Nafion Due to Light-Driven Ion Transport (Mon, 15 May 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b00974
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Probing the Effects of Gating on the Ion Occupancy of the K+ Channel Selectivity Filter Using Two-Dimensional Infrared Spectroscopy (Fri, 12 May 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.7b01594
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Healing High-Loading Sulfur Electrodes with Unprecedented Long Cycling Life: Spatial Heterogeneity Control (Tue, 28 Mar 2017)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.6b12358
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Anisotropic Self-Assembly of Organic–Inorganic Hybrid Microtoroids (Tue, 01 Nov 2016)
TOC Graphic Journal of the American Chemical Society DOI: 10.1021/jacs.6b10080
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